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Come fly with me! Max Planck Institute researchers turn origami paper crane into a conductive structure

Wednesday, May 15th, 2013

Yet again the lowly inkjet printer features in a very high tech project. This time, the printer has been used to print a catalyst on paper that is then turned into conductive graphite. From the May 15, 2013 news item on ScienceDaily,

… Researchers at the Max Planck Institute of Colloids and Interfaces in Potsdam-Golm have created targeted conductive structures on paper using a method that is quite simple: with a conventional inkjet printer, they printed a catalyst on a sheet of paper and then heated it. The printed areas on the paper were thereby converted into conductive graphite. Being an inexpensive, light and flexible raw material, paper is therefore highly suitable for electronic components in everyday objects.

Cost-efficient and flexible microchips are opening up applications in the electronics sector for which silicon chips are too expensive or difficult to make, and for which RFID chips, now available on a widespread basis, simply do not suffice: clothes, for instance, that monitor bodily functions, flexible screens, or labels that give more information about a product then can be printed on the packaging.

The Max Planck Institute of Colloids and Interfaces May 8, 2013 news release, which originated the news item, offers more detail about the advantages that conductive ‘paper’ offers,

Although many scientists around the world are successfully developing flexible chips, they have been forced to almost always rely on plastics as the carrier and, in some cases, use polymers and other organic molecules as conductive components. These materials may meet many requirements; however, they are all, without exception, sensitive to heat. “Their processing cannot be integrated into the usual production of electronics, because temperatures in production can reach over 400 degrees Celsius,” says Cristina Giordano, who leads a working group at the Max Planck Institute of Colloids and Interfaces and as now come up with an alternative solution.

…

Carbon electronics, which Giordano and her colleagues create from paper, can withstand temperatures of around 800 degrees Celsius during production in an oxygen-free environment, and would not have a negative impact on established processes. And that is not the only trump card of paper-based electronics. The light and inexpensive material can be processed very easily, even into three-dimensional conductive structures.

Here’s how the scientists achieved their conductive ‘paper’,

The Potsdam-based researchers convert the cellulose of the paper into graphite with iron nitrate serving as the catalyst. “Using a commercial inkjet printer, we print  a solution of the catalyst in a fine pattern on a sheet of paper,” says Stefan Glatzel, who is responsible for bringing electronics to paper in his doctoral thesis. If the researchers then heat the sheets that were printed with a catalyst to 800 degrees Celsius in a nitrogen atmosphere, the cellulose will continue to release water until all that remains is pure carbon. Whereas an electrically conducting mixture of regularly structured carbon sheets of graphite and iron carbide forms in the printed areas, the non-printed areas are left behind as carbon without a regular structure, and they are less conductive.

That actual, precisely formed conducting paths are created in this way was demonstrated by the researchers in a simple experiment: First, they printed the catalyst on a sheet of paper in the pattern of Minerva, the subtle symbol of the Max Planck Society. The printed pattern was then converted into graphite. They then used the graphite Minerva as a cathode, which was electrolytically coated with copper. The metal was only deposited on the lines sketched by the printer.

My personal favourite is the scientists’ origami crane experiment,

In another experiment, the team in Potsdam demonstrated how three-dimensional, conductive structures can be created using their method. For this experiment, the team folded a sheet of paper into an origami crane. This was then immersed in the catalyst and baked into graphite. “The three-dimensional form was completely retained, but consisted entirely of conductive carbon after the process,” says Stefan Glatzel. He demonstrated this again by electrolytically coating the origami bird with copper. The entire crane subsequently had a copper sheen.

An origami figure takes flight: A crane made from folded paper is immersed in the ferric catalyst (left) by the Max Planck researchers in Potsdam. After the conversion, all that remains besides graphite is magnetic iron carbide, which allows the bird to fly towards the magnets (centre). The picture of a transmission electron microscope reveals the nanostructure of the carbon (right). © MPI of Colloids and Interfaces

An origami figure takes flight: A crane made from folded paper is immersed in the ferric catalyst (left) by the Max Planck researchers in Potsdam. After the conversion, all that remains besides graphite is magnetic iron carbide, which allows the bird to fly towards the magnets (centre). The picture of a transmission electron microscope reveals the nanostructure of the carbon (right).
© MPI of Colloids and Interfaces

Interested parties can find more information at ScienceDaily (May 15, 2013 news item) or here at the Max Planck Institute of Colloids and Interfaces website. For the truly keen, here’s a link to and a citation for the published study,

From Paper to Structured Carbon Electrodes by Inkjet Printing by Stefan Glatzel1, Dr. Zoë Schnepp, and Dr. Cristina Giordano. Angewandte Chemie International Edition, Volume 52, Issue 8, pages 2355–2358, February 18, 2013 Article first published online: 17 JAN 2013
DOI: 10.1002/anie.201207693

This paper is behind a paywall.

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More than human—a bionic ear that extends hearing beyond the usual frequencies

Thursday, May 2nd, 2013

It’s now possible to print a bionic ear in 3D that can hear beyond the human range and all you need is off-the-shelf printing equipment—and technical expertise. A May 2, 2013 news item on Azonano provides more detail,

Scientists at Princeton University used off-the-shelf printing tools to create a functional ear that can “hear” radio frequencies far beyond the range of normal human capability.

“In general, there are mechanical and thermal challenges with interfacing electronic materials with biological materials,” said Michael McAlpine, an assistant professor of mechanical and aerospace engineering at Princeton and the lead researcher. “Previously, researchers have suggested some strategies to tailor the electronics so that this merger is less awkward. That typically happens between a 2D sheet of electronics and a surface of the tissue. However, our work suggests a new approach — to build and grow the biology up with the electronics synergistically and in a 3D interwoven format.”

McAlpine’s team has made several advances in recent years involving the use of small-scale medical sensors and antenna. Last year, a research effort led by McAlpine and Naveen Verma, an assistant professor of electrical engineering, and Fio Omenetto of Tufts University, resulted in the development of a “tattoo” made up of a biological sensor and antenna that can be affixed to the surface of a tooth.

The tooth tattoo is mentioned in my Nov. 9, 2012 posting; I focused more on Tufts University than Princeton in that piece. As for the ear (from the news item on Azonano),

The finished ear consists of a coiled antenna inside a cartilage structure. Two wires lead from the base of the ear and wind around a helical “cochlea” – the part of the ear that senses sound – which can connect to electrodes. Although McAlpine cautions that further work and extensive testing would need to be done before the technology could be used on a patient, he said the ear in principle could be used to restore or enhance human hearing. He said electrical signals produced by the ear could be connected to a patient’s nerve endings, similar to a hearing aid. The current system receives radio waves, but he said the research team plans to incorporate other materials, such as pressure-sensitive electronic sensors, to enable the ear to register acoustic sounds.

Here’s the technique the researchers used to create their bionic ear (from the news item),

Standard tissue engineering involves seeding types of cells, such as those that form ear cartilage, onto a scaffold of a polymer material called a hydrogel. However, the researchers said that this technique has problems replicating complicated three dimensional biological structures. Ear reconstruction “remains one of the most difficult problems in the field of plastic and reconstructive surgery,” they wrote.

To solve the problem, the team turned to a manufacturing approach called 3D printing. These printers use computer-assisted design to conceive of objects as arrays of thin slices. The printer then deposits layers of a variety of materials – ranging from plastic to cells – to build up a finished product. Proponents say additive manufacturing promises to revolutionize home industries by allowing small teams or individuals to create work that could previously only be done by factories.

Creating organs using 3D printers is a recent advance; several groups have reported using the technology for this purpose in the past few months. But this is the first time that researchers have demonstrated that 3D printing is a convenient strategy to interweave tissue with electronics.

The technique allowed the researchers to combine the antenna electronics with tissue within the highly complex topology of a human ear. The researchers used an ordinary 3D printer to combine a matrix of hydrogel and calf cells with silver nanoparticles that form an antenna. The calf cells later develop into cartilage.

Here’s an image of the ear,

Scientists used 3-D printing to merge tissue and an antenna capable of receiving radio signals. Credit: Photo by Frank Wojciechowski

Scientists used 3-D printing to merge tissue and an antenna capable of receiving radio signals. Credit: Photo by Frank Wojciechowski

For interested parties,a link to and a citation for the published research,

A 3D Printed Bionic Ear by Manu S Mannoor , Ziwen Jiang , Teena James , Yong Lin Kong , Karen A Malatesta , Winston Soboyejo , Naveen Verma , David H Gracias , and Michael C. McAlpine. Nano Lett., Just Accepted Manuscript DOI: 10.1021/nl4007744 Publication Date (Web): May 1, 2013

Copyright © 2013 American Chemical Society

This article is behind a paywall.

At this point, the ear is strictly for use in the laboratory they have not run any ‘in vivo’ experiments, which would be one of the next steps and a prerequisite before  human clinical trials are considered.

I have written about human enhancement before, notably in my Aug. 30, 2011 posting where I highlighted this excerpt from an article by Paul Hochman,

“I don’t think I would have said this if it had never happened,” says Bailey, referring to the accident that tore off his pinkie, ring, and middle fingers. “But I told Touch Bionics I’d cut the rest of my hand off if I could make all five of my fingers robotic.” [originally excerpted from Paul Hochman's Feb. 1, 2010 article, Bionic Legs, i-Limbs, and Other Super Human Prostheses You'll Envy for Fast Company]

The Bailey quote stimulated this question for me, what would you choose if you could get an ear that hears beyond the human range?

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“Control my chirality, please,” said the carbon nanotube to the researchers

Tuesday, April 30th, 2013

A combined Finnish, Russian, and Danish team have found a way to control the chirality of single-walled carbon nanotubes according to an Apr. 30, 2013 news item on Azonano,

An ultimate goal in the field of carbon nanotube research is to synthesise single-walled carbon nanotubes (SWNTs) with controlled chiralities. Twenty years after the discovery of SWNTs, scientists from Aalto University in Finland, A.M. Prokhorov General Physics Institute RAS in Russia and the Center for Electron Nanoscopy of Technical University of Denmark (DTU) have managed to control chirality in carbon nanotubes during their chemical vapor deposition synthesis.

The Aalto University Apr. 29, 2013 news release, which originated the news item, goes on to explain,

 Over the years, substantial progress has been made to develop various structure-controlled synthesis methods. However, precise control over the chiral structure of SWNTs has been largely hindered by a lack of practical means to direct the formation of the metal nanoparticle catalysts and their catalytic dynamics during tube growth.

– We achieved an epitaxial formation of Co nanoparticles by reducing a well-developed solid solution in CO, reveals Maoshuai He, a postdoctoral researcher at Aalto University School of Chemical Technology.

– For the first time, the new catalyst was employed for selective growth of SWNTs, adds senior staff scientist Hua Jiang from Aalto University School of Science.

By introducing the new catalysts into a conventional CVD reactor, the research team demonstrated preferential growth of semiconducting SWNTs (～90%) with an exceptionally high population of (6,5) tubes (53%) at 500 °C. Furthermore, they also showed a shift of the chiral preference from (6,5) tubes at 500 °C  to (7, 6) and (9, 4) nanotubes at 400 °C.

– These findings open new perspectives both for structural control of SWNTs and for elucidating their growth mechanisms, thus are important for the fundamental understanding of science behind nanotube growth, comments Professor Juha Lehtonen from Aalto University.

For anyone like me who needs a description of chirality, there’s this from Wikipedia,

Chirality (pron.: /kaɪˈrælɪtiː/) is a property of asymmetry important in several branches of science. The word chirality is derived from the Greek, χειρ (kheir), “hand”, a familiar chiral object.

An object or a system is chiral if it is not identical to its mirror image, that is, it cannot be superposed onto it. A chiral object and its mirror image are called enantiomorphs (Greek opposite forms) or, when referring to molecules, enantiomers. A non-chiral object is called achiral (sometimes also amphichiral) and can be superposed on its mirror image.

…

Human hands are perhaps the most universally recognized example of chirality: The left hand is a non-superimposable mirror image of the right hand; no matter how the two hands are oriented, it is impossible for all the major features of both hands to coincide.[2] This difference in symmetry becomes obvious if someone attempts to shake the right hand of a person using his left hand, or if a left-handed glove is placed on a right hand. In mathematics chirality is the property of a figure that is not identical to its mirror image.

One of the researchers notes why they, or anyone else, would want to control the chirality of carbon nanotubes, from the news release,

– Chirality defines the optical and electronic properties of carbon nanotubes, so controlling it is a key to exploiting their practical applications, says Professor Esko I. Kauppinen, the leader of the Nanomaterials Group in Aalto University School of Science.

ETA Apr. 30, 2013 at 4:20 pm PDT: Here’s a link to and a citation for the team’s published paper,

Chiral-Selective Growth of Single-Walled Carbon Nanotubes on Lattice-Mismatched Epitaxial Cobalt Nanoparticles by Maoshuai He, Hua Jiang, Bilu Liu, Pavel V. Fedotov, Alexander I. Chernov, Elena D. Obraztsova, Filippo Cavalca, Jakob B. Wagner, Thomas W. Hansen, Ilya V. Anoshkin, Ekaterina A. Obraztsova, Alexey V. Belkin, Emma Sairanen, Albert G. Nasibulin,  Juha Lehtonen, & Esko I. Kauppinen. Scientific Reports 3, Article number 1460  doi:10.1038/srep01460 Published15 March 2013

This article is open access.

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Extending memristive theory

Monday, April 29th, 2013

This is kind of fascinating. A German research team based at JARA (Jülich Aachen Research Alliance) is suggesting that memristive theory be extended beyond passive components in their paper about Resistive Memory Cells (ReRAM) which was recently published in Nature Communications. From the Apr. 26, 2013 news item on Azonano,

Resistive memory cells (ReRAM) are regarded as a promising solution for future generations of computer memories. They will dramatically reduce the energy consumption of modern IT systems while significantly increasing their performance.

Unlike the building blocks of conventional hard disk drives and memories, these novel memory cells are not purely passive components but must be regarded as tiny batteries. This has been demonstrated by researchers of Jülich Aachen Research Alliance (JARA), whose findings have now been published in the prestigious journal Nature Communications. The new finding radically revises the current theory and opens up possibilities for further applications. The research group has already filed a patent application for their first idea on how to improve data readout with the aid of battery voltage.

The Apr. 23, 2013 JARA news release, which originated the news item, provides some background information about data memory before going on to discuss the ReRAMs,

Conventional data memory works on the basis of electrons that are moved around and stored. However, even by atomic standards, electrons are extremely small. It is very difficult to control them, for example by means of relatively thick insulator walls, so that information will not be lost over time. This does not only limit storage density, it also costs a great deal of energy. For this reason, researchers are working feverishly all over the world on nanoelectronic components that make use of ions, i.e. charged atoms, for storing data. Ions are some thousands of times heavier that electrons and are therefore much easier to ‘hold down’. In this way, the individual storage elements can almost be reduced to atomic dimensions, which enormously improves the storage density.

Here’s how the ions behave in ReRAMs (from the news release),

In resistive switching memory cells (ReRAMs), ions behave on the nanometre scale in a similar manner to a battery. The cells have two electrodes, for example made of silver and platinum, at which the ions dissolve and then precipitate again. This changes the electrical resistance, which can be exploited for data storage. Furthermore, the reduction and oxidation processes also have another effect. They generate electric voltage. ReRAM cells are therefore not purely passive systems – they are also active electrochemical components. Consequently, they can be regarded as tiny batteries whose properties provide the key to the correct modelling and development of future data storage.

In complex experiments, the scientists from Forschungszentrum Jülich and RWTH Aachen University determined the battery voltage of typical representatives of ReRAM cells and compared them with theoretical values. This comparison revealed other properties (such as ionic resistance) that were previously neither known nor accessible. “Looking back, the presence of a battery voltage in ReRAMs is self-evident. But during the nine-month review process of the paper now published we had to do a lot of persuading, since the battery voltage in ReRAM cells can have three different basic causes, and the assignment of the correct cause is anything but trivial,” says Dr. Ilia Valov, the electrochemist in Prof. Rainer Waser’s research group.

This discovery could lead to optimizing ReRAMs and exploiting them in new applications (from the news release),

“The new findings will help to solve a central puzzle of international ReRAM research,” says Prof. Rainer Waser, deputy spokesman of the collaborative research centre SFB 917 ‘Nanoswitches’ established in 2011. In recent years, these puzzling aspects include unexplained long-term drift phenomena or systematic parameter deviations, which had been attributed to fabrication methods. “In the light of this new knowledge, it is possible to specifically optimize the design of the ReRAM cells, and it may be possible to discover new ways of exploiting the cells’ battery voltage for completely new applications, which were previously beyond the reach of technical possibilities,” adds Waser, whose group has been collaborating for years with companies such as Intel and Samsung Electronics in the field of ReRAM elements.

The part I found most interesting, given my interest in memristors, is this bit about extending the memristor theory, from the news release,

The new finding is of central significance, in particular, for the theoretical description of the memory components. To date, ReRAM cells have been described with the aid of the concept of memristors – a portmanteau word composed of “memory” and “resistor”. The theoretical concept of memristors can be traced back to Leon Chua in the 1970s. It was first applied to ReRAM cells by the IT company Hewlett-Packard in 2008. It aims at the permanent storage of information by changing the electrical resistance. The memristor theory leads to an important restriction. It is limited to passive components. “The demonstrated internal battery voltage of ReRAM elements clearly violates the mathematical construct of the memristor theory. This theory must be expanded to a whole new theory – to properly describe the ReRAM elements,” says Dr. Eike Linn, the specialist for circuit concepts in the group of authors. [emphases mine] This also places the development of all micro- and nanoelectronic chips on a completely new footing.

Here’s a link to and a citation for the paper,

Nanobatteries in redox-based resistive switches require extension of memristor theory by I. Valov,  E. Linn, S. Tappertzhofen,  S. Schmelzer,  J. van den Hurk,  F. Lentz,  & R. Waser. Nature Communications 4, Article number: 1771 doi:10.1038/ncomms2784 Published 23 April 2013

This paper is open access (as of this writing).

Here’s a list of my 2013 postings on memristors and memristive devices,

2.5M Euros for Ireland’s John Boland and his memristive nanowires (Apr. 4, 2013 posting)

How to use a memristor to create an artificial brain (Feb. 26, 2013 posting)

CeNSE (Central Nervous System of the Earth) and billions of tiny sensors from HP plus a memristor update (Feb. 7, 2013 posting)

For anyone who cares to search the blog, there are several more.

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Shapeshifting on demand but no stretching yet: morphees

Monday, April 29th, 2013

This research (Morphees) is from Bristol University where researchers have created prototypes for shapeshifting mobile devices,

A high-fidelity prototype using projection and tracking on wood tiles that are actuated with thin shape-memory alloy wires [downloaded from http://www.bris.ac.uk/news/2013/9332.html/]

A high-fidelity prototype using projection and tracking on wood tiles that are actuated with thin shape-memory alloy wires [downloaded from http://www.bris.ac.uk/news/2013/9332.html/]

The Apr. 28, 2013 news release on EurekAlert provides more detail,

The research, led by Dr Anne Roudaut and Professor Sriram Subramanian, from the University of Bristol’s Department of Computer Science, have used ‘shape resolution’ to compare the resolution of six prototypes the team have built using the latest technologies in shape changing material, such as shape memory alloy and electro active polymer.

One example of a device is the team’s concept of Morphees, self-actuated flexible mobile devices that can change shape on-demand to better fit the many services they are likely to support.

The team believe Morphees will be the next generation of mobile devices, where users can download applications that embed a dedicated form factor, for instance the “stress ball app” that collapses the device in on itself or the “game app” that makes it adopt a console-like shape.

Dr Anne Roudaut, Research Assistant in the Department of Computer Science’s Bristol Interaction and Graphics group, said: “The interesting thing about our work is that we are a step towards enabling our mobile devices to change shape on-demand. Imagine downloading a game application on the app-store and that the mobile phone would shape-shift into a console-like shape in order to help the device to be grasped properly. The device could also transform into a sphere to serve as a stress ball, or bend itself to hide the screen when a password is being typed so passers-by can’t see private information.”

By comparing the shape resolution of their prototypes, the researchers have created insights to help designers towards creating high shape resolution Morphees.

In the future the team hope to build higher shape resolution Morphees by investigating the flexibility of materials. They are also interested in exploring other kinds of deformations that the prototypes did not explore, such as porosity and stretchability.

Here’s the video where the researchers demonstrate their morphees,


The work will be presented at ACM CHI 2013, sometime between Saturday 27 April to Thursday 2 May 2013, in Paris, France. For those who’d like to see the paper which will be presented, here’s a link to it,

Morphees: Toward High “Shape Resolution” in Self-Actuated Flexible Mobile Devices by
Anne Roudaut, Abhijit Karnik, Markus Löchtefeld, and Sriram Subramanian

After reading the news release and watching the video, I am reminded of the ‘morph’ concept, a shapeshifting, wearable device proposed by Cambridge University and Nokia. Last I wrote about that project, they had announced a stretchable skin, as per my Nov. 7, 2011 posting.

For those who are interested in what ACM CHI 2013 is all about, from the home page,

The ACM SIGCHI Conference on Human Factors in Computing Systems is the premier international conference on human-computer interaction. CHI 2013 is about changing perspectives: we draw from the constantly changing perspectives of the diverse CHI community and beyond, but we also change perspectives, offering new visions of people interacting with technology. The conference is multidisciplinary, drawing from science, engineering and design, with contributions from research and industry in 15 different venues. CHI brings together students and experts from over 60 countries, representing different cultures and different application areas, whose diverse perspectives influence each other.

CHI 2013 is located in vibrant Paris, France, the most visited city in the world. The conference will be held at the Palais de Congrès de Paris. First in Europe in research and development, with the highest concentration of higher education students in Europe, Paris is a world-class center for business and culture, with over 3800 historical monuments.The Louvre’s pyramid captures the spirit of CHI’13, offering diverse perspectives on design and technology, contrasting the old and new. The simple glass sides reveal inner complexity, sometimes transparent, sometimes reflecting the people and buildings that surround it, in the constantly
changing Paris light.

CHI 2013 welcomes works addressing research on all aspects of human-computer interaction (HCI), as well as case studies of interactive system designs, innovative proof-of-concept, and presentations by experts on the latest challenges and innovations in the field. In addition to a long-standing focus on professionals in design, engineering, management, and user experience; this year’s conference has made special efforts to serve communities in the areas of: design, management, engineering, user experience, arts, sustainability, children, games and health. We look forward to seeing you at CHI 2013 in Paris!

As I recall, ACM stands for Association of Computing Machinery, CHI stands for computer-human interface, and SIG stands for Special Interest Group.

ETA May 13, 2013: I meant to do this two weeks ago (Apr. 30,2013), ah well. Roel Vertegaal and his team at Canada’s Queen’s University introduced something called a MorePhone, which can curl up and change shape, at the CHI 2013. From the Apr. 30, 2013 news release on EurkeAlert,

Researchers at Queen’s University’s Human Media Lab have developed a new smartphone – called MorePhone – which can morph its shape to give users a silent yet visual cue of an incoming phone call, text message or email.

“This is another step in the direction of radically new interaction techniques afforded by smartphones based on thin film, flexible display technologies” says Roel Vertegaal (School of Computing), director of the Human Media Lab at Queen’s University who developed the flexible PaperPhone and PaperTab.

“Users are familiar with hearing their phone ring or feeling it vibrates in silent mode. One of the problems with current silent forms of notification is that users often miss notifications when not holding their phone. With MorePhone, they can leave their smartphone on the table and observe visual shape changes when someone is trying to contact them.”

MorePhone is not a traditional smartphone. It is made of a thin, flexible electrophoretic display manufactured by Plastic Logic – a British company and a world leader in plastic electronics. Sandwiched beneath the display are a number of shape memory alloy wires that contract when the phone notifies the user. This allows the phone to either curl either its entire body, or up to three individual corners. Each corner can be tailored to convey a particular message. For example, users can set the top right corner of the MorePhone to bend when receiving a text message, and the bottom right corner when receiving an email. Corners can also repeatedly bend up and down to convey messages of greater urgency.

I have written about Vertegaal and his team’s ‘paper’ devices previously. The most recent piece is this Jan. 9, 2013 posting, Canada’s Queen’s University strikes again with its ‘paper’ devices. You can find out more about Plastic Logic here.

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2.5M Euros for Ireland’s John Boland and his memristive nanowires

Thursday, April 4th, 2013

The announcement makes no mention of the memristor or neuromorphic engineering but those are the areas in which  John Boland works and the reason for his 2.5M Euro research award. From the Ap. 3, 2013 news item on Nanowerk,

Professor John Boland, Director of CRANN, the SFI-funded [Science Foundation of Ireland] nanoscience institute based at Trinity College Dublin, and a Professor in the School of Chemistry has been awarded a €2.5 million research grant by the European Research Council (ERC). This is the second only Advanced ERC grant ever awarded in Physical Sciences in Ireland.

The Award will see Professor Boland and his team continue world-leading research into how nanowire networks can lead to a range of smart materials, sensors and digital memory applications. The research could result in computer networks that mimic the functions of the human brain and vastly improve on current computer capabilities such as facial recognition.

The University of Dublin’s Trinity College CRANN (Centre for Research on Adaptive Nanostructures and Nanodevices) April 3, 2013 news release, which originated the news item,  provides details about Boland’s proposed nanowire network,

Nanowires are spaghetti like structures, made of materials such as copper or silicon. They are just a few atoms thick and can be readily engineered into tangled networks of nanowires. Researchers worldwide are investigating the possibility that nanowires hold the future of energy production (solar cells) and could deliver the next generation of computers.

Professor Boland has discovered that exposing a random network of nanowires to stimuli like electricity, light and chemicals, generates chemical reaction at the junctions where the nanowires cross. By controlling the stimuli, it is possible to harness these reactions to manipulate the connectivity within the network. This could eventually allow computations that mimic the functions of the nerves in the human brain – particularly the development of associative memory functions which could lead to significant advances in areas such as facial recognition.

Commenting Professor John Boland said, “This funding from the European Research Council allows me to continue my work to deliver the next generation of computing, which differs from the traditional digital approach.  The human brain is neurologically advanced and exploits connectivity that is controlled by electrical and chemical signals. My research will create nanowire networks that have the potential to mimic aspects of the neurological functions of the human brain, which may revolutionise the performance of current day computers.   It could be truly ground-breaking.”

It’s only in the news release’s accompanying video that the memristor and neuromorphic engineering are mentioned,

I have written many times about the memristor, most recently in a Feb. 26, 2013 posting titled, How to use a memristor to create an artificial brain, where I noted a proposed ‘blueprint’ for an artificial brain. A contested concept, the memristor has attracted critical commentary as noted in a Mar. 19, 2013 comment added to the ‘blueprint’  post,

A Sceptic says:

….

Before talking about blueprints, one has to consider that the dynamic state equations describing so-called non-volatile memristors are in conflict with fundamentals of physics. These problems are discussed in:

“Fundamental Issues and Problems in the Realization of Memristors” by P. Meuffels and R. Soni (http://arxiv.org/abs/1207.7319)

“On the physical properties of memristive, memcapacitive, and meminductive systems” by M. Di Ventra and Y. V. Pershin (http://arxiv.org/abs/1302.7063)

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Shake hands with Sacha, a robot controlled by carbon nanotube transistors

Monday, March 18th, 2013

Since we use computer chips built from silicon in any number devices including robots, the announcement of a robot controlled by the first computer chip built entirely of a material other silicon bears notice. From the Mar. 15, 2013 news item on Nanowerk (Note: Links have been removed),

A group of Stanford researchers recently debuted the first robot controlled by a computer chip built entirely from carbon nanotube transistors, which many scientists predict may eventually replace silicon.

While scientists have produced simple demonstrations of working carbon nanotube circuit components in the past, the Stanford team, led by Professor of Electrical Engineering Philip Wong and Associate Professor of Electrical Engineering and Computer Science Subhasish Mitra Ph.D. ’00, was able to demonstrate an actual subsystem composed entirely of the material.

The news item was originated by a Mar. 7, 2013 article by Nikhita Obeegadoo for the Stanford Daily, where she noted,

The project was presented in the form of a robot named Sacha at the 2013 International Solid-State Circuits Conference (“Sacha, the Stanford Carbon Nanotube Controlled Handshaking Robot”), which was held in San Francisco. According to Mitra, the robot was created to demonstrate the development of a system that can function despite the errors caused by inherently imperfect nanotubes, which have posed issues for research teams working with carbon nanotubes in the past.

…

“Through several generations of technology, devices keep getting smaller and denser, and silicon will no longer be the best material for the purpose in about ten years,” Guha [Supratik Guha, director of physical sciences at IBM’s Yorktown Heights Research Center] said. “For needs that are close to atomic dimensions, carbon nanotubes have just the right shape and the right electrical behavior.”

Eric Juma on his eponymous blog offers more insight into the project in his Mar. 16, 2013 posting,

… The robot contained a carbon nanotube capacitor, a device found in many touchscreens, connected to another nanotube circuit, which turned the analog signal from the capacitor into a digital signal, which was transmitted to the microprocessor that contained CNT transistors. The microporcessor then sent a signal to a motor on the hand of the robot, which shook the person’s hand that touched the capacitors embedded in it.

This is not the first example of carbon nanotube circuitry, but it is the first example of CNTs being produced at mass for a microprocessor and circuit that were integrated. This advancement showed that it is possible to produce mass amounts of CNTs and have them integrate succesfully into a complex system. Although the size of the CNTs in this system are far from the optimal size of 10nm, it is a good starting point, and the nanotubes still can be much further refined.

Carbon nanotubes, although perfect in theory for microprocessors, present new challenges for engineers. The greatest challenge is the actual integration of CNTs into circuitry. Nanotubes often force themselves into a tangled position, which can cause circuits to fail without warning.

Juma gives a good explanation for why there is so much interest in carbon nanotubes in the field of electronics and he provides links to more information about it all. (There’s a video about carbon nanotubes and their various shapes and structures in my Mar. 15, 2013 posting about them.)

Sacha will be seen (or perhaps the work will simply be presented by Max Shulaker?) next in Switzerland at a Mar. 25, 2013 workshop (FED ’13; Functionality-Enhanced Devices Workshop) at the EPFl (École Polytechnique Fédérale de Lausanne.

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Dublin (Ireland) hosts Europe’s largest nanotechnology conference

Thursday, March 14th, 2013

The announcement of Dublin’s nano hosting duties is in a Mar. 14, 2013 news item on Nanowerk  (Note: A link has been removed),

The 6th biannual conference, EuroNanoForum 2013, will gather experts and decision-makers of the nanotechnology community to Dublin this June. EuroNanoForum 2013 is the largest nanotechnology conference in Europe and will focus on the impact of nanotechnology in improving people’s lives, especially in the key societal sectors such as health, energy and environment. The event coincides with Nanotech Europe exhibition and the Nanoweek Ireland.

“The conference showcases innovation as a driver of economic growth. New technologies arising from nano-science and their applications are presented and potential new end products are discussed”, describes Herbert von Bose, Director, European Commission, DG Research & Innovation, Industrial Technologies.

The EuroNanoForum March 14, 2013 news release, which originated the news item, can be found here.

The forum organizers have created a Hot Topics page on the conference website (you can register for EuroNanoForum 2013 here) which provides some compelling reasons for attending,

Self-cleaning walls, lightweight airplanes and hydrogen fueled scooters drive the nano-future at EuroNanoForum 2013

We claim that by 2030, Europe will be a frontrunner in sustainable economy. The European Cleantech sector is steadily growing and it is taking a leading position in the global markets.  Companies, nations, and international consortia will capitalise on the business opportunity and what we have so far seen is just the tip of a vastly growing iceberg.

In EuroNanoForum 2013 Henning Zoz, the President of the Zoz Group, will present a concept which will revolutionize the refueling infrastructure. In the plenary, Nano in everyday life, he will elaborate on his company’s innovation – small tank cartridges containing nanostructured powder that can store an enormous amount of hydrogen virtually without pressure. With such changeable tanks it is already possible to drive a scooter, at Zoz GmbH in Wenden. The innovation ensures that surplus electricity output from renewable energy sources economically converted into hydrogen can be consumed as transportation-fuel.

…

Cure for cancer and improving hearing implants

Hans Hofstraat, VP of Philips Healthcare, and Patrick Boisseau, the Chairman of the ETP Nanomedicine, will lead the cadre of healthcare specialists in EuroNanoForum 2013. In Dublin we will hear what is the role of nanotechnology in answering the societal challenge of ageing populations. Moreover, will nano make vital medicine available to all people – not only in Europe but worldwide?

Over 60 million citizens in the EU suffer from hearing loss with its associated restrictions. Pascal Senn, Project Coordinator of NanoCi project from University of Bern, will present on the first conference day at the Healthcare session, how their project is developing implants to improve hearing. Using functional nano-materials, including carbon nanotubes, NanoCi aims at developing a cost-efficient and fully implantable neuro-prosthesis with substantially increased sound quality.

…

The Graphene Flagship will sail to EuroNanoForum 2013

The European Commission has chosen Graphene as one of Europe’s first 10-year, 1,000 million euro FET flagships. The mission of the flagship is to take graphene and related layered materials from academic laboratories to society, revolutionize multiple industries and create economic growth and new jobs in Europe. The Graphene flagship is a new form of joint, coordinated research initiative of unprecedented scale. It brings together an academic-industrial consortium aiming at a breakthrough for technological innovation. Involved are Nobel Laureates, top-notch research groups and the next generation industrial leaders.

…

From the start in 2013 the Graphene Flagship will coordinate 126 academic and industrial research groups in 17 European countries with an initial 30-month-budget of 54 million euro. The consortium will be extended with another 20-30 groups through an open call, issued soon after the start of the initiative, just after EuroNanoForum 2013. Will you sail with the ship or be left behind on the shore?

Wish I could be there.

ETA Apr. 22, 2013: Drat! I don’t like it when someone else does it. Well, I like it even less when I do it! I see the dates EuroNanoforum dates are not mentioned, they are June 18 – 20, 2013.

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Samsung ‘GROs’ graphene-based micro-antennas and a brief bit about the business of nanotechnology

Monday, February 25th, 2013

A Feb. 22, 2013 news item on Nanowerk highlights a Samsung university grant (GRO) programme which announced funding for graphene-based micro-antennas,

The Graphene-Enabled Wireless Communication project, one of the award-winning proposals under the Samsung Global Research Outreach (GRO) programme, aims to use graphene antennas to implement wireless communication over very short distances (no more than a centimetre) with high-capacity information transmission (tens or hundreds of gigabits per second). Antennas made ??of [sic] graphene could radiate electromagnetic waves in the terahertz band and would allow for high-speed information transmission. Thanks to the unique properties of this nanomaterial, the new graphene-based antenna technology would also make it possible to manufacture antennas a thousand times smaller than those currently used.

The GRO programme—an annual call for research proposals by the Samsung Advanced Institute of Technology (Seoul, South Korea)—has provided the UPC-led project with US$120,000 in financial support.

The Graphene-Enabled Wireless Communication project is a joint project (from the news item; Note: A link has been removed),

“Graphene-Enabled Wireless Communications” – a proposal submitted by an interdepartmental team based at the Universitat Politècnica de Catalunya, BarcelonaTech (UPC) and the Georgia Institute of Technology (Georgia Tech)—will receive US$120,000 to develop micrometre-scale graphene antennas capable of transmitting information at a high speed over very short distances. The project will be carried out in the coming months.

…

The Graphene-Enabled Wireless Communication project, one of the award-winning proposals under the Samsung Global Research Outreach (GRO) programme, aims to use graphene antennas to implement wireless communication over very short distances (no more than a centimetre) with high-capacity information transmission (tens or hundreds of gigabits per second). Antennas made ??of graphene could radiate electromagnetic waves in the terahertz band and would allow for high-speed information transmission. Thanks to the unique properties of this nanomaterial, the new graphene-based antenna technology would also make it possible to manufacture antennas a thousand times smaller than those currently used.

There’s more about the Graphene-Enabled Wireless Communication project here,

 A remarkably promising application of graphene is that of Graphene-enabled Wireless Communications (GWC). GWC advocate for the use of graphene-based plasmonic antennas -graphennas, see Fig. 1- whose plasmonic effects allow them to radiate EM waves in the terahertz band (0.1 – 10 THz). Moreover, preliminary results sustain that this frequency band is up to two orders of magnitude below the optical frequencies at which metallic antennas of the same size resonate, thereby enhancing the transmission range of graphene-based antennas and lowering the requirements on the corresponding transceivers. In short, graphene enables the implementation of nano-antennas just a few micrometers in size that are not doable with traditional metallic materials.

Thanks to both the reduced size and unique radiation capabilities of ZZ, GWC may represent a breakthrough in the ultra-short range communications research area. In this project we will study the application of GWC within the scenario of off-chip communication, which includes communication between different chips of a given device, e.g. a cell phone.

A new term, graphenna, appears to be have been coined. The news item goes on to offer more detail about the project and about the number of collaborating institutions,

The first stage of the project, launched in October 2012, focuses on the theoretical foundations of wireless communications over short distances using graphene antennas. In particular, the group is analysing the behaviour of electromagnetic waves in the terahertz band for very short distances, and investigating how coding and modulation schemes can be adapted to achieve high transmission rates while maintaining low power consumption.

…

The group believes the main benefits of the project in the medium term will derive from its application for internal communication in multicore processors. Processors of this type have a number of sub-processors that share and execute tasks in parallel. The application of wireless communication in this area will make it possible to integrate thousands of sub-processors within a single processor, which is not feasible with current communication systems.

The results of the project will lead to an increase in the computational performance of these devices. This improvement would allow large amounts of data to be processed at very high speed, which would be very useful for streamlining data management at processing centres (“big data”) used, for example, in systems like Facebook and Google. The project, which builds on previous results obtained with the collaboration of the University of Wuppertal in Germany, the Royal Institute of Technology (KTH) in Sweden, and Georgia Tech in the United States, is expected to yield its first results in April 2013.

The project is being carried out by the NaNoNetworking Centre in Catalonia (N3Cat), a network formed at the initiative of researchers with the UPC’s departments of Electronic Engineering and Computer Architecture, together with colleagues at Georgia Tech.

Anyone interested in  Samsung’s GRO programme can find more here,

The SAMSUNG Global Research Outreach (GRO) program, open to leading universities around the world, is Samsung Electronics, Co., Ltd. & related Samsung companies (SAMSUNG)’s annual call for research proposals.

As this Samsung-funded research project is being announced, Dexter Johnson details the business failure of NanoInk in a Feb. 22, 2013 posting on his Nanoclast blog (on the IEEE [International Institute of Electrical and Electronics Engineers] website), Note: Links have been removed,

One of the United State’s first nanotechnology companies, NanoInk, has gone belly up, joining a host of high-profile nanotechnology-based companies that have shuttered their doors in the last 12 months: Konarka, A123 Systems and Ener1.

These other three companies were all tied to the energy markets (solar in the case of Konarka and batteries for both A123 and Ener1), which are typically volatile, with a fair number of shuttered businesses dotting their landscapes. But NanoInk is a venerable old company in comparison to these other three and is more in what could be characterized as the “picks-and-shovels” side of the nanotechnology business, microscopy tools.

Dexter goes on to provide an  analysis of the NanoInk situation which makes for some very interesting reading along with the comments—some feisty, some not—his posting has provoked.

I am juxtaposing the Samsung funding announcement with this mention of Dexter’s piece regarding a  ‘nanotechnology’ business failure in an effort to provide some balance between enthusiasm for the research and the realities of developing businesses and products based on that research.

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CeNSE (Central Nervous System of the Earth) and billions of tiny sensors from HP plus a memristor update

Thursday, February 7th, 2013

Mike Thacker’s Feb. 1, 2013 (?) post features an HP Labs video trumpeting what is described as their most progressive work, from the official HP Labs blog,

… HP Labs in Palo Alto, for example, which is using nanotechnology capabilities to create low-cost censors that act as a central nervous system for the earth. The technology can be used to closely monitor — and quickly respond to — changes in agriculture, food supply and architectural infrastructure around the world.

CeNSE (Central Nervous System of the Earth) sounds like something new, eh? Almost three years ago, Greg Lindsay wrote about CeNSE and its first customer, Shell Oil, in a Feb. 12, 2010 article for Fast Company (Note: Links have been removed),

Just days after Cisco signaled it will horn into IBM’s turf by rewiring an aging city in Massachusetts, Hewlett Packard announced this morning the first commercial application of its own holistic blueprint–the torturously acronymed “CeNSE” (short for Central Nervous System for the Earth). Much like IBM’s “Smarter Planet” campaign, HP proposes sticking billions of sensors on everything in sight and boiling down the resulting flood of data into insights for making the world a better, greener place. But what sets HP apart from its rivals is its determination to create a smarter planet almost entirely within house, from sensors of its own design and manufacture to servers to software to the consultants who will tie it all together. And its first customer could not be less green: Shell Oil.

…

The Shell deal also unintentionally explodes the myth that a smarter planet is necessarily a greener one. HP’s bleeding-edge accelerometers are being deployed for the least green thing you can think of: sucking every last drop of oil out of the ground. While absolutely necessary for the current trajectory of our way of life (and buying us more time to develop alternatives), it’s hard to argue that technology for more efficiently recovering fossil fuels is in any way sustainable. (Although Wacker [Jeff Wacker, the leader of services innovation at HP and the head of its efforts to commercialize CeNSE] gamely argues the same technology is needed for finding empty pockets suitable for carbon sequestration.) While corporate-sponsored smarter cities can, in fact, be greener ones, their charter is the same as it ever was: profit. [emphasis mine]

Lindsay’s article echoes some of what I noted in the context of the Carbon Management Canada (CMC) network (government- and industry-funded) in my Feb. 4, 2013 posting about ultra-sensitive nanosensors and attempts to reduce carbon emissions in the Alberta oil sands. While the industry may work to reduce emissions, its raison d’être is profit and that can lead to complex situations with conflicting agendas.

As for what these billions and billions of tiny sensors might do for us, it seems there might be alternatives to at least one of the capabilities claimed by HP Labs and its sensors, ‘sensing changes in architectural infrastructures’. My Jan. 3, 2013 post, Signal danger with smart paint, mentioned a much more modest effort,

An innovative low-cost smart paint that can detect microscopic faults in wind turbines, mines and bridges before structural damage occurs is being developed by researchers at the University of Strathclyde in Glasgow, Scotland. [emphasis mine]

The environmentally-friendly paint uses nanotechnology to detect movement in large structures, and could shape the future of safety monitoring.

I digress slightly. The reference to the ‘central nervous system of the earth’ and Stanley Williams’ presence in the video reminded me of the memristor and an announcement (mentioned in my April 19, 2012 posting) that HP Labs would be rolling out some memristor-enabled products in 2013. Sadly, later in the year I missed this announcement, from a July 9, 2012 posting by Chris Mellor for TheRegister.co.uk,

Previously he (Stanley Williams) has said that HP and fab partner Hynix would launch a memristor product in the summer of 2013. At the Kavli do [Kavli Foundation Roundtable, June 2012], Williams said: “In terms of commercialisation, we’ll have something technologically viable by the end of next year.”

But that doesn’t mean a commercial product launch, and Hynix’s concerns about memristor device effect on flash are relevant: “Our partner, Hynix, is a major producer of flash memory, and memristors will cannibalise its existing business by replacing some flash memory with a different technology. So the way we time the introduction of memristors turns out to be important. There’s a lot more money being spent on understanding and modeling the market than on any of the research,” said Williams. [emphasis mine]

We might see a memristor product by summer 2014 but it could be later, as Hynix balances memristor device revenues, starting from zero, cutting into flash revenues in the millions of dollars.

I think the reason innovation is often introduced by outsiders is that they have no vested interest in maintaining the status quo as per the situation with Hynix and HP Labs, i.e., not wanting to cannibalize a current and profitable product line by introducing something new and, one gathers, an improvement.

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