Tag Archives: A. Mishchenko

Making the impossible possible: on demand and by design, atomic scale pipes

This research on pipes from the University of Manchester will probably never finds its way into plumbing practices but, apparently, is of great interest in fundamental research. From a Sept. 7, 2016 news item on phys.org,

Materials containing tiny capillaries and cavities are widely used in filtration, separation and many other technologies, without which our modern lifestyle would be impossible. Those materials are usually found by luck or accident rather than design. It has been impossible to create artificial capillaries with atomic-scale precision.

Now a Manchester group led by postdoctoral researcher Radha Boya and Nobel laureate Andre Geim show how to make the impossible possible, as reported in Nature.

A Sept. 7, 2016 University of Manchester press release (also on EurekAlert), which originated the news item,  provides a description of the technology,

The new technology is elegant, adaptable and strikingly simple. In fact, it is a kind of antipode of the famous material graphene. When making graphene, people often take a piece of graphite and use Scotch tape to extract a single atomic plane of carbon atoms, graphene. The remaining graphite is discarded.

In this new research, Manchester scientists similarly extracted a strip of graphene from graphite, but discarded the graphene and focused on what was left: an ultra-thin cavity within the graphite crystal.

Such atomic scale cavities can be made from various materials to achieve not only a desired size but also to choose properties of capillary walls. They can be atomically smooth or rough, hydrophilic or hydrophobic, insulating or conductive, electrically charged or neutral; the list goes on.

The voids can be made as cavities (to confine various substances) or open-ended tunnels (to transport different gases and liquids), which is of huge interest for fundamental research and many applications. It is limited only by imagination what such narrow tunnels with designer properties can potentially do for us.

Properties of materials at this truly atomic scale are expected to be quite different from those we are familiar with in our macroscopic world. To demonstrate that this is the case of their atomic-scale voids, the Manchester group tested how water runs through those ultra-narrow pipes.

To everyone’s surprise, they found water to flow with little friction and at high speed, as if the channels were many thousands times wider than they actually are.

Radha Boya commented ‘This is an entirely new type of nanoscale systems. Such capillaries were never imagined, even in theory. No one thought that this degree of accuracy in design could be possible. New filtration, desalination, gas separation technologies are kind of obvious directions but there are so many others to explore’.

Sir Andre added ‘Making something useful out of an empty space is certainly cute. Finding that this space offers so much of new science is flabbergasting. Even with hindsight, I did not expect the idea to work so well. There are myriads of possibilities for research and development, which now need to be looked at. We are stunned by the choice.’

Here’s a link to and a citation for the paper,

Molecular transport through capillaries made with atomic-scale precision by B. Radha, A. Esfandiar, F. C. Wang, A. P. Rooney, K. Gopinadhan, A. Keerthi, A. Mishchenko, A. Janardanan, P. Blake, L. Fumagalli, M. Lozada-Hidalgo, S. Garaj, S. J. Haigh, I. V. Grigorieva, H. A. Wu, & A. K. Geim. Nature (2016)  doi:10.1038/nature19363 Published online 07 September 2016

This paper is behind a paywall.

Three teams observe graphene butterflies

It took me a few minutes to find the butterflies (visual pattern recognition is not one of my strengths) but here they are,

Caption: Graphene, combined with white graphene, forms stunning 'butterfly' images. Credit: The University of Manchester

Caption: Graphene, combined with white graphene, forms stunning ‘butterfly’ images.
Credit: The University of Manchester

The May 15, 2013 University of Manchester news release (on EurekAlert and on the University of Manchester news site) describes how the ‘butterflies’ are formed,

Writing in Nature, a large international team led Dr Roman Gorbachev from The University of Manchester shows that, when graphene placed on top of insulating boron nitride, or ‘white graphene’, the electronic properties of graphene change dramatically revealing a pattern resembling a butterfly.

The pattern is referred to as the elusive Hofstadter butterfly that has been known in theory for many decades but never before observed in experiments.

More of the science needs to be explained before moving on with the ‘butterflies’ (from the news release),

One of the most remarkable properties of graphene is its high conductivity – thousands of times higher than copper. This is due to a very special pattern created by electrons that carry electricity in graphene. The carriers are called Dirac fermions and mimic massless relativistic particles called neutrinos, studies of which usually require huge facilities such as at CERN. The possibility to address similar physics in a desk-top experiment is one of the most renowned features of graphene.

Now the Manchester scientists have found a way to create multiple clones of Dirac fermions. Graphene is placed on top of boron nitride so that graphene’s electrons can ‘feel’ individual boron and nitrogen atoms. Moving along this atomic ‘washboard’, electrons rearrange themselves once again producing multiple copies of the original Dirac fermions.

Here’s where the butterflies appear (from the news release),

The researchers can create even more clones by applying a magnetic field. The clones produce an intricate pattern; the Hofstadter butterfly. It was first predicted by mathematician Douglas Hofstadter in 1976 and, despite many dedicated experimental efforts, no more than a blurred glimpse was reported before.

In addition to the described fundamental interest, the Manchester study proves that it is possible to modify properties of atomically-thin materials by placing them on top of each other. This can be useful, for example, for graphene applications such as ultra-fast photodetectors and transistors, providing a way to tweak its incredible properties.

Coincidentally, another team has also observed the Hofstadter butterfly on a graphene substrate. From the May 16, 2013 news item on Azonano,

Two research teams at the National High Magnetic Field Laboratory (MagLab) broke through a nearly 40-year barrier recently when they observed a never-before-seen energy pattern.

“The observation of the ‘Hofstadter butterfly’ marks a real landmark in condensed matter physics and high magnetic field research,” said Greg Boebinger, director of the MagLab. “It opens a new experimental direction in materials research.”

This groundbreaking research demanded the ability to measure samples of materials at very low temperatures and very high magnetic fields, up to 35 tesla. Both of those conditions are available at the MagLab, making it an international destination for scientific exploration.

The unique periodic structure used to observe the butterfly pattern was composed of boron nitride (BN) and graphene.

The May 15, 2013 Florida State University news release by Kristin Roberts, which originated the news item, describes the two teams using the MagLab facilities for their ‘butterfly’ observations,

One research team was led by Columbia University’s Philip Kim and included researchers from City University of New York, the University of Central Florida, Tohoku University and the National Institute for Materials Science in Japan. The team’s work will be published today in the Advanced Online Publication of the journal Nature. Similar results were discovered at the MagLab by a group led by Pablo Jarillo-Herrero and Raymond Ashoori at MIT, as well as scientists from Tohoku University and the National Institute for Materials Science in Japan. Their work is expected to be published soon.

For those who just can’t get enough graphene butterflies here are citations for and links to both recently published papers (the Jarillo-Herrero/Ashoori team will be publishing their work soon).

Cloning of Dirac fermions in graphene superlattices by L. A. Ponomarenko, R. V. Gorbachev, G. L. Yu,D. C. Elias, R. Jalil, A. A. Patel, A. Mishchenko, A. S. Mayorov, C. R. Woods, J. R. Wallbank, M. Mucha-Kruczynski, B. A. Piot, M. Potemski, I. V. Grigorieva, K. S. Novoselov, F. Guinea, V. I. Fal’ko & A. K. Geim. Nature doi:10.1038/nature12187 Published online   

and,

Hofstadter’s butterfly and the fractal quantum Hall effect in moiré superlattices by C. R. Dean, L. Wang, P. Maher, C. Forsythe, F. Ghahari, Y. Gao, J. Katoch, M. Ishigami, P. Moon, M. Koshino, T. Taniguchi, K. Watanabe, K. L. Shepard, J. Hone & P. Kim. Nature (2013) doi:10.1038/nature12186 Published online 15 May 2013

Both papers are behind paywalls.