Tag Archives: diamond

Virtual lego used to simulate self-assembling crystal structures

The Jan. 17, 2013 news release on EurekAlert describes a ‘soft’ or virtual lego computer simulation developed at the University of Vienna (Austria),

In developing these novel self-assembling materials, postdoc Barbara Capone has focused on the design of organic and inorganic building blocks, which are robust and can be produced at large scale. Capone has put forward, together with her colleagues at the Universities of Vienna and Mainz, a completely new pathway for the construction of building blocks at the nanoscale.

The team of researchers has shown that so-called block copolymer stars – that means polymers that consist of two different blocks and they are chemically anchored on a common point – have a robust and flexible architecture and they possess the ability to self-assemble at different levels. At the single-molecule level, they first order as soft patchy colloids which serve then as “soft Lego” for the emergence of larger structures. At the next level of self-assembly, the colloids form complex crystal structures, such as diamond or cubic phases.

The spatial ordering in the crystals can be steered through the architecture of the “soft Lego” and opens up the possibility for the construction of new materials at the macroscopic scale with desired structure. In this way, crystals can be built that have applications in, e.g., photonics, acting as filters for light of certain frequencies or as light guides.

You can find illustrations of the ‘diamond’ and the ‘cube’ produced by Capone and her colleagues with the news release on EurekAlert or here at the University of Vienna’s media portal where you may be able to find more information if you can read German. Alternatively, you can read the research paper,

Telechelic Star Polymers as Self-Assembling Units from the Molecular to the Macroscopic Scale by Barbara Capone, Ivan Coluzza, Federica LoVerso, Christos N. Likos, and Ronald Blaak in Physical Review Letters 109 [issue no. 23], 238301 (2012) [5 pages]DOI:10.1103/PhysRevLett.109.238301

This article is behind a paywall.