Posts Tagged ‘graphene’

Making a graphene micro-supercapacitor with a home DVD burner

Thursday, February 21st, 2013

Not all science research and breakthroughs require massive investments of money, sometimes all you need is a home DVD burner as this Feb. 19, 2013 news release on EurekAlert notes,

While the demand for ever-smaller electronic devices has spurred the miniaturization of a variety of technologies, one area has lagged behind in this downsizing revolution: energy-storage units, such as batteries and capacitors.

Now, Richard Kaner, a member of the California NanoSystems Institute at UCLA and a professor of chemistry and biochemistry, and Maher El-Kady, a graduate student in Kaner’s laboratory, may have changed the game.

The UCLA researchers have developed a groundbreaking technique that uses a DVD burner to fabricate micro-scale graphene-based supercapacitors — devices that can charge and discharge a hundred to a thousand times faster than standard batteries. These micro-supercapacitors, made from a one-atom–thick layer of graphitic carbon, can be easily manufactured and readily integrated into small devices such as next-generation pacemakers.

The new cost-effective fabrication method, described in a study published this week in the journal Nature Communications, holds promise for the mass production of these supercapacitors, which have the potential to transform electronics and other fields.

“Traditional methods for the fabrication of micro-supercapacitors involve labor-intensive lithographic techniques that have proven difficult for building cost-effective devices, thus limiting their commercial application,” El-Kady said. “Instead, we used a consumer-grade LightScribe DVD burner to produce graphene micro-supercapacitors over large areas at a fraction of the cost of traditional devices. [emphasis mine] Using this technique, we have been able to produce more than 100 micro-supercapacitors on a single disc in less than 30 minutes, using inexpensive materials.”

The University of California at Los Angeles (UCLA) Feb. 19, 2013 news release written by David Malasarn, the origin of the EurekAlert news release, features more information about the process,

The process of miniaturization often relies on flattening technology, making devices thinner and more like a geometric plane that has only two dimensions. In developing their new micro-supercapacitor, Kaner and El-Kady used a two-dimensional sheet of carbon, known as graphene, which only has the thickness of a single atom in the third dimension.
Kaner and El-Kady took advantage of a new structural design during the fabrication. For any supercapacitor to be effective, two separated electrodes have to be positioned so that the available surface area between them is maximized. This allows the supercapacitor to store a greater charge. A previous design stacked the layers of graphene serving as electrodes, like the slices of bread on a sandwich. While this design was functional, however, it was not compatible with integrated circuits.
In their new design, the researchers placed the electrodes side by side using an interdigitated pattern, akin to interwoven fingers. This helped to maximize the accessible surface area available for each of the two electrodes while also reducing the path over which ions in the electrolyte would need to diffuse. As a result, the new supercapacitors have more charge capacity and rate capability than their stacked counterparts.
Interestingly, the researchers found that by placing more electrodes per unit area, they boosted the micro-supercapacitor’s ability to store even more charge.
Kaner and El-Kady were able to fabricate these intricate supercapacitors using an affordable and scalable technique that they had developed earlier. They glued a layer of plastic onto the surface of a DVD and then coated the plastic with a layer of graphite oxide. Then, they simply inserted the coated disc into a commercially available LightScribe optical drive — traditionally used to label DVDs — and took advantage of the drive’s own laser to create the interdigitated pattern. The laser scribing is so precise that none of the “interwoven fingers” touch each other, which would short-circuit the supercapacitor.
“To label discs using LightScribe, the surface of the disc is coated with a reactive dye that changes color on exposure to the laser light. Instead of printing on this specialized coating, our approach is to coat the disc with a film of graphite oxide, which then can be directly printed on,” Kaner said. “We previously found an unusual photo-thermal effect in which graphite oxide absorbs the laser light and is converted into graphene in a similar fashion to the commercial LightScribe process. With the precision of the laser, the drive renders the computer-designed pattern onto the graphite oxide film to produce the desired graphene circuits.”
“The process is straightforward, cost-effective and can be done at home,” El-Kady said. “One only needs a DVD burner and graphite oxide dispersion in water, which is commercially available at a moderate cost.”
The new micro-supercapacitors are also highly bendable and twistable, making them potentially useful as energy-storage devices in flexible electronics like roll-up displays and TVs, e-paper, and even wearable electronics.

The reference to e-paper and roll-up displays calls to mind work being done at Queen’s University (Kingston, Canada) and Roel Vertegaal’s work on bendable, flexible phones and computers (my Jan. 9, 2013 posting). Could this work on micro-supercapacitors have an impact on that work?

Here’s an image (supplied by UCLA) of the micro-supercapacitors ,

Kaner and El-Kady's micro-supercapacitors

Kaner and El-Kady’s micro-supercapacitors

UCLA has  also supplied a video of Kaner and El-Kady discussing their work,

Interestingly this video has been supported by GE (General Electric), a company which seems to be doing a great deal to be seen on the internet these days as per my Feb. 11, 2013 posting titled, Visualizing nanotechnology data with Seed Media Group and GE (General Electric).

Getting back to the researchers, they are looking for industry partners as per Malasarn’s news release.

AAAS 2013 meeting in Boston,US and Canadian research excellence

Thursday, February 7th, 2013

The 2013 annual meeting for the American Association for the Advancement of Science (AAAS) will be held in Boston, Massachusetts from Feb. 14 – 18, 2013 with a much better theme this year, The Beauty and Benefits of Science, than last year’s, Flattening the World. (It didn’t take much to improve the theme, eh?)

Plenary speakers range from AAAS’s president, William N. Press to Nathan Myhrvold, a venture capitalist to astrophysicist, Robert Kirshner to Cynthia Kenyon, a molecular biologist to Sherry Turkle. From the AAAS webpage describing Turkle’s 2013 plenary lecture,

Sherry Turkle

Abby Rockefeller Mauzé Professor of the Social Studies of Science and Technology in the Program in Science, Technology, and Society, MIT

The Robotic Moment: What Do We Forget When We Talk to Machines?

Dr. Turkle is founder and director of the MIT Initiative on Technology and Self. She received a joint doctorate in sociology and personality psychology from Harvard University and is a licensed clinical psychologist. Her research focuses on the psychology of human relationships with technology, especially in the realm of how people relate to computational objects. She is an expert on mobile technology, social networking, and sociable robotics and a regular media commentator on the social and psychological effects of technology. Her most recent book is Alone Together: Why We Expect More from Technology and Less from Each Other.

Given my experience last year in the 2012 meeting media room, I’m surprised to see a social media session is planned, from the session webpage,

Engaging with Social Media
Communicating Science
Thursday, February 14, 2013: 3:00 PM-4:30 PM
Ballroom A (Hynes Convention Center)

In a constantly changing online landscape, what is the best way for scientists and engineers to engage the public through social media? This session will discuss how people are accessing science information via blogs and social networks and the importance of researchers getting involved directly. [emphasis mine]  Speakers will address the ways that researchers can create meaningful interactions with the public through social media.

Organizer: Cornelia Dean, The New York Times
Co-Organizer: Dennis Meredith, Science Communication Consultant
Moderator: Carl Zimmer, Independent Science Journalist

Speakers:
XXXX Scicurious, Neurotic Physiology
Science Blogging for Fun and Profit
Christie Wilcox, University of Hawaii
Science in a Digital Age
Dominique Brossard, University of Wisconsin
Science and the Public in New Information Environments

I’d love to see how the theme of ‘researcher engaging directly’ gets developed. In theory, I have no problems with the concept. Unfortunately, those words are sometimes code for this perspective, ‘only experts (scientists/accredited journalists) should discuss or write about science’. A couple of quick comments, my Jan. 13, 2012 posting featured an interview with Carl Zimmer, this session’s moderator, about his science tattoo book and Dominique Brossard, one of the speakers, was last mentioned here in my Jan. 24, 2013 posting titled, Tweet your nano, in the context of a research study on social media and nanotechnology.

In keeping with the times (as per my Jan. 28, 2013 posting about the colossal research prizes for the Graphene and Human Brain Project initiatives), the 2012 AAAS annual meeting features a Brain Function and Plasticity thread or subtheme. There’s this session amongst others,

The Connectome: From the Synapse to Brain Networks in Health and Disease
Brain Function and Plasticity
Saturday, February 16, 2013: 8:30 AM-11:30 AM
Room 304 (Hynes Convention Center)

A series of innovative studies are being done to map the brain from the molecular to the systems level both structurally and functionally. At the synaptic level, how neurotransmitters, their receptors, and signaling pathways influence neural function and plasticity is becoming much better understood. Integrating neuronal function at the level of single neurons and groups of neurons into larger circuits at the anatomical level in the mammalian brain, while a daunting task, is being studied by advanced imaging techniques requiring vast amounts of information storage and processing. To integrate local circuit function with whole brain function, understanding the structure and processing of brain networks is critical. A major project to accomplish this task, the Human Connectome Project, is in the process of integrating the structure and function of brain networks using the most advanced imaging and analysis techniques in 1,200 people, including twins and their nontwin siblings. This step will allow for major new insights into not only brain structure and function, but also their genetic underpinnings. Comparing this information in both the normal brain and in different brain disorders such as neurodegenerative diseases is providing novel insights into how understanding brain function from the molecular to the systems level will provide insights into normal brain function and disease pathogenesis as well as provide new treatment strategies.

Organizer:

David Holtzman, Washington University

Speakers:

Mark F. Bear, Massachusetts Institute of Technology
Molecules and Mechanisms Involved in Synaptic Plasticity in Health and Disease
Jeff Lichtman, Harvard University
Connectomics: Developing a Wiring Diagram for the Mammalian Brain
Steve Petersen, Washington University
The Human Connectome Project
Marcus E. Raichle, Washington University
The Brain’s Dark Energy and the Default Mode Network
Nicole Calakos, Duke University
Synaptic Plasticity in the Basal Ganglia in Health and Disease
William W. Seeley, University of California
Brain Networks: Linking Structure and Function in Neurodegenerative Diseases

Then, there’s this session featuring graphene,

What’s Hot in Cold
Sunday, February 17, 2013: 8:30 AM-11:30 AM
Room 308 (Hynes Convention Center)

The study of ultracold atoms and molecules is now the frontier of low-temperature science, reaching temperatures of a few hundred picokelvin above absolute zero. This field was made possible by a technique that did not exist 30 years ago: laser cooling of atoms. It is hardly obvious that the laser, which produces the most intense light on Earth and is routinely used in industrial applications for cutting and welding medal, would also provide the most powerful coolant. Such are the surprises of science, where a breakthrough in one area transforms others in unexpected ways. Since 1997, eight Nobel Laureates in physics have been recognized for contributions to ultracold atomic and molecular science, which has become one of the most vibrant fields in physics, cutting across traditional disciplinary boundaries, e.g., atomic, molecular, and optical; condensed matter; statistical physics; and nuclear and particle physics. This field builds on two accomplishments that it was the first to achieve: first, the production of quantum degenerate matter using a wide range of elements and, second, exquisite control of quantum degenerate matter at the atomic level. These have led to record low temperatures, ultraprecise atomic clocks, and new forms of quantum matter that generalize ideas from magnetism superconductivity and graphene physics.

Organizer:

Charles W. Clark, Joint Quantum Institute

Speakers:

Markus Greiner, Harvard University
Quantum Simulation: A Microscopic View of Quantum Matter
Ana Maria Rey, University of Colorado
Atomic Clocks: From Precise Timekeepers to Quantum Simulators
Daniel Greif, ETH Zurich
Exploring Dirac Points with Ultracold Fermions in a Tunable Honeycomb Lattice
Gretchen Campbell, Joint Quantum Institute
Superflow in Bose-Einstein Condensate Rings: Tunable Weak Links in Atom Circuits
Benjamin Lev, Stanford University
New Physics in Strongly Magnetic Ultracold Gases

Amongst all these other sessions, there’s a session about Canadian science,

Introduction to Canadian Research Excellence: Evidence & Examples
Friday, February 15, 2013: 11:00 AM-12:00 PM
Room 205 (Hynes Convention Center)

The Canada Pavilion in the Exhibit Hall gives a taste of what lies north of Boston and the 49th parallel. Join us at this workshop to learn about opportunities in Canada for research and study. Canada recently completed a comprehensive analysis of its domestic science and technology strengths. The final report of the expert panel of the Council of Canadian Academies will be presented, including the use of global benchmarks and insights on international collaborations. Two of the drivers for Canadian excellence will be introduced: large-scale science facilities in key fields and a system of targeted fellowships and research chairs that recruit globally.

Coordinator:

Tim Meyer, TRIUMF

Presenters:

Tim Meyer, TRIUMF,
Chad Gaffield, Social Sciences and Humanities Research Council of Canada
Eliot Phillipson, University of Toronto

“Introduced,” really? Large scale science facilities are not new in Canada or anywhere else for that matter and the programmes of targeted fellowships have been around long enough and successful enough that it is being copied.

First, there was the Canada Research Chair programme, which was instituted in 2000. From the About Us page (Note: A link has been removed),

The Canada Research Chairs program stands at the centre of a national strategy to make Canada one of the world’s top countries in research and development. [emphasis mine]

In 2000, the Government of Canada created a permanent program to establish 2000 research professorships—Canada Research Chairs—in eligible degree-granting institutions across the country.

The Canada Research Chairs program invests $300 million per year to attract and retain some of the world’s most accomplished and promising minds.

This was programme was followed up with the Canada Excellence Research Chairs Program in 2008, from the Background page (Note: A link has been removed),

Launched in 2008, the Canada Excellence Research Chairs (CERC) Program supports Canadian universities in their efforts to build on Canada’s growing reputation as a global leader in research and innovation. The program awards world-renowned researchers and their teams up to $10 million over seven years to establish ambitious research programs at Canadian universities. These awards are among the most prestigious and generous available globally.

In May 2010, the first group of Canada Excellence Research Chairs was announced. Selected through a rigorous, multilevel peer review process, these chairholders are helping Canada build a critical mass of expertise in the four priority research areas of the federal government’s science and technology strategy …

Here’s an excerpt from my Feb. 21, 2012 posting,

Canadians have been throwing money at scientists for some years now (my May 20, 2010 posting about the Canada Excellence Research Chairs programme). We’ve attempted to recruit from around the world with our ‘research chairs’ and our ‘excellence research chairs’ and our Network Centres of Excellence (NCE) all serving as enticements.

The European Research Council (ERC) has announced that they will be trying to beat us at our own game at the AAAS 2012 annual meeting in Vancouver (this new ERC programme was launched in Boston, Massachusetts in January 2012).

The Canadian report these folks will be discussing was released in Sept. 2012 and was  featured here in a two-part commentary,

The State of Science and Technology in Canada, 2012 report—examined (part 1: the executive summary)

The State of Science and Technology in Canada, 2012 report—examined (part 2: the rest of the report)

My Sept. 27, 2012 posting features my response to the report’s launch on that day.

As for the AAAS 2013 annual meeting, there’s a lot, lot more of it and it’s worth checking out, if for no other reason than to anticipate the types of science stories you will be seeing in the coming months.

Graphene and its grain boundaries

Wednesday, January 16th, 2013

Most folks who follow the graphene scene are familiar with the honeycomb structure (hexagonal network) shown in diagram after diagram but I imagine there’s more than one of us who didn’t realize that defects can occur at the boundaries, from the Jan. 15, 2012 news release on EurekAlert,

When graphene is grown, lattices of the carbon grains are formed randomly, linked together at different angles of orientation in a hexagonal network. However, when those orientations become misaligned during the growth process, defects called grain boundaries (GBs) form. These boundaries scatter the flow of electrons in graphene, a fact that is detrimental to its successful electronic performance.

The Jan. 14, 2013 University of Illinois Beckman Institute news release written by Steve McGoughey, which originated the item on  EurekAlert, provides insight into the problem and its solution,

Beckman Institute researchers Joe Lyding and Eric Pop and their research groups have now given new insight into the electronics behavior of graphene with grain boundaries that could guide fabrication methods toward lessening their effect. The researchers grew polycrystalline graphene by chemical vapor deposition (CVD), using scanning tunneling microscopy (STM) and spectroscopy for analysis, to examine at the atomic scale grain boundaries on a silicon wafer. They reported their results in the journal ACS Nano.

“We obtained information about electron scattering at the boundaries that shows it significantly limits the electronic performance compared to grain boundary free graphene,” Lyding said. “Grain boundaries form during graphene growth by CVD, and, while there is much worldwide effort to minimize the occurrence of grain boundaries, they are a fact of life for now.

“For electronics you would want to be able to make it on a wafer scale. Boundary free graphene is a key goal. In the interim we have to live with the grain boundaries, so understanding them is what we’re trying to do.”

Lyding compared graphene lattices made with the CVD method to pieces of a cyclone fence.

“If you had two pieces of fence, and you laid them on the ground next to each other but they weren’t perfectly aligned, then they wouldn’t match,” he said. “That’s a grain boundary, where the lattice doesn’t match.”

Their analysis showed that when the electrons’ itinerary takes them to a grain boundary, it is like, Lyding said, hitting a hill.

“The electrons hit this hill, they bounce off, they interfere with themselves and you actually see a standing wave pattern,” he said. “It’s a barrier so they have to go up and over that hill. Like anything else, that is going to slow them down. That’s what Justin was able to measure with these spectroscopy measurements.

“Basically a grain boundary is a resistor in series with a conductor. That’s always bad. It means it’s going to take longer for an electron to get from point A to point B with some voltage applied.”

In the paper, the researchers were able to report on their analysis of the orientation angles between pieces of graphene as they grew together, and found “no preferential orientation angle between grains, and the GBs are continuous across graphene wrinkles and Si02 topography.” They reported that analysis of those patterns “indicates that backscattering and intervalley scattering are the dominant mechanisms responsible for the mobility reduction in the presence of GBs in CVD-grown graphene.”

The researchers work is aimed not just at understanding, but also at controlling grain boundaries. One of their findings – that GBs are aperiodic – replicated other work and could have implications for controlling them, as they wrote in the paper: “Combining the spectroscopic and scattering results suggest that GBs that are more periodic and well-ordered lead to reduced scattering from the GBs.”

“I think if you have to live with grain boundaries you would like to be able to control exactly what their orientation is and choose an angle that minimizes the scattering,” Lyding said.

Here’s a citation and link for the article,

Atomic-Scale Evidence for Potential Barriers and Strong Carrier Scattering at Graphene Grain Boundaries: A Scanning Tunneling Microscopy Study by Justin C. Koepke, Joshua D. Wood, David Estrada, Zhun-Yong Ong, Kevin T. He, Eric Pop, and Joseph W. Lyding in ACS Nano, Article ASAP DOI: 10.1021/nn302064p Publication Date (Web): December 13, 2012

Copyright © 2012 American Chemical Society

The article has not been published in print and it is behind a paywall.

National Graphene Institute at the UK’s University of Manchester

Monday, January 14th, 2013

It will house the UK’s graphene research efforts according to the Jan. 14, 2013 news item Nanowerk,

This is the first glimpse of the new £61m research institute into wonder material graphene, which is to be built at The University of Manchester.

The stunning, glass-fronted National Graphene Institute (NGI) will be the UK’s home of research into the world’s thinnest, strongest and most conductive material, providing the opportunity for researchers and industry to work together on a huge variety of potential applications.

The University of Manchester Jan. 14, 2013 news release, which originated the news item, spells out some of the hopes and dreams along with descriptions of the building plans,

It is hoped the centre will initially create around 100 jobs, with the long-term expectation of many thousands more in the North West and more widely in the UK.

The 7,600 square metre building will house state-of-the-art facilities, including two ‘cleanrooms’ – one which will take up the whole of the lower ground floor – where scientists can carry out experiments and research without contamination.

The Institute will also feature a 1,500 square metre research lab for University of Manchester graphene scientists to collaborate with their colleagues from industry and other UK universities.

Funding for the NGI will come from £38m from the Government, as part of £50m allocated for graphene research, and the University has applied for £23m from the European Research and Development Fund (ERDF). The NGI will operate as a ‘hub and spoke’ model, working with other UK institutions involved in graphene research.

Some of the world’s leading companies are also expected to sign up to work at the NGI, where they will be offered the chance to work on cutting edge projects, across various sectors, with Nobel Laureates and other leading members of the graphene team.

Graphene, isolated for the first time at The University of Manchester by Professor Andre Geim and Professor Kostya Novoselov in 2004, has the potential to revolutionise a huge number of diverse applications; from smartphones and ultrafast broadband to drug delivery and computer chips.


Professor Colin Bailey, Vice-President and Dean of the Faculty of Engineering and Physical Sciences, added: “The National Graphene Institute will be the world’s leading centre of graphene research, combining the expertise of University of Manchester academics with their counterparts at other UK universities and with leading global commercial organisations.

“The potential for its impact on the city and the North West is huge, and will be one of the most exciting centres of cutting edge research in the UK.”

Work is set to start on the five-story NGI, which will have its entrance on Booth Street East, in March, and is expected to be completed in early 2015.

UK National Graphene Institute (NGI) Illustration courtesy of the University of Manchester, UK

UK National Graphene Institute (NGI) Illustration courtesy of the University of Manchester, UK

The University of Manchester is one of the institutions that forms the Graphene Flagship consortium which is currently competing for one of two European Union prizes of 1 Billion Euros for research to be awarded later this year.

Latest on UK and graphene

Friday, December 28th, 2012

The Brits are at it again with another graphene funding announcement, from the Dec. 28, 2012 news item on Azonano,

The Chancellor of the Exchequer, George Osborne MP, today announced £21.5 million of capital investment to commercialise graphene, one of the thinnest, lightest, strongest and most conductive materials to have been discovered, marked by the 2010 Nobel Prize in Physics as one of the world’s most ground breaking scientific achievements.

Three research projects at Imperial will share the Engineering and Physical Sciences Research Council (EPSRC) funding as part of a new programme with a number of industrial partners, including aeroplane manufacturer Airbus. The scientists receiving the grant hope to develop graphene technologies that will contribute to the UK economy and can be applied by industries around the world.

The Imperial College of London Dec. 27, 2012 news release, which originated the item, describes how the college’s £4.5M award will be used for three of its graphene projects,

In one project worth £1.35 million, led by Professor Tony Kinloch from the Department of Mechanical Engineering with colleagues from the Departments of Chemistry and Chemical Engineering, researchers will explore how combining graphene with current materials can improve the properties of aeroplane parts, such as making them resistant to lightning-strikes. They hope the same technology can also be used to develop coatings for wind-turbine blades, to make them scratch resistant and physically tougher in extreme weather conditions.

Professor Eduardo Saiz, from the Department of Materials, will develop new manufacturing processes using liquids that contain tiny suspended particles of graphene, in order to reduce the cost of currently expensive industrial techniques. This project will receive £1.91 million funding and involves scientists from Imperial’s Departments of Chemistry and Chemical Engineering, and Queen Mary, University of London.

£1.37 million of funding received by Professor Norbert Klein, also from the Department of Materials and shared with Imperial’s Department of Physics, will pay for new equipment to deposit extremely thin sheets of graphene, so scientists can explore its electrical properties. They hope that new medical scanning technology may be developed as a result of how graphene responds to high frequency electromagnetic waves, from microwave to terahertz frequencies and all the way to the wavelengths of visible light.

As noted on numerous occasions here  (most recently in an Oct. 11, 2012 posting), there is a competition for two prizes of 1 billion Euros each to be awarded to two European research projects in the European Union’s Future and Emerging Technologies Initiatives (FET). There are six flagship projects (whittled down from a larger number a few years ago) competing to be one of the two winners. There’s more about the FET Graphene Flagship project here. As you might expect, the Brits are heavily involved in the graphene flagship project.

Hydro-Québec, graphite, and lithium-ion batteries

Tuesday, November 27th, 2012

While Dexter Johnson at Nanoclast blog writes about an investigation into why the storage capacity of lithium-ion (Li-ion) batteries degrades in his Nov. 26, 2012 posting (Newly Developed Live Nanoscale Imaging Technique Promises Improvement in Li-ion Batteries), Hydro-Québec and Grafoid Inc. have signed a development deal for the next generation of lithium iron phosphate materials to be combined with graphene for next generation rechargeable batteries. From the Nov. 27, 2012 news item on Nanowerk,

The 50-50 collaborative agreement sets out terms with the objective of creating patentable inventions by combining graphene, supplied by Grafoid, with Hydro-Québec’s patented lithium iron phosphate technologies.

Two key, specific commercial target markets – the rechargeable automobile battery sectors and batteries for mobile electronic devices used in smartphones, computing tablets and laptop computers – were identified in the agreement.

Hydro-Québec will study Grafoid’s graphene conductivity, electrochemical performance and its effects in electrode formulations, electrolyte and separator optimizations. Detailed characterizations of Grafoid’s supplied materials will be undertaken at IREQ’s cutting edge facilities using its advanced electron microscopy, spectrographic and other in-house technologies.

Hydro-Québec will also supply lithium iron phosphate materials and its electrochemistry know how which it acquired under license from famed American inventor Dr. John Goodenough.

The Nov. 26, 2012 news release from Focus Graphite, which originated the news item, provides additional detail about the various principles in the deal,

About Focus Graphite

Focus Graphite Inc. is an emerging mid-tier junior mining development company, a technology solutions supplier and a business innovator. Focus is the owner of the Lac Knife graphite deposit located in the Côte-Nord region of northeastern Québec. The Lac Knife project hosts a NI 43-101 compliant Measured and Indicated mineral resource of 4.972 Mt grading 15.7% carbon as crystalline graphite with an additional Inferred mineral resource of 3.000 Mt grading 15.6% crystalline graphite  Focus’ goal is to assume an industry leadership position by becoming a low-cost producer of technology-grade graphite. On October 29th, 2012 the Company released the results of a Preliminary Economic Analysis (“PEA”) of the Lac Knife project which demonstrates that the project has robust economics and excellent potential to become a profitable producer of graphite.  As a technology-oriented enterprise with a view to building long-term, sustainable shareholder value, Focus Graphite is also investing in the development of graphene applications and patents through Grafoid Inc.

About Grafoid Inc.

Grafoid, Inc. is a privately held Canadian corporation investing in graphene applications and economically scalable production processes for graphene and graphene derivatives from raw, unprocessed, graphite ore. Focus Graphite Inc., (TSX-V: FMS; OTCQX: FCSMF; FSE: FKC) holds a 40% interest in Grafoid Inc. [emphasis mine]

About IREQ

Hydro-Québec’s research institute, IREQ, is a global leader in the development of advanced materials for battery manufacturing and creates leading edge processes from its state of the art facilities. IREQ holds more than 100 patent rights and has issued over 40 licenses for battery materials to some of the world’s most successful battery manufacturers and materials suppliers. Its areas of expertise include energy storage and IREQ is a lead partner with private sector companies in Québec to build EV and HEV charging stations in support of its technology developments. Its material development contributions are helping to develop safe, high-performance lithium ion batteries that can be charged more quickly and a greater number of times. IREQ promotes open innovation and partners with private firms, universities, government agencies and research centers in Québec and abroad. Its partnerships allow IREQ to develop, industrialize and market technologies resulting from those innovation projects.

About Hydro-Québec

Hydro-Québec is Canada’s largest electricity producer among the world’s largest hydroelectric power producers and a public utility that generates, transmits and distributes electricity. Its sole shareholder is the Québec government. It primarily exploits renewable generating options, in particular hydropower, and supports the development of wind energy through purchases from independent power producers. Its research institute, IREQ, conducts R&D in energy efficiency, energy storage and other energy-related fields. Hydro-Québec invests more than $100 million per year in research.

Here’s one last bit I want to highlight from the Focus Graphite news release,

“Commercially, and ultimately, our technology development partnership with Hydro-Québec aims to produce high capacity, LFP-graphene batteries with ultra short charging times and longer recyclable lifetimes,” Mr. Economo said [Gary Economo, President and Chief Executive Officer of both Grafoid Inc. and Focus Graphite].

He said the parties chose to focus their collaboration on LFP-graphene batteries and materials because of their short-term-to-market potential.

In light of Dexter’s very informative posting about Li-ion batteries and the investigation into why the storage capatcity degrades, I find this Hydro-Québec/Grafoid Inc. development provides insight into the relationship between scientific research and business and insight into the risks as the various groups compete to bring products to market or to improve those products such that they come to dominate the market.

One last comment, graphite flakes are also mined in Ontario as per both my July 25, 2011 posting and my Feb. 6, 2012 posting about Northern Graphite Corporation and its Bissett Creek mine.

Nano crafts class: get out your ‘paper’ and scissors

Thursday, November 15th, 2012

It’s not all atomic force microscopy and nanotweezers as scientists keep reminding us that the techniques we learned in kindergarten can be all the high technology we need even when working at the nanoscale. From the Nov. 14, 2012 news item on ScienceDaily,

Two Northwestern University researchers have discovered a remarkably easy way to make nanofluidic devices: using paper and scissors. And they can cut a device into any shape and size they want, adding to the method’s versatility.

The Nov. 14, 2012 Northwestern University news release by Megan Fellman explains both nanofluidic devices and the new technique,

Nanofluidic devices are attractive because their thin channels can transport ions — and with them a higher than normal electric current — making the devices promising for use in batteries and new systems for water purification, harvesting energy and DNA sorting.

The “paper-and-scissors” method one day could be used to manufacture large-scale nanofluidic devices without relying on expensive lithography techniques.

The Northwestern duo found that simply stacking up sheets of the inexpensive material graphene oxide creates flexible “paper” with tens of thousands of very useful channels. A tiny gap forms naturally between neighboring sheets, and each gap is a channel through which ions can flow.

Using a pair of regular scissors, the researchers simply cut the paper into a desired shape, which, in the case of their experiments, was a rectangle.

“In a way, we were surprised that these nanochannels actually worked, because creating the device was so easy,” said Jiaxing Huang, who conducted the research with postdoctoral fellow Kalyan Raidongia. “No one had thought about the space between sheet-like materials before. Using the space as a flow channel was a wild idea. We ran our experiment at least 10 times to be sure we were right.”

The process is a little more complex than kindergarten crafts (from Fellman’s news release),

To create a working device, the researchers took a pair of scissors and cut a piece of their graphene oxide paper into a centimeter-long rectangle. They then encased the paper in a polymer, drilled holes to expose the ends of the rectangular piece and filled up the holes with an electrolyte solution (a liquid containing ions) to complete the device.

Next they put electrodes at both ends and tested the electrical conductivity of the device. Huang and Raidongia observed higher than normal current, and the device worked whether flat or bent.

The nanochannels have significantly different — and desirable — properties from their bulk channel counterparts, Huang said. The nanochannels have a concentrating effect, resulting in an electric current much higher than those in bulk solutions.

Graphene oxide is basically graphene sheets decorated with oxygen-containing groups. It is made from inexpensive graphite powders by chemical reactions known for more than a century.

Scaling up the size of the device is simple. Tens of thousands of sheets or layers create tens of thousands of nanochannels, each channel approximately one nanometer high. There is no limit to the number of layers — and thus channels — one can have in a piece of paper.

To manufacture very massive arrays of channels, one only needs to put more graphene oxide sheets in the paper or to stack up many pieces of paper. A larger device, of course, can handle larger quantities of electrolyte.

Kindergarten techniques worked well for Andre Geim and Konstantin Novoselov who received Nobel prizes for their work on graphene (from my Oct. 7,2010 posting),

The technique that Geim and Novoselov used to create the first graphene sheets both amuses and fascinates me (from the article by Kit Eaton on the Fast Company website),

The two scientists came up with the technique that first resulted in samples of graphene–peeling individual atoms-deep sheets of the material from a bigger block of pure graphite. The science here seems almost foolishly simple, but it took a lot of lateral thinking to dream up, and then some serious science to investigate: Geim and Novoselo literally “ripped” single sheets off the graphite by using regular adhesive tape.

Then, there’s the ‘Shrinky Dinks’ nanopatterning technique (from my Aug. 16,2010 posting),

Scientists at a Northwestern University laboratory have taken to using a children’s arts and crafts product, Shrinky Dinks, for a new way to create large area nanoscale patterns on the cheap.

It’s good to be reminded that science at its heart is not about expensive equipment and complicated techniques but a means of exploring the world around us with the means at hand.

Tooth tattoos at Tufts University

Friday, November 9th, 2012

In spring 2012, there was a fluttering in the blogosphere about tooth tattoos with the potential for monitoring dental health. As sometimes happens, I put off posting about the work until it seemed everyone else had written about it (e.g. Mar. 30, 2012 posting by Dexter Johnson for his Nanoclast blog on the IEEE website) and there was nothing left for me to say.  Happily, the researchers at Tufts University (where part of this research [Princeton University is also involved] is being pursued) have released more information in a Nov. 1, 2012 news article by David Levin,

The sensor, dubbed a “tooth tattoo,” was developed by the Princeton nanoscientist Michael McAlpine and Tufts bioengineers Fiorenzo Omenetto, David Kaplan and Hu Tao. The team first published their research last spring in the journal Nature Communications.

The sensor is relatively simple in its construction, says McAlpine. It’s made up of just three layers: a sheet of thin gold foil electrodes, an atom-thick layer of graphite known as graphene and a layer of specially engineered peptides, chemical structures that “sense” bacteria by binding to parts of their cell membranes.

“We created a new type of peptide that can serve as an intermediary between bacteria and the sensor,” says McAlpine. “At one end is a molecule that can bond with the graphene, and at the other is a molecule that bonds with bacteria,” allowing the sensor to register the presence of bacteria, he says.

Because the layers of the device are so thin and fragile, they need to be mounted atop a tough but flexible backing in order to transfer them to a tooth. The ideal foundation, McAlpine says, turns out to be silk—a substance with which Kaplan and Omenetto have been working for years.

By manipulating the proteins that make up a single strand of silk, it’s possible to create silk structures in just about any shape, says Omenetto, a professor of biomedical engineering at Tufts. Since 2005, he’s created dozens of different structures out of silk, from optical lenses to orthopedic implants. Silk is “kind of like plastic, in that we can make [it] do almost anything,” he says. “We have a lot of control over the material. It can be rigid. It can be flexible. We can make it dissolve in water, stay solid, become a gel—whatever we need.”

Omenetto, Kaplan and Tao created a thin, water-soluble silk backing for McAlpine’s bacterial sensor—a film that’s strong enough to hold the sensor components in place, but soft and pliable enough to wrap easily around the irregular contours of a tooth.

To apply the sensor, McAlpine says, you need only to wet the surface of the entire assembly—silk, sensor and all—and then press it onto the tooth. Once there, the silk backing will dissolve within 15 or 20 minutes, leaving behind the sensor, a rectangle of interwoven gold and black electrodes about half the size of a postage stamp and about as thick as a sheet of paper. The advantage of being attached directly to a tooth means that the sensor is in direct contact with bacteria in the mouth—an ideal way to monitor oral health.

Because the sensor doesn’t carry any onboard batteries, it must be both read and powered simultaneously through a built-in antenna. Using a custom-made handheld device about the size of a TV remote, McAlpine’s team can “ping” that antenna with radio waves, causing it to resonate electronically and send back information that the device then uses to determine if bacteria are present.

The sensor (A), attached to a tooth (B) and activated by radio signals (C), binds with certain bacteria (D). Illustration: Manu Mannoor/Nature Communications (downloaded from http://now.tufts.edu/articles/tooth-tattoo)

In addition to its potential for  monitoring dental health, the tooth tattoo could replace some of the more invasive health monitoring techniques (e.g., drawing blood), from the Tufts University article,

In addition to monitoring oral health, Kugel [Gerard Kugel, Tufts professor of prosthodontics and operative dentistry and associate dean for research at Tufts School of Dental Medicine] believes the tooth tattoo might be useful for monitoring a patient’s overall health. Biological markers for many diseases—from stomach ulcers to AIDS—appear in human saliva, he says. So if a sensor could be modified to react to those markers, it potentially could help dentists identify problems early on and refer patients to a physician before a condition becomes serious.

“The mouth is a window to the rest of the body,” Kugel says. “You can spot a lot of potential health problems through saliva, and it’s a much less invasive way to do diagnostic tests than drawing blood.”

Before monitoring of any type can take place, there is at least one major hurdle still be overcome. Humans are quite sensitive to objects being placed in their mouths. According to one of the researchers, we can sense objects that are 50 to 60 microns wide, about the thickness piece of paper, and that may be too uncomfortable to bear.

H/T Nov. 9, 2012 news item on Nanowerk for pointing me towards the latest information about these tooth tattoos.

Follow the ‘graphene brick’ road

Thursday, October 11th, 2012

Today (Oct. 11, 2012), I’m highlighting a second article in Nature. This time it’s a “A roadmap for graphene ” (behind a paywall) in the Oct. 11, 2012 online issue of Nature written by Nobel Prize-winner Professor Kostya Novoselov of the University of Manchester; V. I. Fal′ko Department of Physics, Lancaster University;  L. Colombo, Texas Instruments Incorporated; P. R. Gellert, AstraZeneca; M. G. Schwab, BASF SE; and K. Kim, Samsung Advanced Institute of Technology.

If you can get behind the paywall, the article offers excellent insight into the state of graphene research and the state of graphene applications.  The authors cover:

Challenges in Production

Chemical vapour deposition

Synthesis on SiC

Other growth methods

Graphene electronics

Flexible electronics

High-frequency transistors

Logic transistor

Photonics

Photodetectors

Optical modulator

Mode-locked laser/THz generator

Optical polarization controller

Composite materials, paints, and coating

Energy generation and storage

Graphene for sensors and metrology

Bioapplications

You can get more details about the article from the Oct. 11, 2012 news release from the University of Manchester,

The authors estimate that the first graphene touchscreen devices could be on the market within three to five years, but will only realise its full potential in flexible electronics applications.

Rollable e-paper is another application which should be available as a prototype by 2015 – graphene’s flexibility proving ideal for fold-up electronic sheets which could revolutionise electronics.

Timescales for applications vary greatly upon the quality of graphene required, the report claims. For example, the researchers estimate devices including photo-detectors, high-speed wireless communications and THz generators (for use in medical imaging and security devices) would not be available until at least 2020, while anticancer drugs and graphene as a replacement for silicon is unlikely to become a reality until around 2030.

I notice the lead authors are from the University of Manchester and Lancaster University. These UK educational institutions are part of the FET (Future and Emerging Technologies) GRAPHENE-CA flagship project, which is in competition for one of two prizes of 1B Euros for research. As I’ve noted previously in my Feb. 21, 2012 posting and many others, the UK is leading a tremendous public relations/marketing campaign on behalf of this project and the UK’s own interests. Good luck to them as I believe the announcement of which are the two winning projects from a field of six should be made in the next few months.

The current international infatuation with roadmaps sometimes reminds me of The Wizard of Oz and the Yellow Brick Road,

I always appreciate the optimism shown by the lead character, Dorothy, as she takes off for parts unknown.

Graphene, replacing silicon, and epitaxial growth

Monday, October 1st, 2012

Researchers in Norway have created a semiconductor on a graphene substrate—absolutely no silicon in the substrate. From the Sept. 28, 2012 news item on Nanowerk,

Norwegian researchers are the world’s first to develop a method for producing semiconductors from graphene. This finding may revolutionise the technology industry.
The method involves growing semiconductor-nanowires on graphene. To achieve this, researchers “bomb” the graphene surface with gallium atoms and arsenic molecules, thereby creating a network of minute nanowires.
The result is a one-micrometre thick hybrid material which acts as a semiconductor. By comparison, the silicon semiconductors in use today are several hundred times thicker. The semiconductors’ ability to conduct electricity may be affected by temperature, light or the addition of other atoms.

The Research Council of Norway’s Sept.28, 2012 news release, which originated the news item, offers this,

Graphene is the thinnest material known, and at the same time one of the strongest. It consists of a single layer of carbon atoms and is both pliable and transparent. The material conducts electricity and heat very effectively. And perhaps most importantly, it is very inexpensive to produce.

“Given that it’s possible to make semiconductors out of graphene instead of silicon, we can make semiconductor components that are both cheaper and more effective than the ones currently on the market,” explains Helge Weman of the Norwegian University of Science and Technology (NTNU). Dr Weman is behind the breakthrough discovery along with Professor Bjørn-Ove Fimland.

“A material comprising a pliable base that is also transparent opens up a world of opportunities, one we have barely touched the surface of,” says Dr Weman. “This may bring about a revolution in the production of solar cells and LED components. Windows in traditional houses could double as solar panels or a TV screen. Mobile phone screens could be wrapped around the wrist like a watch. In short, the potential is tremendous.”

The researchers have patented this work and founded a startup company, CrayoNano. They provide a video animation of the process,

The narrator mentions epataxial growth and the gallium arsenide nanowires being grown on the graphene substrate. For anyone not familiar with ‘epataxial growth’, I found a definition in another Sept. 28, 2012 news item about graphene research on Nanowerk,

One of the best ways of producing high quality graphene is to grow it epitaxially (in layers) from crystals of silicon carbide. For use in electronic devices, it is important to be able to count the number of graphene layers that are grown, as single and double layers of graphene have different electrical properties.

This research out of the UK is based on using silicon as a substrate and you can find out more (excerpted from the  news item about the National Physical Laboratory’s graphene research on Nanowerk),

Recent National Physical Laboratory research, published in the Journal of Applied Physics (“Identification of epitaxial graphene domains and adsorbed species in ambient conditions using quantified topography measurements” [open access]), looked at different topography approaches of determining graphene thickness and investigated the factors that can influence the accuracy of the results, such as atmospheric water and other adsorbates on the graphene surface.

Getting back to graphene substrates, the Research Council of Norway’s news release provides the reminder that this research is about business,

The researchers will now begin to create prototypes directed towards specific areas of application. They have been in contact with giants in the electronics industry such as Samsung and IBM. “There is tremendous interest in producing semiconductors out of graphene, so it shouldn’t be difficult to find collaborative partners,” Dr Weman adds.

The researchers are hoping to have the new semiconductor hybrid materials on the commercial market in roughly five years.

Dexter Johnson in a Sept. 28, 2012 posting on his Nanoclast blog, which is hosted by the IEEE (Institute of Electrical and Electronics Engineers), provides some business perspective,

Weman notes: “Companies like IBM and Samsung are driving this development in the search for a replacement for silicon in electronics as well as for new applications, such as flexible touch screens for mobile phones. Well, they need not wait any more. Our invention fits perfectly with the production machinery they already have. We make it easy for them to upgrade consumer electronics to a level where design has no limits.”

As magnanimous as Weman’s invitation sounds, one can’t help but think it comes from concern. The prospect of a five-year-development period before a product gets to market might be somewhat worrying for a group of scientists who just launched a new startup. A nice licensing agreement from one of the big electronics companies must look appealing right about now.