Tag Archives: Greece

Historic and other buildings get protection from pollution?

This Sept. 15, 2017 news item on Nanowerk announces a new product for protecting buildings from pollution,

The organic pollution decomposing properties of titanium dioxide (TiO2 ) have been known for about half a century. However, practical applications have been few and hard to develop, but now a Greek paint producer claims to have found a solution

A Sept. 11, 2017 Youris (European Research Media Center) press release by Koen Mortelmans which originated the news item expands on the theme,

The photocatalytic properties of anatase, one of the three naturally occurring forms of titanium dioxide, were discovered in Japan in the late 1960s. Under the influence of the UV-radiation in sunlight, it can decompose organic pollutants such as bacteria, fungi and nicotine, and some inorganic materials into carbon dioxide. The catalytic effect is caused by the nanostructure of its crystals.

Applied outdoors, this affordable and widely available material could represent an efficient self-cleaning solution for buildings. This is due to the chemical reaction, which leaves a residue on building façades, a residue then washed away when it rains. Applying it to monuments in urban areas may save our cultural heritage, which is threatened by pollutants.

However, “photocatalytic paints and additives have long been a challenge for the coating industry, because the catalytic action affects the durability of resin binders and oxidizes the paint components,” explains Ioannis Arabatzis, founder and managing director of NanoPhos, based in the Greek town of Lavrio, in one of the countries home to some of the most important monuments of human history. The Greek company is testing a paint called Kirei, inspired by a Japanese word meaning both clean and beautiful.

According to Arabatzis, it’s an innovative product because it combines the self-cleaning action of photocatalytic nanoparticles and the reflective properties of cool wall paints. “When applied on exterior surfaces this paint can reflect more than 94% of the incident InfraRed radiation (IR), saving energy and reducing costs for heating and cooling”, he says. “The reflection values are enhanced by the self-cleaning ability. Compared to conventional paints, they remain unchanged for longer.”

The development of Kirei has been included in the European project BRESAER (BREakthrough Solutions for Adaptable Envelopes in building Refurbishment) which is studying a sustainable and adaptable “envelope system” to renovate buildings. The new paint was tested and subjected to quality controls following ISO standard procedures at the company’s own facilities and in other independent laboratories. “The lab results from testing in artificial, accelerated weathering conditions are reliable,” Arabatzis claims. “There was no sign of discolouration, chalking, cracking or any other paint defect during 2,000 hours of exposure to the simulated environmental conditions. We expect the coating’s service lifetime to be at least ten years.”

Many studies are being conducted to exploit the properties of titanium dioxide. Jan Duyzer, researcher at the Netherlands Organisation for Applied Scientific Research (TNO) in Utrecht, focused on depollution: “There is no doubt about the ability of anatase to decrease the levels of nitrogen oxides in the air. But in real situations, there are many differences in pollution, wind, light, and temperature. We were commissioned by the Dutch government specifically to find a way to take nitrogen oxides out of the air on roads and in traffic tunnels. We used anatase coated panels. Our results were disappointing, so the government decided to discontinue the research. Furthermore, we still don’t know what caused the difference between lab and life. Our best current hypothesis is that the total surface of the coated panels is very small compared to the large volumes of polluted air passing over them,” he tells youris.com.

Experimental deployment of titanium dioxide panels on an acoustic wall along a Dutch highway – Courtesy of Netherlands Organisation for Applied Scientific Research (TNO)

“In laboratory conditions the air is blown over the photocatalytic surface with a certain degree of turbulence. This results in the NOx-particles and the photocatalytic material coming into full contact with one another,” says engineer Anne Beeldens, visiting professor at KU Leuven, Belgium. Her experience with photocatalytic TiO2 is also limited to nitrogen dioxide (NOx) pollution.

In real applications, the air stream at the contact surface becomes laminar. This results in a lower velocity of the air at the surface and a lower depollution rate. Additionally, not all the air will be in contact with the photocatalytic surfaces. To ensure a good working application, the photocatalytic material needs to be positioned so that all the air is in contact with the surface and flows over it in a turbulent manner. This would allow as much of the NOx as possible to be in contact with photocatalytic material. In view of this, a good working application could lead to a reduction of 5 to 10 percent of NOx in the air, which is significant compared to other measures to reduce pollutants.”

The depollution capacity of TiO2 is undisputed, but most applications and tests have only involved specific kinds of substances. More research and measurements are required if we are to benefit more from the precious features of this material.

I think the most recent piece here on protecting buildings, i.e., the historic type, from pollution is an Oct. 21, 2014 posting: Heart of stone.

Sustainable Nanotechnologies (SUN) project draws to a close in March 2017

Two Oct. 31, 2016 news item on Nanowerk signal the impending sunset date for the European Union’s Sustainable Nanotechnologies (SUN) project. The first Oct. 31, 2016 news item on Nanowerk describes the projects latest achievements,

The results from the 3rd SUN annual meeting showed great advancement of the project. The meeting was held in Edinburgh, Scotland, UK on 4-5 October 2016 where the project partners presented the results obtained during the second reporting period of the project.

SUN is a three and a half year EU project, running from 2013 to 2017, with a budget of about €14 million. Its main goal is to evaluate the risks along the supply chain of engineered nanomaterials and incorporate the results into tools and guidelines for sustainable manufacturing.

The ultimate goal of the SUN Project is the development of an online software Decision Support System – SUNDS – aimed at estimating and managing occupational, consumer, environmental and public health risks from nanomaterials in real industrial products along their lifecycles. The SUNDS beta prototype has been released last October, 2015, and since then the main focus has been on refining the methodologies and testing them on selected case studies i.e. nano-copper oxide based wood preserving paint and nano- sized colourants for plastic car part: organic pigment and carbon black. Obtained results and open issues were discussed during the third annual meeting in order collect feedbacks from the consortium that will inform, in the next months, the implementation of the final version of the SUNDS software system, due by March 2017.

An Oct. 27, 2016 SUN project press release, which originated the news item, adds more information,

Significant interest has been payed towards the results obtained in WP2 (Lifecycle Thinking) which main objectives are to assess the environmental impacts arising from each life cycle stage of the SUN case studies (i.e. Nano-WC-Cobalt (Tungsten Carbide-cobalt) sintered ceramics, Nanocopper wood preservatives, Carbon Nano Tube (CNT) in plastics, Silicon Dioxide (SiO2) as food additive, Nano-Titanium Dioxide (TiO2) air filter system, Organic pigment in plastics and Nanosilver (Ag) in textiles), and compare them to conventional products with similar uses and functionality, in order to develop and validate criteria and guiding principles for green nano-manufacturing. Specifically, the consortium partner COLOROBBIA CONSULTING S.r.l. expressed its willingness to exploit the results obtained from the life cycle assessment analysis related to nanoTiO2 in their industrial applications.

On 6th October [2016], the discussions about the SUNDS advancement continued during a Stakeholder Workshop, where representatives from industry, regulatory and insurance sectors shared their feedback on the use of the decision support system. The recommendations collected during the workshop will be used for the further refinement and implemented in the final version of the software which will be released by March 2017.

The second Oct. 31, 2016 news item on Nanowerk led me to this Oct. 27, 2016 SUN project press release about the activities in the upcoming final months,

The project has designed its final events to serve as an effective platform to communicate the main results achieved in its course within the Nanosafety community and bridge them to a wider audience addressing the emerging risks of Key Enabling Technologies (KETs).

The series of events include the New Tools and Approaches for Nanomaterial Safety Assessment: A joint conference organized by NANOSOLUTIONS, SUN, NanoMILE, GUIDEnano and eNanoMapper to be held on 7 – 9 February 2017 in Malaga, Spain, the SUN-CaLIBRAte Stakeholders workshop to be held on 28 February – 1 March 2017 in Venice, Italy and the SRA Policy Forum: Risk Governance for Key Enabling Technologies to be held on 1- 3 March in Venice, Italy.

Jointly organized by the Society for Risk Analysis (SRA) and the SUN Project, the SRA Policy Forum will address current efforts put towards refining the risk governance of emerging technologies through the integration of traditional risk analytic tools alongside considerations of social and economic concerns. The parallel sessions will be organized in 4 tracks:  Risk analysis of engineered nanomaterials along product lifecycle, Risks and benefits of emerging technologies used in medical applications, Challenges of governing SynBio and Biotech, and Methods and tools for risk governance.

The SRA Policy Forum has announced its speakers and preliminary Programme. Confirmed speakers include:

  • Keld Alstrup Jensen (National Research Centre for the Working Environment, Denmark)
  • Elke Anklam (European Commission, Belgium)
  • Adam Arkin (University of California, Berkeley, USA)
  • Phil Demokritou (Harvard University, USA)
  • Gerard Escher (École polytechnique fédérale de Lausanne, Switzerland)
  • Lisa Friedersdor (National Nanotechnology Initiative, USA)
  • James Lambert (President, Society for Risk Analysis, USA)
  • Andre Nel (The University of California, Los Angeles, USA)
  • Bernd Nowack (EMPA, Switzerland)
  • Ortwin Renn (University of Stuttgart, Germany)
  • Vicki Stone (Heriot-Watt University, UK)
  • Theo Vermeire (National Institute for Public Health and the Environment (RIVM), Netherlands)
  • Tom van Teunenbroek (Ministry of Infrastructure and Environment, The Netherlands)
  • Wendel Wohlleben (BASF, Germany)

The New Tools and Approaches for Nanomaterial Safety Assessment (NMSA) conference aims at presenting the main results achieved in the course of the organizing projects fostering a discussion about their impact in the nanosafety field and possibilities for future research programmes.  The conference welcomes consortium partners, as well as representatives from other EU projects, industry, government, civil society and media. Accordingly, the conference topics include: Hazard assessment along the life cycle of nano-enabled products, Exposure assessment along the life cycle of nano-enabled products, Risk assessment & management, Systems biology approaches in nanosafety, Categorization & grouping of nanomaterials, Nanosafety infrastructure, Safe by design. The NMSA conference key note speakers include:

  • Harri Alenius (University of Helsinki, Finland,)
  • Antonio Marcomini (Ca’ Foscari University of Venice, Italy)
  • Wendel Wohlleben (BASF, Germany)
  • Danail Hristozov (Ca’ Foscari University of Venice, Italy)
  • Eva Valsami-Jones (University of Birmingham, UK)
  • Socorro Vázquez-Campos (LEITAT Technolоgical Center, Spain)
  • Barry Hardy (Douglas Connect GmbH, Switzerland)
  • Egon Willighagen (Maastricht University, Netherlands)
  • Nina Jeliazkova (IDEAconsult Ltd., Bulgaria)
  • Haralambos Sarimveis (The National Technical University of Athens, Greece)

During the SUN-caLIBRAte Stakeholder workshop the final version of the SUN user-friendly, software-based Decision Support System (SUNDS) for managing the environmental, economic and social impacts of nanotechnologies will be presented and discussed with its end users: industries, regulators and insurance sector representatives. The results from the discussion will be used as a foundation of the development of the caLIBRAte’s Risk Governance framework for assessment and management of human and environmental risks of MN and MN-enabled products.

The SRA Policy Forum: Risk Governance for Key Enabling Technologies and the New Tools and Approaches for Nanomaterial Safety Assessment conference are now open for registration. Abstracts for the SRA Policy Forum can be submitted till 15th November 2016.
For further information go to:

There you have it.

YBC 7289: a 3,800-year-old mathematical text and 3D printing at Yale University

1,300 years before Pythagoras came up with the theorem associated with his name, a school kid in Babylon formed a disc out of clay and scratched out the theorem when the surface was drying.  According to an April 12, 2016 news item on phys.org the Bablyonians got to the theorem first, (Note: A link has been removed),

Thirty-eight hundred years ago, on the hot river plains of what is now southern Iraq, a Babylonian student did a bit of schoolwork that changed our understanding of ancient mathematics. The student scooped up a palm-sized clump of wet clay, formed a disc about the size and shape of a hamburger, and let it dry down a bit in the sun. On the surface of the moist clay the student drew a diagram that showed the people of the Old Babylonian Period (1,900–1,700 B.C.E.) fully understood the principles of the “Pythagorean Theorem” 1300 years before Greek geometer Pythagoras was born, and were also capable of calculating the square root of two to six decimal places.

Today, thanks to the Internet and new digital scanning methods being employed at Yale, this ancient geometry lesson continues to be used in modern classrooms around the world.

Just when you think it’s all about the theorem, the story which originated in an April 11, 2016 Yale University news release by Patrick Lynch takes a turn,

“This geometry tablet is one of the most-reproduced cultural objects that Yale owns — it’s published in mathematics textbooks the world over,” says Professor Benjamin Foster, curator of the Babylonian Collection, which includes the tablet. It’s also a popular teaching tool in Yale classes. “At the Babylonian Collection we have a very active teaching and learning function, and we regard education as one of the core parts of our mission,” says Foster. “We have graduate and undergraduate groups in our collection classroom every week.”

The tablet, formally known as YBC 7289, “Old Babylonian Period Mathematical Text,” came to Yale in 1909 as part of a much larger collection of cuneiform tablets assembled by J. Pierpont Morgan and donated to Yale. In the ancient Mideast cuneiform writing was created by using a sharp stylus pressed into the surface of a soft clay tablet to produce wedge-like impressions representing pictographic words and numbers. Morgan’s donation of tablets and other artifacts formed the nucleus of the Yale Babylonian Collection, which now incorporates 45,000 items from the ancient Mesopotamian kingdoms.

Discoverying [sic] the tablet’s mathematical significance

The importance of the geometry tablet was first recognized by science historians Otto Neugebauer and Abraham Sachs in their 1945 book “Mathematical Cuneiform Texts.”

“Ironically, mathematicians today are much more fascinated with the Babylonians’ ability to accurately calculate irrational numbers like the square root of two than they are with the geometry demonstrations,” notes associate Babylonian Collection curator Agnete Lassen.

“The Old Babylonian Period produced many tablets that show complex mathematics, but it also produced things you might not expect from a culture this old, such as grammars, dictionaries, and word lists,” says Lassen “One of the two main languages spoken in early Babylonia  was dying out, and people were careful to document and save what they could on cuneiform tablets. It’s ironic that almost 4,000 years ago people were thinking about cultural preservation, [emphasis mine] and actively preserving their learning for future generations.”.

This business about ancient peoples trying to preserve culture and learning for future generations suggests that the efforts in Palmyra, Syria (my April 6, 2016 post about 3D printing parts of Palmyra) are born of an age-old impulse. And then the story takes another turn and becomes a 3D printing story (from the Yale University news release),

Today, however, the tablet is a fragile lump of clay that would not survive routine handling in a classroom. In looking for alternatives that might bring the highlights of the Babylonian Collection to a wider audience, the collection’s curators partnered with Yale’s Institute for the Preservation of Cultural Heritage (IPCH) to bring the objects into the digital world.

Scanning at the IPCH

The IPCH Digitization Lab’s first step was to do reflectance transformation imaging (RTI) on each of fourteen Babylonian Collection objects. RTI is a photographic technique that enables a student or researcher to look at a subject with many different lighting angles. That’s particularly important for something like a cuneiform tablet, where there are complex 3D marks incised into the surface. With RTI you can freely manipulate the lighting, and see subtle surface variations that no ordinary photograph would reveal.

Chelsea Graham of the IPCH Digitization Lab and her colleague Yang Ying Yang of the Yale Computer Graphics Group then did laser scanning of the tablet to create a three-dimensional geometric model that can be freely rotated onscreen. The resulting 3D models can be combined with many other types of digital imaging to give researchers and students a virtual tablet onscreen, and the same data can be use to create a 3D printed facsimile that can be freely used in the classroom without risk to the delicate original.
3D printing digital materials

While virtual models on the computer screen have proved to be a valuable teaching and research resource, even the most accurate 3D model on a computer screen doesn’t convey the tactile  impact, and physicality of the real object. Yale’s Center for Engineering Innovation and Design has collaborated with the IPCH on a number of cultural heritage projects, and the center’s assistant director, Joseph Zinter, has used its 3D printing expertise on a wide range of engineering, basic science, and cultural heritage projects.

“Whether it’s a sculpture, a rare skull, or a microscopic neuron or molecule highly magnified, you can pick up a 3D printed model and hold it, and it’s a very different and important way to understand the data. Holding something in your hand is a distinctive learning experience,” notes Zinter.

Sharing cultural heritage projects in the digital world

Once a cultural artifact has entered the digital world there are practical problems with how to share the information with students and scholars. IPCH postdoctoral fellows Goze Akoglu and Eleni Kotoula are working with Yale computer science faculty member Holly Rushmeier to create an integrated collaborative software platform to support the research and sharing of cultural heritage artifacts like the Babylonian tablet.

“Right now cultural heritage professionals must juggle many kinds of software, running several types of specialized 2D and 3D media viewers as well as conventional word processing and graphics programs. Our vision is to create a single virtual environment that accommodates many kinds of media, as well as supporting communication and annotation within the project,” says Kotoula.

The wide sharing and disseminating of cultural artifacts is one advantage of digitizing objects, notes professor Rushmeier, “but the key thing about digital is the power to study large virtual collections. It’s not about scanning and modeling the individual object. When the scanned object becomes part of a large collection of digital data, then machine learning and search analysis tools can be run over the collection, allowing scholars to ask questions and make comparisons that aren’t possible by other means,” says Rushmeier.

Reflecting on the process that brings state-of-the-art digital tools to one of humanity’s oldest forms of writing, Graham said “It strikes me that this tablet has made a very long journey from classroom to classroom. People sometimes think the digital or 3D-printed models are just a novelty, or just for exhibitions, but you can engage and interact much more with the 3D printed object, or 3D model on the screen. I think the creators of this tablet would have appreciated the efforts to bring this fragile object back to the classroom.”

There is also a video highlighting the work,

Greece and Russia agree to cooperate on quantum and nanotechnology research

I don’t often get a chance to feature Greece here but an April 4, 2016 news item on tornos news (and also on ANAmpa: Athens News Agency [and] Macedonian Press Agency) provides an opportunity,

Greece’s Alternate Minister for Research and Innovation Costas Fotakis and Russian Federation Deputy Minister for Education and Science Ludmila Ogorodova on Friday [April 1, 2016] signed an agreement for cooperation between the two countries in specialist new technologies, such as quantum technology, nanotechnology and related areas.

According to an announcement, the agreement covers four innovative applications in quantum nano-electronics, nanophotonics, quantum information-communication and metamaterials. It extends an invitation to research and technology centres, universities and even public and private research companies to submit proposals in the area of quantum technologies by the end of next June. It envisages financing of up to one million euros in each of the four proposed areas, for programmes to be implemented over 24-36 months.

In spite of the difficult conditions created by the economic crisis, Greece has research centres that have achieved international acclaim and excellence in the emerging field of quantum technology,

So it seems Greece is supplying the quantum expertise and Russia the nanotechnology expertise. It’s a bit surprising that Anatoly Chubais isn’t mentioned since every reference that I’ve ever seen to Russian nanotechnology includes his name as the head of Russia’s state-funded RUSNANO (Russian Nanotechnology Corporation).

A study in contrasts: innovation and education strategies in US and British Columbia (Canada)

It’s always interesting to contrast two approaches to the same issue, in this case, innovation and education strategies designed to improve the economies of the United States and of British Columbia, a province in Canada.

One of the major differences regarding education in the US and in Canada is that the Canadian federal government, unlike the US federal government, has no jurisdiction over the matter. Education is strictly a provincial responsibility.

I recently wrote a commentary (a Jan. 19, 2016 posting) about the BC government’s Jan. 18, 2016 announcement of its innovation strategy in a special emphasis on the education aspect. Premier Christy Clark focused largely on the notion of embedding courses on computer coding in schools from K-12 (kindergarten through grade 12) as Jonathon Narvey noted in his Jan. 19, 2016 event recap for Betakit,

While many in the tech sector will be focused on the short-term benefits of a quick injection of large capital [a $100M BC Tech Fund as part of a new strategy was announced in Dec. 2015 but details about the new #BCTECH Strategy were not shared until Jan. 18, 2016], the long-term benefits for the local tech sector are being seeded in local schools. More than 600,000 BC students will be getting basic skills in the K-12 curriculum, with coding academies, more work experience electives and partnerships between high school and post-secondary institutions.

Here’s what I had to say in my commentary (from the Jan. 19, 2016 posting),

… the government wants to embed  computer coding into the education system for K-12 (kindergarten to grade 12). One determined reporter (Canadian Press if memory serves) attempted to find out how much this would cost. No answer was forthcoming although there were many words expended. Whether this failure was due to ignorance (disturbing!) or a reluctance to share (also disturbing!) was impossible to tell. Another reporter (Georgia Straight) asked about equipment (coding can be taught with pen and paper but hardware is better). … Getting back to the reporter’s question, no answer was forthcoming although the speaker was loquacious.

Another reporter asked if the government had found any jurisdictions doing anything similar regarding computer coding. It seems they did consider other jurisdictions although it was claimed that BC is the first to strike out in this direction. Oddly, no one mentioned Estonia, known in some circles as E-stonia, where the entire school system was online by the late 1990s in an initiative known as the ‘Tiger Leap Foundation’ which also supported computer coding classes in secondary school (there’s more in Tim Mansel’s May 16, 2013 article about Estonia’s then latest initiative to embed computer coding into grade school.) …

Aside from the BC government’s failure to provide details, I am uncomfortable with what I see as an overemphasis on computer coding that suggests a narrow focus on what constitutes a science and technology strategy for education. I find the US approach closer to what I favour although I may be biased since they are building their strategy around nanotechnology education.

The US approach had been announced in dribs and drabs until recently when a Jan. 26, 2016 news item on Nanotechnology Now indicated a broad-based plan for nanotechnology education (and computer coding),

Over the past 15 years, the Federal Government has invested over $22 billion in R&D under the auspices of the National Nanotechnology Initiative (NNI) to understand and control matter at the nanoscale and develop applications that benefit society. As these nanotechnology-enabled applications become a part of everyday life, it is important for students to have a basic understanding of material behavior at the nanoscale, and some states have even incorporated nanotechnology concepts into their K-12 science standards. Furthermore, application of the novel properties that exist at the nanoscale, from gecko-inspired climbing gloves and invisibility cloaks, to water-repellent coatings on clothes or cellphones, can spark students’ excitement about science, technology, engineering, and mathematics (STEM).

An earlier Jan. 25, 2016 White House blog posting by Lisa Friedersdorf and Lloyd Whitman introduced the notion that nanotechnology is viewed as foundational and a springboard for encouraging interest in STEM (science, technology, engineering, and mathematics) careers while outlining several formal and information education efforts,

The Administration’s updated Strategy for American Innovation, released in October 2015, identifies nanotechnology as one of the emerging “general-purpose technologies”—a technology that, like the steam engine, electricity, and the Internet, will have a pervasive impact on our economy and our society, with the ability to create entirely new industries, create jobs, and increase productivity. To reap these benefits, we must train our Nation’s students for these high-tech jobs of the future. Fortunately, the multidisciplinary nature of nanotechnology and the unique and fascinating phenomena that occur at the nanoscale mean that nanotechnology is a perfect topic to inspire students to pursue careers in science, technology, engineering, and mathematics (STEM).

The Nanotechnology: Super Small Science series [mentioned in my Jan. 21, 2016 posting] is just the latest example of the National Nanotechnology Initiative (NNI)’s efforts to educate and inspire our Nation’s students. Other examples include:

The announcement about computer coding and courses being integrated in the US education curricula K-12 was made in US President Barack Obama’s 2016 State of the Union speech and covered in a Jan. 30, 2016 article by Jessica Hullinger for Fast Company,

In his final State Of The Union address earlier this month, President Obama called for providing hands-on computer science classes for all students to make them “job ready on day one.” Today, he is unveiling how he plans to do that with his upcoming budget.

The President’s Computer Science for All Initiative seeks to provide $4 billion in funding for states and an additional $100 million directly to school districts in a push to provide access to computer science training in K-12 public schools. The money would go toward things like training teachers, providing instructional materials, and getting kids involved in computer science early in elementary and middle school.

There are more details in the Hullinger’s article and in a Jan. 30, 2016 White House blog posting by Megan Smith,

Computer Science for All is the President’s bold new initiative to empower all American students from kindergarten through high school to learn computer science and be equipped with the computational thinking skills they need to be creators in the digital economy, not just consumers, and to be active citizens in our technology-driven world. Our economy is rapidly shifting, and both educators and business leaders are increasingly recognizing that computer science (CS) is a “new basic” skill necessary for economic opportunity and social mobility.

CS for All builds on efforts already being led by parents, teachers, school districts, states, and private sector leaders from across the country.

Nothing says one approach has to be better than the other as there’s usually more than one way to accomplish a set of goals. As well, it’s unfair to expect a provincial government to emulate the federal government of a larger country with more money to spend. I just wish the BC government (a) had shared details such as the budget allotment for their initiative and (b) would hint at a more imaginative, long range view of STEM education.

Going back to Estonia one last time, in addition to the country’s recent introduction of computer coding classes in grade school, it has also embarked on a nanotechnology/nanoscience educational and entrepreneurial programme as noted in my Sept. 30, 2014 posting,

The University of Tartu (Estonia) announced in a Sept. 29, 2014 press release an educational and entrepreneurial programme about nanotechnology/nanoscience for teachers and students,

To bring nanoscience closer to pupils, educational researchers of the University of Tartu decided to implement the European Union LLP Comenius project “Quantum Spin-Off – connecting schools with high-tech research and entrepreneurship”. The objective of the project is to build a kind of a bridge: at one end, pupils can familiarise themselves with modern science, and at the other, experience its application opportunities at high-tech enterprises. “We also wish to inspire these young people to choose a specialisation related to science and technology in the future,” added Lukk [Maarika Lukk, Coordinator of the project].

The pupils can choose between seven topics of nanotechnology: the creation of artificial muscles, microbiological fuel elements, manipulation of nanoparticles, nanoparticles and ionic liquids as oil additives, materials used in regenerative medicine, deposition and 3D-characterisation of atomically designed structures and a topic covered in English, “Artificial robotic fish with EAP elements”.

Learning is based on study modules in the field of nanotechnology. In addition, each team of pupils will read a scientific publication, selected for them by an expert of that particular field. In that way, pupils will develop an understanding of the field and of scientific texts. On the basis of the scientific publication, the pupils prepare their own research project and a business plan suitable for applying the results of the project.

In each field, experts of the University of Tartu will help to understand the topics. Participants will visit a nanotechnology research laboratory and enterprises using nanotechnologies.

The project lasts for two years and it is also implemented in Belgium, Switzerland and Greece.

As they say, time will tell.

Memristor shakeup

New discoveries suggest that memristors do not function as was previously theorized. (For anyone who wants a memristor description, there’s this Wikipedia entry.) From an Oct. 13, 2015 posting by Alexander Hellemans for the Nanoclast blog (on the IEEE [Institute for Electrical and Electronics Engineers]), Note: Links have been removed,

What’s going to replace flash? The R&D arms of several companies including Hewlett Packard, Intel, and Samsung think the answer might be memristors (also called resistive RAM, ReRAM, or RRAM). These devices have a chance at unseating the non-volatile memory champion because, they use little energy, are very fast, and retain data without requiring power. However, new research indicates that they don’t work in quite the way we thought they do.

The fundamental mechanism at the heart of how a memristor works is something called an “imperfect point contact,” which was predicted in 1971, long before anybody had built working devices. When voltage is applied to a memristor cell, it reduces the resistance across the device. This change in resistance can be read out by applying another, smaller voltage. By inverting the voltage, the resistance of the device is returned to its initial value, that is, the stored information is erased.

Over the last decade researchers have produced two commercially promising types of memristors: electrochemical metallization memory (ECM) cells, and valence change mechanism memory (VCM) cells.

Now international research teams lead by Ilia Valov at the Peter Grünberg Institute in Jülich, Germany, report in Nature Nanotechnology and Advanced Materials that they have identified new processes that erase many of the differences between EMC and VCM cells.

Valov and coworkers in Germany, Japan, Korea, Greece, and the United States started investigating memristors that had a tantalum oxide electrolyte and an active tantalum electrode. “Our studies show that these two types of switching mechanisms in fact can be bridged, and we don’t have a purely oxygen type of switching as was believed, but that also positive [metal] ions, originating from the active electrode, are mobile,” explains Valov.

Here are links to and citations for both papers,

Graphene-Modified Interface Controls Transition from VCM to ECM Switching Modes in Ta/TaOx Based Memristive Devices by Michael Lübben, Panagiotis Karakolis, Vassilios Ioannou-Sougleridis, Pascal Normand, Pangiotis Dimitrakis, & Ilia Valov. Advanced Materials DOI: 10.1002/adma.201502574 First published: 10 September 2015

Nanoscale cation motion in TaOx, HfOx and TiOx memristive systems by Anja Wedig, Michael Luebben, Deok-Yong Cho, Marco Moors, Katharina Skaja, Vikas Rana, Tsuyoshi Hasegawa, Kiran K. Adepalli, Bilge Yildiz, Rainer Waser, & Ilia Valov. Nature Nanotechnology (2015) doi:10.1038/nnano.2015.221 Published online 28 September 2015

Both papers are behind paywalls.

Superposition in biological processes

Applying the concept of superposition to photosynthesis and olfaction is not the first thought that would have occurred to me on stumbling across the European Union’s PAPETS project (Phonon-Assisted Processes for Energy Transfer and Sensing). Thankfully, a July 9, 2015 news item on Nanowerk sets the record straight (Note: A link has been removed),

Quantum physics is helping researchers to better understand photosynthesis and olfaction.

Can something be for instance in two different places at the same time? According to quantum physics, it can. More precisely, in line with the principle of ‘superposition’, a particle can be described as being in two different states simultaneously.

While it may sound like voodoo to the non-expert, superposition is based on solid science. Researchers in the PAPETS project are exploring this and other phenomena on the frontier between biology and quantum physics. Their goal is to determine the role of vibrational dynamics in photosynthesis and olfaction.

A July 7, 2015 research news article on the CORDIS website, which originated the news item, further explains (Note: A link has been removed),

Quantum effects in a biological system, namely in a photosynthetic complex, were first observed by Greg Engel and collaborators in 2007, in the USA. These effects were reproduced in different laboratories at a temperature of around -193 degrees Celsius and subsequently at ambient temperature.

‘What’s surprising and exciting is that these quantum effects have been observed in biological complexes, which are large, wet and noisy systems,’ says PAPETS project coordinator, Dr. Yasser Omar, researcher at Instituto de Telecomunicações and professor at Universidade de Lisboa [Portugal]. ‘Superposition is fragile and we would expect it to be destroyed by the environment.’

Superposition contributes to more efficient energy transport. An exciton, a quantum quasi-particle carrying energy, can travel faster along the photosynthetic complex due to the fact that it can exist in two states simultaneously. When it comes to a bifurcation it need not choose left or right. It can proceed down both paths simultaneously.

‘It’s like a maze,’ says Dr. Omar. ‘Only one door leads to the exit but the exciton can probe both left and right at the same time. It’s more efficient.’

Dr. Omar and his colleagues believe that a confluence of factors help superposition to be effected and maintained, namely the dynamics of the vibrating environment, whose role is precisely what the PAPETS project aims to understand and exploit.

Theory and experimentation meet

The theories being explored by PAPETS are also tested in experiments to validate them and gain further insights. To study quantum transport in photosynthesis, for example, researchers shoot fast laser pulses into biological systems. They then observe interference along the transport network, a signature of wavelike phenomena.

‘It’s like dropping stones into a lake,’ explains Dr. Omar. ‘You can then see whether the waves that are generated grow bigger or cancel each other when they meet.’

Applications: more efficient solar cells and odour detection

While PAPETS is essentially an exploratory project, it is generating insights that could have practical applications. PAPETS’ researchers are getting a more fundamental understanding of how photosynthesis works and this could result in the design of much more efficient solar cells.

Olfaction, the capacity to recognise and distinguish different odours, is another promising area. Experiments focus on the behaviour of Drosophila flies. So far, researchers suspect that the tunnelling of electrons associated to the internal vibrations of a molecule may be a signature of odour. Dr. Omar likens this tunnelling to a ping-pong ball resting in a bowl that goes through the side of the bowl to appear outside it.

This work could have applications in the food, water, cosmetics or drugs industries. Better artificial odour sensing could be used to detect impurities or pollution, for example.

‘Unlike seeing, hearing or touching, the sense of smell is difficult to reproduce artificially with high efficacy,’ says Dr. Omar.

The PAPETS project, involving 7 partners, runs from September 2014 to August 2016 and has a budgeted EU contribution funding of EUR 1.8 million.

You can find out more about PAPETS here. In the meantime, I found the other partners in the project (in addition to Portugal), from the PAPETS Partners webpage (Note: Links have been removed),

– Controlled Quantum Dynamics Group, Universität Ulm (UULM), Germany. PI: Martin Plenio and Susana Huelga.
– Biophysics Research Group, Vrije Universiteit Amsterdam (VUA), Netherlands. PI: Rienk van Grondelle and Roberta Croce.
– Department of Chemical Sciences, Università degli Studi di Padova (UNIPD), Italy. PI: Elisabetta Collini.
– Biomedical Sciences Research Centre “Alexander Fleming” (FLEMING), Athens, Greece. PI: Luca Turin and Efthimios M. Skoulakis.
– Biological Physics and Complex Systems Group, Centre National de la Recherche Scientifique (CNRS), Orléans, France. PI: Francesco Piazza.
– Quantum Physics of Biomolecular Processes, University College London (UCL), UK. PI: Alexandra Olaya-Castro.

NANoReg invites you to April 11, 2014 workshop in Athens, Greece

For anyone interested in nanomaterials and/or attending an EHS-themed (environment, health, and safety) event in Athens, Greece, NANoREG is holding an April 2014 workshop at the Industrial Technologies 2014 conference (April 9 – 11, 2014). From a March 14, 2014 news item on Nanowerk (Some links have been removed),

NANoREG will identify EHS [environment, health, and safety] aspects that are most relevant from a regulatory point of view. It will provide tools for testing the EHS aspects and the assessment and management of the risks to the regulators and other stakeholders.

To assure that the final results of the project can be implemented in an efficient and effective way, Industry and Regulators are strongly involved in the project.
We kindly invite you to attend the NANoREG workshop and to give your opinion on the regulatory testing of nanomaterials, as a valuable contribution to future economic success of nanotechnology!

The workshop will take place on Friday, April 11, 2014 from 11:15 a.m. to 1:30 p.m. in Athens, Greece, as part of the Industrial Technologies 2014 event. For registration please use the offi cial registration portal: www.naturalway.gr/industrial_technologies

Here’s more about the workshop from the NANoREG workshop page on the Industrial Technologies 2014 website,

1. The NANoREG approach: Answers from Science to the questions/needs of Industry and the Regulation Authorities.
2. First entrypoints, the regulatory questions and needs, an overview, matching of needs
3. NANoREG results: Materials, SOPs and the advancement of Regulatory Risk Assessment and Testing.
4.Overview of the NANoREG projects.
5. Whe window for industry participation, keeping pace with innovation.
6. Modes of collaboartion [sic] for industry.
7. Outlook

A joint workshops of EU FP7 Projects SANOWORK, nanoMICEX and Scaffold funded under the topic NMP.2011.1.3-2 “Worker Protection and exposure risk management strategies for nanomaterials production, use and disposal”, will focus on the main achievements of the three Projects in the related area. All three projects are committed to support the needs of companies and aim to provide a practical overview of the results of current research in the field of management of exposure to nanomaterials.

Here are links to the other three projects collaborating on the NANoREG workshop  SANOWORKnanoMICEX, and Scaffold.

600 BCE (before the common era) was a very good year for French wine

It’s quite the detective story, almost 20 years to unravel the mystery of where and when viniculture started in France. A Penn Museum June 3 (?), 2013 news release (also found on EurekAlert) provides some fascinating detail about the detective work and about wine,

9,000-year-old ancient Near Eastern ‘wine culture,’ traveling land and sea, reaches southern coastal France, via ancient Etruscans of Italy, in 6th-5th century BCE

Imported ancient Etruscan amphoras and a limestone press platform, discovered at the ancient port site of Lattara in southern France, have provided the earliest known biomolecular archaeological evidence of grape wine and winemaking—and point to the beginnings of a Celtic or Gallic vinicultural industry in France circa 500-400 BCE. Details of the discovery are published as “The Beginning of Viniculture in France” in the June 3, 2013 issue of Proceedings of the National Academy of Sciences (PNAS). Dr. Patrick McGovern, Director of the Biomolecular Archaeology Laboratory at the University of Pennsylvania Museum of Archaeology and Anthropology and author of Ancient Wine: The Search for the Origins of Viniculture (Princeton University Press, 2006) is the lead author on the paper, which was researched and written in collaboration with colleagues from France and the United States.

For Dr. McGovern, much of whose career has been spent examining the archaeological data, developing the chemical analyses, and following the trail of the Eurasian grapevine (Vitis vinifera) in the wild and its domestication by humans, this confirmation of the earliest evidence of viniculture in France is a key step in understanding the ongoing development of what he calls the “wine culture” of the world—one that began in the Turkey’s Taurus Mountains, [sic[ the Caucasus Mountains, and/or the Zagros Mountains of Iran about 9,000 years ago.

“Now we know that the ancient Etruscans lured the Gauls into the Mediterranean wine culture by importing wine into southern France. This built up a demand that could only be met by establishing a native industry, likely done by transplanting the domesticated vine from Italy, and enlisting the requisite winemaking expertise from the Etruscans.”

The news release provides a high level (general with too few details for my taste) description of the technology used for this research,

After sample extraction, ancient organic compounds were identified by a combination of state-of-the-art chemical techniques, including infrared spectrometry, gas chromatography-mass spectrometry, solid phase microextraction, ultrahigh-performance liquid chromatography tandem mass spectrometry, and one of the most sensitive techniques now available, used here for the first time to analyze ancient wine and grape samples, liquid chromatography-Orbitrap mass spectrometry.

All the samples were positive for tartaric acid/tartrate (the biomarker or fingerprint compound for the Eurasian grape and wine in the Middle East and Mediterranean), as well as compounds deriving from pine tree resin. Herbal additives to the wine were also identified, including rosemary, basil and/or thyme, which are native to central Italy where the wine was likely made. (Alcoholic beverages, in which resinous and herbal compounds are more easily put into solution, were the principle medications of antiquity.)

Nearby, an ancient pressing platform, made of limestone and dated circa 425 BCE, was discovered. Its function had previously been uncertain. Tartaric acid/tartrate was detected in the limestone, demonstrating that the installation was indeed a winepress. Masses of several thousand domesticated grape seeds, pedicels, and even skin, excavated from an earlier context near the press, further attest to its use for crushing transplanted, domesticated grapes and local wine production. Olives were extremely rare in the archaeobotanical corpus at Lattara until Roman times. This is the first clear evidence of winemaking on French soil.

Here’s what the ancient wine press looks like,

Caption: This is an ancient pressing platform from Lattara, seen from above. Note the spout for drawing off a liquid. It was raised off the courtyard floor by four stones. Masses of grape remains were found nearby. Credit: Photograph courtesy of Michael Py, copyright l'Unité de Fouilles et de Recherches Archéologiques de Lattes.

Caption: This is an ancient pressing platform from Lattara, seen from above. Note the spout for drawing off a liquid. It was raised off the courtyard floor by four stones. Masses of grape remains were found nearby.
Credit: Photograph courtesy of Michael Py, copyright l’Unité de Fouilles et de Recherches Archéologiques de Lattes.

Here’s how McGovern describes his work and its relationship to the history of viniculture in Europe and the ancient Near East, from the news release,

For nearly two decades, Dr. McGovern has been following the story of the origin and expansion of a worldwide “wine culture”—one that has its earliest known roots in the ancient Near East, circa 7000-6000 BCE, with chemical evidence for the earliest wine at the site of Hajji Firiz in what is now northern Iran, circa 5400-5000 BCE. Special pottery types for making, storing, serving and drinking wine were all early indicators of a nascent “wine culture.”

Viniculture—viticulture and winemaking—gradually expanded throughout the Near East. From the beginning, promiscuous domesticated grapevines crossed with wild vines, producing new cultivars. Dr. McGovern observes a common pattern for the spreading of the new wine culture: “First entice the rulers, who could afford to import and ostentatiously consume wine. Next, foreign specialists are commissioned to transplant vines and establish local industries,” he noted. “Over time, wine spreads to the larger population, and is integrated into social and religious life.”

Wine was first imported into Egypt from the Levant by the earliest rulers there, forerunners of the pharaohs, in Dynasty 0 (circa 3150 BCE). By 3000 BCE the Nile Delta was being planted with vines by Canaanite viniculturalists. As the earliest merchant seafarers, the Canaanites were also able to take the wine culture out across the Mediterranean Sea. Biomolecular archaeological evidence attests to a locally produced, resinated wine on the island of Crete by 2200 BCE.

“As the larger Greek world was drawn into the wine culture, “ McGovern noted, “the stage was set for commercial maritime enterprises in the western Mediterranean. Greeks and the Phoenicians—the Levantine successors to the Canaanites—vied for influence by establishing colonies on islands and along the coasts of North Africa, Italy, France, and Spain. The wine culture continued to take root in foreign soil—and the story continues today.”

Where wine went, so other cultural elements eventually followed—including technologies of all kinds and social and religious customs—even where another fermented beverage made from different natural products had long held sway. In the case of Celtic Europe, grape wine displaced a hybrid drink of honey, wheat/barley, and native wild fruits (e.g., lingonberry and apple) and herbs (such as bog myrtle, yarrow, and heath

I wonder why wine displaced Celtic Europe’s hybrid honey drink. Did wine taste better and/or did get folks drunk faster?

For anyone who’s interested in the research, here’s a link to and a citation for the paper,

Beginning of viniculture in France by Patrick E. McGovern, Benjamin P. Luley, Nuria Rovira, Armen Mirzoiand, Michael P. Callahane, Karen E. Smithf, Gretchen R. Halla, Theodore Davidsona, and Joshua M. Henkina. Published online before print June 3, 2013, doi: 10.1073/pnas.1216126110 PNAS June 3, 2013

The paper is behind a paywall.

Antikythera; ancient computer and a 100 year adventure

This post has been almost two years in the making, which seems laughable when considering that the story starts in 100 BCE (before the common era).

Picture ancient Greece and a Roman sailing ship holding an object we know as an Antikythera, named after the Greek island near where the ship was wrecked and where it lay undiscovered until 1900. From the Dec.10, 2010 posting by GrrlScientist on the Guardian science blogs,

Two years ago [2008], a paper was published in Nature describing the function of the oldest known scientific computer, a device built in Greece around 100 BCE. Recovered in 1901 from a shipwreck near the island of Antikythera, this mechanism had been lost and unknown for 2000 years. It took one century for scientists to understand its purpose: it is an astronomical clock that determines the positions of celestial bodies with extraordinary precision. In 2010, a fully-functional replica was constructed out of Lego.

Here’s the video mentioned by Grrl Scientist,

As noted in the video, it is a replica that requires twice as many gears as the original to make the same calculations. It seems we still haven’t quite caught up with the past.

Bob Yirka’s April 4, 2011 article for phys.org describes some of the research involved in decoding the mechanism,

If modern research is correct, the device worked by hand cranking a main dial to display a chosen date, causing the wheels and gears inside to display (via tabs on separate dials) the position of the sun, moon, and the five known planets at that time, for that date; a mechanical and technical feat that would not be seen again until the fourteenth century in Europe with precision clocks.

Now James Evans and his colleagues at the University of Puget Sound in Washington State, have shown that instead of trying to use the same kind of gear mechanism to account for the elliptical path the Earth takes around the sun, and subsequent apparent changes in speed, the inventor of the device may have taken a different tack, and that was to stretch or distort the zodiac on the dial face to change the width of the spaces on the face to make up for the slightly different amount of time that is represented as the hand moves around the face.

In a paper published in the Journal for the History of Astronomy, Evans describes how he and his team were able to examine x-rays taken of the corroded machine (69 then later 88 degrees of the circle) and discovered that the two circles that were used to represent the Zodiac and Egyptian calendar respectively, did indeed differ just enough to account for what appeared to be the irregular movement during different parts of the year.

Though not all experts agree on the findings, this new evidence does appear to suggest that an attempt was made by the early inventor to take into account the elliptical nature of the Earth orbiting the sun, no small thing.

Jenny Winder’s June 11, 2012 article for Universe Today and republished on phys.org provides more details about the gears and the theories behind the device,

The device is made of bronze and contains 30 gears though it may have had as many as 72 originally. Each gear was meticulously hand cut with between 15 and 223 triangular teeth, which were the key to discovering the mechanism’s various functions. It was based on theories of astronomy and mathematics developed by Greek astronomers who may have drawn from earlier Babylonian astronomical theories and its construction could be attributed to the astronomer Hipparchus or, more likely, Archimedes the famous Greek mathematician, physicist, engineer, inventor and astronomer. … [emphases mine]

I’ve highlighted the verbs which suggest they’re still conjecturing as to where the theories and knowledge to develop this ancient computer came from. Yirka’s article mentions that some folks believe that the Antikythera may be the result of alien visitations, along with the more academic guesses about the Babylonians and the Greeks.

I strongly recommend reading the articles and chasing down more videos about the Antikythera on Youtube as the story is fascinating and given the plethora of material (including a book and website by Jo Marchant, Decoding the Heavens), I don’t seem to be alone in my fascination.