Tag Archives: Hui-Ming Cheng

Should October 2013 be called ‘the month of graphene’?

Since the Oct. 10-11, 2013 Graphene Flagship (1B Euros investment) launch, mentioned in my preview Oct. 7, 2013 posting, there’ve been a flurry of graphene-themed news items both on this blog and elsewhere and I’ve decided to offer a brief roundup what I’ve found elsewhere.

Dexter Johnson offers a commentary in the pithily titled, Europe Invests €1 Billion to Become “Graphene Valley,” an Oct. 15, 2013 posting on his Nanoclast blog (on the IEEE [Institute of Electrical and Electronics Engineers] website) Note: Links have been removed,

The initiative has been dubbed “The Graphene Flagship,” and apparently it is the first in a number of €1 billion, 10-year plans the EC is planning to launch. The graphene version will bring together 76 academic institutions and industrial groups from 17 European countries, with an initial 30-month-budget of €54M ($73 million).

Graphene research is still struggling to find any kind of applications that will really take hold, and many don’t expect it will have a commercial impact until 2020. What’s more, manufacturing methods are still undeveloped. So it would appear that a 10-year plan is aimed at the academic institutions that form the backbone of this initiative rather than commercial enterprises.

Just from a political standpoint the choice of Chalmers University in Sweden as the base of operations for the Graphene Flagship is an intriguing choice. …

I have to agree with Dexter that choosing Chalmers University over the University of Manchester where graphene was first isolated is unexpected. As a companion piece to reading Dexter’s posting in its entirety and which features a video from the flagship launch, you might want to try this Oct. 15, 2013 article by Koen Mortelmans for Youris (h/t Oct. 15, 2013 news item on Nanowerk),

Andre Konstantin Geim is the only person who ever received both a Nobel and an Ig Nobel. He was born in 1958 in Russia, and is a Dutch-British physicist with German, Polish, Jewish and Ukrainian roots. “Having lived and worked in several European countries, I consider myself European. I don’t believe that any further taxonomy is necessary,” he says. He is now a physics professor at the University of Manchester. …

He shared the Noble [Nobel] Prize in 2010 with Konstantin Novoselov for their work on graphene. It was following on their isolation of microscope visible grapheme flakes that the worldwide research towards practical applications of graphene took off.  “We did not invent graphene,” Geim says, “we only saw what was laid up for five hundred year under our noses.”

Geim and Novoselov are often thought to have succeeded in separating graphene from graphite by peeling it off with ordinary duct tape until there only remained a layer. Graphene could then be observed with a microscope, because of the partial transparency of the material. That is, after dissolving the duct tape material in acetone, of course. That is also the story Geim himself likes to tell.

However, he did not use – as the urban myth goes – graphite from a common pencil. Instead, he used a carbon sample of extreme purity, specially imported. He also used ultrasound techniques. But, probably the urban legend will survive, as did Archimedes’ bath and Newtons apple. “It is nice to keep some of the magic,” is the expression Geim often uses when he does not want a nice story to be drowned in hard facts or when he wants to remain discrete about still incomplete, but promising research results.

Mortelmans’ article fills in some gaps for those not familiar with the graphene ‘origins’ story while Tim Harper’s July 22, 2012 posting on Cientifica’s (an emerging technologies consultancy where Harper is the CEO and founder) TNT blog offers an insight into Geim’s perspective on the race to commercialize graphene with a paraphrased quote for the title of Harper’s posting, “It’s a bit silly for society to throw a little bit of money at (graphene) and expect it to change the world.” (Note: Within this context, mention is made of the company’s graphene opportunities report.)

With all this excitement about graphene (and carbon generally), the magazine titled Carbon has just published a suggested nomenclature for 2D carbon forms such as graphene, graphane, etc., according to an Oct. 16, 2013 news item on Nanowerk (Note: A link has been removed),

There has been an intense research interest in all two-dimensional (2D) forms of carbon since Geim and Novoselov’s discovery of graphene in 2004. But as the number of such publications rise, so does the level of inconsistency in naming the material of interest. The isolated, single-atom-thick sheet universally referred to as “graphene” may have a clear definition, but when referring to related 2D sheet-like or flake-like carbon forms, many authors have simply defined their own terms to describe their product.

This has led to confusion within the literature, where terms are multiply-defined, or incorrectly used. The Editorial Board of Carbon has therefore published the first recommended nomenclature for 2D carbon forms (“All in the graphene family – A recommended nomenclature for two-dimensional carbon materials”).

This proposed nomenclature comes in the form of an editorial, from Carbon (Volume 65, December 2013, Pages 1–6),

All in the graphene family – A recommended nomenclature for two-dimensional carbon materials

  • Alberto Bianco
    CNRS, Institut de Biologie Moléculaire et Cellulaire, Immunopathologie et Chimie Thérapeutique, Strasbourg, France
  • Hui-Ming Cheng
    Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016, China
  • Toshiaki Enoki
    Department of Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, Tokyo, Japan
  • Yury Gogotsi
    Materials Science and Engineering Department, A.J. Drexel Nanotechnology Institute, Drexel University, 3141 Chestnut Street, Philadelphia, PA 19104, USA
  • Robert H. Hurt
    Institute for Molecular and Nanoscale Innovation, School of Engineering, Brown University, Providence, RI 02912, USA
  • Nikhil Koratkar
    Department of Mechanical, Aerospace and Nuclear Engineering, The Department of Materials Science and Engineering, Rensselaer Polytechnic Institute, 110 8th Street, Troy, NY 12180, USA
  • Takashi Kyotani
    Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan
  • Marc Monthioux
    Centre d’Elaboration des Matériaux et d’Etudes Structurales (CEMES), UPR-8011 CNRS, Université de Toulouse, 29 Rue Jeanne Marvig, F-31055 Toulouse, France
  • Chong Rae Park
    Carbon Nanomaterials Design Laboratory, Global Research Laboratory, Research Institute of Advanced Materials, Department of Materials Science and Engineering, Seoul National University, Seoul 151-744, Republic of Korea
  • Juan M.D. Tascon
    Instituto Nacional del Carbón, INCAR-CSIC, Apartado 73, 33080 Oviedo, Spain
  • Jin Zhang
    Center for Nanochemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

This editorial is behind a paywall.

Graphene, IBM’s first graphene-based integrated circuit, and the European Union’s pathfinder programme in information technologies

A flat layer of carbon atoms packed into a two-dimensional honeycomb arrangement, graphene is being touted as a miracle (it seems)  material which will enable new kinds of electronic products. Recently, there have been a number of news items and articles featuring graphene research.

Here’s my roundup of the latest and greatest graphene news. I’m starting with an application that is the closest to commercialization: IBM recently announced the creation of the first graphene-based integrated circuit. From the Bob Yirka article dated June 10, 2011 on physorg.com,

Taking a giant step forward in the creation and production of graphene based integrated circuits, IBM has announced in Science, the fabrication of a graphene based integrated circuit [IC] on a single chip. The demonstration chip, known as a radio frequency “mixer” is capable of producing frequencies up to 10 GHz, and demonstrates that it is possible to overcome the adhesion problems that have stymied researchers efforts in creating graphene based IC’s that can be used in analog applications such as cell phones or more likely military communications.

The graphene circuits were started by growing a two or three layer graphene film on a silicon surface which was then heated to 1400°C. The graphene IC was then fabricated by employing top gated, dual fingered graphene FET’s (field-effect transistors) which were then integrated with inductors. The active channels were made by spin-coating the wafer with a thin polymer and then applying a layer of hydrogen silsequioxane. The channels were then carved by e-beam lithography. Next, the excess graphene was removed with an oxygen plasma laser, and then the whole works was cleaned with acetone. The result is an integrated circuit that is less than 1mm2 in total size.

Meanwhile, there’s a graphene research project in contention for a major research prize in Europe. Worth 1B Euros, the European Union’s 2011 pathfinder programme (Future and Emerging Technologies [Fet11]) in information technology) will select two from six pilot actions currently under way to be awarded a Flagship Initiative prize.  From the Fet11 flagships project page,

FET Flagships are large-scale, science-driven and mission oriented initiatives that aim to achieve a visionary technological goal. The scale of ambition is over 10 years of coordinated effort, and a budget of up to one billion Euro for each Flagship. They initiatives are coordinated between national and EU programmes and present global dimensions to foster European leadership and excellence in frontier research.

To prepare the launch of the FET Flagships, 6 Pilot Actions are funded for a 12-month period starting in May 2011. In the second half of 2012 two of the Pilots will be selected and launched as full FET Flagship Initiatives in 2013.

Here’s the description of the Graphene Science and technology for ICT and beyond pilot action,

Graphene, a new substance from the world of atomic and molecular scale manipulation of matter, could be the wonder material of the 21st century. Discovering just how important this material will be for Information and Communication Technologies is the long term focus of the Flagship Initiative, simply called, GRAPHENE. This aims to explore revolutionary potentials, in terms of both conventional as well as radically new fields of Information and Communication Technologies applications.

Bringing together multiple disciplines and addressing research across a whole range of issues, from fundamental understandings of material properties to Graphene production, the Flagship will provide the platform for establishing European scientific and technological leadership in the application of Graphene to Information and Communication Technologies. The proposed research includes coverage of electronics, spintronics, photonics, plasmonics and mechanics, all based on Graphene.

[Project Team:]

Andrea Ferrari, Cambridge University, UK
Jari Kinaret, Chalmers University, Sweden
Vladimir Falko, Lancaster University, UK
Jani Kivioja, NOKIA, Finland [emphases mine]

Not so coincidentally (given one member of the team is associated with Nokia and another is associated with Cambridge University), the Nokia Research Centre jointly with Cambridge University issued a May 4, 2011 news release (I highlighted it in my May 6, 2011 posting [scroll down past the theatre project information]) about the Morph concept (a rigid, flexible, and stretchable phone/blood pressure cuff/calculator/and  other electronic devices in one product) which they have been publicizing for years now. The news release concerned itself with how graphene would enable the researchers to take the Morph from idea to actuality. The webpage for the Graphene Pilot Action is here.

There’s something breathtaking when there is no guarantee of success about the willingness to invest up to 1B Euros in a project that spans 10 years. We’ll have to wait until 2013 before learning whether the graphene project will be one of the two selected as Flagship Initiatives.

I must say the timing for the 2010 Nobel Prize for Physics which went to two scientists (Andre Geim and Konstantin Novoselov) for their groundbreaking work with graphene sems interesting (featured in my Oct. 7, 2010 posting) in light of this graphene activity.

The rest of these graphene items are about research that could lay the groundwork for future commercialization.

Friday, June 13, 2011 there was a news item about foaming graphene on Nanowerk (from the news item),

Hui-Ming Cheng and co-workers from the Chinese Academy of Sciences’ Institute of Metal Research at Shenyang have now devised a chemical vapor deposition (CVD) method for turning graphene sheets into porous three-dimensional ‘foams’ with extremely high conductivity (“Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition” [published in Nature Materials 10, 424–428 (2011) doi:10.1038/nmat3001 Published online 10 April 2011]). By permeating this foam with a siloxane-based polymer, the researchers have produced a composite that can be twisted, stretched and bent without harming its electrical or mechanical properties.

Here’s an image from the Nature Publishing Group (NPG) of both the vapour and the bendable, twistable, stretchable composite (downloaded from the news item on Nanowerk where you can find a larger version of the image),

A scanning electron microscopy image of the net-like structure of graphene foam (left), and a photograph of a highly conductive elastic conductor produced from the foam. (© 2011 NPG)

The ‘elastic’ conductor (image to the right) reminds me of the ‘paper’ phone which I wrote about May 8, 2011 and May 12, 2011. (It’s a project where teams from Queen’s University [in Ontario] and Arizona State University are working to create flexible screens that give you telephony, music playing and other capabilities  much like the Morph concept.)

Researchers in Singapore have developed a graphene quantum dot using a C60 (a buckminster fullerene). From the June 13, 2011 news item (Graphene: from spheres to perfect dots) on Nanowerk,

An electron trapped in a space of just a few nanometers across behaves very differently to one that is free. Structures that confine electrons in all three dimensions can produce some useful optical and electronic effects. Known as quantum dots, such structures are being widely investigated for use in new types of optical and electronics technologies, but because they are so small it is difficult to fabricate quantum dots reproducibly in terms of shape and size. Researchers from the National University of Singapore (NUS) and A*STAR have now developed a technique that enables graphene quantum dots of a known size to be created repeatedly and quickly (“Transforming C60 molecules into graphene quantum dots” [published in Nature Nanotechnology 6, 247–252 (2011) doi:10.1038/nnano.2011.30 Published online 20 March 2011]).

This final bit is about a nano PacMan that allows for more precise patterning from a June 13, 2011 article written by Michael Berger,

A widely discussed method for the patterning of graphene is the channelling of graphite by metal nanoparticles in oxidizing or reducing environments (see for instance: “Nanotechnology PacMan cuts straight graphene edges”).

“All previous studies of channelling behavior have been limited by the need to perform the experiment ex situ, i.e. comparing single ‘before’ and ‘after’ images,” Peter Bøggild, an associate professor at DTU [Danish Technical University] Nanotech, explains to Nanowerk. “In these and other ex situ experiments the dynamic behavior must be inferred from the length of channels and heating time after completion of the experiment, with the rate of formation of the channel assumed to be consistent over the course of the experiment.”

In new work, reported in the June 9, 2011 advance online edition of Nano Letters (“Discrete dynamics of nanoparticle channelling in suspended graphene” [published in Nano Letters, Article ASAP, DOI: 10.1021/nl200928k, Publication Date (Web): June 9, 2011]), Bøggild and his team report the nanoscale observation of this channelling process by silver nanoparticles in an oxygen atmosphere in-situ on suspended mono- and bilayer graphene in an environmental transmission electron microscope, enabling direct concurrent observation of the process, impossible in ex-situ experiments.

Personally, I love the youtube video I’ve included here largely because it features blobs (as many of these videos do) where they’ve added music and titles (many of these videos do not) so you can better appreciate the excitement,

From the article by Michael Berger,

As a result of watching this process occur live in a transmission electron microscope, the researchers say they have seen many details that were hidden before, and video really brings the “nano pacman” behavior to life …

There’s a reason why they’re so interested in cutting graphene,

“With a deeper understanding of the fine details we hope to one day use this nanoscale channelling behavior to directly cut desired patterns out of suspended graphene sheets, with a resolution and accuracy that isn’t achievable with any other technique,” says Bøggild. “A critical advantage here is that the graphene crystal structure guides the patterning, and in our case all of the cut edges of the graphene are ‘zigzag’ edges.”

So there you have it. IBM creates the first integrated graphene-based circuit, there’s the prospect of a huge cash prize for a 10-year project on graphene so they could produce the long awaited Morph concept and other graphene-based electronics products while a number of research teams around the world continue teasing out its secrets with graphene ‘foam’ projects, graphene quantum dots, and nano PacMen who cut graphene’s zigzag edges with precision.

ETA June 16, 2011: For those interested in the business end of things, i.e. market value of graphene-based products, Cameron Chai features a report, Graphene: Technologies, Applications, and Markets, in his June 16, 2011 news item on Azonano.