Implantable electronics that can deliver drugs, monitor vital signs and perform other health-related roles are on the horizon. But finding a way to power them remains a challenge. Now scientists have built a flexible nanogenerator out of cellulose, an abundant natural material, that could potentially harvest energy from the body — its heartbeats, blood flow and other almost imperceptible but constant movements. …
Efforts to convert the energy of motion — from footsteps, ocean waves, wind and other movement sources — are well underway. Many of these developing technologies are designed with the goal of powering everyday gadgets and even buildings. As such, they don’t need to bend and are often made with stiff materials. But to power biomedical devices inside the body, a flexible generator could provide more versatility. So Md. Mehebub Alam and Dipankar Mandal at Jadavpur University in India set out to design one.
The researchers turned to cellulose, the most abundant biopolymer on earth, and mixed it in a simple process with a kind of silicone called polydimethylsiloxane — the stuff of breast implants — and carbon nanotubes. Repeated pressing on the resulting nanogenerator lit up about two dozen LEDs instantly. It also charged capacitors that powered a portable LCD, a calculator and a wrist watch. And because cellulose is non-toxic, the researchers say the device could potentially be implanted in the body and harvest its internal stretches, vibrations and other movements [also known as, harvesting biomechanical motion].
I did take a peek at the paper to see if I could determine whether or not they had used wood-derived cellulose and whether cellulose nanocrystals had been used. Based on the references cited for the paper, I think the answer to both questions is yes.
My latest piece on harvesting biomechanical motion is a June 24, 2014 post where I highlight a research project in Korea and another one in the UK and give links to previous posts on the topic.
Developed by Canadian, Indian and Sri Lankan researchers in a collaborative project funded by the International Development Research Centre (IDRC), the nanotech mango boxes are said to improve the fruit’s resilience and therefore boost quality over long shipping distances.
The project – which also includes the Tamil Nadu Agricultural University, India and the Industrial Technical Institute, Sri Lanka – has tested the use of the bio-compound hexanal, an artificially synthesized version of a natural substance produced by injured plants to reduce post-harvest losses.
Researchers from the University of Guelph, Canada, Tamil Nadu Agricultural University, India, and the Industrial Technical Institute, Sri Lanka, have shown that a natural compound known as hexanal delays the ripening of mangos. Using nanotechnology, the team will continue to develop hexanal-impregnated packaging and biowax coatings to improve the fruit’s resilience during handling and shipping for use in Asia, Africa, and the Caribbean. It will also expand its research to include other fruit and look at ways to commercialize the technologies.
New funding will allow the research teams to further develop the new technologies and involve partners who can bring them to market to reach greater numbers of small-holder farmers.
Talking to mediapersons after taking part in a workshop on ‘Enhanced Preservation of Fruits using Nanotechnology Project’ held at the Horticultural College and Research Institute, Periyakulam near here on Monday [Dec. 28, 2015], he [K.S. Subramanian, Professor, Department of Nano Science and Technology, TNAU, Coimbatore] said countries like Sri Lanka, Tanzania, Kenya and West Indies will benefit. Post-harvest loss in African countries was approximately 80 per cent, whereas it was 25 to 30 per cent in India, he said.
With the funds sanctioned by Canadian Department of Foreign Affairs, Trade and Development and International Development Research Centre, Canada, the TN Agricultural University, Coimbatore, involving scientists in University of Guelph, Canada, Industrial Technology Institute, Colombo, Sokoine University of Agriculture, Tanzania, University of Nairobi [Kenya], University of West Indies, Trinidad and Tobago, have jointly developed Hexanal formulation, a nano-emulsion, to minimise post harvest loss and extend shelf life of mango.
Field trials have been carried out successfully in Dharmapuri and Krishnagiri on five varieties – Neelam, Bangalura, Banganapalle, Alphonso and Imam Pasand. Pre-harvest spray of Hexanal formulation retained fruits in the trees for three weeks and three more weeks in storage.
Extending life to six to eight weeks will benefit exporters immensely as they required at least six weeks to take fruits to European and the US market. Existing technologies were sufficient to retain fruits up to four weeks only. Domestic growers too can delay harvest and tap market when in demand.
Nano technology is an ideal tool to extend the shelf life and delay in ripening mango in trees, but proper bio-safety tests should be done before introducing it to farmers, according to Deputy Director General of ICAR N.K. Krishnakumar.
Inaugurating a workshop on Enhanced Preservation of Fruits using Nanotechnology Project held at the Horticultural College and Research Institute at Periyakulam near here on Monday [Dec. 28, 2015], he said that bio safety test was very important before implementing any nano-technology. Proper adoption of new technologies would certainly enhance the income of farmers, he added.
Demand for organic fruits was very high in foreign countries, he said, adding that Japan and Germany were prepared to buy large quantum of organic pomegranate. Covering fruits in bags would ensure uniform colour and quality, he said.
He appealed to scale down use of chemical pesticides and fertilizers to improve quality and taste. He said dipping mango in water mixed with salt will suffice to control fungus.
Postgraduate and research students should take up a problem faced by farmers and find a solution to it by working in his farm. His thesis could be accepted for offering degree only after getting feedback from that farmer. Such measure would benefit college, students and farmers, Mr. Krishnakumar added.
It’s good to get an update on the project’s progress and, while it’s not clear from the excerpts I have here, they are testing hexanal with on fruit other than mangoes.
While zinc is a metal, it’s also a nutrient vital to plants as a Nov. 5, 2015 news item on ScienceDaily notes,
With the world population expected to reach 9 billion by 2050, engineers and scientists are looking for ways to meet the increasing demand for food without also increasing the strain on natural resources, such as water and energy — an initiative known as the food-water-energy nexus.
Ramesh Raliya, PhD, a postdoctoral researcher, and Pratim Biswas, PhD, the Lucy & Stanley Lopata Professor and chair of the Department of Energy, Environmental & Chemical Engineering, both at the School of Engineering & Applied Science at Washington University in St. Louis, are addressing this issue by using nanoparticles to boost the nutrient content and growth of tomato plants. Taking a clue from their work with solar cells, the team found that by using zinc oxide and titanium dioxide nanoparticles, the tomato plants better absorbed light and minerals, and the fruit had higher antioxidant content.
“When a plant grows, it signals the soil that it needs nutrients,” Biswas says. “The nutrient it needs is not in a form that the plant can take right away, so it secretes enzymes, which react with the soil and trigger bacterial microbes to turn the nutrients into a form that the plant can use. We’re trying to aid this pathway by adding nanoparticles.”
Zinc is an essential nutrient for plants, helps other enzymes function properly and is an ingredient in conventional fertilizer. Titanium is not an essential nutrient for plants, Raliya says, but boosts light absorption by increasing chlorophyll content in the leaves and promotes photosynthesis, properties Biswas’ lab discovered while creating solar cells.
The team used a very fine spray using novel aerosolization techniques to directly deposit the nanoparticles on the leaves of the plants for maximum uptake.
“We found that our aerosol technique resulted in much greater uptake of nutrients by the plant in comparison to application of the nanoparticles to soil,” Raliya says. “A plant can only uptake about 20 percent of the nutrients applied through soil, with the remainder either forming stable complexes with soil constituents or being washed away with water, causing runoff. In both of the latter cases, the nutrients are unavailable to plants.”
Overall, plants treated with the nanoparticles via aerosol routes produced nearly 82 percent (by weight) more fruit than untreated plants. In addition, the tomatoes from treated plant showed an increase in lycopene, an antioxidant linked to reduced risk of cancer, heart disease and age-related eye disorders, of between 80 percent and 113 percent.
Previous studies by other researchers have shown that increasing the use of nanotechnology in agriculture in densely populated countries such as India and China has made an impact on reducing malnutrition and child mortality. These tomatoes will help address malnutrition, Raliya says, because they allow people to get more nutrients from tomatoes than those conventionally grown.
In the study, published online last month in the journal Metallomics, the team found that the nanoparticles in the plants and the tomatoes were well below the USDA limit and considerably lower than what is used in conventional fertilizer. However, they still have to be cautious and select the best concentration of nanoparticles to use for maximum benefit, Biswas says.
Raliya and the rest of the team are now working to develop a new formulation of nanonutrients that includes all 17 elements required by plants.
“In 100 years, there will be more cities and less farmland, but we will need more food,” Raliya says. “At the same time, water will be limited because of climate change. We need an efficient methodology and a controlled environment in which plants can grow.”
The story of science in the Muslim world is extraordinary, influencing science to this day, and is not well known even within its own community. The days when Muslim or Islamic scientists led the world are long gone and that is cause for concern. An Oct. 29, 2015 Malaysian Industry-Government Group for High Technology press release on EurekAlert argues that universities in Muslim countries must reinvent themselves to transform society and achieve scientific excellence,
A Task Force of international experts, formed by the Muslim World Science Initiative, today released a report [Science at Universities of the Muslim World] on the state of science at universities of the Muslim world.
To assess the state of science at universities of the Muslim world, the Task Force reviewed the rankings of Muslim-world’s universities globally, scientific production (number of papers published and citations), the level of spending on research and development (R&D), female participation in the scientific workforce, and other indicators.
The results were compared to those of countries deemed comparable in terms of gross domestic product (GDP) per capita, e.g. Brazil, Israel, Spain, South Africa, and South Korea.
The Task Force noted recent improvements in scientific publishing across a number of countries and a relatively healthy gender ratio among university students, even though the overall state of science in the Muslim World remains ‘poor,’ as depicted by
the disproportionately small number of Nobel Laureates
the small number of universities in top global rankings
the low spending on R&D, and
the abysmal performance of pre-university students on math and science tests
Seeking to assess if universities were the ‘main culprits’ in this sorry state of affairs, the Task Force highlighted significant challenges at the Universities of the Muslim World.
In particular, the Task Force lamented the fact that science education in most Organization of Islamic Cooperation (OIC) member countries was extremely narrow in focus and did little to enable students to think critically, especially beyond their respective domains of specialty.
The Task Force calls for broad liberal education for scientists and engineers to enable them to function effectively in addressing complex multi-disciplinary challenges that the world faces today.
The Task Force also noted that self-censorship was often practiced in the selection of topics to be taught, particularly regarding controversial subjects such as the theory of evolution.
The Task Force called for the introduction and systematic study of philosophy of science and history of the sciences of the Muslim ‘Golden Age’ and beyond for students to navigate and develop a perspective on these difficult disciplinary boundaries and overlaps. The language of instruction also created significant challenges.
Faculty members were also ill-trained to teach using cutting-edge methods such as inquiry-based science education and had little autonomy to innovate.
While the Task Force called for greater autonomy for the universities, it also emphasized that they must become meritocracies and aspire for true scientific excellence rather than playing for temporary gains in numbers or rankings. It also calls for zero tolerance on plagiarism and other forms of academic misconduct.
The Report of the Task Force includes: a foreword by the Chair, Tan Sri Zakri Abdul Hamid, the main assessment and recommendations, and individual essays written by the Task Force members on issues, including
Science, Society & the University
Are universities of the Muslim world helping spread a culture of science through society?
Should Religion Be Kept Out of the Science Classroom?
STEM Education and the Muslim Gender Divide and
The Need of Liberal Education for Science and Engineering
The Task Force is putting out an open call for universities across the Muslim world to join a voluntary Network of Excellence of Universities for Science (NEXUS), to be launched early next year.
This peer group will be managed by the task force and housed in Tan Sri Zakri’s office. NEXUS will run summer schools for university administrators, monitor the progress of reforms at participating universities, and issue a peer report card that will assess the performance of the universities in meeting milestones, thus recognizing and inspiring further improvements. True transformation will require much broader action from ministries, regulators and funding agencies, and these may be the most resistant to change.
Releasing the Report of the Task Force, Tan Sri Zakri Abdul Hamid stressed that “universities must reinvent themselves to lead the scientific reforms in the Muslim World, and as they do so they must embrace key ideas of merit and transparency, engagement with society, and pedagogical and curricular innovation.”
Professor Nidhal Guessoum, the Task Force’s Convenor, noted that “Task Force members strongly believe that the most appropriate venue for action on our recommendations is the university itself. The most essential ingredient in creating excellence in science and science teaching at a university is a realization, within a university’s highest leadership and its faculty, of the need to give up the old and dated ways, renew the purpose, and re-write the genetic code of their university.
Dr. Athar Osama, the Director of the Project noted that “the purpose of Muslim World Science Initiative is to jumpstart a dialogue within the society on critical issues at the intersection of science, society, and Islam. The Task Force has done a commendable job in laying the groundwork for a very important conversation about our universities.”
The divide between science/technology/engineering/mathematics (STEM) education and other fields of interest such as social sciences, the arts, and the humanities may be larger in the Islamic world (and to some extent reversed with humanities looking down on science) but it is a problem elsewhere, often expressed as a form of snobbery, as I alluded to in my Aug. 7, 2015 posting titled: Science snobbery and the problem of accessibility.
An Oct. 28, 2015 Nature essay about Islam, science, and the report by Nidhal Guessou and Athar Osama (two members of the Task Force; Note: Links have been removed) provides more context,
The Islamic civilization lays claim to the world’s oldest continually operational university. The University of Qarawiyyin was founded in Fes, Morocco, in ad 859, at the beginning of an Islamic Golden Age. Despite such auspicious beginnings, universities in the region are now in dire straits, as demonstrated by a report we have authored, released this week (see go.nature.com/korli3).
The 57 countries of the Muslim world — those with a Muslim-majority population, and part of the Organisation of Islamic Cooperation (OIC) — are home to nearly 25% of the world’s people. But as of 2012, they had contributed only 1.6% of the world’s patents, 6% of its academic publications, and 2.4% of the global research expenditure1, 2.
The authors note problems and at least one success with regard to curriculum (from the Nature essay; Note: Links have been removed),
Science classes themselves have serious problems. The textbooks used in OIC universities are often imported from the United States or Europe. Although the content is of a high standard, they assume a Western experience and use English or French as the language of instruction. This disadvantages many students, and creates a disconnect between their education and culture. To encourage the production of higher-quality, local textbooks and other academic material, universities need to reward staff for producing these at least as much as they do for research publication.
Some basic facts are seen as controversial, and marginalized. Evolution, for example, is usually taught only to biology students, often as “a theory”, and is rarely connected to the rest of the body of knowledge. One ongoing study has found, for example, that most Malaysian physicians and medical students reject evolution (see go.nature.com/38cswo). Evolution needs to be taught widely and shown to be compatible with Islam and its culture6. Teaching the philosophy and history of science would help, too.
The global consensus is that enquiry-based science education fosters the deepest understanding of scientific concepts and laws. But in most OIC universities, lecture-based teaching still prevails. Exceptions are rare. One is the Petroleum Institute, an engineering university in Abu Dhabi, UAE, where the faculty has created a hands-on experience with positive results on student interest and enrolment, particularly of women.
For anyone interested in the full report, it can be requested from the Muslim Science website.
One final comment, here’s the list of task force members in the Oct. 29, 2015 news release which includes someone from Mauritius (my father was born there),
Tan Sri Zakri Abdul Hamid, Science Advisor to Prime Minister of Malaysia, Chair of the Task Force on Science at the Universities of the Muslim World
Prof. Nidhal Guessoum, American University of Sharjah, UAE, Convenor of the Task Force on Science at Universities of the Muslim World
Dr. Mohammad Yusoff Sulaiman, President and CEO, MiGHT, Malaysia, Co-Convenor of the Task Force on Science at Universities of the Muslim World.
Dr. Moneef Zou’bi, Executive Director, Islamic World Academy of Science (IAS)
Prof. Adil Najam, Dean Frederick S. Pardee School of Global Studies, Boston University and former Vice Chancellor, Lahore University of Management Sciences (LUMS)
Prof. Ameenah Gurib-Fakim, Fellow of IAS, President of the Republic of Mauritius, and Professor at University of Mauritius
Prof. Mustafa El-Tayeb, President , Future University, Khartoum, Sudan
Prof. Abdur Razak Dzulkifli, President of International Association of Universities (IAU), and former Vice Chancellor USM, Malaysia
Dr. Nadia Alhasani, Dean of Student Life (formerly Dean of Women in Science and Engineering (WiSE), The Petroleum Institute, Abu Dhabi, UAE
Prof. Jamal Mimouni, Professor, University of Constantine-1, Algeria
Dr. Dato Lee Yee Cheong, Chair ISTIC Governing Board / Chair IAP SEP Global Council
Prof. Michael Reiss, Professor of Science Education, UCL Institute of Education, University College, London, Expert Advisor to the Muslim-Science.Com Task Force on Science at Universities of the Muslim World
Prof. Bruce Alberts, Professor of Biochemistry, University of California, San Francisco; President Emeritus, National Academy of Sciences, and Recipient, 2014 US Presidential Medal of Science, Expert Advisor to the Muslim-Science.Com Task Force on Science at Universities of the Muslim World
Professor Shoaib S. H. Zaidi, Professor and Dean of School of Sciences and Engineering, Habib University, Karachi
Dr. Athar Osama, Founder Muslim World Science Initiative, and Project Director of the Task Forces Project.
This show is still making its way around the world with the latest stop, as of Oct. 20, 2015, at the Library of Alexandria in Egypt.
A Jan. 21, 2010 article by Nick Higham and Margaret Ryan for BBC (British Broadcasting Corporation) news online describes some of the exhibit highlights,
From about 700 to 1700, many of history’s finest scientists and technologists were to be found in the Muslim world.
In Christian Europe the light of scientific inquiry had largely been extinguished with the collapse of the Roman empire. But it survived, and indeed blazed brightly, elsewhere.
From Moorish Spain across North Africa to Damascus, Baghdad, Persia and all the way to India, scientists in the Muslim world were at the forefront of developments in medicine, astronomy, engineering, hydraulics, mathematics, chemistry, map-making and exploration.
Salim Al-Hassani, a former professor of engineering at Umist (University of Manchester Institute of Science and Technology) is a moving force behind the exhibition, 1001 Inventions.
Visitors to the exhibition will be greeted by a 20 ft high replica of a spectacular clock designed in 1206 by the inventor Al-Jazari.
It incorporates elements from many cultures, representing the different cultural and scientific traditions which combined and flowed through the Muslim world.
The clock’s base is an elephant, representing India; inside the elephant the water-driven works of the clock derive from ancient Greece.
A Chinese dragon swings down from the top of the clock to mark the hours. At the top is a phoenix, representing ancient Egypt.
Sitting astride the elephant and inside the framework of the clock are automata, or puppets, wearing Arab turbans.
Elsewhere in the exhibition are displays devoted to water power, the spread of education (one of the world’s first universities was founded by a Muslim woman, Fatima al-Fihri), Muslim architecture and its influence on the modern world and Muslim explorers and geographers.
There is a display of 10th Century surgeons’ instruments, a lifesize model of a man called Abbas ibn Firnas, allegedly the first person to have flown with wings, and a model of the vast 100 yard-long junk commanded by the Muslim Chinese navigator, Zheng He.
The description of the exhibition items is compelling.
Science and the modern world debate (Humanism and Islam)
Yasmin Khan has written up a transcript of sorts in a Nov. 6, 2015 posting on the Guardian science blogs about a science debate (which took place Wednesday, Oct. 28, 2015 in London, UK) where Humanist and Islamic perspectives were being discussed (Note: Links have been removed),
Two important figures came head-to-head at Conway Hall, to discuss Islamic versus Humanist perspectives on science and the modern world. Jim Al-Khalili made the final public appearance of his term as president of the British Humanist Association during this stimulating, and at times provoking, debate with Ziauddin Sardar, chair of the Muslim Institute.
Al-Khalili advocated the values of the European Enlightenment, arguing that ever since the “Age of Reason” took hold during the 18th century, Humanists have looked to science instead of religion to explore and comprehend the world. Sardar upheld the view that it is the combination of faith and reason that offers a fuller understanding of the world, maintaining that it was this worldview that enabled the development of science in the Islamic golden Age.
A practising Muslim, Sardar is on an independent mission to promote rational, considered thought in interpreting the Qur’an. He explained that when he came to the UK from Pakistan, he found comfort in the familiar language of mathematics, which set him on a trajectory to train as a physicist: “God doesn’t need me, I need him. It makes me a better person and a better scientist”, he said.
In short, Sardar’s view is that although human knowledge at times converges with the Qur’an, the text should certainly not be treated as a scientific encyclopaedia. In support of this view, Sardar lamented the emergence of the I’jaz movement, which insists the Qur’an contains descriptions of modern scientific phenomena ranging from quantum mechanics to accurate descriptions of the stages of embryology and geology. In Sardar’s opinion, this stems from insecurity and a personal need to vindicate Islam to others.
Jim Al-Khalili agreed that ascribing literal meanings to religious texts can be perilous and that these verses should be interpreted more metaphorically. Likewise, when Einstein famously said “God does not play dice” he was using a figure of speech to acknowledge that there are things we don’t yet understand but this shouldn’t stop us from trying to find out more.
Whilst Al-Khalili is a staunch atheist, he adopts what he describes as an “accommodationist” approach in his interactions with people of religious faith: “I don’t think people who believe in God are irrational, I just don’t see a need to believe there is a purpose for why things are the way they are.” Born in Bagdad, Al-Khalili grew up in Iraq. His mother was Christian and his father was Shia, but he never heard them quarrel about religion. By the time he reached his teens he felt that he had distanced himself from needing any form of spirituality and his subsequent scientific training cemented this worldview. He asserted that his core values are empathy, humility and respect, without being driven by a reward in an afterlife: “It’s not just people of religious faith that have a moral compass – morality is what makes us human.”
I encourage you to read Khan’s piece (Nov. 6, 2015 posting) in its entirety as she provides historical and contemporary context to what seems to have been a fascinating and nuanced debate. Plus, there’s a bit of a bonus at the end where Khan is described as the producer of Sindbad Sci-Fi, a website where they are Reimagining Arab Science Fiction. From the website’s About page,
Sindbad Sci-Fi is an initiative for spurring the discovery of and engagement with Arab Science Fiction through dialogue. Our aim is to sustain a growing community of interest through brokering face-to-face and online discussion, building new partnerships and project collaborations along the way.
Many of us know and love Sindbad the sailor as the fictional sailor from the Arabian Book of OneThousand and One Nights, considered as being an early composite work of proto-science fiction and fantasy. His extraordinary voyages led him to adventures in magical places whilst meeting monsters and encountering supernatural phenomena.
Sindbad Sci-Fi is reviving Sindbad’s adventurous spirit for exploration and discovery. Join us as we continue star trekking across the Middle East, North Africa, South Asia and beyond. Together, we will boldly go where no one else has gone before!
I’m pretty sure somebody associated with this site is a Star Trek fan.
If you’ve been looking for a practical guide to handling nanomaterials you may find that nanoToGo fills the bill. From an Oct. 23, 2015 posting by Lynn Bergeson for Nanotechnology Now,
In September 2015, “Nano to go!” was published. See http://nanovalid.eu/index.php/nanovalid-publications/306-nanotogo “Nano to go!” is “a practically oriented guidance on safe handling of nanomaterials and other innovative materials at the workplace.” The German Federal Institute for Occupational Health (BAuA) developed it within the NanoValid project.
From the nanoToGo webpage on the NanoValid project website (Note: Links have been removed),
Nano to go! contains a brochure, field studies, presentations and general documents to comprehensively support risk assessment and risk management. …
The brochure Safe handling of nanomaterials and other advanced materials at workplacessupports risk assessment and risk management when working with nanomaterials. It provides safety strategies and protection measures for handling nanomaterials bound in solid matrices, dissolved in liquids, insoluble or insoluble powder form, and for handling nanofibres. Additional recommendations are given for storage and disposal of nanomaterials, for protection from fire and explosion, for training and instruction courses, and for occupational health.
The field studies comprise practical examples of expert assessment of safety and health at different workplaces. They contain detailed descriptions of several exposure measurements at pilot plants and laboratories. The reports describe methods, sampling strategies and devices, summarise and discuss results, and combine measurements and non-measurement methods.
Useful information, templates and examples, such as operating instructions, a sampling protocol, a dialogue guide and a short introduction to safety management and nanomaterials.
Ready to use presentations for university lecturers, supervisors and instruction courses, complemented with explanatory notes.
The ‘brochure’ is 56 pages; I would have called it a manual.
The EU FP7 [Framework Programme 7] large-scale integrating project NanoValid (contract: 263147) has been launched on the 1st of November 2011, as one of the “flagship” nanosafety projects. The project consists of 24 European partners from 14 different countries and 6 partners from Brazil, Canada, India and the US and will run from 2011 to 2015, with a total budget of more than 13 mio EUR (EC contribution 9.6 mio EUR). Main objective of NanoValid is to develop a set of reliable reference methods and materials for the fabrication, physicochemical (pc) characterization, hazard identification and exposure assessment of engineered nanomaterials (EN), including methods for dispersion control and labelling of ENs. Based on newly established reference methods, current approaches and strategies for risk and life cycle assessment will be improved, modified and further developed, and their feasibility assessed by means of practical case studies.
This is a pretty remarkable demonstration made more so when you find out the flame retardant is naturally derived and nontoxic. From an Oct. 5, 2015 news item on Nanowerk,
Inspired by a naturally occurring material found in marine mussels, researchers at The University of Texas at Austin have created a new flame retardant to replace commercial additives that are often toxic and can accumulate over time in the environment and living animals, including humans.
Flame retardants are added to foams found in mattresses, sofas, car upholstery and many other consumer products. Once incorporated into foam, these chemicals can migrate out of the products over time, releasing toxic substances into the air and environment. Throughout the United States, there is pressure on state legislatures to ban flame retardants, especially those containing brominated compounds (BRFs), a mix of human-made chemicals thought to pose a risk to public health.
A team led by Cockrell School of Engineering associate professor Christopher Ellison found that a synthetic coating of polydopamine — derived from the natural compound dopamine — can be used as a highly effective, water-applied flame retardant for polyurethane foam. Dopamine is a chemical compound found in humans and animals that helps in the transmission of signals in the brain and other vital areas. The researchers believe their dopamine-based nanocoating could be used in lieu of conventional flame retardants.
“Since polydopamine is natural and already present in animals, this question of toxicity immediately goes away,” Ellison said. “We believe polydopamine could cheaply and easily replace the flame retardants found in many of the products that we use every day, making these products safer for both children and adults.”
Using far less polydopamine by weight than typical of conventional flame retardant additives, the UT Austin team found that the polydopamine coating on foams leads to a 67 percent reduction in peak heat release rate, a measure of fire intensity and imminent danger to building occupants or firefighters. The polydopamine flame retardant’s ability to reduce the fire’s intensity is about 20 percent better than existing flame retardants commonly used today.
Researchers have studied the use of synthetic polydopamaine for a number of health-related applications, including cancer drug delivery and implantable biomedical devices. However, the UT Austin team is thought to be one of the first to pursue the use of polydopamine as a flame retardant. To the research team’s surprise, they did not have to change the structure of the polydopamine from its natural form to use it as a flame retardant. The polydopamine was coated onto the interior and exterior surfaces of the polyurethane foam by simply dipping it into a water solution of dopamine for several days.
Ellison said he and his team were drawn to polydopamine because of its ability to adhere to surfaces as demonstrated by marine mussels who use the compound to stick to virtually any surface, including Teflon, the material used in nonstick cookware. Polydopamine also contains a dihydroxy-ring structure linked with an amine group that can be used to scavenge or remove free radicals. Free radicals are produced during the fire cycle as a polymer degrades, and their removal is critical to stopping the fire from continuing to spread. Polydopamine also produces a protective coating called char, which blocks fire’s access to its fuel source — the polymer. The synergistic combination of both these processes makes polydopamine an attractive and powerful flame retardant.
Ellison and his team are now testing to see whether they can shorten the nanocoating treatment process or develop a more convenient application process.
“We believe this alternative to flame retardants can prove very useful to removing potential hazards from products that children and adults use every day,” Ellison said. “We weren’t expecting to find a flame retardant in nature, but it was a serendipitous discovery.”
This paper is behind a paywall. It should be noted that researchers from the University of Southern Mississippi and the Council of Scientific & Industrial Research (CSIR)-National Chemical Laboratory in Pune, India were also involved in this work.
Machines that are much smaller than the width of a human hair could one day help clean up carbon dioxide pollution in the oceans. Nanoengineers at the University of California, San Diego have designed enzyme-functionalized micromotors that rapidly zoom around in water, remove carbon dioxide and convert it into a usable solid form.
The proof of concept study represents a promising route to mitigate the buildup of carbon dioxide, a major greenhouse gas in the environment, said researchers. …
“We’re excited about the possibility of using these micromotors to combat ocean acidification and global warming,” said Virendra V. Singh, a postdoctoral scientist in Wang’s [nanoengineering professor and chair Joseph Wang] research group and a co-first author of this study.
In their experiments, nanoengineers demonstrated that the micromotors rapidly decarbonated water solutions that were saturated with carbon dioxide. Within five minutes, the micromotors removed 90 percent of the carbon dioxide from a solution of deionized water. The micromotors were just as effective in a sea water solution and removed 88 percent of the carbon dioxide in the same timeframe.
“In the future, we could potentially use these micromotors as part of a water treatment system, like a water decarbonation plant,” said Kevin Kaufmann, an undergraduate researcher in Wang’s lab and a co-author of the study.
The micromotors are essentially six-micrometer-long tubes that help rapidly convert carbon dioxide into calcium carbonate, a solid mineral found in eggshells, the shells of various marine organisms, calcium supplements and cement. The micromotors have an outer polymer surface that holds the enzyme carbonic anhydrase, which speeds up the reaction between carbon dioxide and water to form bicarbonate. Calcium chloride, which is added to the water solutions, helps convert bicarbonate to calcium carbonate.
The fast and continuous motion of the micromotors in solution makes the micromotors extremely efficient at removing carbon dioxide from water, said researchers. The team explained that the micromotors’ autonomous movement induces efficient solution mixing, leading to faster carbon dioxide conversion. To fuel the micromotors in water, researchers added hydrogen peroxide, which reacts with the inner platinum surface of the micromotors to generate a stream of oxygen gas bubbles that propel the micromotors around. When released in water solutions containing as little as two to four percent hydrogen peroxide, the micromotors reached speeds of more than 100 micrometers per second.
However, the use of hydrogen peroxide as the micromotor fuel is a drawback because it is an extra additive and requires the use of expensive platinum materials to build the micromotors. As a next step, researchers are planning to make carbon-capturing micromotors that can be propelled by water.
“If the micromotors can use the environment as fuel, they will be more scalable, environmentally friendly and less expensive,” said Kaufmann.
The researchers have provided an image which illustrates the carbon-capturing motors in action,
Nanoengineers have invented tiny tube-shaped micromotors that zoom around in water and efficiently remove carbon dioxide. The surfaces of the micromotors are functionalized with the enzyme carbonic anhydrase, which enables the motors to help rapidly convert carbon dioxide to calcium carbonate. Image credit: Laboratory for Nanobioelectronics, UC San Diego Jacobs School of Engineering.
Carbon nanotubes for carbon dioxide capture (carbon capture)
In a Sept. 22, 2015 posting by Dexter Johnson on his Nanoclast blog (located on the IEEE [Institute for Electrical and Electronics Engineers] website) describes research where carbon nanotubes are being used for carbon capture,
Now researchers at Technische Universität Darmstadt in Germany and the Indian Institute of Technology Kanpur have found that they can tailor the gas adsorption properties of vertically aligned carbon nanotubes (VACNTs) by altering their thickness, height, and the distance between them.
“These parameters are fundamental for ‘tuning’ the hierarchical pore structure of the VACNTs,” explained Mahshid Rahimi and Deepu Babu, doctoral students at the Technische Universität Darmstadt who were the paper’s lead authors, in a press release. “This hierarchy effect is a crucial factor for getting high-adsorption capacities as well as mass transport into the nanostructure. Surprisingly, from theory and by experiment, we found that the distance between nanotubes plays a much larger role in gas adsorption than the tube diameter does.”
Dexter provides a good and brief summary of the research.
A groundswell of global support for developing nanotechnology as a pollution remediation technique will continue for the foreseeable future. BCC Research reveals in its new report that this key driver, along with increasing worldwide concerns over removing pollutants and developing alternative energy sources, will drive growth in the nanotechnology environmental applications market.
The global nanotechnology market in environmental applications is expected to reach $25.7 billion by 2015 and $41.8 billion by 2020, conforming to a five-year (2015-2020) compound annual growth rate (CAGR) of 10.2%. Air remediation as a segment will reach $10.2 billion and $16.7 billion in 2015 and 2020, respectively, reflecting a five-year CAGR of 10.3%. Water remediation as a segment will grow at a five-year CAGR of 12.4% to reach $10.6 billion in 2020.
As nanoparticles push the limits and capabilities of technology, new and better techniques for pollution control are emerging. Presently, nanotechnology’s greatest potential lies in air pollution remediation.
“Nano filters could be applied to automobile tailpipes and factory smokestacks to separate out contaminants and prevent them from entering the atmosphere. In addition, nano sensors have been developed to sense toxic gas leaks at extremely low concentrations,” says BCC research analyst Aneesh Kumar. “Overall, there is a multitude of promising environmental applications for nanotechnology, with the main focus area on energy and water technologies.”
The single-carbon-atom-thick material, graphene, featuring ripples is not easy to understand. Instead of creating such ripples physically, physicists investigating this kind of unusually shaped material rely on a quantum simulator. It is made up of an artificial lattice of light – called ultra-cold optical lattice – akin to eggs held in the cavities of an egg tray. This approach allowed a team of theoretical physicists from India to shed some light – literally and figuratively – on the properties of rippled graphene. These findings have just been published in EPJ B by Tridev Mishra and colleagues from the Birla Institute of Technology and Science, in Pilani, India. Ultimately, this work could find applications in novel graphene-based sensors.
Optical lattices are perfect simulators. They are like mini-laboratories suitable for studying the response of a material after it has been subjected to controllable parameters inducing a deformation. What makes this particular study novel is that the team has managed to control the creation of a curved space or ripples in graphene by relying on an optical lattice simulator. The authors have thus developed a theory describing how a sequence of pulses, whose amplitude can be modulated, changes an optical lattice – specifically, the background geometry of its constituent particles. Previous modelling attempts only described static curved graphene.
Mishra and colleagues have established equations of the energy for particles caught in an optical lattice. This, in turn, simulates the energy of the electrons in a graphene sheet with a curvature. They then use a map to translate the physical characteristics of the approximation used in the curved space picture of graphene to the more realistic optical lattice picture. They thus obtain an understanding of the dynamics of the evolution from the ‘egg in a tray’ structure of the optical lattice in terms of the properties of ‘an omelette style’ continuum of energy found in graphene.
First off, this post features an open access paper summarizing global regulation of nanotechnology in agriculture and food production. From a Sept. 11, 2015 news item on Nanowerk,
An overview of regulatory solutions worldwide on the use of nanotechnology in food and feed production shows a differing approach: only the EU and Switzerland have nano-specific provisions incorporated in existing legislation, whereas other countries count on non-legally binding guidance and standards for industry. Collaboration among countries across the globe is required to share information and ensure protection for people and the environment, according to the paper …
The paper “Regulatory aspects of nanotechnology in the agri/feed/food sector in EU and non-EU countries” reviews how potential risks or the safety of nanotechnology are managed in different countries around the world and recognises that this may have implication on the international market of nano-enabled agricultural and food products.
Nanotechnology offers substantial prospects for the development of innovative products and applications in many industrial sectors, including agricultural production, animal feed and treatment, food processing and food contact materials. While some applications are already marketed, many other nano-enabled products are currently under research and development, and may enter the market in the near future. Expected benefits of such products include increased efficacy of agrochemicals through nano-encapsulation, enhanced bioavailability of nutrients or more secure packaging material through microbial nanoparticles.
As with any other regulated product, applicants applying for market approval have to demonstrate the safe use of such new products without posing undue safety risks to the consumer and the environment. Some countries have been more active than others in examining the appropriateness of their regulatory frameworks for dealing with the safety of nanotechnologies. As a consequence, different approaches have been adopted in regulating nano-based products in the agri/feed/food sector.
The analysis shows that the EU along with Switzerland are the only ones which have introduced binding nanomaterial definitions and/or specific provisions for some nanotechnology applications. An example would be the EU labelling requirements for food ingredients in the form of ‘engineered nanomaterials’. Other regions in the world regulate nanomaterials more implicitly mainly by building on non-legally binding guidance and standards for industry.
The overview of existing legislation and guidances published as an open access article in the Journal Regulatory Toxicology and Pharmacology is based on information gathered by the JRC, RIKILT-Wageningen and the European Food Safety Agency (EFSA) through literature research and a dedicated survey.
Here’s a link to and a citation for the paper,
Regulatory aspects of nanotechnology in the agri/feed/food sector in EU and non-EU countries by Valeria Amenta, Karin Aschberger, , Maria Arena, Hans Bouwmeester, Filipa Botelho Moniz, Puck Brandhoff, Stefania Gottardo, Hans J.P. Marvin, Agnieszka Mech, Laia Quiros Pesudo, Hubert Rauscher, Reinhilde Schoonjans, Maria Vittoria Vettori, Stefan Weigel, Ruud J. Peters. Regulatory Toxicology and Pharmacology Volume 73, Issue 1, October 2015, Pages 463–476 doi:10.1016/j.yrtph.2015.06.016
This is the most inclusive overview I’ve seen yet. The authors cover Asian countries, South America, Africa, and the MIddle East, as well as, the usual suspects in Europe and North America.
Given I’m a Canadian blogger I feel obliged to include their summary of the Canadian situation (Note: Links have been removed),
The Canadian Food Inspection Agency (CFIA) and Public Health Agency of Canada (PHAC), who have recently joined the Health Portfolio of Health Canada, are responsible for food regulation in Canada. No specific regulation for nanotechnology-based food products is available but such products are regulated under the existing legislative and regulatory frameworks.11 In October 2011 Health Canada published a “Policy Statement on Health Canada’s Working Definition for Nanomaterials” (Health Canada, 2011), the document provides a (working) definition of NM which is focused, similarly to the US definition, on the nanoscale dimensions, or on the nanoscale properties/phenomena of the material (see Annex I). For what concerns general chemicals regulation in Canada, the New Substances (NS) program must ensure that new substances, including substances that are at the nano-scale (i.e. NMs), are assessed in order to determine their toxicological profile ( Environment Canada, 2014). The approach applied involves a pre-manufacture and pre-import notification and assessment process. In 2014, the New Substances program published a guidance aimed at increasing clarity on which NMs are subject to assessment in Canada ( Environment Canada, 2014).
Canadian and US regulatory agencies are working towards harmonising the regulatory approaches for NMs under the US-Canada Regulatory Cooperation Council (RCC) Nanotechnology Initiative.12 Canada and the US recently published a Joint Forward Plan where findings and lessons learnt from the RCC Nanotechnology Initiative are discussed (Canada–United States Regulatory Cooperation Council (RCC) 2014).
Based on their summary of the Canadian situation, with which I am familiar, they’ve done a good job of summarizing. Here are a few of the countries whose regulatory instruments have not been mentioned here before (Note: Links have been removed),
In Turkey a national or regional policy for the responsible development of nanotechnology is under development (OECD, 2013b). Nanotechnology is considered as a strategic technological field and at present 32 nanotechnology research centres are working in this field. Turkey participates as an observer in the EFSA Nano Network (Section 3.6) along with other EU candidate countries Former Yugoslav Republic of Macedonia, and Montenegro (EFSA, 2012). The Inventory and Control of Chemicals Regulation entered into force in Turkey in 2008, which represents a scale-down version of the REACH Regulation (Bergeson et al. 2010). Moreover, the Ministry of Environment and Urban Planning published a Turkish version of CLP Regulation (known as SEA in Turkish) to enter into force as of 1st June 2016 (Intertek).
The Russian legislation on food safety is based on regulatory documents such as the Sanitary Rules and Regulations (“SanPiN”), but also on national standards (known as “GOST”) and technical regulations (Office of Agricultural Affairs of the USDA, 2009). The Russian policy on nanotechnology in the industrial sector has been defined in some national programmes (e.g. Nanotechnology Industry Development Program) and a Russian Corporation of Nanotechnologies was established in 2007.15 As reported by FAO/WHO (FAO/WHO, 2013), 17 documents which deal with the risk assessment of NMs in the food sector were released within such federal programs. Safe reference levels on nanoparticles impact on the human body were developed and implemented in the sanitary regulation for the nanoforms of silver and titanium dioxide and, single wall carbon nanotubes (FAO/WHO, 2013).
Other countries included in this overview are Brazil, India, Japan, China, Malaysia, Iran, Thailand, Taiwan, Australia, New Zealand, US, South Africa, South Korea, Switzerland, and the countries of the European Union.
I don’t often stumble across information about Kenya’s nanotechnology efforts (my last was in a Sept. 1, 2011 posting) but I’m going include my latest find here even though I can’t track down the original source for the information. From an April 29, 2015 news item on SpyGhana (original source: Xinhua News Agency, official press agency of the People’s Republic of China),
The Kenyan government will soon adopt a comprehensive policy to promote use of nanotechnology in diverse fields like medicine, agriculture, manufacturing and environment.
“Nanotechnology as a science promises more for less. The competitive edge for Kenya as a developing nation lies in robust investments in this technology,” Njeri Wamae, chairman of National Commission for Science, Technology and Innovation (NACOSTI), said in Nairobi.
Nanotechnology is relatively new in Kenya though the government has prioritized its development through research, training and setting up of supportive infrastructure.
Wamae noted that enactment of a nanotechnology policy will position Kenya as a hub for emerging technologies that would revolutionalize key sectors of the economy.
Policy briefs from Kenya’s scientific research body indicates that globally, nanotechnology was incorporated into manufacturing goods worth over 30 billion U.S. dollars in 2005.
The briefs added that nanotechnology related business was worth 2.6 trillion dollars by 2015. Kenya has borrowed best practices from industrialized countries and emerging economies to develop nanotechnology.
Professor Erastus Gatebe, an official at Kenya Industrial Research and Development Institute (KIRDI), noted that China and India offers vital lessons on harnessing nanotechnology to propel industrial growth.
The ATPS has secured funding for a new Integrated Program (IP) on “Nanotechnologies for Development in India, Kenya and the Netherlands: Towards a Framework for Democratic Governance of Risks in Developing Countries, January 2010 – 2014, in liaison with partners in Europe and India. This IP which is led by Prof. Wiebe Bijker of the University of Maastricht, the Netherlands addresses the inevitable risks and benefits associated with emerging technologies, such as nanotechnology through a triangulation of PhD and Post-Doctoral positions drawn from Africa (2), India (1) and the Netherlands (2) based at the University of Maastricht but address core areas of the nanotechnology governance in Africa, India and the Netherlands. The program will be coordinated by Prof. Wiebe Bijker, the University of Maastricht, in the Netherlands; with the University of Hyderabad, India; the ATPS and the University of Nairobi, Kenya as partners.
The National Science, Technology and Innovation (ST&I) Week, organised by the Ministry of Higher Education, Science and Technology, is a major event on the annual calendar of the Kenyan Government.
The theme for 2013, “Science, Technology and Innovation for the realisation of Kenya’s Vision 2030 and beyond” is aligned with the national vision to transform Kenya into a newly industrialised, middle-income country providing a high-quality life to all its citizens in a safe and secure environment by the year 2030. pemphasis mine]
Nanotechnology, the science of the future
SAASTA representatives Mthuthuzeli Zamxaka and Sizwe Khoza were invited to participate in this year’s festival in Nairobi [Kenya] on behalf of the Nanotechnology Public Engagement Programme (NPEP).
Zamxaka delivered a stirring presentation titled Nanotechnology Public Engagement: The Case of South Africa. He introduced the topic of nanotechnology, focusing on engagement, outreach and awareness. …
Zamxaka touched on a number of nanotechnologies that are currently being applied, such as the research conducted by the Johns Hopkins University in Maryland on biodegradable nano-sized particles that can easily slip through the body’s sticky and viscous mucus secretions to deliver a sustained-release medication cargo. It is believed that these nanoparticles, which degrade over time into harmless components, could one day carry life-saving drugs to patients suffering from dozens of health conditions, including diseases of the eye, lung, gut or female reproductive tract.
For anyone interested , look here for Kenya’s Vision 2030. Harkening back to the first news item and the mention of NACOSTI, Kenya’s National Commission for Science, Technology and Innovation, it can be found here.