Tag Archives: iridescence

Peacocks and their structural colour inspire better resolution in e-readers

Thank goodness birds, insects, and other denizens of the natural world have not taken to filing patents otherwise we’d be having some serious problems in the courts as I have hinted in previous postings including this March 29, 2012 posting titled, Butterflies give and give … .

This time, it’s the peacock which is sharing its intellectual property as per this Feb. 5, 2013 news item on ScienceDaily,

Now, researchers at the University of Michigan have found a way to lock in so-called structural color, which is made with texture rather than chemicals. A paper on the work is published online in the current edition of the Nature journal Scientific Reports.

In a peacock’s mother-of-pearl tail, precisely arranged hairline grooves reflect light of certain wavelengths. That’s why the resulting colors appear different depending on the movement of the animal or the observer. Imitating this system—minus the rainbow effect—has been a leading approach to developing next-generation reflective displays.

The University of Michigan Feb. 5, 2013 news release, which originated the news item, provides information about potential applications and more details about the science,

The new U-M research could lead to advanced color e-books and electronic paper, as well as other color reflective screens that don’t need their own light to be readable. Reflective displays consume much less power than their backlit cousins in laptops, tablet computers, smartphones and TVs. The technology could also enable leaps in data storage and cryptography. Documents could be marked invisibly to prevent counterfeiting.

Led by Jay Guo, professor of electrical engineering and computer science, the researchers harnessed the ability of light to funnel into nanoscale metallic grooves and get trapped inside. With this approach, they found the reflected hues stay true regardless of the viewer’s angle.

“That’s the magic part of the work,” Guo said. “Light is funneled into the nanocavity, whose width is much, much smaller than the wavelength of the light. And that’s how we can achieve color with resolution beyond the diffraction limit. Also counterintuitive is that longer wavelength light gets trapped in narrower grooves.”

The diffraction limit was long thought to be the smallest point you could focus a beam of light to. Others have broken the limit as well, but the U-M team did so with a simpler technique that also produces stable and relatively easy-to-make color, Guo said.

“Each individual groove—much smaller than the light wavelength—is sufficient to do this function. In a sense, only the green light can fit into the nanogroove of a certain size,” Guo said.

The U-M team determined what size slit would catch what color light. Within the framework of the print industry standard cyan, magenta and yellow color model, the team found that at groove depths of 170 nanometers and spacing of 180 nanometers, a slit 40 nanometers wide can trap red light and reflect a cyan color. A slit 60 nanometers wide can trap green and make magenta. And one 90 nanometers wide traps blue and produces yellow. The visible spectrum spans from about 400 nanometers for violet to 700 nanometers for red.

“With this reflective color, you could view the display in sunlight. It’s very similar to color print,” Guo said.

Particularly interesting (for someone who worked in the graphic arts/printing industry as I did) are the base colours being used to create all the other colours,

To make color on white paper, (which is also a reflective surface), printers arrange pixels of cyan, magenta and yellow in such a way that they appear to our eyes as the colors of the spectrum. [emphasis mine] A display that utilized Guo’s approach would work in a similar way.

To demonstrate their device, the researchers etched nanoscale grooves in a plate of glass with the technique commonly used to make integrated circuits, or computer chips. Then they coated the grooved glass plate with a thin layer of silver. When light—which is a combination of electric and magnetic field components—hits the grooved surface, its electric component creates what’s called a polarization charge at the metal slit surface, boosting the local electric field near the slit. That electric field pulls a particular wavelength of light in.

The base colours in printing are CMYK (cyan, magenta, yellow, black). At least, that was the case when I worked in the graphic arts industry and quick search on the web suggests that standard still holds.(Have I missed a refinement?) In any event, here’s an image that demonstrates how this new colour scale can be used,

University of Michigan researchers created the color in these tiny Olympic rings using precisely-sized nanoscale slits in a glass plate coated with silver. Each ring is about 20 microns, smaller than the width of a human hair. They can produce different colors with different widths of the slits. Yellow is produced with slits that are each 90 nanometers wide. The technique takes advantage of a phenomenon called light funneling that can catch and trap particular wavelengths of light, and it could lead to reflective display screens with colors that stay true regardless of the viewer's angle. Image credit: Jay Guo, College of Engineering

University of Michigan researchers created the color in these tiny Olympic rings using precisely-sized nanoscale slits in a glass plate coated with silver. Each ring is about 20 microns, smaller than the width of a human hair. They can produce different colors with different widths of the slits. Yellow is produced with slits that are each 90 nanometers wide. The technique takes advantage of a phenomenon called light funneling that can catch and trap particular wavelengths of light, and it could lead to reflective display screens with colors that stay true regardless of the viewer’s angle. Image credit: Jay Guo, College of Engineering

You can find more about this work in the ScienceDaily news item, which includes a link to the abstract, or in the University of Michigan news release, which includes more images from the scientists.

Nerve endings, iridescence, and camouflage amongst the squid

Iridescence is a magical thing as far as I’m concerned. I know the scientists at the Marine Biology Laboratory (MBL) in Woods Hole, Massachusetts have mundane reasons for studying the iridescence in squid but I detect a hint of the fascination in the description of their work in the Aug. 27, 2012 news item on ScienceDaily,

Squid skin is extraordinary because it has two ways to produce color and pattern. Pigmented organs called chromatophores create patterns with yellow, red, and brown colors. Underneath the pigments, iridophores, aggregations of iridescent cells in the skin, reflect light and add blue, green, and pink colors to the overall appearance of the skin. Collectively these two groups of skin elements can create spectacular optical illusions with patterns of color, brightness, and contrast change.

“For 20 years we have been wondering how the dynamically changeable iridescence is controlled by the squid,” says study co-author Roger Hanlon. “At long last we have clean evidence that there are dedicated nerve fibers that turn on and tune the color and brightness of iridophores. It is not an exaggeration to call this “electric skin.” The complex nerve network distributed throughout the squid’s skin instantly coordinates tens of thousands of chromatophores with iridescent reflectors for rapidly changing behaviors ranging from camouflage to signaling.”

The Aug. 24, 2012 MBL news release, which originated the news item, provides details about the study,

Working with longfin inshore squid (Doryteuthis pealeii), the researchers took a new approach to investigating the mystery behind the iridophore control mechanism.  By tracing a highly branched network of nerves and stimulating them electrically, they found that they could activate progressive color shifts from red and orange to yellow, green, and blue in just 15 seconds. The findings suggest that the specific color of each iridophore, as well as speed of change, is controlled by the nervous system, as is spatial chromatophore patterning that occurs in the skin layer just above.

The scientists have provided some images to illustrate the process,

Nerves in red can be easily traced among the distinctive chromatophores and iridophores that they innervate. (Credit: Wardill, Gonzalez-Bellido, Crook & Hanlon, Proceedings of the Royal Society B: Biological Sciences)

Neurally stimulated squid iridophore. (Credit: Wardill, Gonzalez-Bellido, Crook & Hanlon, Proceedings of the Royal Society B: Biological Sciences)

They’ve also created a brief, silent video showing the process of becoming iridescent in action,

What I found particularly interesting about iridescence and colour  in squid was this (from the Aug. 24, news release),

How squid choose and hold particular skin colors to help camouflage themselves remains unknown and is particularly interesting because the animals are completely colorblind.

For anyone interested in reading the study, here’s the citation from the ScienceDaily news item,

T. J. Wardill, P. T. Gonzalez-Bellido, R. J. Crook, R. T. Hanlon. Neural control of tuneable skin iridescence in squid. Proceedings of the Royal Society B: Biological Sciences, 2012; DOI: 10.1098/rspb.2012.1374

The article is behind a paywall.

ETA Aug. 28, 2012 1:15 pm PDT: I forgot to mention the ‘camouflage’ part of the headline in the context of this story. The ability to change colour in response to stimulae of one sort of another is often for the purpose of camouflage/concealment, a matter of some interest to the military. In this case (from the Aug. 24, 2012 news release),

The work was funded by grants from the Office of Naval Research (ONR), Defense Advanced Research Projects Agency (DARPA), and Air Force Office of Scientific Research.

I last wrote about squid and camouflage in my Aug. 17, 2012 posting on soft robots.

Morpho butterflies detect heat for GE

One wonders if Morpho butterflies are going to decide that they need to protect their intellectual property. Yet another scientific group has found a way to exploit the nanostructures on the Morpho butterfly’s wing.  From the Feb. 13, 2012 news item on Nanowerk,

GE [General Electric] scientists are exploring many potential thermal imaging and sensing applications with their new detection concept such as medical diagnostics, surveillance, non-destructive inspection and others, where visual heat maps of imaged areas serve as a valuable condition indicator. Some examples include:

  • Thermal Imaging for advanced medical diagnosis – to better visualize inflammation in the body and understand changes in a patient’s health earlier.
  • Advanced thermal vision – to see things at night and during the day in much greater detail than what is possible today.
  • Fire thermal Imaging – to aid firefighters with new handheld devices to enhance firefighter safety in operational situations
  • Thermal security surveillance – to improve public safety and homeland protection
  • Thermal characterization of wound infections – to facilitate early diagnosis.

“The iridescence of Morpho butterflies has inspired our team for yet another technological opportunity. This time we see the potential to develop the next generation of thermal imaging sensors that deliver higher sensitivity and faster response times in a more simplified, cost-effective design,” said Dr. Radislav Potyrailo, Principal Scientist at GE Global Research who leads GE’s bio-inspired photonics programs. “This new class of thermal imaging sensors promises significant improvements over existing detectors in their image quality, speed, sensitivity, size, power requirements, and cost.”

GE has provided a video and description that illustrates this newest biomimicry work. First the description then the video (from http://www.youtube.com/watch?v=UoaILSCzlTo&feature=youtu.be)

This is a thermographic video of a Morpho butterfly structure in response to heat pulses produced by breathing onto the whole butterfly structure (video part 1) and onto its localized areas (video part 2). Nanostructures on Morpho butterfly wings coated with carbon nanotubes can sense temperature chances down to .02 degrees Celsius, at a response rate of 1/40 of a second. This is a demonstration of how new bio-inspired designs by GE scientists could enable more advanced applications for industrial inspection, medical diagnostics and military. This video was filmed by Bryan Whalen in the Electronics Cooling Lab at GE Global Research.

This newest work seems to have its origins in a DARPA-funded (US Defense Advanced Research Projects Agency) GE project. From the Aug. 12, 2010 GE news release,

Scientists at GE Global Research, GE’s technology development arm, in collaboration with Air Force Research Laboratory, State University at Albany, and University of Exeter, have received a four-year, $6.3 million award from the Defense Advanced Research Projects Agency (DARPA) to develop new bio-inspired nanostructured sensors that would enable faster, more selective detection of dangerous warfare agents and explosives.

Three years ago, GE scientists discovered that nanostructures from wing scales of butterflies exhibited acute chemical sensing properties. [emphasis bold] Since then, GE scientists have been developing a dynamic, new sensing platform that replicates these unique properties.  Recognizing the potential of GE’s sensing technologies for improving homeland protection, DARPA is supporting further research. [emphasis mine]

For anyone who’s particularly interested in the technical details, Dexter Johnson offers more in his Feb. 13, 2012 posting about this research on the Nanoclast blog for the IEEE (Institute of Electrical and Electronics Engineers).

Marc Rembold’s nanotechnological colours at Jacana Gallery in Vancouver

Jacana Gallery (2435 Granville St., Vancouver, Canada) is displaying a piece described by a Swiss artist as (from the Marc Rembold webpage on the Jacana Gallery website)

Using high tech nanotechnological colours, materials and instruments I have the possibility to create more real (nearer to the liquid space) and strong colours. It allows me to define and create colours in a contemporary manner instead of using traditional pigments. In the series  LIQUIDS there is no use of pigments in oil or acrylic, no painterly technique, and no other ordinary processes to create colours is involved.

From there, the colours in their visible forms are treated manually and finally the polymethylmethacrylat process brings to the colors a final optical effect, giving them the visual quality of liquid precious stones.

Using high tech nanotechnological colours, materials and instruments I have the possibility to create more real (nearer to the liquid space) and strong colours. It allows me to define and create colours in a contemporary manner instead of using traditional pigments. In the series < LIQUIDS there is no use of pigments in oil or acrylic, no painterly technique, and no other ordinary processes to create colours is involved.

From there, the colours in their visible forms are treated manually and finally the polymethylmethacrylat process brings to the colors a final optical effect, giving them the visual quality of liquid precious stones.

The concept behind my work is the materialisation of light. Through electronic instrumentation and contemporary imaging processes, I bring the invisible realm of light’s colour spectrum to our eyes. I explore ways to manifest the beauty of something immaterial into vibrant, pure liquid-like colour.

Here’s Marc Rembold’s Welly, the work being featured at Jacana,

Welly by Marc Rembold (downloaded from the Jacana Gallery website)

I’m not sure how these colours are nanotechnological but they are certainly stunning. This reminds me of the work that’s based on Morpho butterfly wings, opals, jewel beetles, and other naturally iridescent animals and objects. All of it has to do with mimicking nanoscale structures in order to obtain certain optical properties. My May 20, 2011 posting is the latest on mimicking those optical properties.

 

UK team works on anti-counterfeiting using Morpho butterfly and jewel beetles as inspiration

The Morpho butterfly, peacock feather, and beetle shells exert a fascination for scientists these days. What they have in common is iridescence and that optical property is being pursued with single-minded passion. A research team from Sheffield University in the UK is the latest to come up with a prototype film which exploits the nanostructures making iridescent colour possible. From the May 18, 2011 news item on Nanowerk,

Scientists from the University of Sheffield have developed pigment-free, intensely coloured polymer materials, which could provide new, anti-counterfeit devices on passports or banknotes due to their difficulty to copy (“Continuously tuneable optical filters from self-assembled block copolymer blends”).

The polymers do not use pigments but instead exhibit intense colour due to their structure, similar to the way nature creates colour for beetle shells and butterfly wings.

Dr Andrew Parnell, from the University of Sheffield’s Department of Physics and Astronomy, said: “Our aim was to mimic the wonderful and funky coloured patterns found in nature, such as Peacock feathers. We now have a painter’s palette of colours that we can choose from using just two polymers to do this. We think that these materials have huge potential to be used commercially.”

Here’s a video of the work (there’s no explanation of what you’re seeing; the silence is total),

A minute and half of shiny stuff, I love the zen quality. Although I don’t really understand it, I do enjoy not knowing, just seeing.

There are two teams in Canada working along the same lines, Opalux (a spin-off company from the University of Toronto) about which I posted on Jan. 21, 2011 and Nanotech Security Corporation (a spin-off company from Simon Fraser University) about which I posted on Jan. 17, 2011. Both companies are also working to create films useful in anti-counterfeiting strategies.

Mark MacLachlan talks about beetles, biomimcry, and nanocrystalline cellulose

After mentioning the Café Scientifique talk coming up on Tuesday, March 29, 2011 at Vancouver’s (Canada) Railway Club in my March 24, 2011 posting (http://www.frogheart.ca/?p=3171), I’m happy to say that Mark MacLachlan, the featured speaker, has answered a few questions about himself, his work and what he plans to talk about. Here he is,

(a) Could you tell me a little bit about yourself and why you’re giving a talk for Café Scientifique?

I grew up in Quesnel then obtained my BSc degree at UBC and my PhD at the University of Toronto. After a 2 year post-doc at MIT, I returned to UBC where I have been a chemistry professor since 2001.

My research is in materials chemistry – we develop new materials that “do things”. That might include materials that change properties when exposed to another chemical (i.e., sensing) or light, or materials that can store gases in their interior. We are excited about developing new materials with unusual properties.

(b) How did you decide on your topic? Are people demanding to know about biomimcry?

I was invited to give a talk on our work we published in Nature on the coloured glasses. As these materials mimic the structures of beetle shells, I thought that would be an interesting angle for a more general talk.

(c) The description for your upcoming talk in common with the description of a paper you and your team published Nov. 2010 in Nature mentions irridescent beetle exoskeletons. Which came first, an interest in irridescence or an interest in nanocrystalline cellulose (or is nanocrystals of cellulose)? And, how was the connection between the two made?

An interest in NCC came first. We were working with NCC to develop composites of NCC/glass when we discovered the iridescent materials. It was then a few months later that we made the connection to beetle exoskeletons.

(d) What can your audience expect? Will you be singing about biomimicry and/or nanocrystalling cellulose or offering a mixed media show as part of the talk?

I will be talking about biomimicry a little and mostly about the materials. I plan to take a few samples with me.

e) Is your talk connected to the Nano Days events which run from March 26 – April 3, 2011 or is it coincidence?

Just a coincidence – this is the first I’ve heard of Nano Days!

f) Is there anything you’d like to add?

I’ve never been to Café Scientifique before and I am looking forward to this opportunity to share some science!

Thank you Mark MacLachlan. If you want to know more, check out the Railway Club at 579 Dunsmuir St. The event starts at 7:30 pm on Tuesday, March 29, 2011.