Tag Archives: Michigan Technological University (Michigan Tech)

Watching a nanosized space rocket under a microscope

That is a silent video depicting the research. For anyone who may be puzzled, there’s an Aug. 8, 2016 news item on Nanowerk featuring the research announcement from Michigan Technological University (Note: A link has been removed),

Researchers at the University of Maryland and Michigan Technological University have operated a tiny proposed satellite ion rocket under a microscope to see how it works (Nanotechnology, “Radiation-induced solidification of ionic liquid under extreme electric field”).

The rocket, called an electrospray thruster, is a drop of molten salt. When electricity is applied, it creates a field on the tip of the droplet, until ions begin streaming off the end. The force created by the rocket is less than the weight of a human hair, but in the vacuum of space it is enough to push a small object forward with a constant acceleration. Many of these tiny thrusters packed together could propel a spacecraft over great distances, maybe even to the nearest exoplanet, and they are particularly useful for Earth-orbiting nanosatellites, which can be as small as a shoe box. These thrusters are currently being tested on the European Space Agency’s LISA Pathfinder, which hopes to poise objects in space so precisely that they would only be disturbed by gravitational waves.

An Aug, 8, 2016 Michigan Technological University news release on EurekAlert, which originated the news item, explains further,

these droplet engines have a problem: sometimes they form needle-like spikes that disrupt the way the thruster works – they get in the way of the ions flowing outward and turn the liquid to a gel. Lyon B. King and Kurt Terhune, mechanical engineers at Michigan Tech, wanted to find out how this actually happens.

“The challenge is making measurements of features as small as a few molecules in the presence of a strong electric field, which is why we turned to John Cumings at the University of Maryland,” King says, explaining Cumings is known for his work with challenging materials and that they needed to look for a needle in a haystack. “Getting a close look at these droplets is like looking through a straw to find a penny somewhere on the floor of a room–and if that penny moves out of view, like the tip of the molten salt needles do–then you have to start searching for it all over again.”

At the Advanced Imaging and Microscopy Lab at the University of Maryland, Cumings put the tiny thruster in a transmission electron microscope – an advanced scope that can see things down to millionths of a meter. They watched as the droplet elongated and sharpened to a point, and then started emitting ions. Then the tree-like defects began to appear.

The researchers say that figuring out why these branched structures grow could help prevent them from forming. The problem occurs when high-energy electrons, like those used in the microscope’s imaging beam, impact the fluid causing damage to the molecules that they strike. This damages the molten salt’s molecular structure, so it thickens into a gel and no longer flows properly.

“We were able to watch the dendritic structures accumulate in real time,” says Kurt Terhune, a mechanical engineering graduate student and the study’s lead author. “The specific mechanism still needs to be investigated, but this could have importance for spacecraft in high-radiation environments.”

He adds that the microscope’s electron beam is more powerful than natural settings, but the gelling effect could affect the lifetime of electrospray thrusters in low-Earth and geosynchronous orbit.

Here’s a link to and a citation for the paper,

Radiation-induced solidification of ionic liquid under extreme electric field by Kurt J Terhune, Lyon B King, Kai He, and John Cumings. Nanotechnology, Volume 27, Number 37 DOI: http://dx.doi.org/10.1088/0957-4484/27/37/375701 Published 3 August 2016

© 2016 IOP Publishing Ltd

This paper is behind a paywall.

You gotta shake, shake, shake those nanomaterials out of the water

A team at Michigan Technological University (Michigan Tech) has developed a simple technique for clearing nanoparticles from water according to a Dec. 10, 2015 news item on Nanotechnology Now,

Nano implies small—and that’s great for use in medical devices, beauty products and smartphones—but it’s also a problem. The tiny nanoparticles, nanowires, nanotubes and other nanomaterials that make up our technology eventually find their way into water. The Environmental Protection Agency says more 1,300 commercial products use some kind of nanomaterial. And we just don’t know the full impact on health and the environment.

A Dec. 10, 2015 Michigan Tech news release, which originated the news item, describes the concept and the research in more detail,

“Look at plastic,” says Yoke Khin Yap, a professor of physics at Michigan Technological University. “These materials changed the world over the past decades—but can we clean up all the plastic in the ocean? We struggle to clean up meter-scale plastics, so what happens when we need to clean on the nano-scale?”

The method sounds like a salad dressing recipe: take water, sprinkle in nanomaterials, add oil and shake.

Water and oil don’t mix, of course, but shaking them together is what makes salad dressing so great. Only instead of emulsifying and capturing bits of shitake or basil in tiny olive oil bubbles, this mixture grabs nanomaterials.

Dongyan Zhang, a research professor of physics at Michigan Tech, led the experiments, which covered tests on carbon nanotubes, graphene, boron nitride nanotubes, boron nitride nanosheets and zinc oxide nanowires. Those are used in everything from carbon fiber golf clubs to sunscreen.

“These materials are very, very tiny, and that means if you try to remove them and clean them out of contaminated water, that it’s quite difficult,” Zhang says, adding that techniques like filter paper or meshes often don’t work.

What makes shaking work is the shape of one- and two-dimensional nanomaterials. As the oil and water separate after some rigorous shaking, the wires, tubes and sheets settle at the bottom of the oil, just above the water. The oils trap them. However, zero-dimensional nanomaterials, such as nanospheres do not get trapped.

The researchers, according to the news release, are attempting to anticipate the potential contamination of our water supply by nanomaterials and provide a solution before it happens,

We don’t have to wait until the final vote is in on whether nanomaterials have a positive or negative impact on people’s health and environmental health. With the simplicity of this technique, and how prolific nanomaterials are becoming, removing nanomaterials makes sense. Also, finding ways to effectively remove nanomaterials sooner rather than later could improve the technology’s market potential.

“Ideally for a new technology to be successfully implemented, it needs to be shown that the technology does not cause adverse effects to the environment,” Yap, Zhang and their co-authors write. “Therefore, unless the potential risks of introducing nanomaterials into the environment are properly addressed, it will hinder the industrialization of products incorporating nanotechnology.”

Purifying water and greening nanotechnology could be as simple as shaking a vial of water and oil.

Here’s a video about the research supplied by Michigan Tech,

Here’s a link to and a citation for the paper,

A Simple and Universal Technique To Extract One- and Two-Dimensional Nanomaterials from Contaminated Water by Bishnu Tiwari, Dongyan Zhang, Dustin Winslow, Chee Huei Lee, Boyi Hao, and Yoke Khin Yap. ACS Appl. Mater. Interfaces, 2015, 7 (47), pp 26108–26116 DOI: 10.1021/acsami.5b07542 Publication Date (Web): November 9, 2015

Copyright © 2015 American Chemical Society

This paper is behind a paywall.