Tag Archives: National Natural Science Foundation of China

The new knitting: electronics and batteries

Researchers from China have developed a new type of yarn for flexible electronics. A March 28, 2018 news item on Nanowerk announces the work, (Note: A link has been removed),

When someone thinks about knitting, they usually don’t conjure up an image of sweaters and scarves made of yarn that can power watches and lights. But that’s just what one group is reporting in ACS Nano (“Waterproof and Tailorable Elastic Rechargeable Yarn Zinc Ion Batteries by a Cross-Linked Polyacrylamide Electrolyte”). They have developed a rechargeable yarn battery that is waterproof and flexible. It also can be cut into pieces and still work.

A March 28, 2018 2018 American Chemical Society (ACS) news release (also on EurekAlert), which originated the news item, expands on the theme (Note: Links have been removed),

Most people are familiar with smartwatches, but for wearable electronics to progress, scientists will need to overcome the challenge of creating a device that is deformable, durable, versatile and wearable while still holding and maintaining a charge. One dimensional fiber or yarn has shown promise, since it is tiny, flexible and lightweight. Previous studies have had some success combining one-dimensional fibers with flexible Zn-MnO2 batteries, but many of these lose charge capacity and are not rechargeable. So, Chunyi Zhi and colleagues wanted to develop a rechargeable yarn zinc-ion battery that would maintain its charge capacity, while being waterproof and flexible.

The group twisted carbon nanotube fibers into a yarn, then coated one piece of yarn with zinc to form an anode, and another with magnesium oxide to form a cathode. These two pieces were then twisted like a double helix and coated with a polyacrylamide electrolyte and encased in silicone. Upon testing, the yarn zinc-ion battery was stable, had a high charge capacity and was rechargeable and waterproof. In addition, the material could be knitted and stretched. It also could be cut into several pieces, each of which could power a watch. In a proof-of-concept demonstration, eight pieces of the cut yarn battery were woven into a long piece that could power a belt containing 100 light emitting diodes (known as LEDs) and an electroluminescent panel.

The authors acknowledge funding from the National Natural Science Foundation of China and the Research Grants Council of Hong Kong Joint Research Scheme, City University of Hong Kong and the Sichuan Provincial Department of Science & Technology.

Here’s an image the researchers have used to illustrate their work,


Courtesy: American Chemical Society

Here’s a link to and a citation for the paper,

Waterproof and Tailorable Elastic Rechargeable Yarn Zinc Ion Batteries by a Cross-Linked Polyacrylamide Electrolyte by Hongfei Li, Zhuoxin Liu, Guojin Liang, Yang Huang, Yan Huang, Minshen Zhu, Zengxia Pe, Qi Xue, Zijie Tang, Yukun Wang, Baohua Li, and Chunyi Zhi. ACS Nano, Article ASAP DOI: 10.1021/acsnano.7b09003 Publication Date (Web): March 28, 2018

Copyright © 2018 American Chemical Society

This paper is behind a paywall.

A gripping problem: tree frogs lead the way

Courtesy: University of Glasgow

At least once a year, there must be a frog posting here (ETA: July 31, 2018 at 1640 hours: unusually, this is my second ‘frog’ posting in one week; my July 26, 2018 posting concerns a very desperate frog, Romeo). Prior to Romeo, this March 15, 2018 news item on phys.org tickled my fancy,

Scientists researching how tree frogs climb have discovered that a unique combination of adhesion and grip gives them perfect technique.

The new research, led by the University of Glasgow and published today [March 15, 2018] in the Journal of Experimental Biology, could have implications for areas of science such as robotics, as well as the production of climbing equipment and even tyre manufacture.

A March 15, 2018 University of Glasgow press release, which originated the news item, provides a little more detail,

Researchers found that, using their fluid-filled adhesive toe pads, tree frogs are able to grip to surfaces to climb. When surfaces aren’t smooth enough to allow adhesion, researchers found that the frogs relied on their long limbs to grip around objects.

University of Glasgow scientists Iain Hill and Jon Barnes gave the tree frogs a series of narrow and wide cylinders to climb. The research team found that on the narrow cylinders the frogs used their grip and adhesion pads, allowing them to climb the obstacle at speed. Wider cylinders were too large for the frogs to grip, so they could only climb more slowly using their suction adhesive pads.

When the cylinders were coated in sandpaper, preventing adhesion, the frogs could only climb the narrow ones slowly, using their grip. They were not able to climb the wider cylinders covered in sandpaper as they couldn’t use their grip or adhesion.

Dr Barnes said: “I have worked on tree frog research for many years and I find them fascinating. Work on tree frogs has been of interest to industry and other areas of science in the past, since their climbing abilities can offer us insights into the most efficient way to climb and stick to surfaces.

“Climbing robots, for instance, need ways to stick, they could be based either on gecko climbing or tree frog climbing.  This research demonstrates how a good climbing robot would need to combine gripping and adhesion to climb more efficiently.”

The study, “The biomechanics of tree frogs climbing curved surfaces: a gripping problem” is published in the Journal ofExperimental Biology. The work was funded by the Royal Society, London and by grants from the National Natural Science Foundation of China and the Natural Science Foundation of Jiangsu Province.

Here’s a link to and a citation for the paper (I love the pun in the title),

The biomechanics of tree frogs climbing curved surfaces: a gripping problem by Iain D. C. Hill, Benzheng Dong, W. Jon. P. Barnes, Aihong Ji, Thomas Endlein. Journal of Experimental Biology 2018 : jeb.168179 doi: 10.1242/jeb.168179 Published 19 January 2018

This paper is behind a paywall.

Nano with green tea for sensitive teeth

The future will be beautiful if scientists are successful with a new DNA (deoxyribonucleic acid) sunscreen (my Aug. 3, 2017 posting) and a new dental material for people with sensitive teeth. From an Aug. 2, 2017 news item on phys.org,

An ice cold drink is refreshing in the summer, but for people with sensitive teeth, it can cause a painful jolt in the mouth. This condition can be treated, but many current approaches don’t last long. Now researchers report in the journal ACS [American Chemical Society] Applied Materials & Interfaces the development of a new material with an extract from green tea that could fix this problem—and help prevent cavities in these susceptible patients.

An Aug. 2, 2017 ACS news release, which originated the news item, describes the problem and the work in more detail,

Tooth sensitivity commonly occurs when the protective layers of teeth are worn away, revealing a bony tissue called dentin. This tissue contains microscopic hollow tubes that, when exposed, allow hot and cold liquids and food to contact the underlying nerve endings in the teeth, causing pain. Unprotected dentin is also vulnerable to cavity formation. Plugging these tubes with a mineral called nanohydroxyapatite is a long-standing approach to treating sensitivity. But the material doesn’t stand up well to regular brushing, grinding, erosion or acid produced by cavity-causing bacteria. Cui Huang and colleagues wanted to tackle sensitivity and beat the bacteria at the same time.

The researchers encapsulated nanohydroxyapatite and a green tea polyphenol — epigallocatechin-3-gallate, or EGCG — in silica nanoparticles, which can stand up to acid and wear and tear. EGCG has been shown in previous studies to fight Streptococcus mutans, which forms biofilms that cause cavities. Testing on extracted wisdom teeth showed that the material plugged the dentin tubules, released EGCG for at least 96 hours, stood up to tooth erosion and brushing and prevented biofilm formation. It also showed low toxicity. Based on these findings, the researchers say the material could indeed be a good candidate for combating tooth sensitivity and cavities.

The authors acknowledge funding from the National Natural Science Foundation of China, the Natural Science Foundation of Hubei Province of China and the Fundamental Research Funds for the Central Universities.

Here’s a link to and a citation for the paper,

Development of Epigallocatechin-3-gallate-Encapsulated Nanohydroxyapatite/Mesoporous Silica for Therapeutic Management of Dentin Surface by Jian Yu, Hongye Yang, Kang Li, Hongyu Ren, Jinmei Lei, and Cui Huang. ACS Appl. Mater. Interfaces, Article ASAP DOI: 10.1021/acsami.7b06597 Publication Date (Web): July 13, 2017

Copyright © 2017 American Chemical Society

This paper is behind a paywall.

Powering up your graphene implants so you don’t get fried in the process

A Sept. 23, 2016 news item on phys.org describes a way of making graphene-based medical implants safer,

In the future, our health may be monitored and maintained by tiny sensors and drug dispensers, deployed within the body and made from graphene—one of the strongest, lightest materials in the world. Graphene is composed of a single sheet of carbon atoms, linked together like razor-thin chicken wire, and its properties may be tuned in countless ways, making it a versatile material for tiny, next-generation implants.

But graphene is incredibly stiff, whereas biological tissue is soft. Because of this, any power applied to operate a graphene implant could precipitously heat up and fry surrounding cells.

Now, engineers from MIT [Massachusetts Institute of Technology] and Tsinghua University in Beijing have precisely simulated how electrical power may generate heat between a single layer of graphene and a simple cell membrane. While direct contact between the two layers inevitably overheats and kills the cell, the researchers found they could prevent this effect with a very thin, in-between layer of water.

A Sept. 23, 2016 MIT news release by Emily Chu, which originated the news item, provides more technical details,

By tuning the thickness of this intermediate water layer, the researchers could carefully control the amount of heat transferred between graphene and biological tissue. They also identified the critical power to apply to the graphene layer, without frying the cell membrane. …

Co-author Zhao Qin, a research scientist in MIT’s Department of Civil and Environmental Engineering (CEE), says the team’s simulations may help guide the development of graphene implants and their optimal power requirements.

“We’ve provided a lot of insight, like what’s the critical power we can accept that will not fry the cell,” Qin says. “But sometimes we might want to intentionally increase the temperature, because for some biomedical applications, we want to kill cells like cancer cells. This work can also be used as guidance [for those efforts.]”

Sandwich model

Typically, heat travels between two materials via vibrations in each material’s atoms. These atoms are always vibrating, at frequencies that depend on the properties of their materials. As a surface heats up, its atoms vibrate even more, causing collisions with other atoms and transferring heat in the process.

The researchers sought to accurately characterize the way heat travels, at the level of individual atoms, between graphene and biological tissue. To do this, they considered the simplest interface, comprising a small, 500-nanometer-square sheet of graphene and a simple cell membrane, separated by a thin layer of water.

“In the body, water is everywhere, and the outer surface of membranes will always like to interact with water, so you cannot totally remove it,” Qin says. “So we came up with a sandwich model for graphene, water, and membrane, that is a crystal clear system for seeing the thermal conductance between these two materials.”

Qin’s colleagues at Tsinghua University had previously developed a model to precisely simulate the interactions between atoms in graphene and water, using density functional theory — a computational modeling technique that considers the structure of an atom’s electrons in determining how that atom will interact with other atoms.

However, to apply this modeling technique to the group’s sandwich model, which comprised about half a million atoms, would have required an incredible amount of computational power. Instead, Qin and his colleagues used classical molecular dynamics — a mathematical technique based on a “force field” potential function, or a simplified version of the interactions between atoms — that enabled them to efficiently calculate interactions within larger atomic systems.

The researchers then built an atom-level sandwich model of graphene, water, and a cell membrane, based on the group’s simplified force field. They carried out molecular dynamics simulations in which they changed the amount of power applied to the graphene, as well as the thickness of the intermediate water layer, and observed the amount of heat that carried over from the graphene to the cell membrane.

Watery crystals

Because the stiffness of graphene and biological tissue is so different, Qin and his colleagues expected that heat would conduct rather poorly between the two materials, building up steeply in the graphene before flooding and overheating the cell membrane. However, the intermediate water layer helped dissipate this heat, easing its conduction and preventing a temperature spike in the cell membrane.

Looking more closely at the interactions within this interface, the researchers made a surprising discovery: Within the sandwich model, the water, pressed against graphene’s chicken-wire pattern, morphed into a similar crystal-like structure.

“Graphene’s lattice acts like a template to guide the water to form network structures,” Qin explains. “The water acts more like a solid material and makes the stiffness transition from graphene and membrane less abrupt. We think this helps heat to conduct from graphene to the membrane side.”

The group varied the thickness of the intermediate water layer in simulations, and found that a 1-nanometer-wide layer of water helped to dissipate heat very effectively. In terms of the power applied to the system, they calculated that about a megawatt of power per meter squared, applied in tiny, microsecond bursts, was the most power that could be applied to the interface without overheating the cell membrane.

Qin says going forward, implant designers can use the group’s model and simulations to determine the critical power requirements for graphene devices of different dimensions. As for how they might practically control the thickness of the intermediate water layer, he says graphene’s surface may be modified to attract a particular number of water molecules.

“I think graphene provides a very promising candidate for implantable devices,” Qin says. “Our calculations can provide knowledge for designing these devices in the future, for specific applications, like sensors, monitors, and other biomedical applications.”

This research was supported in part by the MIT International Science and Technology Initiative (MISTI): MIT-China Seed Fund, the National Natural Science Foundation of China, DARPA [US Defense Advanced Research Projects Agency], the Department of Defense (DoD) Office of Naval Research, the DoD Multidisciplinary Research Initiatives program, the MIT Energy Initiative, and the National Science Foundation.

Here’s a link to and a citation for the paper,

Intercalated water layers promote thermal dissipation at bio–nano interfaces by Yanlei Wang, Zhao Qin, Markus J. Buehler, & Zhiping Xu. Nature Communications 7, Article number: 12854 doi:10.1038/ncomms12854 Published 23 September 2016

This paper is open access.

Dual purpose: loofah and battery?

Sadly, the proposed batteries are not dual purpose although they are based on loofah material. From a June 15, 2016 news item on phys.org,

Today’s mobile lifestyle depends on rechargeable lithium batteries. But to take these storage devices to the next level—to shore up the electric grid or for widespread use in vehicles, for example—they need a big boost in capacity. To get lithium batteries up to snuff for more ambitious applications, researchers report in the journal ACS Applied Materials & Interfaces a new solution that involves low-cost, renewable loofah sponges.

A June 15, 2016 American Chemical Society press release (also on EurekAlert), which originated the news item, expands on the theme,

The lithium-ion batteries that power most of our devices still have some room for improvement. But some experts predict that even when these batteries are fully optimized, they still will not be able to meet the power needs for larger-scale applications, such as taking a car 500 miles on one charge. Scientists looking to go beyond lithium-ion have turned to lithium-sulfur and other options. But a major challenge to commercializing these technologies remains: The cathodes crumble over time, leading to progressively lower capacity. Shanqing Zhang, Yanglong Hou, Li-Min Liu and colleagues wanted to find a way to stabilize these alternatives.

The researchers developed a “blocking” layer of highly conductive, porous carbon derived from a loofah sponge. The loofah-derived membrane helped prevent the cathode from dissolving in lithium-sulfur, lithium-selenium and lithium-iodine batteries — and all three types performed well consistently over 500 to 5,000 cycles. The loofah sponge carbon could be the advance needed to move these batteries forward in a low-cost, sustainable way, the researchers say.

Here’s a link to and a citation for the paper,

Multifunctional Nitrogen-Doped Loofah Sponge Carbon Blocking Layer for High-Performance Rechargeable Lithium Batteries by Xingxing Gui, Chuan-Jia Tong, Sarish Rehman, Li-Min Liu, Yanglong Hou, and Shanqing Zhang. ACS Appl. Mater. Interfaces, Article ASAP DOI: 10.1021/acsami.6b02378 Publication Date (Web): June 02, 2016

Copyright © 2016 American Chemical Society

This paper is behind a paywall.

The researchers have made an image illustrating the work available,

Courtesy American Chemical Society

Courtesy American Chemical Society

Here’s one final bit from the press release,

The authors acknowledge funding from the Australian Research Council, the National Natural Science Foundation of China and the Ministry of Education of China.

Funding sources can be very interesting and this adds confirmation of China’s focus on the environment and sustainability.