Tag Archives: Paul Scherrer Institute

Radiation-free quantum technology with graphene

Leave a reply

A July 8, 2021 news item on Nanowerk announces research from Finland and Switzerland that could have an impact on real world quantum technologies (Note: A link has been removed),

Rare-earth compounds have fascinated researchers for decades due to the unique quantum properties they display, which have so far remained totally out of reach of everyday compounds. One of the most remarkable and exotic properties of those materials is the emergence of exotic superconducting states, and particularly the superconducting states required to build future topological quantum computers.

While these specific rare-earth compounds, known as heavy fermion superconductors, have been known for decades, making usable quantum technologies out of them has remained a critically open challenge. This is because these materials contain critically radioactive compounds, such as uranium and plutonium, rendering them of limited use in real-world quantum technologies.

New research has now revealed an alternative pathway to engineer the fundamental phenomena of these rare-earth compounds solely with graphene, which has none of the safety problems of traditional rare-earth compounds.

The exciting result in the new paper shows how a quantum state known as a “heavy fermion” can be produced by combining three twisted graphene layers. A heavy fermion is a particle – in this case an electron – that behaves like it has a lot more mass than it actually does. The reason it behaves this way stems from unique quantum many-body effects that were mostly only observed in rare-earth compounds until now.

This heavy fermion behavior is known to be the driving force of the phenomena required to use these materials for topological quantum computing. This new result demonstrates a new, non-radioactive way of achieving this effect using only carbon, opening up a pathway for sustainably exploiting heavy fermion physics in quantum technologies.

A July 8, 2021 Aalto University press release (also on EurekAlert), which originated the news item, provides more details,

In the paper authored by Aline Ramires, (Paul Scherrer Institute, Switzerland) and Jose Lado (Aalto University), the researchers show how it is possible to create heavy fermions with cheap, non-radioactive materials. To do this, they used graphene, which is a one-atom thick layer of carbon. Despite being chemically identical to the material that is used in regular pencils, the sub-nanometre thickness of graphene means that it has unexpectedly unique electrical properties. By layering the thin sheets of carbon on top of one another in a specific pattern, where each sheet is rotated in relation to the other, the researchers can create the quantum properties effect that results in the electrons in the graphene behaving like heavy fermions.

“Until now, practical applications of heavy fermion superconductors for topological quantum computing has not been pursued much, partially because it required compounds containing uranium and plutonium, far from ideal for applications due to their radioactive nature”, says Professor Lado, “In this work we show that one can aim to realize the exactly very same physics just with graphene. While in this work we only show the emergence of heavy fermion behavior, addressing the emergence of topological superconductivity is a natural next step, which could potentially have a groundbreaking impact for topological quantum computing.”

Topological superconductivity is a topic of critical interest for quantum technologies, also tackled by alternative strategies in other papers from Aalto University Department of Applied Physics, including a previous paper by Professor Lado. “These results potentially provide a carbon-based platform for exploitation of heavy fermion phenomena in quantum technologies, without requiring rare-earth elements”, concludes Professor Lado.

Here’s a link to and a citation for the paper,

Emulating Heavy Fermions in Twisted Trilayer Graphene by Aline Ramires and Jose L. Lado. Phys. Rev. Lett. 127, 026401 DOI: https://doi.org/10.1103/PhysRevLett.127.026401 Published 7 July 2021 © 2021 American Physical Society

This paper is behind a paywall.

How vibrations affect nanoscale materials

Leave a reply

A March 9, 2016 news item on ScienceDaily announces work concerning atomic vibrations,

All materials are made up of atoms, which vibrate. These vibrations, or ‘phonons’, are responsible, for example, for how electric charge and heat is transported in materials. Vibrations of metals, semiconductors, and insulators in are well studied; however, now materials are being nanosized to bring better performance to applications such as displays, sensors, batteries, and catalytic membranes. What happens to vibrations when a material is nanosized has until now not been understood.

A March 9, 2016 ETH Zurich press release (also on EurekAlert), which originated the news item, describes the world of vibration at the nanoscale and the potential impact this new information could have,

Soft Surfaces Vibrate Strongly

In a recent publication in Nature, ETH Professor Vanessa Wood and her colleagues explain what happens to atomic vibrations when materials are nanosized and how this knowledge can be used to systematically engineer nanomaterials for different applications.

The paper shows that when materials are made smaller than about 10 to 20 nanometers – that is, 5,000 times thinner than a human air – the vibrations of the outermost atomic layers on surface of the nanoparticle are large and play an important role in how this material behaves.

“For some applications, like catalysis, thermoelectrics, or superconductivity, these large vibrations may be good, but for other applications like LEDs or solar cells, these vibrations are undesirable,” explains Wood.

Indeed, the paper explains why nanoparticle-based solar cells have until now not met their full promise.  The researchers showed using both experiment and theory that surface vibrations interact with electrons to reduce the photocurrent in solar cells.

“Now that we have proven that surface vibrations are important, we can systematically design materials to suppress or enhance these vibrations,” say Wood.

Improving Solar Cells

Wood’s research group has worked for a long time on a particular type of nanomaterial – colloidal nanocrystals – semiconductors with a diameter of 2 to 10 nanometers.  These materials are interesting because their optical and electrical properties are dependent on their size, which can be easily changed during their synthesis.

These materials are now used commercially as red- and green-light emitters in LED-based TVs and are being explored as possible materials for low cost, solution-processed solar cells.  Researchers have noticed that placing certain atoms around the surface of the nanocrystal can improve the performance of solar cells. The reason why this worked had not been understood.  The work published in the Nature paper now gives the answer:  a hard shell of atoms can suppress the vibrations and their interaction with electrons.  This means a higher photocurrent and a higher efficiency solar cell.

Big Science to Study the Nanoscale

Experiments were conducted in Professor Wood’s labs at ETH Zurich and at the Swiss Spallation Neutron Source at the Paul Scherrer Institute. By observing how neutrons scatter off atoms in a material, it is possible to quantify how atoms in a material vibrate. To understand the neutron measurements, simulations of the atomic vibrations were run at the Swiss National Supercomputing Center (CSCS) in Lugano. Wood says, “without access to these large facilities, this work would not have been possible. We are incredibly fortunate here in Switzerland to have these world class facilities.”

The researchers have made available an image illustrating their work,

Vibrations of atoms in materials, the "phonons", are responsible for how electric charge and heat is transported in materials (Graphics: Deniz Bozyigit / ETH Zurich)

Vibrations of atoms in materials, the “phonons”, are responsible for how electric charge and heat is transported in materials (Graphics: Deniz Bozyigit / ETH Zurich)

Here’s a link to and a citation for the paper,

Soft surfaces of nanomaterials enable strong phonon interactions by Deniz Bozyigit, Nuri Yazdani, Maksym Yarema, Olesya Yarema, Weyde Matteo Mario Lin, Sebastian Volk, Kantawong Vuttivorakulchai, Mathieu Luisier, Fanni Juranyi, & Vanessa Wood. Nature (2016)  doi:10.1038/nature16977 Published online 09 March 2016

This paper is behind a paywall.