Tag Archives: Polytechnique de Montréal

Graphene-boron nitride material research from Rice University (US) and Polytechnique Montréal (Canada)

A Jan. 13, 2016 Rice University news release (also on EurekAlert) highlights computational research on hybrid material (graphene-boron nitride),

Developing novel materials from the atoms up goes faster when some of the trial and error is eliminated. A new Rice University and Montreal Polytechnic study aims to do that for graphene and boron nitride hybrids.

Rice materials scientist Rouzbeh Shahsavari and Farzaneh Shayeganfar, a postdoctoral researcher at Montreal Polytechnic (also known as École Polytechnique de Montréal or Polytechnique de Montréal), designed computer simulations that combine graphene, the atom-thick form of carbon, with either carbon or boron nitride nanotubes.

Their hope is that such hybrids can leverage the best aspects of their constituent materials. Defining the properties of various combinations would simplify development for manufacturers who want to use these exotic materials in next-generation electronics. The researchers found not only electronic but also magnetic properties that could be useful.

Shahsavari’s lab studies materials to see how they can be made more efficient, functional and environmentally friendly. They include macroscale materials like cement and ceramics as well as nanoscale hybrids with unique properties.

“Whether it’s on the macro- or microscale, if we can know specifically what a hybrid will do before anyone goes to the trouble of fabricating it, we can save cost and time and perhaps enable new properties not possible with any of the constituents,” Shahsavari said.

His lab’s computer models simulate how the intrinsic energies of atoms influence each other as they bond into molecules. For the new work, the researchers modeled hybrid structures of graphene and carbon nanotubes and of graphene and boron nitride nanotubes.

“We wanted to investigate and compare the electronic and potentially magnetic properties of different junction configurations, including their stability, electronic band gaps and charge transfer,” he said. “Then we designed three different nanostructures with different junction geometry.”

Two were hybrids with graphene layers seamlessly joined to carbon nanotubes. The other was similar but, for the first time, they modeled a hybrid with boron nitride nanotubes. How the sheets and tubes merged determined the hybrid’s properties. They also built versions with nanotubes sandwiched between graphene layers.

Graphene is a perfect conductor when its atoms align as hexagonal rings, but the material becomes strained when it deforms to accommodate nanotubes in hybrids. The atoms balance their energies at these junctions by forming five-, seven- or eight-member rings. These all induce changes in the way electricity flows across the junctions, turning the hybrid material into a valuable semiconductor.

The researchers’ calculations allowed them to map out a number of effects. For example, it turned out the junctions of the hybrid system create pseudomagnetic fields.

“The pseudomagnetic field due to strain was reported earlier for graphene, but not these hybrid boron nitride and carbon nanostructures where strain is inherent to the system,” Shahsavari said. He noted the effect may be useful in spintronic and nano-transistor applications.

“The pseudomagnetic field causes charge carriers in the hybrid to circulate as if under the influence of an applied external magnetic field,” he said. “Thus, in view of the exceptional flexibility, strength and thermal conductivity of hybrid carbon and boron nitride systems, we propose the pseudomagnetic field may be a viable way to control the electronic structure of new materials.”

All the effects serve as a road map for nanoengineering applications, Shahsavari said.

“We’re laying the foundations for a range of tunable hybrid architectures, especially for boron nitride, which is as promising as graphene but much less explored,” he said. “Scientists have been studying all-carbon structures for years, but the development of boron nitride and other two-dimensional materials and their various combinations with each other gives us a rich set of possibilities for the design of materials with never-seen-before properties.”

Shahsavari is an assistant professor of civil and environmental engineering and of materials science and nanoengineering.

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Rice supported the research, and computational resources were provided by Calcul Quebec and Compute Canada.

Here’s a link to and a citation for the paper,

Electronic and pseudomagnetic properties of hybrid carbon/boron-nitride nanomaterials via ab-initio calculations and elasticity theory by Farzaneh Shayeganfar and Rouzbeh Shahsavari. Carbon Volume 99, April 2016, Pages 523–532 doi:10.1016/j.carbon.2015.12.050

This paper is behind a paywall.

Here’s an image illustrating the hybrid material,

Caption: The calculated properties of a three-dimensional hybrid of graphene and boron nitride nanotubes would have pseudomagnetic properties, according to researchers at Rice University and Montreal Polytechnic. Credit: Shahsavari Lab/Rice University

Caption: The calculated properties of a three-dimensional hybrid of graphene and boron nitride nanotubes would have pseudomagnetic properties, according to researchers at Rice University and Montreal Polytechnic. Credit: Shahsavari Lab/Rice University

Seeing quantum objects with the naked eye

This research is a collaborative effort between the Polytechnique de Montréal (or École polytechnique de Montréal; Canada) and the Imperial College of London (UK) according to a July 14, 2015 news item on Nanotechnology Now,

For the first time, the wavelike behaviour of a room-temperature polariton condensate has been demonstrated in the laboratory on a macroscopic length scale. This significant development in the understanding and manipulation of quantum objects is the outcome of a collaboration between Professor Stéphane Kéna-Cohen of Polytechnique Montréal, Professor Stefan Maier and research associate Konstantinos Daskalakis of Imperial College London. …

A July 14, 2015 Polytechnique de Montréal news release supplies an explanation of this ‘sciencish’ accomplishment,

Quantum objects visible to the naked eye

Quantum mechanics tells us that objects exhibit not only particle-like behaviour, but also wavelike behaviour with a wavelength inversely proportional to the object’s velocity. Normally, this behaviour can only be observed at atomic length scales. There is one important exception, however: with bosons, particles of a particular type that can be combined in large numbers in the same quantum state, it is possible to form macroscopic-scale quantum objects, called Bose-Einstein condensates.

These are at the root of some of quantum physics’ most fascinating phenomena, such as superfluidity and superconductivity. Their scientific importance is so great that their creation, nearly 70 years after their existence was theorized, earned researchers Eric Cornell, Wolfgang Ketterle and Carl Wieman the Nobel Prize in Physics in 2001.

A trap for half-light, half-matter quasi-particles

Placing particles in the same state to obtain a condensate normally requires the temperature to be lowered to a level near absolute zero: conditions achievable only with complex laboratory techniques and expensive cryogenic equipment.

“Unlike work carried out to date, which has mainly used ultracold atomic gases, our research allows comprehensive studies of condensation to be performed in condensed matter systems under ambient conditions” explains Mr. Daskalakis. He notes that this is a key step toward carrying out physics projects that currently remain purely theoretical.

To produce the room-temperature condensate, the team of researchers from Polytechnique and Imperial College first created a device that makes it possible for polaritons – hybrid quasi-particles that are part light and part matter – to exist. The device is composed of a film of organic molecules 100 nanometres thick, confined between two nearly perfect mirrors. The condensate is created by first exciting a sufficient number of polaritons using a laser and then observed via the blue light it emits. Its dimensions can be comparable to that of a human hair, a gigantic size on the quantum scale.

“To date, the majority of polariton experiments continue to use ultra-pure crystalline semiconductors,” says Professor Kéna-Cohen. “Our work demonstrates that it is possible to obtain comparable quantum behaviour using ‘impure’ and disordered materials such as organic molecules. This has the advantage of allowing for much simpler and lower-cost fabrication.”

The size of the condensate is a limiting factor

In addition to directly observing the organic polariton condensate’s wavelike behaviour, the experiment showed researchers that ultimately the condensate size could not exceed approximately 100 micrometres. Beyond this limit, the condensate begins to destroy itself, fragmenting and creating vortices.

Toward future polariton lasers and optical transistors

In a condensate, the polaritons all behave the same way, like photons in a laser. The study of room-temperature condensates paves the way for future technological breakthroughs such as polariton micro-lasers using low-cost organic materials, which are more efficient and require less activation power than  conventional lasers. Powerful transistors entirely powered by light are another possible application.

The research team foresees that the next major challenge in developing such applications will be to obtain a lower particle-condensation threshold so that the external laser used for pumping could be replaced by more practical electrical pumping.

Fertile ground for studying fundamental questions

According to Professor Maier, this research is also creating a platform to facilitate the study of fundamental questions in quantum mechanics. “It is linked to many modern and fascinating aspects of many-body physics, such as Bose-Einstein condensation and superfluidity, topics that also intrigue the general public,” he notes.

Professor Kéna-Cohen concludes: “One fascinating aspect, for example, is the extraordinary transition between the state of non-condensed particles and the formation of a condensate. On a small scale, the physics of this transition resemble an important step in the formation of the Universe after the Big Bang.”

Here’s a link to and a citation for the paper,

Spatial Coherence and Stability in a Disordered Organic Polariton Condensate by K. S. Daskalakis, S. A. Maier, and S. Kéna-Cohen Phys. Rev. Lett. 115 (3), 035301 DOI: 10.1103/PhysRevLett.115.035301 Published 13 July 2015

This article is behind a paywall but there is an earlier open access version  here: http://arxiv.org/pdf/1503.01373v2.