Tag Archives: Science Exchange

Super-black nanotechnology, space exploration, and carbon nanotubes grown by atomic layer deposition (ALD)

Super-black in this context means that very little light is reflected by the carbon nanotubes that a team at the US National Aeronautics and Space Administration (NASA) have produced. From a July 17, 2013 NASA news release (also here on EurekAlert),

A NASA engineer has achieved yet another milestone in his quest to advance an emerging super-black nanotechnology that promises to make spacecraft instruments more sensitive without enlarging their size.

A team led by John Hagopian, an optics engineer at NASA’s Goddard Space Flight Center in Greenbelt, Md., has demonstrated that it can grow a uniform layer of carbon nanotubes through the use of another emerging technology called atomic layer deposition or ALD. The marriage of the two technologies now means that NASA can grow nanotubes on three-dimensional components, such as complex baffles and tubes commonly used in optical instruments.

“The significance of this is that we have new tools that can make NASA instruments more sensitive without making our telescopes bigger and bigger,” Hagopian said. “This demonstrates the power of nanoscale technology, which is particularly applicable to a new class of less-expensive tiny satellites called Cubesats that NASA is developing to reduce the cost of space missions.”

(It’s the first time I’ve seen atomic layer deposition (ALD) described as an emerging technology; I’ve always thought of it as well established.)  Here’s a 2010 NASA video, which  provides a good explanation of this team’s work,

With the basic problem being less data due to light reflection from the instruments used to make the observations in space, the researchers determined that ALD might provide carbon nanotubes suitable for super-black instrumentation for space exploration. From the NASA news release,

To determine the viability of using ALD to create the catalyst layer, while Dwivedi [NASA Goddard co-investigator Vivek Dwivedi, University of Maryland] was building his new ALD reactor, Hagopian engaged through the Science Exchange the services of the Melbourne Centre for Nanofabrication (MCN), Australia’s largest nanofabrication research center. The Science Exchange is an online community marketplace where scientific service providers can offer their services. The NASA team delivered a number of components, including an intricately shaped occulter used in a new NASA-developed instrument for observing planets around other stars.

Through this collaboration, the Australian team fine-tuned the recipe for laying down the catalyst layer — in other words, the precise instructions detailing the type of precursor gas, the reactor temperature and pressure needed to deposit a uniform foundation. “The iron films that we deposited initially were not as uniform as other coatings we have worked with, so we needed a methodical development process to achieve the outcomes that NASA needed for the next step,” said Lachlan Hyde, MCN’s expert in ALD.

The Australian team succeeded, Hagopian said. “We have successfully grown carbon nanotubes on the samples we provided to MCN and they demonstrate properties very similar to those we’ve grown using other techniques for applying the catalyst layer. This has really opened up the possibilities for us. Our goal of ultimately applying a carbon-nanotube coating to complex instrument parts is nearly realized.”

For anyone who’d like a little more information about the Science Exchange, I posted about this scientific markeplace both on Sept. 2, 2011 after it was launched in August of that year and later on Dec. 19, 2011 in a followup about a specific nano project.

Getting back to super-black nanotechnology, here’s what the NASA team produced, from the news release,

During the research, Hagopian tuned the nano-based super-black material, making it ideal for this application, absorbing on average more than 99 percent of the ultraviolet, visible, infrared and far-infrared light that strikes it — a never-before-achieved milestone that now promises to open new frontiers in scientific discovery. The material consists of a thin coating of multi-walled carbon nanotubes about 10,000 times thinner than a strand of human hair.

Once a laboratory novelty grown only on silicon, the NASA team now grows these forests of vertical carbon tubes on commonly used spacecraft materials, such as titanium, copper and stainless steel. Tiny gaps between the tubes collect and trap light, while the carbon absorbs the photons, preventing them from reflecting off surfaces. Because only a small fraction of light reflects off the coating, the human eye and sensitive detectors see the material as black.

Before growing this forest of nanotubes on instrument parts, however, materials scientists must first deposit a highly uniform foundation or catalyst layer of iron oxide that supports the nanotube growth. For ALD, technicians do this by placing a component or some other substrate material inside a reactor chamber and sequentially pulsing different types of gases to create an ultra-thin film whose layers are literally no thicker than a single atom. Once applied, scientists then are ready to actually grow the carbon nanotubes. They place the component in another oven and heat the part to about 1,832  F (750 C). While it heats, the component is bathed in carbon-containing feedstock gas.

Congratulations to the team, I gather they’ve been working on this light absorption project for quite a while.

Science research marketplace

What’s a scientist to do when they need to get access to facilities and/or equipment not available in their own laboratory or their colleagues’ laboratories? The answer is go to Science Exchange. This ‘marketplace for science experiments’ opened for business in early August 2011 and, in less than one month, over 1000 scientists have signed up. Institutions such as Stanford University, Princeton University, Duke University, Johns Hopkins University, and another 60 or more have registered with the Exchange.

According to the Sept. 2, 2011 article by Michael Coren on the Fast Company website,

By connecting researchers with underutilized (or just cheaper) facilities and equipment to meet research needs, the business of scientific discovery may be on the verge of what Exchange’s co-founder Elizabeth Iorns said in an interview with Nature News is “totally disruptive” change that  “could transform the current very inefficient use of funds and dramatically change the way in which scientists do research.”

In the August 29, 2011 Nature News article by Zoë Corbyn, Irons describes the impetus for Science Exchange,

It was through my work as a breast-cancer biologist at the University of Miami in Florida. I wanted to conduct some experiments outside my field, and realized that I needed an external provider. What followed was an entirely frustrating process, and when I found the provider it was difficult to pay them because they were outside my university’s purchasing system. When I talked to other scientists, it became clear that this was a really big problem, but also one that could be solved with a marketplace. Development of the website started around a kitchen table in Miami in April.

Here’s an example of the activity taking place on the Exchange,

Prices can vary dramatically: for example, through our platform I have seen bids to perform a microRNA study ranging from US$3,500 to $9,000. Those who do the work can also build reputations independent of their publications by gaining feedback from those they work with.

This is intended as a profit-making endeavour with transaction costs of 5% for bids of $5000 and less while more costly bids will be assessed a lower percentage on a sliding scale. Angel investors have already contributed $320,000 and $1M more is being sought. Originally focused on the US, the founders have discovered there is international interest.