Category Archives: military

Nano-clouds change colour and temperature and can provide thermal camouflage

Caption: The bio-inspired metasurfaces act like a real cloud, enabling daytime cooling, heating and thermal camouflage in a single solution. Credit: Mady Elbahri / Aalto University

While I don’t have a military story for today (Remembrance Day, November 11, 2025), there is the ‘camouflage’ story. A June 30, 2025 news item on Nanowerk announces research into mimicking clouds,

How does a cloud stay cool under direct sunlight –– or seem to vanish in infrared? In nature, phenomena like white cumulus clouds, grey storm systems, and even the hollow hairs of polar bears offer remarkable lessons in balancing temperature, colour and invisibility. Inspired by these atmospheric marvels, researchers have now created a nanoscale ‘cloud’ metasurface capable of dynamically switching between white and grey states — cooling or heating on demand –– all while evading thermal detection.

…..

A June 27, 2025 Aalto University press release (also on EurekAlert but published June 30, 2025), which originated the news item, further describes research into simulating clouds,\

There is a major global push for passive, energy-efficient thermal management in building materials, wearables, sensors and defence applications. This newly invented system fits perfectly into emerging fields like radiative cooling, adaptive coatings, and thermal heating and thermal camouflage under climate and security pressures.

Much like the transformation from bright cumulus to dark cumulonimbus clouds, this metasurface uses multiple scattering, absorption and polarizonic reflection principles to modulate light and heat. In its ‘white’ state, it strongly backscatters sunlight to enable radiative cooling, while the ‘grey’ state absorbs sunlight efficiently for high-performance heating. Crucially, both states remain ‘invisible’ to infrared sensors due to low mid-infrared emissivity — something no previous surface has achieved.

‘We’ve engineered a nanoscale cloud on every surface. It can tune its colour and temperature like a real cloud — between cooling white and heating grey — while staying hidden from thermal cameras,’ Professor Mady Elbahri from Aalto University explains.

Both white and grey metasurfaces overcome limitations of traditional coatings

Typical white paints cool surfaces by scattering sunlight in all directions, but they still glow in heat vision. This new material works more like a cloud — cooling by bouncing sunlight back and staying hidden from heat sensors.

Conventional white coatings (e.g., titanium dioxide, TiO₂ based) scatter sunlight diffusively, but are only effective in shaded conditions or at night. Their high emissivity in the 8–13 μm range makes them bright in thermal infrared imaging, limiting use in thermal stealth.
‘This new white plasmonic metasurface scatters sunlight through disordered metallic nanostructures while minimising thermal emission — cooling surfaces in full sunlight and remaining thermally camouflaged. This feature makes the innovation groundbreaking,’ says Adel Assad, a PhD student in the group.

Black materials get hot in the sun but also light up thermal cameras as they emit infrared strongly.

‘This grey surface gets hotter than black—but without sending out heat that can be seen by heat sensors. This could be a game-changer for smart textiles, building materials, and camouflage, says Moheb Abdelaziz, a postdoctoral researcher in the group.

Great potential grows from humble beginnings

The research opens new pathways in adaptive surface engineering. Potential applications span from zero-energy building facades that switch between heating and cooling to smart textiles that regulate body temperature without electronics. The discovery also presents opportunities in low-visibility sensors and devices for defence and surveillance.

The next step for the research is to explore dynamic coatings using electrochromic or phase-changing layers for real-time, user-controlled switching between states.

The researchers are proud that the remarkable findings came despite an initial project rejection.

‘With no dedicated funding after initial setbacks, we relied on shared vision and collaboration –– especially with our partners in Germany –– to turn doubt into discovery. It’s proof that science, like clouds, can rise against the odds,’ says Elbahri.

Here’s a link to and a citation for the paper,

Cloud Inspired White and Grey Plasmonic Metasurfaces for Camouflaged Thermal Management by Mhd Adel Assad, Moheb Abdelaziz, Torge Hartig, Thomas Strunskus, Alexander Vahl, Franz Faupel, Mady Elbahri. Advanced Materials DOI: https://doi.org/10.1002/adma.202501080 First published: 06 June 2025

This paper is behind a paywall.

Nanotechnology-enabled contact lenses that give infrared vision to humans

A May 22, 2025 news item on Nanowerk announced a nanotechnology-enabled contact lens that made international news, Note: A link has been removed,

Neuroscientists and materials scientists have created contact lenses that enable infrared vision in both humans and mice by converting infrared light into visible light. Unlike infrared night vision goggles, the contact lenses, described in the Cell Press journal Cell (“Near-infrared spatiotemporal color vision in humans enabled by upconversion contact lenses”), do not require a power source—and they enable the wearer to perceive multiple infrared wavelengths. Because they’re transparent, users can see both infrared and visible light simultaneously, though infrared vision was enhanced when participants had their eyes closed.

“Our research opens up the potential for non-invasive wearable devices to give people super-vision,” says senior author Tian Xue, a neuroscientist at the University of Science and Technology of China. “There are many potential applications right away for this material. For example, flickering infrared light could be used to transmit information in security, rescue, encryption or anti-counterfeiting settings.”

A May 22, 2025 Cell Press news release on EurekAlert, which originated the news item, goes on to describe how researchers were able to introduce new capabilities for contact lenses,

The contact lens technology uses nanoparticles that absorb infrared light and convert it into wavelengths that are visible to mammalian eyes (e.g., electromagnetic radiation in the 400-700 nm range). The nanoparticles specifically enable detection of “near-infrared light,” which is infrared light in the 800-1600 nm range, just beyond what humans can already see. The team previously showed that these nanoparticles enable infrared vision in mice when injected into the retina, but they wanted to design a less invasive option.  

To create the contact lenses, the team combined the nanoparticles with flexible, non-toxic polymers that are used in standard soft contact lenses. After showing that the contact lenses were non-toxic, they tested their function in both humans and mice. 

They found that contact lens-wearing mice displayed behaviors suggesting that they could see infrared wavelengths. For example, when the mice were given the choice of a dark box and an infrared-illuminated box, contact-wearing mice chose the dark box whereas contact-less mice showed no preference. The mice also showed physiological signals of infrared vision: the pupils of contact-wearing mice constricted in the presence of infrared light, and brain imaging revealed that infrared light caused their visual processing centers to light up.  

In humans, the infrared contact lenses enabled participants to accurately detect flashing morse code-like signals and to perceive the direction of incoming infrared light. “It’s totally clear cut: without the contact lenses, the subject cannot see anything, but when they put them on, they can clearly see the flickering of the infrared light,” said Xue. “We also found that when the subject closes their eyes, they’re even better able to receive this flickering information, because near-infrared light penetrates the eyelid more effectively than visible light, so there is less interference from visible light.”  

An additional tweak to the contact lenses allows users to differentiate between different spectra of infrared light by engineering the nanoparticles to color-code different infrared wavelengths. For example, infrared wavelengths of 980 nm were converted to blue light, wavelengths of 808 nm were converted to green light, and wavelengths of 1,532 nm were converted to red light. In addition to enabling wearers to perceive more detail within the infrared spectrum, these color-coding nanoparticles could be modified to help color blind people see wavelengths that they would otherwise be unable to detect. 

“By converting red visible light into something like green visible light, this technology could make the invisible visible for color blind people,” says Xue. 

Because the contact lenses have limited ability to capture fine details (due to their close proximity to the retina, which causes the converted light particles to scatter), the team also developed a wearable glass system using the same nanoparticle technology, which enabled participants to perceive higher-resolution infrared information.   

Currently, the contact lenses are only able to detect infrared radiation projected from an LED light source, but the researchers are working to increase the nanoparticles’ sensitivity so that they can detect lower levels of infrared light.  

“In the future, by working together with materials scientists and optical experts, we hope to make a contact lens with more precise spatial resolution and higher sensitivity,” says Xue.  

Jennifer Ouellette’s May 22, 2025 article for Ars Technica emphasizes the military aspect of this work,

Tired of using bulky night vision goggles for your clandestine nocturnal activities? An interdisciplinary team of Chinese neuroscientists and materials scientists has developed near-infrared contact lenses that enabled both mice and humans to see in the dark, even with their eyes closed, according to a new paper published in the journal Cell.

Humans and other mammals can only perceive a limited range of the electromagnetic spectrum (light), usually in the 400–700 nm range. There are creatures that can see in infrared (snakes, mosquitoes, bullfrogs) or ultraviolet (bees, birds), and goldfish can perceive both. But humans must augment themselves with technology in order to expand our range of vision.

Night vision goggles and similar devices have been around since the 1930s, including infrared-visible converters, but these require external energy sources, and the converters have a multilayer structure that makes them opaque and hence challenging to integrate with a human eye. The authors previously were able to confer near-infrared vision to mice by injecting nanoparticles that bind to photoreceptors into their eyes—basically creating a near-infrared nanoantenna—but realized that most people would be averse to the prospect of sticking needles in their eyes. So they looked for a better alternative. Contact lenses seemed the obvious choice.

Ouellette’s May 22, 2025 article is a good read.

Caption: Study participant putting contacts in Credit: Yuqian Ma, Yunuo Chen, Hang Zhao

Here’s a link to and a citation for the paper,

Near-infrared spatiotemporal color vision in humans enabled by upconversion contact lenses by Yuqian Ma (马玉乾), Yunuo Chen (陈雨诺), Sheng Wang, Zi-Han Chen, Yuanwei Zhang, Ling Huang, Xinxin Zhang, Fei Yin, Yunxuan Wang, Mingzhu Yang, Zhanjun Li, Kai Huang, Xin Fang, Zishuo Li, Minghong Wang, Wenhui Liu, Jia-Nan Li, Longfei Li, Hang Zhao, Min Wei, Yiming Shi, Rong Liu, Mei Zhang, Jutao Chen, Jiawei Shen, Jianjun Meng, Yupeng Yang, Fan Zhang, Xinglong Gong, Gang Han, Tian Xue (薛天). Cell Volume 188, Issue 13, 26 June 2025, Pages 3375-3388.e18 DOI: https://doi.org/10.1016/j.cell.2025.04.019 Available online 22 May 2025, Version of Record 26 June 2025

This paper is behind a paywall.

Precise color control in anti-counterfeiting technology with silver nanoparticles trapped in a polymer matrix

A December 4, 2024 news item on phys.org announces a new anti-counterfeiting technology from South Korea, Note: A link has been removed,

In a significant advancement in the field of anti-counterfeiting technology, Professor Jiseok Lee and his research team in the School of Energy and Chemical Engineering at UNIST [Ulsan National Institute of Science and Technology] have developed a new hidden anti-counterfeiting technology, harnessing the unique properties of silver nanoparticles (AgNPs). The results are published in Advanced Materials.

“The technology we have developed holds significant promise in preventing the counterfeiting of valuable artworks and defense materials, particularly in scenarios where authenticity must be verified against potential piracy,” Professor Lee explained.

The original December 4, 2024 Ulsan National Institute of Science and Technology (UNIST) press release by JooHyeon Heo, which originated the news item, provides more details about the work,

Abstract
Silver nanoparticles (AgNPs) are known for their unique plasmonic colors and interaction with light, making them ideal for color printing and data encoding. Traditional methods like electron beam lithography (EBL) and focused ion beam (FIB) milling, however, suffer from low throughput and high costs. In this paper, a scalable and cost-efficient method is introduced for producing multiplexed plasmonic colors by in situ photoreducing AgNPs within microgel architectures with controlled porosity. Utilizing a digital micro-mirror device (DMD)-based flow microlithography system combined with a programmable dithering-mask technique, the high-throughput synthesis of shape or barcoded microparticles is facilitated, along with large-scale, high-resolution images embedded with hidden multiplexed plasmonic colors. This approach allows for a hidden multiplexed plasmonic color code library, significant enhancing the encoding capacity of barcode microparticles from 33 to 303 (a 1000-fold increase). Additionally, quantitative agreement is achieved between chemically encrypted and optically decrypted plasmonic colors using a deep learning classifier. Moreover, the method also supports the production of large scale (>5.6 × 5.6 cm2), high-resolution (>300 dpi) microgel arrays encrypted with multiple plasmonic colors in under 30 min. The multiplexed plasmonic coloration strategy in microgel architectures paves a new way for hidden data storage, secure optical labeling, and anti-counterfeiting technologies.

The portrait of Mookpododo—an ink on-silk painting of grapes featured on the genuine Korean ₩50,000 bill—radiates a bright fluorescent green, an effect achieved through security ink that is visible under ultraviolet (UV) light. This feature remains concealed from the naked eye and is intended for use by professionals in financial institutions and other high-security environments.

[see news item]

The team leveraged the inherent disadvantage of AgNPs, which tend to discolor upon exposure to UV light, to create a controlled color development process. By trapping silver nanoparticles within a polymer matrix, researchers can manipulate particle size and, consequently, the color emitted under UV light. Larger polymer nets yield silver nanoparticles that appear yellow, while smaller nets produce a red hue, allowing for precise control of the resultant colors based on ingredient combinations.

Using these high-molecular structures as pixels, the research team successfully crafted high-resolution color images. Utilizing an automated photo-etching technique, they reduced the fabrication time to one-tenth of traditional methods, producing an image of a parrot larger than a standard business card in just 30 minutes. This digital process allows for flawless color printing, with precise control over saturation and tone.

In addition to images, anti-counterfeiting data can be discreetly embedded in arrangements of polymer structures that resemble red, yellow, and blue barcodes. The color response varies with UV exposure time, allowing for the storage of temporal information within the barcode structure. This innovative approach enables information storage capabilities to increase over 1,000-fold compared to conventional methods, with a potential for unlimited data encoding by arranging barcode particles without additional synthesis.

To enhance the reliability of this technology, the research team developed an artificial intelligence algorithm capable of analyzing barcode authenticity. This AI system boasts a remarkable reliability rate of 98.36%, distinguishing genuine barcodes from counterfeit ones by assessing material composition, UV exposure duration, and barcode integrity.

“The simplicity of the manufacturing process and the reproducibility of colors present a substantial opportunity for the advancement of information encryption systems, particularly in anti-counterfeiting applications,” stated Byungcheon Yoo, the lead author of the study.

The groundbreaking findings from this research were published in the online version of Advanced Materials on November 20, 2024. This research was supported by the National Research Foundation of Korea (NRF).

Here’s a link to and a citation for the paper,

High-Throughput Multiplexed Plasmonic Color Encryption of Microgel Architectures via Programmable Dithering-Mask Flow Microlithography by Byungcheon Yoo, Chaeyeong Ryu, Seunghwan Lee, Sanggyun Jeong, Younghoon You, Dahye Baek, Dowon Kim, Inkyu Jeon, Ki-Seok An, Jongwon Oh, Jiseok Lee. Advanced Materials DOI: https://doi.org/10.1002/adma.202405388 First published: 20 November 2024

This paper is behind a paywall.

Water, critical minerals, technology and US expansionist ambitions (Manifest Destiny)

I was taught in high school that the US was running out of its resources and that Canada still had much of its resources. That was decades ago. As well, throughout the years, usually during a vote in Québec about separating, I’ve heard rumblings about the US absorbing part or all of Canada as something they call ‘Manifest Destiny,’ which dates back to the 19th century.

Unlike the previous forays Into Manifest Destiny, this one has not been precipitated by any discussion of separation.

Manifest Destiny

It took a while for that phrase to emerge this time but when it finally did the Canadian Broadcasting Corporation (CBC) online news published a January 19, 2025 article by Ainsley Hawthorn providing some context for the term, Note: Links have been removed,

U.S. president-elect Donald Trump says he’s prepared to use economic force to turn Canada into America’s 51st state, and it’s making Canadians — two-thirds of whom believe he’s sincere — anxious. 

But the last time Canada faced the threat of American annexation, it united us more than ever before, leading to the foundation of our country as we know it today.

In the 1860s, several prominent U.S. politicians advocated for annexing the colonies of British North America. 

“I look on Rupert’s Land [modern-day Manitoba and parts of Alberta, Saskatchewan, Nunavut, Ontario, and Quebec] and Canada, and see how an ingenious people and a capable, enlightened government are occupied with bridging rivers and making railroads and telegraphs,” Secretary of State William Henry Seward told a crowd in St. Paul, Minn. while campaigning on behalf of presidential candidate Abraham Lincoln.

“I am able to say, it is very well; you are building excellent states to be hereafter admitted into the American Union.”

Seward believed in Manifest Destiny, the doctrine that the United States would inevitably expand across the entire North American continent. While he seems to have preferred to acquire territory through negotiation rather than aggression, Canadians weren’t wholly assured of America’s peaceful intentions. 

In the late 1850s and early 1860s, Canadian parliament had been so deadlocked it had practically come to a standstill. Within just a few years, American pressure created a sense of unity so great it led to Confederation.

The current conversation around annexation is likewise uniting Canada’s leaders to a degree we’ve rarely seen in recent years. 

Representatives across the political spectrum are sharing a common message, the same message as British North Americans in the late nineteenth century: despite our problems, Canadians value Canada.

Critical minerals and water

Prime Minister Justin Trudeau had a few comments to make about US President Donald Trump’s motivation for ‘absorbing’ Canada as the 51st state, from a February 7, 2025 CBC news online article by Peter Zimonjic, ·

Prime Minister Justin Trudeau told business leaders at the Canada-U.S. Economic Summit in Toronto that U.S. President Donald Trump’s threat to annex Canada “is a real thing” motivated by his desire to tap into the country’s critical minerals.

“Mr. Trump has it in mind that the easiest way to do it is absorbing our country and it is a real thing,” Trudeau said, before a microphone cut out at the start of the closed-door meeting. 

The prime minister made the remarks to more than 100 business leaders after delivering an opening address to the summit Friday morning [February 7, 2025], outlining the key issues facing the country when it comes to Canada’s trading relationship with the U.S.

After the opening address, media were ushered out of the room when a microphone that was left on picked up what was only meant to be heard by attendees [emphasis mine].

Automotive Parts Manufacturers’ Association president Flavio Volpe was in the room when Trudeau made the comments. He said the prime minister went on to say that Trump is driven because the U.S. could benefit from Canada’s critical mineral resources.

There was more, from a February 7, 2025 article by Nick Taylor-Vaisey for Politico., Note: A link has been removed,

In remarks caught on tape by The Toronto Star, Trudeau suggested the president is keenly aware of Canada’s vast mineral resources. “I suggest that not only does the Trump administration know how many critical minerals we have but that may be even why they keep talking about absorbing us and making us the 51st state,” Trudeau said.

All of this reminded me of US President Joe Biden’s visit to Canada and his interest in critical minerals which I mentioned briefly in my comments about the 2023 federal budget, from my April 17, 2023 posting (scroll down to the ‘Canadian economic theory (the staples theory), mining, nuclear energy, quantum science, and more’ subhead,

Critical minerals are getting a lot of attention these days. (They were featured in the 2022 budget, see my April 19, 2022 posting, scroll down to the Mining subhead.) This year, US President Joe Biden, in his first visit to Canada as President, singled out critical minerals at the end of his 28 hour state visit (from a March 24, 2023 CBC news online article by Alexander Panetta; Note: Links have been removed),

There was a pot of gold at the end of President Joe Biden’s jaunt to Canada. It’s going to Canada’s mining sector.

The U.S. military will deliver funds this spring to critical minerals projects in both the U.S. and Canada. The goal is to accelerate the development of a critical minerals industry on this continent.

The context is the United States’ intensifying rivalry with China.

The U.S. is desperate to reduce its reliance on its adversary for materials needed to power electric vehicles, electronics and many other products, and has set aside hundreds of millions of dollars under a program called the Defence Production Act.

The Pentagon already has told Canadian companies they would be eligible to apply. It has said the cash would arrive as grants, not loans.

On Friday [March 24, 2023], before Biden left Ottawa, he promised they’ll get some.

The White House and the Prime Minister’s Office announced that companies from both countries will be eligible this spring for money from a $250 million US fund.

Which Canadian companies? The leaders didn’t say. Canadian officials have provided the U.S. with a list of at least 70 projects that could warrant U.S. funding.

“Our nations are blessed with incredible natural resources,” Biden told Canadian parliamentarians during his speech in the House of Commons.

Canada in particular has large quantities of critical minerals [emphasis mine] that are essential for our clean energy future, for the world’s clean energy future.

I don’t think there’s any question that the US knows how much, where, and how easily ‘extractable’ Canadian critical minerals might be.

Pressure builds

On the same day (Monday, February 3, 2025) the tariffs were postponed for a month,Trudeau had two telephone calls with US president Donald Trump. According to a February 9, 2025 article by Steve Chase and Stefanie Marotta for the Globe and Mail, Trump and his minions are exploring the possibility of acquiring Canada by means other than a trade war or economic domination,

“He [Trudeau] talked about two phone conversations he had with Mr. Trump on Monday [February 3, 2025] before the President agreed to delay to steep tariffs on Canadian goods for 30 days.n

During the calls, the Prime Minister recalled Mr. Trump referred to a four-page memo that included a list of grievances he had with Canadian trade and commercial rules, including the President’s false claim that US banks are unable to operate in Canada. …

In the second conversation with Mr. Trump on Monday, the Prime Minister told the summit, the President asked him whether he was familiar with the Treaty of 1908, a pact between the United States and Britain that defined the border between the United States and Canada. he told Mr. Trudeau, he should look it up.

Mr. Trudeau told the summit he thought the treaty had been superseded by other developments such as the repatriation the Canadian Constitution – in other words, that the border cannot be dissolved by repealing that treaty. He told the audience that international law would prevent the dissolution 1908 Treaty leading to the erasure of the border. For example, various international laws define sovereign borders, including the United Nationals Charter of which both countries are signatories and which has protection to territorial integrity.

A source familiar with the calls said Mr. Trump’s reference to the 1908 Treaty was taken as an implied threat. … [p. A3 in paper version]

I imagine Mr. Trump and/or his minions will keep trying to find one pretext or another for this attempt to absorb or annex or wage war (economically or otherwise) on Canada.

What makes Canadian (and Greenlandic) minerals and water so important?

You may have noticed the January 21, 2025 announcement by Mr. Trump about the ‘Stargate Project,’ a proposed US $500B AI infrastructure company (you can find more about the Stargate Project (Stargate LLC) in its Wikipedia entry).

Most likely not a coincidence, on February 10, 2025 President of France, Emmanuel Macron announced a 109B euros investment in French AI sector, from the February 9, 2025 Reuters preannouncement article,

France will announce private sector investments totalling some 109 billion euros ($112.5 billion [US]) in its artificial intelligence sector during the Paris AI summit which opens on Monday, President Emmanuel Macron said.

The financing includes plans by Canadian investment firm [emphasis mine] Brookfield to invest 20 billion euros in AI projects in France and financing from the United Arab Emirates which could hit 50 billion euros in the years ahead, Macron’s office said.

Big projects, non? It’s no surprise critical minerals will be necessary but the need for massive amounts of water may be. My October 16, 2023 posting focuses on water and AI development, specifically ChatGPT-4,

A September 9, 2023 news item (an Associated Press article by Matt O’Brien and Hannah Fingerhut) on phys.org and also published September 12, 2023 on the Iowa Public Radio website, describe an unexpected cost for building ChatGPT and other AI agents, Note: Links [in the excerpt] have been removed,

The cost of building an artificial intelligence product like ChatGPT can be hard to measure.

But one thing Microsoft-backed OpenAI needed for its technology was plenty of water [emphases mine], pulled from the watershed of the Raccoon and Des Moines rivers in central Iowa to cool a powerful supercomputer as it helped teach its AI systems how to mimic human writing.

As they race to capitalize on a craze for generative AI, leading tech developers including Microsoft, OpenAI and Google have acknowledged that growing demand for their AI tools carries hefty costs, from expensive semiconductors to an increase in water consumption.

But they’re often secretive about the specifics. Few people in Iowa knew about its status as a birthplace of OpenAI’s most advanced large language model, GPT-4, before a top Microsoft executive said in a speech it “was literally made next to cornfields west of Des Moines.”

In its latest environmental report, Microsoft disclosed that its global water consumption spiked 34% from 2021 to 2022 (to nearly 1.7 billion gallons , or more than 2,500 Olympic-sized swimming pools), a sharp increase compared to previous years that outside researchers tie to its AI research. [emphases mine]

As for how much water was diverted in Iowa for a data centre project, from my October 16, 2023 posting

Jason Clayworth’s September 18, 2023 article for AXIOS describes the issue from the Iowan perspective, Note: Links [from the excerpt] have been removed,

Future data center projects in West Des Moines will only be considered if Microsoft can implement technology that can “significantly reduce peak water usage,” the Associated Press reports.

Why it matters: Microsoft’s five WDM data centers — the “epicenter for advancing AI” — represent more than $5 billion in investments in the last 15 years.

Yes, but: They consumed as much as 11.5 million gallons of water a month for cooling, or about 6% of WDM’s total usage during peak summer usage during the last two years, according to information from West Des Moines Water Works.

The bottom line is that these technologies consume a lot of water and require critical minerals.

Greenland

Evan Dyer’s January 16, 2025 article for CBC news online describes both US military strategic interests and hunger for resources, Note 1: Article links have been removed; Note 2: I have added one link to a Wikipedia entry,

The person who first put a bug in Donald Trump’s ear about Greenland — if a 2022 biography is to be believed — was his friend Ronald Lauder, a New York billionaire and heir to the Estée Lauder cosmetics fortune.

But it would be wrong to believe that U.S. interest in Greenland originated with idle chatter at the country club, rather than real strategic considerations.

Trump’s talk of using force to annex Greenland — which would be an unprovoked act of war against a NATO ally — has been rebuked by Greenlandic, Danish and European leaders. A Fox News team that travelled to Greenland’s capital Nuuk reported back to the Trump-friendly show Fox & Friends that “most of the people we spoke with did not support Trump’s comments and found them offensive.”

Certainly, military considerations motivated the last U.S. attempt at buying Greenland in 1946.

The military value to the U.S. of acquiring Greenland is much less clear in 2025 than it was in 1946.

Russian nuclear submarines no longer need to traverse the GIUK [the GIUK gap; “{sometimes written G-I-UK} is an area in the northern Atlantic Ocean that forms a naval choke point. Its name is an acronym for Greenland, Iceland, and the United Kingdom, the gap being the two stretches of open ocean among these three landmasses.”]. They can launch their missiles from closer to home.

And in any case, the U.S. already has a military presence on Greenland, used for early warning, satellite tracking and marine surveillance. The Pentagon simply ignored Denmark’s 1957 ban on nuclear weapons on Greenlandic territory. Indeed, an American B-52 bomber carrying four hydrogen bombs crashed in Greenland in 1968.

“The U.S. already has almost unhindered access [emphasis mine], and just building on their relationship with Greenland is going to do far more good than talk of acquisition,” said Dwayne Menezes, director of the Polar Research and Policy Initiative in London.

The complication, he says, is Greenland’s own independence movement. All existing defence agreements involving the U.S. presence in Greenland are between Washington and the Kingdom of Denmark. [emphasis mine]

“They can’t control what’s happening between Denmark and Greenland,” Menezes said. “Over the long term, the only way to mitigate that risk altogether is by acquiring Greenland.”

Menezes also doesn’t believe U.S. interest in Greenland is purely military.

And Trump’s incoming national security adviser Michael Waltz [emphasis mine] appeared to confirm as much when asked by Fox News why the administration wanted Greenland.

This is about critical minerals, this is about natural resources [emphasis mine]. This is about, as the ice caps pull back, the Chinese are now cranking out icebreakers and are pushing up there.”

While the United States has an abundance of natural resources, it risks coming up short in two vital areas: rare-earth minerals and freshwater.

Greenland’s apparent barrenness belies its richness in those two key 21st-century resources.

The U.S. rise to superpower was driven partly by the good fortune of having abundant reserves of oil, which fuelled its industrial growth. The country is still a net exporter of petroleum.

China, Washington’s chief strategic rival, had no such luck. It has to import more than two-thirds of its oil, and is now importing more than six times as much as it did in 2000.

But the future may not favour the U.S. as much as the past.

I stand corrected, where oil is concerned. From Dyer’s January 16, 2025 article, Note: Links have been removed,

It’s China, and not the U.S., that nature blessed with rich deposits of rare-earth elements, a collection of 17 metals such as yttrium and scandium that are increasingly necessary for high-tech applications from cellphones and flat-screen TVs to electric cars.

The rare-earth element neodymium is an essential part of many computer hard drives and defence systems including electronic displays, guidance systems, lasers, radar and sonar.

Three decades ago, the U.S. produced a third of the world’s rare-earth elements, and China about 40 per cent. By 2011, China had 97 per cent of world production, and its government was increasingly limiting and controlling exports.

The U.S. has responded by opening new mines and spurring recovery and recycling to reduce dependence on China.

Such efforts have allowed the U.S. to claw back about 20 per cent of the world’s annual production of rare-earth elements. But that doesn’t change the fact that China has about 44 million tonnes of reserves, compared to fewer than two million in the U.S.

“There’s a huge dependency on China,” said Menezes. “It offers China the economic leverage, in the midst of a trade war in particular, to restrict supply to the West, thus crippling industries like defence, the green transition. This is where Greenland comes in.”

Greenland’s known reserves are almost equivalent to those of the entire U.S., and much more may lie beneath its icebound landscape. 

“Greenland is believed to be able to meet at least 25 per cent of global rare-earth demand well into the future,” he said.

An abundance of freshwater

The melting ice caps referenced by Trump’s nominee for national security adviser are another Greenlandic resource the world is increasingly interested in.

Seventy per cent of the world’s freshwater is locked up in the Antarctic ice cap. Of the remainder, two-thirds is in Greenland, in a massive ice cap that is turning to liquid at nearly twice the volume of melting in Antarctica.

“We know this because you can weigh the ice sheet from satellites,” said Christian Schoof, a professor of Earth, ocean and atmospheric sciences at the University of British Columbia who spent part of last year in Greenland studying ice cap melting.

“The ice sheet is heavy enough that it affects the orbit of satellites going over it. And you can record the change in that acceleration of satellites due to the ice sheet over time, and directly weigh the ice sheet.”

“There is a growing demand for freshwater on the world market, and the use of the vast water potential in Greenland may contribute to meeting this demand,” the Greenland government announces on its website.

The Geological Survey of Denmark and Greenland found 10 locations that were suitable for the commercial exploitation of Greenland’s ice and water, and has already issued a number of licenses.

Schoof told CBC News that past projects that attempted to tow Greenlandic ice to irrigate farms in the Middle East “haven’t really taken off … but humans are resourceful and inventive, and we face some really significant issues in the future.”

For the U.S., those issues include the 22-year-long “megadrought” which has left the western U.S. [emphases mine] drier than at any time in the past 1,200 years, and which is already threatening the future of some American cities.

As important as they are, there’s more than critical minerals and water, according to Dyer’s January 16, 2025 article

Even the “rock flour” that lies under the ice cap could have great commercial and strategic importance.

Ground into nanoparticles by the crushing weight of the ice, research has revealed it to have almost miraculous properties, says Menezes.

“Scientists have found that Greenlandic glacial flour has a particular nutrient composition that enables it to be regenerative of soil conditions elsewhere,” he told CBC News. “It improves agricultural yields. It has direct implications for food security.”

Spreading Greenland rock flour on corn fields in Ghana produced a 30 to 50 per cent increase in crop yields. Similar yield gains occurred when it was spread on Danish fields that produce the barley for Carlsberg beer.

Canada

It’s getting a little tiring keeping up with Mr. Trump’s tariff tear (using ‘tear’ as a verbal noun; from the Cambridge dictionary, verb: TEAR definition: 1. to pull or be pulled apart, or to pull pieces off: 2. to move very quickly …).

The bottom line is that Mr. Trump wants something and certainly Canadian critical minerals and water constitute either his entire interest or, at least, his main interest for now, with more to be determined later.

Niall McGee’s February 9, 2025 article for the Globe and Mail provides an overview of the US’s dependence on Canada’s critical minerals,

The US relies on Canada for a huge swath of its critical mineral imports, including 40 per cent of its primary nickel for its defence industry, 30 per cent of its uranium, which is used in its nuclear-power fleet, and 79 per cent of its potash for growing crops.

The US produces only small amounts of all three, while Canada is the world’s biggest potash producer, the second biggest in uranium, and number six in nickel.

If the US wants to buy fewer critical minerals from Canada, in many cases it would be forced to source them from hostile countries such as Russia and China.

Vancouver-based Teck Resources Ltd. is one of the few North American suppliers of germanium. The critical mineral is used in fibre-optic networks, infrared vision systems, solar panels. The US relies on Canada for 23 per cent of its imports of germanium.

China in December [2024] banned exports of the critical mineral to the US citing national security concerns. The ban raised fears of possible shortages for the US.

“It’s obvious we have a lot of what Trump wants to support America’s ambitions, from both an economic and a geopolitical standpoint,” says Martin Turenne, CEO of Vancouver-based FPX Nickel Corp., which is developing a massive nickel project in British Columbia. [p. B5 paper version]

Akshay Kulkarni’s January 15, 2025 article for CBC news online provides more details about British Columbia and its critical minerals, Note: Links have been removed,

The premier had suggested Tuesday [January 14, 2025] that retaliatory tariffs and export bans could be part of the response, and cited a smelter operation located in Trail, B.C. [emphasis mine; keep reading], which exports minerals that Eby [Premier of British Columbia, David Eby] said are critical for the U.S.

The U.S. and Canada both maintain lists of critical minerals — ranging from aluminum and tin to more obscure elements like ytterbium and hafnium — that both countries say are important for defence, energy production and other key areas.

Michael Goehring, the president of the Mining Association of B.C., said B.C. has access to or produces 16 of the 50 minerals considered critical by the U.S.

Up-close picture of red and blue atoms.
Individual atoms of silicon and germanium are seen following an Atomic Probe Tomography (APT) measurement at Polytechnique Montreal. Both minerals are manufactured in B.C. (Christinne Muschi/The Canadian Press)

“We have 17 critical mineral projects on the horizon right now, along with a number of precious metal projects,” he told CBC News on Tuesday [January 14, 2025].

“The 17 critical mineral projects alone represent some $32 billion in potential investment for British Columbia,” he added.

John Steen, director of the Bradshaw Research Institute for Minerals and Mining at the University of B.C., pointed to germanium — which is manufactured at Teck’s facility in Trail [emphasis mine] — as one of the materials most important to U.S industry.

There are a number of mines and manufacturing facilities across B.C. and Canada for critical minerals.

The B.C. government says the province is Canada’s largest producer of copper, and only producer of molybdenum, which are both considered critical minerals.

There’s also graphite, not in BC but in Québec. This April 8, 2023 article by Christian Paas-Lang for CBC news online focuses largely on issues of how to access and exploit graphite and also, importantly, indigenous concerns, but this excerpt focuses on graphite as a critical mineral,

A mining project might not be what comes to mind when you think of the transition to a lower emissions economy. But embedded in electric vehicles, solar panels and hydrogen fuel storage are metals and minerals that come from mines like the one in Lac-des-Îles, Que.

The graphite mine, owned by the company Northern Graphite, is just one of many projects aimed at extracting what are now officially dubbed “critical minerals” — substances of significant strategic and economic importance to the future of national economies.

Lac-des-Îles is the only significant graphite mining project in North America, accounting for Canada’s contribution to an industry dominated by China.

There was another proposed graphite mine in Québec, which encountered significant push back from the local Indigenous community as noted in my November 26, 2024 posting, “Local resistance to Lomiko Metals’ Outaouais graphite mine.” The posting also provides a very brief update of graphite mining in Canada.

It seems to me that water does not get the attention that it should and that’s why I lead with water in my headline. Eric Reguly’s February 9, 2025 article in the Globe and Mail highlights some of the water issues facing the US, not just Iowa,

Water may be the real reason, or one of the top reasons, propelling his [Mr. Trump’s] desire to turn Canada into Minnesota North. Canadians represent 0.5 per cent of the globe’s population yet sit on 20% or more of its fresh water. Vast tracts of the United States routinely suffer from water shortages, which are drying up rivers – the once mighty Colorado River no longer reaches the Pacific Ocean – shrinking aquifers beneath farmland and preventing water-intensive industries from building factories. Warming average temperatures will intensify the shortages. [p. B2 in paper version]

Reguly is more interested in the impact water shortages have on industry. He also offers a brief history of US interest in acquiring Canadian water resources dating back to the first North America Free Trade Agreement (NAFTA) that came into effect on January 1, 1994.

A March 6, 2024 article by Elia Nilsen for CNN television news online details Colorado river geography and gives you a sense of just how serious the situation is, Note: Links have been removed,

Seven Western states are starting to plot a future for how much water they’ll draw from the dwindling Colorado River in a warmer, drier world.

The river is the lifeblood for the West – providing drinking water for tens of millions, irrigating crops, and powering homes and industry with hydroelectric dams.

This has bought states more time to figure out how to divvy up the river after 2026, when the current operating guidelines expire.

To that end, the four upper basin river states of Colorado, Utah, New Mexico and Wyoming submitted their proposal for how future cuts should be divvied up among the seven states to the federal government on Tuesday [March 5, 2024], and the three lower basin states of California, Arizona and Nevada submitted their plan on Wednesday [March 6, 2024].

One thing is clear from the competing plans: The two groups of states do not agree so far on who should bear the brunt of future cuts if water levels drop in the Colorado River basin.

As of a December 12, 2024 article by Shannon Mullane for watereducationcolorado.org, the states are still wrangling and they are not the only interested parties, Note: A link has been removed,

… officials from seven states are debating the terms of a new agreement for how to store, release and deliver Colorado River water for years to come, and they have until 2026 to finalize a plan. This month, the tone of the state negotiations soured as some state negotiators threw barbs and others called for an end to the political rhetoric and saber-rattling.

The state negotiators are not the only players at the table: Tribal leaders, federal officials, environmental organizations, agricultural groups, cities, industrial interests and others are weighing in on the process.

Water use from the Colorado river has international implications as this February 5, 2025 essay (Water is the other US-Mexico border crisis, and the supply crunch is getting worse) by Gabriel Eckstein, professor of law at Texas A&M University and Rosario Sanchez, senior research scientist at Texas Water Resources Institute and at Texas A&M University for The Conversation makes clear, Note: Links have been removed,

The Colorado River provides water to more than 44 million people, including seven U.S. and two Mexican states, 29 Indian tribes and 5.5 million acres of farmland. Only about 10% of its total flow reaches Mexico. The river once emptied into the Gulf of California, but now so much water is withdrawn along its course that since the 1960s it typically peters out in the desert.

At least 28 aquifers – underground rock formations that contain water – also traverse the border. With a few exceptions, very little information on these shared resources exists. One thing that is known is that many of them are severely overtapped and contaminated.

Nonetheless, reliance on aquifers is growing as surface water supplies dwindle. Some 80% of groundwater used in the border region goes to agriculture. The rest is used by farmers and industries, such as automotive and appliance manufacturers.

Over 10 million people in 30 cities and communities throughout the border region rely on groundwater for domestic use. Many communities, including Ciudad Juarez; the sister cities of Nogales in both Arizona and Sonora; and the sister cities of Columbus in New Mexico and Puerto Palomas in Chihuahua, get all or most of their fresh water from these aquifers.

A booming region

About 30 million people live within 100 miles (160 kilometers) of the border on both sides. Over the next 30 years, that figure is expected to double.

Municipal and industrial water use throughout the region is also expected to increase. In Texas’ lower Rio Grande Valley, municipal use alone could more than double by 2040.

At the same time, as climate change continues to worsen, scientists project that snowmelt will decrease and evaporation rates will increase. The Colorado River’s baseflow – the portion of its volume that comes from groundwater, rather than from rain and snow – may decline by nearly 30% in the next 30 years.

Precipitation patterns across the region are projected to be uncertain and erratic for the foreseeable future. This trend will fuel more extreme weather events, such as droughts and floods, which could cause widespread harm to crops, industrial activity, human health and the environment.

Further stress comes from growth and development. Both the Colorado River and Rio Grande are tainted by pollutants from agricultural, municipal and industrial sources. Cities on both sides of the border, especially on the Mexican side, have a long history of dumping untreated sewage into the Rio Grande. Of the 55 water treatment plants located along the border, 80% reported ongoing maintenance, capacity and operating problems as of 2019.

Drought across the border region is already stoking domestic and bilateral tensions. Competing water users are struggling to meet their needs, and the U.S. and Mexico are straining to comply with treaty obligations for sharing water [emphasis mine].

Getting back to Canada and water, Reguly’s February 9, 2025 article notes Mr. Trump’s attitude towards our water,

Mr. Trump’s transaction-oriented brain know that water availability translates into job availability. If Canada were forced to export water by bulk to the United States, Canada would in effect be exporting jobs and America absorbing them. In the fall [2024] when he was campaigning, he called British Columbia “essentially a very large faucet” [emphasis mine] that could be used to overcome California’s permanent water deficit.

In Canada’s favour, Canadians have been united in their opposition to bulk water exports. That sentiment is codified in the Transboundary Waters Protection Act, which bans large scale removal from waterways shared with the United States. … [p. B2 in paper version]

It’s reassuring to read that we have some rules regarding water removal but British Columbia also has a water treaty with the US, the Columbia River Treaty, and an update to it lingers in limbo as Kirk Lapointe notes in his February 6, 2025 article for vancouverisawesome.com. Lapointe mentions shortcomings on both sides of the negotiating table for the delay in ratifying the update while expressing concern over Mr. Trump’s possible machinations should this matter cross his radar.

What about Ukraine’s critical mineral?

A February 13, 2025 article by Geoff Nixon for CBC news online provides some of the latest news on the situation between the US and the Ukraine, Note: Links have been removed,

Ukraine has clearly grabbed the attention of U.S. President Donald Trump with its apparent willingness to share access to rare-earth resources with Washington, in exchange for its continued support and security guarantees.

Trump wants what he calls “equalization” for support the U.S. has provided to Ukraine in the wake of Russia’s full-scale invasion. And he wants this payment in the form of Ukraine’s rare earth minerals, metals “and other things,” as the U.S. leader put it last week.

U.S. Treasury Secretary Scott Bessent has travelled to Ukraine to discuss the proposition, which was first raised with Trump last fall [2024], telling reporters Wednesday [February 12, 2025] that he hoped a deal could be reached within days.

Bessent says such a deal could provide a “security shield” in post-war Ukraine. Ukrainian President Volodymyr Zelenskyy, meanwhile, said in his daily address that it would both strengthen Ukraine’s security and “give new momentum to our economic relations.”

But just how much trust can Kyiv put in a Trump-led White House to provide support to Ukraine, now and in the future? Ukraine may not be in a position to back away from the offer, with Trump’s interest piqued and U.S. support remaining critical for Kyiv after nearly three years of all-out war with Russia.

“I think the problem for Ukraine is that it doesn’t really have much choice,” said Oxana Shevel, an associate professor of political science at Boston’s Tufts University.

Then there’s the issue of the Ukrainian minerals, which have to remain in Kyiv’s hands in order for the U.S. to access them — a point Zelenskyy and other Ukraine officials have underlined.

There are more than a dozen elements considered to be rare earths, and Ukraine’s Institute of Geology says those that can be found in Ukraine include lanthanum, cerium, neodymium, erbium and yttrium. EU-funded research also indicates that Ukraine has scandium reserves. But the details of the data are classified.

Rare earths are used in manufacturing magnets that turn power into motion for electric vehicles, in cellphones and other electronics, as well as for scientific and industrial applications.

Trump has said he wants the equivalent of $500 billion US in rare earth minerals.

Yuriy Gorodnichenko, a professor of economics at the University of California, Berkeley, says any effort to develop and extract these resources won’t happen overnight and it’s unclear how plentiful they are.

“The fact is, nobody knows how much you have for sure there and what is the value of that,” he said in an interview.

“It will take years to do geological studies,” he said. “Years to build extraction facilities.” 

Just how desperate is the US?

Yes, the United States has oil but it doesn’t have much in the way of materials it needs for the new technologies and it’s running out of something very basic: water.

I don’t know how desperate the US is but Mr. Trump’s flailings suggest that the answer is very, very desperate.

*ETA February 18, 2025: For anyone interested in more information about water, Canada, and the US, Joel Dryden’s February 18, 2025 article, “Trump’s musings on ‘very large faucet’ in Canada part of looming water crisis, say researchers” for CBC news online, which offers more information about the situation.

Novel visible light communication encryption technology using chiral nanoparticles

One of the most intriguing (yes, it’s a pun) encryption stories (for me) is centuries old and concerns Mary Queen of Scots, from a February 10, 2023 article by Meilan Solly for Smithsonian Magazine, Note: Links have been removed,

Over the course of her 19 years in captivity, Mary, Queen of Scots, wrote thousands of letters to ambassadors, government officials, fellow monarchs and conspirators alike. Most of these missives had the same underlying goal: securing the deposed Scottish queen’s freedom. After losing her throne in 1567, Mary had fled to England, hoping to find refuge at her cousin Elizabeth I’s court. (Mary’s paternal grandmother, Margaret Tudor, was the sister of Elizabeth’s father, Henry VIII.) Instead, the English queen imprisoned Mary, keeping her under house arrest for nearly two decades before ordering her execution in 1587.

Mary’s letters have long fascinated scholars and the public, providing a glimpse into her relentless efforts to secure her release. But the former queen’s correspondence often raises more questions than it answers, in part because Mary took extensive steps to hide her messages from the prying eyes of Elizabeth’s spies. In addition to folding the pages with a technique known as letterlocking, she employed ciphers and codes of varying complexity.

More than 400 years after Mary’s death, a chance discovery by a trio of code breakers is offering new insights into the queen’s final years. As the researchers write in the journal Cryptologia, they originally decided to examine a cache of coded notes housed at the National Library of France as part of a broader push to “locate, digitize, transcribe, decipher and analyze” historic ciphers. Those pages turned out to be 57 of Mary’s encrypted letters, the majority of which were sent to Michel de Castelnau, the French ambassador to England, between 1578 and 1584. All but seven were previously thought to be lost.

Interspersed with a collection of early 16th-century Italian papers, the documents were written in mysterious symbols that offered no clues “as to their sender, recipients or date,” lead author George Lasry, a computer scientist and cryptographer based in Israel, tells Smithsonian magazine. It was only when the scholars spotted the word “Walsingham”—the last name of Elizabeth’s spymaster, Francis Walsingham—that they realized the letters’ significance.

“This was the ‘bingo moment,’” Lasry says. “We were very excited.”

Before getting too excited, the trio set out to confirm whether the letters were already known to historians. While they found copies of a few in British archives, “50 or so are new to historians—and a real gold mine for them,” says Lasry. In total, the letters contain 50,000 words of deciphered material.

Fascinating, non?

An October 10, 2024 news item on Nanowerk sheds light (more wordplay) on a contemporary approach to encryption,

Seoul National University(SNU) College of Engineering announced that a joint research team led by Professor Ki Tae Nam from the Department of Materials Science and Engineering at SNU and Professor Junil Choi from the Korea Advanced Institute of Science and Technology (KAIST) has developed a novel visible light communication encryption technology with high security using chiral nanoparticles.

A September 30, 2024 Seoul National University (SNU) press release (also on EurekAlert but published on October 10, 2024), which originated the news item, describes the research in more detail,

Just as a lighthouse provides a guiding beam in the vast darkness of the sea, light-based information transmission has been a crucial means of communication throughout human history. Recently, next-generation communication technology based on visible light, which possesses high frequencies and linearity, has gained attention. It offers advantages such as integration with lighting systems and is free from the electromagnetic interference associated with conventional communication networks. With high security and fast transmission speeds, visible light communication is particularly suitable for local communication systems, especially in military operations involving vehicles, drones, and personnel.

In addition to intensity and wavelength (color), light can carry a vast amount of information through polarization. For instance, 3D movies use polarized filters to deliver two different polarized images to the viewer’s eyes, creating a sense of depth. Recently, efforts have been made to improve the security and performance of visible light communication, including the incorporation of technologies related to polarization, such as quantum information communication based on the superposition of polarization.

The SNU-KAIST joint research team focused on how light polarization can be significantly modulated through interaction with nanomaterials. In this study, they developed an innovative visible light communication encryption technology based on new materials. The core of this technology lies in chiral nanomaterials, which exhibit a symmetric structure when viewed in a mirror but do not overlap. These materials can significantly adjust the tilt of the polarization axis or its rotational properties. Having previously published two papers in 2018 and 2022 in the prestigious journal Nature on “the synthesis and optical device application of chiral nanoparticles with world-class polarization control performance,” the research team has now introduced a visible light communication encryption technology that cannot be replicated or intercepted without detailed information about the nanoparticles.

The chiral nanoparticles used in this technology are created by twisting their crystal structure using biomolecules like proteins and DNA, which possess natural chirality. The optical properties of these nanoparticles cannot be replicated without complete sequence information of the biomolecules used in their synthesis. Therefore, chiral nanoparticles function like fingerprints or unclonable keys in visible light communication, allowing only the receiver with the actual nanoparticles to correctly decode the information. This encryption technology is expected to have significant utility in secure point-to-point communication systems, such as those used in military operations involving drones.

Furthermore, the research team developed a spatiotemporal polarization control device capable of transmitting encrypted polarization information. By combining quantum nanorods, which efficiently emit polarized light, with nanowire materials that provide rotational properties to the light, they used 3D printing to fabricate a polarization control device with hundreds of micrometers of spatial resolution and nanoseconds of temporal resolution, allowing all polarization states to be represented without restriction. The transmitting unit can encrypt and transmit polarization information in a form suited to the polarization control properties of the nanoparticles using this device. This technology is expected to be the foundation for mass production of devices that can control spatiotemporal polarization without being constrained by form factor.

Professor Ki Tae Nam from SNU’s Department of Materials Science and Engineering said, “This research, which actively combines new material technologies with communication technologies, played a crucial role in developing the world’s first and only visible light communication encryption technology. We expect this technology to not only contribute to national defense but also be commercialized rapidly in industrial fields like display technology.” Professor Junil Choi from KAIST’s School of Electrical Engineering added, “This outstanding research result was achieved through joint efforts between material science and electrical engineering experts. In the future, we aim to further develop visible light communication technology based on nanoparticles to create communication systems that are fundamentally impossible to eavesdrop on.” Co-first author Jeong Hyun Han also stated, “We anticipate that this encryption system will act as a platform with great scalability and impact in the field of optical information transmission based on polarization.”

This research was supported by the Future Defense Technology Development Program of the Agency for Defense Development, the Basic Research Laboratory Program of the National Research Foundation of Korea, and private support from LG Display. The research outcome, which has been recognized for its significance, was published in the prestigious multidisciplinary journal Nature Communications on September 27 [2024].

Here’s a link to and a citation for the paper,

Spatiotemporally modulated full-polarized light emission for multiplexed optical encryption by Jiawei Lv, Jeong Hyun Han, Geonho Han, Seongmin An, Seung Ju Kim, Ryeong Myeong Kim, Jung‐El Ryu, Rena Oh, Hyuckjin Choi, In Han Ha, Yoon Ho Lee, Minje Kim, Gyeong-Su Park, Ho Won Jang, Junsang Doh, Junil Choi & Ki Tae Nam. Nature Communications volume 15, Article number: 8257 (2024) DOI: https://doi.org/10.1038/s41467-024-52358-7 Published: 27 September 2024

This paper is open access.

Prototype of nanofibre uniforms for Australian military

CSIRO project lead Dr Yen Truong (L) and Head of Program Management at DMTC, Deepak Ganga (R) with the prototype uniform. Courtesy: CSIRO

I last had a story about the Australian military and advanced technology in a June 18, 2023 posting titled, “Mind-controlled robots based on graphene: an Australian research story” where soldiers were patrolling with mind-controlled robotic dogs.

This story is textile-oriented (h/t Azonano’s September 24, 2024 news item). A September 24, 2024 Commonwealth Scientific and Industrial Research Organisation (CSIRO) press release announces a new kind of uniform,

Researchers at Australia’s national science agency, CSIRO, have successfully developed a next-generation uniform prototype that employs nanofibres to safeguard Australian troops from chemical and biological threats.

The innovative material is a lightweight fabric that effectively filters out harmful particles while remaining light-weight and breathable, keeping the wearer comfortable in extreme temperatures.

CSIRO Manufacturing Research Unit Director, Dr Marcus Zipper said this textile innovation was the result of collaboration with industry and research partners, including DMTC.

“Our nanofibre technology, pioneered by CSIRO scientists, has the potential to significantly improve the level of protection soldiers’ uniforms provide and can also be used for non-military applications, including protecting emergency responders and hazmat crews,” Dr Zipper said.

“CSIRO research and development in materials science looks to improve how a particular material functions – we work across a broad range of advanced materials including metals, composites, polymers, adsorbents and nanofibres,” Dr Zipper said.

The initial phase of this project was funded by the Department of Defence. The successful nanofibre suit prototype was coordinated by DMTC Limited.

Also involved in supporting the project are Bruck Textiles, Defence Science and Technology Group and RMIT University.

Head of Program Management at DMTC, Deepak Ganga, said the new prototype uniform could deliver a significant leap forward in soldier protection, ensuring better comfort and mobility in harsh environments.

“This project demonstrates the power of collaboration. CSIRO’s scientific excellence in nanofibre research has been matched with the expertise of our partners in textiles, defence science, and manufacturing,” Mr Ganga said.

“This has resulted in a groundbreaking solution that offers benefits for Australian troops, for the first responder community and, potentially for Australia’s alliance partners,” he said.

CSIRO project lead Dr Yen Truong said key to the prototype’s success lies in its innovative nanofibre technology, developed by CSIRO scientists.

“We harnessed the unique properties of nanofibres to create a lightweight fabric that effectively filters out harmful particles while remaining highly breathable,” said Dr Truong.

“In rigorous testing, the prototype surpassed all performance targets for air filtration, air permeability, thermal comfort, and chemical protection.

“This means it effectively filters pollutants from the air, allows for breathability, maintains comfortable temperatures even in extreme conditions, and offers superior protection from hazardous chemicals.”

With DMTC Limited, Dr Truong and team are seeking funding to progress to the next stage of development, which is expected to involve field testing with Australian Defence Force personnel and further refinement of scaled manufacturing processes with industrial partners.

As you can see, they’re being quite close-lipped about how or from what the textile is constituted. This September 24, 2024 CSIRO article by Rebecca Willetts offers a little more information,

For soldiers on the frontline, chemical and biological hazards are a sobering threat.

Traditional bulky protective suits offer a crucial layer of protection but come at the expense of breathability and mobility. This can lead to discomfort, heat stress and even hinder performance in harsh environments – potentially jeopardising the wearer’s health.

Our researchers are working to revolutionise personal protective equipment. We’ve developed a next-generation suit prototype that prioritises safety and comfort for soldiers and first responders.  

The secret to our breakthrough lies in nanofibres – incredibly fine filaments at least 100 times thinner than a human hair. These tiny wonders have an extraordinary surface area that prevents harmful aerosol particles from passing through. What truly sets them apart is their breathability. Unlike traditional protective materials, nanofibre layers allow air to circulate freely – ensuring the wearer remains comfortable even in extreme conditions.

Senior researcher Dr Yen Truong is leading the project at CSIRO. She explains that nanofibres have the potential to revolutionise the way we think about protective gear. 

“They offer a unique combination of filtration performance while maintaining breathability. The latter represents a challenge that has long hampered the development of effective lower thermal burden protective suits,” she says. 

The Nano Protective Adsorbent Composite (NPAC) project, which was made possible with Federal Government support, began in 2017. 

Our team of scientists at CSIRO worked hand-in-hand with experts from Bruck Textiles, the Defence Science and Technology Group and RMIT University under the coordination of DMTC. This collaboration brought together knowledge and experience in nanotechnology, textile manufacturing, defence science and fashion design. 

The first success was the development of the innovative nanofibre-based fabric. This fabric acts as a barrier against harmful airborne particles while maintaining airflow. Scaling up this technology from the laboratory to commercial production presented a significant challenge.

“It’s easy enough to create a composite nanofibre material in a small lab setting, but transitioning to mass production is a different thing altogether,” Yen says. 

Our pilot-scale electrospinning machine produces the nanofibre. This larger-than-typical lab equipment played a crucial role in the production of larger quantities of fabric.

This demonstrated the technology’s potential for commercialisation, paving the way for real-world applications. A major breakthrough came in 2023 when Bruck Textiles, a leading Australian textile manufacturer, successfully produced 90 metres of the fabric. This material was then fabricated into a prototype uniform, which underwent rigorous testing. 

In testing it surpassed performance targets for air filtration, air permeability, thermal comfort, and chemical protection. This meant the suit not only protected the wearer from hazardous substances, but also offered comfort and mobility in demanding situations.

“We envision a future where firefighters, paramedics and other frontline workers can focus on their critical tasks without being hindered by heavy, cumbersome protective gear,” Yen says.

It’s a long way from 90 meters of fabric to producing the quantities required to outfit military and other personnel. I wish them good luck!

As for more details about the nanofibers, I wasn’t able to find much about them in a relatively short online search but i did find more about Dr. Truong’s work here on her ResearchGate profile page.

First-of-its-kind thermally-insulated and breathable soft robotic clothing for use in extreme heat

An August 15, 2024 news item on ScienceDaily announces research that may help make people safer in extreme heat,

As global warming intensifies, people increasingly suffer from extreme heat. For those working in a high-temperature environment indoors or outdoors, keeping thermally comfortable becomes particularly crucial. A team led by Dr Dahua SHOU, Limin Endowed Young Scholar in Advanced Textiles Technologies and Associate Professor of the School of Fashion and Textiles of The Hong Kong Polytechnic University (PolyU) has developed first-of-its-kind thermally-insulated and breathable soft robotic clothing that can automatically adapt to changing ambient temperatures, thereby helping to ensure worker safety in hot environments. Their research findings have been published in the international interdisciplinary journal Advanced Science.

An August 14, 2024 Hong Kong Polytechnic University press release (also on EurekAlert but published on August 15, 2024), which originated the news item, elaborates on the issue and on the proposed solution,

Maintaining a constant body temperature is one of the most critical requirements for living and working. High-temperature environments elevate energy consumption, leading to increased heat stress, thus exacerbating chronic conditions such as cardiovascular disease, diabetes, mental health issues and asthma, while also increasing the risk of infectious disease transmission. According to the World Health Organisation, globally, there were approximately 489,000 heat-related deaths annually between 2000 and 2019, with 45% occurring in Asia and 36% in Europe.

Thermal protective clothing is essential to safeguard individuals in extreme high-temperature environments, such as firefighters who need to be present at fires [sic] scenes and construction workers who work outdoors for extended periods. However, traditional gear has been limited by statically fixed thermal resistance, which can lead to overheating and discomfort in moderate conditions, while its heat insulation may not offer sufficient protection in extreme fire events and other high-temperature environments. To address this issue, Dr Shou and his team have developed intelligent soft robotic clothing for automatic temperature adaptation and thermal insulation in hot environments, offering superior personal protection and thermal comfort across a range of temperatures.

Their research was inspired by biomimicry in nature, like the adaptive thermal regulation mechanism in pigeons, which is mainly based on structural changes. Pigeons use their feathers to trap a layer of air surrounding their skin to reduce heat loss to the environment. When the temperature drops, they fluff up their feathers to trap a significant amount of still air, thereby increasing thermal resistance and retaining warmth.

The protective clothing developed by the team uses soft robotic textile for dynamic adaptive thermal management. Soft actuators, designed like a human network-patterned exoskeleton and encapsulating a non-toxic, non-flammable, low-boiling-point fluid, were strategically embedded within the clothing. This thermo-stimulated system turns the fluid from a liquid into a gas when the ambient temperature rises, causing expansion of soft actuators and thickening the textile matrix, thereby enhancing the gap of still air and doubling the thermal resistance from 0.23 to 0.48 Km²/W. The protective clothing can also keep the inner surface temperatures at least 10°C cooler than conventional heat-resistant clothing, even when the outer surface reaches 120°C.

This unique soft robotic textile, made by thermoplastic polyurethane, is soft, resilient and durable. Notably, it is far more skin-friendly and conformable than temperature-responsive clothing embedded with shape-memory alloys and is adjustable for a wide range of protective clothing. The soft actuators have exhibited no signs of leakage after undergoing rigorous standard washing tests. The porous, spaced knitting structure of the material can also significantly reduce convective heat transfer while maintaining high moisture breathability. Not relying on thermoelectric chips or circulatory liquid cooling systems for cooling or heat conduction, the light-weighted, soft robotic clothing can effectively regulate temperature itself without any energy consumption.

Dr Shou said, “Wearing heavy firefighting gear can feel extremely stifling. When firefighters exit a fire scene and remove their gear, they are sometimes drained nearly a pound of sweat from their boots [sic]. This has motivated me to develop a novel suit capable of adapting to various environmental temperatures while maintaining excellent breathability. Our soft robotic clothing can seamlessly adapt to different seasons and climates, multiple working and living conditions, and transitions between indoor and outdoor environments to help users experience constant thermal comfort under intense heat.”

Looking forward, Dr Shou finds the innovation to have a wide range of potential applications, from activewear, winter jackets, healthcare apparel and outdoor gear, to sustainable textile-based insulation for construction and buildings, contributing to energy-saving efforts. Supported by the Innovation and Technology Commission and the Hong Kong Research Institute of Textiles and Apparel, Dr Shou and his team have also extended the thermo-adaptive concept to develop inflatable, breathable jackets and warm clothing. This soft robotic clothing is suitable for low-temperature environments or sudden temperature drops to aid those who are stranded in the wilderness to maintain normal body temperature.

Here’s a link to and a citation for the paper,

Soft Robotic Textiles for Adaptive Personal Thermal Management by Xiaohui Zhang, Zhaokun Wang, Guanghan Huang, Xujiang Chao, Lin Ye, Jintu Fan, Dahua Shou. Volume 11, Issue 21 June 5, 2024 2309605 First published online: 26 March 2024 DOI: https://doi.org/10.1002/advs.202309605

This paper is open access.

Fluorescent nanoparticles could transform how we visualize fingerprints

It seems to be the day for fingerprints (see the first posting “Fingerprint detection improved with carbon-coated nanoparticles” published earlier today, September 17,2024).

This new technique announced in a September 12, 2024 news item on phys.org features fluorescent nanoparticles,

Researchers created a fluorescent nanoparticle using a combination of materials (MCM-41, chitosan and dansylglycine) to examine latent fingerprints. These nanoparticles have special properties that make them adhere well to fingerprint residues, even old ones.

The nanoparticles work on various surfaces, including metal, plastic, glass and complex objects such as polymer banknotes. They have the potential to be used directly at crime scenes without lab facilities, which is a significant advantage over some previous reagents. They produce high-quality fingerprint images, with the vast majority of those tested meeting the UK Home Office standards for a successful identification.

Caption: Development of latent fingerprints. Representative images on stainless steel are shown, illuminated by and viewed under visible light (a) before development and (b) after development with MCM-41@Ch@DnsGly NPs. Corresponding images generated by illumination with UV light (λex = 365 nm) after MCM-41@Ch@DnsGly NP development are shown on (c) stainless steel, (d) glass, (e) plastic and (f) unfired brass cartridge case substrates. Credit: RSC Advances

A September 12, 2024 Diamond Light Source press release (also on EurekAlert), which originated the news item, provides more detail about the research and the international collaboration of scientists developing the new technique, Note: Links have been removed,

The research was published in a Royal Society of Chemistry paper, highlighting that the new nanomaterial has proven to be a versatile and effective tool for visualising fingermark evidence. Small angle X-ray scattering (SAXS) techniques at Diamond provided useful data to validate these results.

The research team includes scientists from the Technical and Scientific Section of Alagoas, Federal Police, Brazil; the National Institute of Criminalistics of the Federal Police, Brazil; the University of Leicester’s School of Chemistry; the Federal University of Alagoas, Brazil; and the UK’s national synchrotron, Diamond Light Source. 

Ridge patterns on fingertips remain unchanged during and beyond a person’s life. They provide the primary method of personal identification in criminal investigations. When an object’s surface is touched by a finger, sweat and oily substances are transferred and deposited onto the surface, resulting in the formation of a mark. Most fingermarks are invisible to the naked eye and are referred to as latent fingermarks.

The international collaboration of researchers developed the new nanostructured hybrid material, MCM-41@chitosan@dansylglycine, to visualise latent fingermarks. This material combines mesoporous silica nanoparticles with a fluorescent dye (dansylglycine) and chitosan, a polysaccharide derived from the exoskeletons of shrimps, crabs and lobsters.

Latent fingermarks require physicochemical development techniques to enhance their visibility and make them interpretable for forensic purposes. Traditional methods for developing fingerprints include optical, physical, and chemical processes that involve interaction between the developing agent (often a coloured or fluorescent reagent) and the fingermark residue. These methods have limitations in recovering high-quality results in certain conditions.

Recently, new methods using mass spectrometry, spectroscopy, electrochemistry, and nanoparticles have improved the development of latent fingermarks. These techniques offer better contrast, sensitivity, and selectivity, with low toxicity. The ability to adjust nanomaterial properties further enhances the detection of both fresh and aged fingermarks.

Mesoporous silica nanoparticles (MSNs) have attracted significant interest since the discovery of the M41S family of molecular sieves, which encompasses MCM-41, MCM-48, and SBA-15. These nanoparticles are characterised by their controlled particle size, porosity, high specific surface area, chemical stability, and ease of surface functionalisation.

Profa. Adriana Ribeiro, Federal University of Alagoas comments: “There are few studies employing chitosan for detection and enhancement of latent fingerprints and, to the best of our knowledge, no reports of the use of hierarchically structured MSNs modified with chitosan (MSN@Ch) for such applications – which was our strategy in this research. We exploited the MCM’s desirable characteristics – notably high surface area and surface modification – for the case of MCM-41 to enhance the interaction between the development reagent and fingerprint residue.”

The team added dansyl fluorophores which exhibit intense absorption bands in the near UV region and emit strong fluorescence in the visible spectrum with high emission quantum yields.

Professor of Physical Chemistry, Robert Hillman, University of Leicester concludes: “The overarching aim of this study was to create a versatile and effective latent fingermark visualisation material based on MSNs, chitosan and dansyl derivatives. These nanoparticles were applied as latent fingermark developers for marks on surfaces of diverse chemical composition, topography, optical characteristics and spatially variant nature, typical of forensically challenging evidence. For quality assessment of the enhanced fingermarks, we analysed the developed images using the UK Home Office scale, forensic protocols and, in terms of their constituent features, (minutiae), specialist forensic software. Across a substantive collection of marks deposited on chemically diverse surfaces and subject to complex environmental and temporal histories, the overwhelming majority of the enhanced images presented sufficient minutiae for comparison with model dactyloscopy images.”

Diamond Light Source CEO Prof. Gianluigi Botton adds: “It is pleasing to see that Diamond’s unique analytical tools once again have delivered outstanding science. Our network of international users is key to making sure our science delivers results. This advance in nanomaterials could be a step change in how forensics may be applied in the future.”

Diamond Light Source provides industrial and academic user communities with access to state-of-the-art analytical tools to enable world-changing science. Shaped like a huge ring, it works like a giant microscope, accelerating electrons to near light speeds, to produce a light 10 billion times brighter than the Sun, which is then directed off into 33 laboratories known as ‘beamlines’. Additionally, Diamond offers access to several integrated laboratories including the world-class Electron Bio-imaging Centre (eBIC) and the Electron Physical Science Imaging Centre (ePSIC).  

Diamond serves as an agent of change, addressing 21st century challenges such as disease, clean energy, food security and more. Since operations started, more than 16,000 researchers from both academia and industry have used Diamond to conduct experiments, with the support of approximately 760 world-class staff. Almost 12,000 scientific articles have been published by its users and scientists.  

Funded by the UK Government through the Science and Technology Facilities Council (STFC), and by the Wellcome Trust, Diamond is one of the most advanced scientific facilities in the world, and its pioneering capabilities are helping to keep the UK at the forefront of scientific research.  

Diamond was set-up as an independent not for profit company through a joint venture, between the UKRI’s Science and Technology Facilities Council and one of the world’s largest biomedical charities, the Wellcome Trust – each respectively owning 86% and 14% of the shareholding.  

The University of Leicester is led by discovery and innovation – an international centre for excellence renowned for research, teaching and broadening access to higher education. It is among the Top 30 universities in the Times Higher Education (THE)’s Research Excellence Framework (REF) 2021 rankings with 89% of research assessed as world-leading or internationally excellent, with wide-ranging impacts on society, health, culture, and the environment. In 2023, the University received an overall Gold in the Teaching Excellence Framework (TEF) 2023, making it one of a small number of institutions nationally to achieve TEF Gold alongside a top 30 REF performance. The University is home to more than 20,000 students and approximately 4,000 staff.

Federal University of Alagoas (UFAL) Located in the city of Maceió, the Federal University of Alagoas (UFAL) is the major University in coastal state Alagoas.  It is currently considered one of the main research centers in the Brazilian Northeast region. The Federal University of Alagoas (UFAL) is a national reference in teaching, research and extension activities, establishing itself as an excellent support for the demands of society. It is the largest public higher education institution in the state of Alagoas and was ranked 49th among the best universities in Brazil in the 2023 edition of the World University Rankings (CWUR).  One of the reasons for reaching this level was the impact of institutional support and investment in research. All of this is the result of the prioritization of research at the University over the last four years, which is reflected in quality teaching and service. UFAL has 82.1% of its publications with national and international collaboration. And most of the citations were from works produced with researchers from other countries.

Here’s a link to and a citation for the paper,

Dansyl fluorophore functionalized hierarchically structured mesoporous silica nanoparticles as novel latent fingerprint development agents by Lais F. A. M. Oliveira, Lais V. A. T. da Silva, Artur F. Sonsin, Meclycia S. Alves, Cristiane V. Costa, Jeane C. S. Melo, Nicholas Ross, Paul T. Wady, Thomas Zinn, Ticiano G. do Nascimento, Eduardo J. S. Fonseca, Alexandro M. L. de Assis, A. Robert Hillman and Adriana S. Ribeiro. RSC Adv., 2024,14, 22504-22512 DOI: DOI: https://doi.org/10.1039/D4RA03074E First published: 17 Jul 2024

This article is open access.

Fingerprint detection improved with carbon-coated nanoparticles

Fig. 7. Fingerprint ridge patterns of WLC-Mn-Fe2O3 nanocomposite powder obtained on aluminium foil at daylight. Courtesy: Researchers and Hybrid Advances journal

South African researchers have developed a new technique for detecting fingerprints according to a June 17, 2024 news item by Samuel Jarman on phys.org (or you can see the originating June 17, 2024 press release by Jarman of sciencpod on behalf of the Nelson Mandela University), Note: Links have been removed,

Fingerprint detection is one of the most important techniques in forensic investigation. When fingerprints are dusted with a carbon-based powder, the material will adhere to the moisture and grease left behind by the unique patterns of ridges and valleys on the perpetrator’s fingertip. The resulting pattern can then be analyzed under a microscope, and compared with suspects’ fingerprints.

Researchers led by Bienvenu Gael Fouda-Mbanga at Nelson Mandela University, Gzeberha, South Africa, have discovered a new type of powder for dusting fingerprints. It allowed them to image their nanoscale details more clearly, while deepening the contrast between ridges and valleys. This work is now published in Hybrid Advances.

Made from manganese-doped iron oxide nanoparticles, and coated in an activated wool char, this new material could help forensic investigators solve crimes more easily.

Recently, metal-oxide nanoparticles have become increasingly popular in fingerprint detection. Not only are they easy to produce, but they also have a high surface area and chemical reactivity, allowing them to interact strongly with the chemical compounds contained in fingerprint residues. When coated in carbon, these nanoparticles create a deeper contrast in fingerprint images, making them far easier to analyse.

In their study, Fouda-Mbanga’s team fabricated their iron oxide nanoparticles using a low-cost, environmentally friendly ‘hydrothermal’ method. They then coated the particles with activated charred wool. This widely available agricultural waste product is chemically inert, making it safer to use than conventional carbon-based powders, while also enhancing the stability of the more reactive nanoparticles.

To examine their powder’s performance, the researchers used it to dust fingerprint residues on a non-porous aluminium surface. They then employed several different types of electron microscopy and light spectroscopy to image them.

The images they produced were incredibly promising, revealing details down to a nanoscale resolution while showing a starker contrast than many types of powder tested in previous studies. Following this success, Fouda-Mbanga’s team now hope that their approach to nanoparticle fabrication could soon be applied more widely in forensic investigation.

Here’s a link to and a citation for the paper,

Nanoarchitectonics of WLC-H3PO4–MnFe2O3 nanocomposite for latent fingerprint detection by B.G. Fouda-Mbanga, T. seyisi, K. Pillay, Zikhona TN. Hybrid Advances Volume 5, April 2024, 100122 DOI: https://doi.org/10.1016/j.hybadv.2023.100122 First Available online 5 December 2023, Version of Record 7 December 2023.

This paper is open access.

Three century long development of a scientific idea: body armor made from silk

Credit: Unsplash/CC0 Public Domain [downloaded from https://phys.org/news/2024-04-body-armor-silk-apparently-edge.html]

Lloyd Strickland’s (professor of Philosophy and Intellectual History, Manchester Metropolitan University) fascinating April 9, 2024 essay on The Conversation (h/t April 10, 2024 news item on phys.org) illustrates the long and winding road to scientific and technological discoveries, Note: Links have been removed,

Separate teams of Chinese and American scientists are reported to be developing body armour using the silk from genetically modified silkworms. The researchers modified the genes of silkworms to make them produce spider silk instead of their own silk.

Harnessing the properties of spider silk has been a longstanding aim because the material is as strong as steel, yet also highly elastic. However, the idea of using silk to make bulletproof vests is not a new idea. Instead, it goes back centuries.

The invention of the silk bulletproof vest is often credited to the American physician George Emory Goodfellow (1855–1910), following his observation that silk was impenetrable to bullets.

But the idea was in fact proposed more than two centuries earlier by the German polymath Gottfried Wilhelm Leibniz (1646–1716), best known as inventor of calculus and binary arithmetic. …

You’ll notice it’s almost two centuries between the idea being proposed and someone working out a way to make a silk bulletproof vest. First, Liebniz (from Strickland’s April 9, 2024 essay), Note: Links have been removed,

In one of these little-known writings, unassumingly entitled “Plan for a military manufacturing process”, Leibniz sought to identify a material suitable for making a lightweight, flexible, bulletproof fabric. He briefly considered metal wires, layered metal sheets, and layered “goldbeater’s skin”, which is a material made from ox intestine. However, he devoted most of his attention to silk.

Whereas Goodfellow had observed the impenetrability of silk by bullets, Leibniz never had. Instead, he thought silk was the most promising material for a bulletproof fabric due to being lightweight, flexible, and strong. “Of all the materials we use for fabrics, and which can be obtained in quantity, there is nothing firmer than a silk thread,” he wrote.

Noting that silk was never firmer than in the cocoon, “where the silk is still gathered in the way that nature produced it”, Leibniz proposed making a fabric formed of silkworm cocoons tightly pressed together with a little glue.

He realised that while such a sheet could not easily be pierced, due to the tightly-woven silk in the cocoons, it would be prone to tearing where one cocoon met the next. Thus, he inferred that a bullet would not make a hole in the fabric, but instead tear whatever cocoon it hit from the surrounding ones, and drive it into the body, similar to what Goodfellow would observe with the silk handkerchief two centuries later.

Leibniz’s solution to the tearing problem was to propose layering sheets of pressed silkworm cocoons on top of each other. He illustrated this with a rudimentary diagram of a row of circles stacked on top of one another in a lattice arrangement, where a small interstice is left between adjoining circles.

Layering cocoons in such a hexagonal packing arrangement ensures that the weak parts of one layer are covered by the strong parts of another. This way, the fabric would not tear or be pierced when hit by a bullet. The result, Leibniz claimed, would be a fabric suitable for covering almost the whole body, especially if it was made to be oversized, affording the wearer freedom of movement.

Leibniz never realised his proposal to create bulletproof clothing using silk.

Strickland’s April 9, 2024 essay offers more about how Goodfellow’s field observations led to the invention of the first silk bulletproof vest by a Catholic priest.

Scott Burton’s undated article for bodyarmornews.com on spider silk and bulletproof body armour offers information about current efforts by US and Chinese scientists to incorporate spider proteins by gene editing silkworms capable of producing enough hybrid silk for enhanced body armour.

A century later, what appears to be the latest breakthrough was announced in a September 24, 2023 news item on chinadaily.com (and noted in Burton’s article),

Chinese scientists have developed the first whole full-length spider silk fiber obtained from genetically-engineered silkworms, exhibiting a six-fold toughness when compared to a bulletproof vest.

The results pave the way for spider silk’s commercialization as a sustainable substitute for synthetic fibers, and it can be used in making surgical sutures and comfortable bulletproof vests, according to the study.

Here’s a link to and a citation for the paper,

High-strength and ultra-tough whole spider silk fibers spun from transgenic silkworms by Junpeng Mi, Yizhong Zhou, Sanyuan Ma, Xingping Zhou, Shouying Xu, Yuchen Yang, Yuan Sun, Qingyou Xia, Hongnian Zhu, Suyang Wang, Luyang Tian, Qing Men. Matter Volume 6, ISSUE 10, P3661-3683, October 04, 2023 DOI: https://doi.org/10.1016/j.matt.2023.08.013 First published online: September 20, 2023

This paper is behind a paywall.