Tag Archives: Alexander Moewes

Gerhard Herzberg , the University of Saskatchewan, and the 1971 Nobel Prize for Chemistry

Half a century ago, a scientist won a Nobel Prize for Chemistry for work he’d done at the University of Saskatchewan and, later, at a National Research Council of Canada laboratory. The Nobel Prize was an unlikely event for more than one reason.

The history description I like the best is also the clunkiest (due to links and citations). From the essay by Denisa Popa for the Defining Moments Canada website (Note 1: I have removed the links; Note 2: NSERC is the Natural Sciences and Engineering Research Council of Canada),

Gerhard Herzberg was born in Hamburg, Germany on December 25th, 1904. From an early age Herzberg developed a keen interest in the sciences, particularly astronomy, physics and chemistry (Stoicheff, 2002). … Herzberg initially considered a career in astronomy, but lacked the funds to pursue it any further (NSERC). In 1924, he ultimately decided to pursue engineering physics and enrolled in the Technical University at Darmstadt (NSERC). By the time he was 24 years old, he was well established in his field, publishing a number of academic papers on the topics of atomic and molecular physics, as well as obtaining a Doctorate in Engineering Physics in 1928 (NSERC).

Following his graduation, he entered a postdoctoral fellowship at the University of Göttingen (University of Saskatchewan). Following that, Herzberg returned to Darmstadt where he spent five years conducting research on spectroscopy (University of Saskatchewan).  Spectroscopy is used to analyze the ability of molecules and compounds to emit and absorb different wavelengths of light and electromagnetic radiation (Herschbach, 1999). Through understanding the properties of the light/radiation that is emitted (or absorbed) scientists can learn more about the characteristics of molecules and compounds, including their structure and the types of chemical bonds they contain (Herschbach, 1999). 

While completing his postdoctoral fellowship, Herzberg met Luise Hedwig Oettinger, a university student also focusing on spectroscopic research (Stoicheff, 2002). The pair grew close and eventually married on December 30th, 1929 (Stoicheff, 2002). Over the years Luise, who received her Ph.D from the University of Frankfurt in 1933, co-authored a number of scientific papers with her husband (Stoicheff, 2002). The Herzbergs’ academic life in Germany would soon end in 1934 when the Nazi regime rose to power and began implementing new restrictions against Jewish scholars in academic institutions (Stoicheff, 2002). Herzberg received notice that he would no longer be permitted to teach at Darmstadt because of Luise’s Jewish heritage (Stoicheff, 2002; University of Saskatchewan). With the help of John W. T. Spinks (a chemist who visited and became closely acquainted with Herzberg in Darmstadt) and Walter C. Murray at the University of Saskatchewan, as well as funding from the Carnegie Foundation (as the university’s budget was limited during the depression era), the Herzbergs moved to Saskatoon that following year (NSERC). 

From 1935 to 1945 Herzberg established himself at the University of Saskatchewan, where he continued his research on molecular and atomic spectroscopy, publishing three new books (NSERC). He then spent the following three years at the University of Chicago’s Yerkes Observatory investigating “the absorption spectra of many molecules of astrophysical interest.” (NSERC) In 1948, the Herzbergs relocated back to Canada when Herzberg was invited to “establish a laboratory for fundamental research in spectroscopy” at the National Research Council (NRC) of Canada. (NSERC) It was during his time at the NRC that one of his key discoveries was made–the observation of the spectra of methylene radical (CH2) (Stoicheff, 2002). Scientists describe free radicals as chemical species that have an unpaired electron in the outer valence shell (Winnewisser, 2004). Free radicals can be found as intermediates in a variety of chemical reactions (Herschbach, 1999). It was Herzberg’s contribution to the understanding of free radicals that contributed to his Nobel Prize win in 1971 (NSERC). Dr. Gerhard Herzberg had two children and passed away on March 3rd, 1999 at the age of 94 (Herschbach, 1999). 

Kathryn Warden’s Saskatechwan-forward article was first published in August 2021 in the University of Saskatchewan’s Green & White magazine (Note: A link has been removed),

When Gerhard Herzberg was awarded the Nobel Prize in chemistry 50 years ago for ground-breaking discoveries in a lifelong exploration of the structure of matter, he publicly thanked the University of Saskatchewan.

“It is obvious that the work that has earned me the Nobel Prize was not done without a great deal of help,” Herzberg said in his acceptance speech, acknowledging “the full and understanding support” of successive USask presidents and faculty who “did their utmost to make it possible for me to proceed with my scientific work.”

Herzberg’s brilliance in studying the spectra of atoms and molecules to understand their physical properties significantly advanced astronomy, chemistry and physics—enhancing knowledge of the atmospheres of stars and planets and determining the existence of some molecules never before imagined.

“He was certainly a pioneer,” said USask PhD student Natasha Vetter, winner of both the 2014 Herzberg Scholarship and the 2018 Herzberg Fellowship. “Without his work, the fundamental tools we use as chemists and biochemists wouldn’t exist. I feel pretty honoured to be part of that legacy and to have received those awards.”

While at USask from 1935 to 1945, Herzberg made discoveries that laid the groundwork for his work at Chicago’s Yerkes Observatory and then at the National Research Council (NRC), culminating in his celebrated work on free radicals—highly unstable, short-lived molecules that are everywhere: in our bodies, in materials and in space. They help important reactions take place but an imbalance can cause damage such as cancer or age-related illness. Knowledge of their structure is now used to make pharmaceuticals, medical radiation tests, light sensors, and a wide range of innovative materials.

“This was the beginning of molecular spectroscopy, and it was an exciting time because it was all so new,” said Alexander Moewes, Canada Research Chair in Materials Science with Synchrotron Radiation.

“Herzberg was unravelling the structure of molecules, specifically free radicals. Many of today’s drugs and human biochemistry processes are governed by these molecules. So much that we have developed today would not have been discovered if Herzberg hadn’t done this fundamental research. This can’t be overstated.”

In honour of Herzberg, the University of Saskatchewan is naming both a hall and a lecture theatre at the Canadian Light Source (CLS), Canada’s synchrotron facility, after Herzberg, from a November 10, 2021 University of Saskatchewan news release,

As part of a national initiative to mark the 50th anniversary of Gerhard Herzberg’s Nobel Prize, the University of Saskatchewan (USask) is naming the main experimental hall of the Canadian Light Source (CLS) and a prominent physics lecture theatre on campus after the renowned scientist.

“Canada and the University of Saskatchewan welcomed Herzberg and his wife when no other country or university did,” said Stoicheff [USask President Peter Stoicheff]. “His legacy is evident today in so many ways, including at our Canadian Light Source where scientists from across Canada and around the world continue to unravel the mysteries of atomic structure.”

The Herzberg Experimental Hall is at the heart of the CLS, “the brightest light in Canada.” The enormous hall the size of a football field houses the synchrotron which supplies light to the many beamlines where wide-ranging experiments are conducted. The naming was endorsed by both the CLS board of directors and the CLS Users’ Executive Committee, and subsequently approved by the President’s Advisory Committee on Naming University Assets.

“As the father of modern spectroscopy, Herzberg conducted experiments that fundamentally changed scientific understanding of how molecules absorb and emit light,” said CLS board chair Pierre Lapointe.

“So it is very fitting that we honour his legacy at the Canadian Light Source where scientists from across Canada and around the world carry on the important work of using light to investigate the structure of matter—work that is leading to discoveries in fields as diverse as health, environment and new materials.” 

In his 2020 co-authored book on the history of the CLS, former CLS director Michael Bancroft said Herzberg’s fundamental research program in spectroscopy at USask in the 1930s paved the way for Canada’s only synchrotron.  He states that the close friendship that developed between USask chemistry researcher John Spinks and Herzberg in 1933 and 1934 in Germany, along with Herzberg’s subsequent hiring by USask President Walter Murray in 1935, “were the most important events in eventually landing the Canadian Light Source over 60 years later.” 

As Herzberg was a member of the USask physics department for a decade, the Physics 107 Lecture Theatre, across from a display dedicated to Herzberg, will be named the Dr. Gerhard Herzberg Lecture Theatre.

Chris Putnam’s December 10, 2021 article for the University of Saskatchewan highlights Herzberg’s other interests such as music and humanitarian work.

Finally, Herzberg gave an interview to Mary Christine King on May 5, 1986 (audio file and text) for the Science History Institute. Here’s a little more about Ms. King who died months after the interview,

“… born in China and educated in Ireland. She obtained a BSc degree in chemistry from the University of London in 1968, which was followed by an MSc in polymer and fiber science (1970) and a PhD for a thesis on the hydrodynamic properties of paraffins in solution (1973), both from the University of Manchester Institute of Science and Technology. After working with Joseph Needham at Cambridge, she received a PhD in the history and philosophy of science from the Open University (1980) and thereafter worked at the University of California, Berkeley, and at the University of Ottawa, … King died in an automobile accident in late 1987 …”

The interview is an oral history as recounted by Herzberg.

Silicene in Saskatchewan (Canada)

There’s some very exciting news coming out of the province of Saskatchewan (Canada) about silicene, a material some view as a possible rival to graphene (although that’s problematic according to my Jan. 12, 2014 posting) while others (US National Argonne Laboratory) challenge its existence (my Aug. 1,  2014 posting).

The researchers in Saskatchewan seem quite confident in silicene’s existence according to a Sept. 9, 2014 news item on phys.org,

“Once a device becomes too small it falls prey to the strange laws of the quantum world,” says University of Saskatchewan researcher Neil Johnson, who is using the Canadian Light Source synchrotron to help develop the next generation of computer materials. Johnson is a member of Canada Research Chair Alexander Moewes’ group of graduate students studying the nature of materials using synchrotron radiation.

His work focuses on silicene, a recent and exciting addition to the class of two-dimensional materials. Silicene is made up of an almost flat hexagonal pattern of silicon atoms. Every second atom in each hexagonal ring is slightly lifted, resulting in a buckled sheet that looks the same from the top or the bottom.

A Sept. 9, 2014 Canadian Light Source news release, which originated the news item, provides background as to how Johnson started studying silicene and some details about the work,

In 2012, mere months before Johnson began to study silicene, it was discovered and first created by the research group of Prof. Guy Le Lay of Aix-Marseille University, using silver as a base for the thin film. The Le Lay group is the world-leader in silicene growth, and taught Johnson and his colleagues how to make it at the CLS themselves.

“I read the paper when the Le Lay announced they had made silicene, and within three or four months, Alex had arranged for us to travel down to the Advanced Light Source with these people who had made it for the first time,” says Johnson. It was an exciting collaboration for the young physicist.

“This paper had already been cited over a hundred times in a matter of months. It was a major paper, and we were going to measure this new material that no one had really started doing experiments on yet.”

The most pressing question facing silicene research was its potential as a semiconductor. Today, most electronics use silicon as a switch, and researchers looking for new materials to manage quantum effects in computing could easily use the 2-D version if it was also semiconducting.

Calculations had shown that because of the special buckling of silicene, it would have what’s called a Dirac cone – a special electronic structure that could allow researchers to tune the band gap, or the energy space between electron levels. The band gap is what makes a semiconductor: if the space is too small, the material is simply a conductor. Too large, and there is no conduction at all.

Since silicene has only ever been made on a silver base, the materials community also wondered if silicene would maintain its semiconducting properties in this condition. Though its atomic structure is slightly different than freestanding silicene, it was still predicted to have a band gap. However, silver is a metal, which may make the silicene act as a metal as well.

No one really knew how silicene would behave on its silver base.

To adapt the Le Lay group’s silicene-growing process to the equipment at the CLS took several days of work. Though their team had succeeded in silicene synthesis at the Advanced Light Source at Berkeley lab, they had no way to keep those samples under vacuum to prevent them from oxygen damage. Thanks to the work of fellow beamteam members Drs. David Muir and Israel Perez, samples grown at the CLS could be produced, transported and measured in a matter of hours without ever leaving a vacuum chamber.

Johnson grew the silicene sheets at the Resonant Elastic and Inelastic X-ray Scattering (REIXS), beamline, then transferred them in a vacuum to the XAS/XES endstation for analysis. Finally, Johnson could find the answer to the silicene question.

“I didn’t really know what to expect until I saw the XAS and XES on the same energy scale, and I thought to myself, that looks like a metal,” says Johnson.

And while that result is unfortunate for those searching for a new computing wonder material, it does provide some vital information to that search.

“Our result does help to guide the hunt for 2-D silicon in the future, suggesting that metallic substrates should be avoided at all costs,” Johnson explains. “We’re hopeful that we can grow a similar structure on other substrates, ideally ones that leave the semiconducting nature of silicene intact.”

That work is already in process, with Johnson and his colleagues planning to explore three other growing bases this summer, along with multilayers and nanoribbons of silicene.

Like the Dutch researchers in the Jan. 12, 2014 posting, Johnson finds that silicene is not serious competition for graphene (as regards to its electrical properties), but he does not challenge its existence. He does note problems with the silver substrate although he comes to a different conclusion than did the Argonne National Laboratory researchers (Aug. 1,  2014 posting).

Here’s a link to and a citation for Johnson’s paper,

The Metallic Nature of Epitaxial Silicene Monolayers on Ag(111) by Neil W. Johnson, Patrick Vogt, Andrea Resta, Paola De Padova, Israel Perez, David Muir, Ernst Z. Kurmaev, Guy Le Lay, and Alexander Moewes. Advanced Functional Materials Volume 24, Issue 33, pages 5253–5259, September 3, 2014 DOI: 10.1002/adfm.201400769 Article first published online: 10 JUN 2014

This paper is behind a paywall.