Tag Archives: buckypaper

A better buckypaper

‘Buckyballs’ is a slang term for buckminster fullerenes, spheres made up of a carbon atoms arranged in hexagons. It’s a tribute of sorts to Buckminster Fuller, an architect, designer, systems theorist and more, who developed a structure known as a geodesic dome which bears a remarkable resemblance to the carbon atom spheres known as buckyballs or buckminster fullerenes or fullerenes or C60 (for a carbon-based fullerene) for short. Carbon nanotubes are sometimes called buckytubes and there is a material known as buckypaper. A Sept. 20, 2016 news item on Nanowerk describes the latest work on buckypaper,

Researchers at the Masdar Institute of Science and Technology have developed a novel type of “buckypaper” – a thin film composed of carbon nanotubes – that has better thermal and electrical properties than most types of buckypaper previously developed. Researchers believe the innovative buckypaper could be used to create ultra-lightweight composite materials for numerous aerospace and energy applications, including advanced lightning strike protection on airplanes and more powerful lithium-ion batteries.

Masdar Institute’s Associate Professors of Mechanical and Materials Engineering Dr. Rashid Abu Al-Rub and Dr. Amal Al Ghaferi, along with Post-Doctoral Researcher Dr. Hammad Younes, developed the buckypaper with carbon nanostructures provided by global security, aerospace, and information technology company Lockheed Martin.

A Sept. 20, 2016 Masdar Institute (United Arab Emirates) press release, which originated the news item, describes the research in more detail,

The black, powdery flakes provided by Lockheed Martin’s Applied NanoStructured Solutions (ANS) contain hundreds of carbon nanotubes, which are one-atom thick sheets of graphene rolled into a tube that have extraordinary mechanical, electrical and thermal properties. Lockheed Martin’s carbon nanostructures are unique because the carbon nanotubes within each flake are all properly aligned, making them good conductors of heat and electricity.

“Lockheed Martin’s carbon nanostructures have many potential applications, but in its powdery form, it cannot be used. It has to be fabricated in a way that keeps the unique properties of the carbon nanotube,” explained Dr. Al Ghaferi. “The challenge we faced was to create something useful with the carbon nanotubes without losing any of their unique properties or disturbing the alignment.”

Dr. Younes said: “Each flake is a carbon nanostructure containing many aligned carbon nanotubes. The alignment of the tubes creates a path for conductivity, much like a wire, making the nanostructure an exceptionally good conductor of electricity.”

The Masdar Institute team mixed the carbon nanotubes with a polymer and their resulting buckypaper, which successfully maintained the alignment of the carbon nanotubes, demonstrated high thermal-electrical conductivity and superior mechanical properties.

“We have a secret recipe for self-aligning the carbon nanotubes within the buckypaper. This self-aligning is key in significantly enhancing the electrical, thermal and mechanical properties of our fabricated buckypapers,” explained Dr. Abu Al-Rub.

Despite their microscopic size – a carbon nanotube’s diameter is about 10,000 times smaller than a human hair – carbon nanotubes’ impact on technology has been huge. At the individual tube level, carbon nanotubes are 200 times stronger, five times more elastic, and five times more electrically conductive than steel.

Because of their extraordinary strength, thermal and electrical properties, and miniscule size, carbon nanotubes can be used in a number of applications, including ultra-thin energy storage devices, smaller and more efficient computer chips, photovoltaic solar cells, flexible electronics, cancer detection, and lightning-resistant coatings on airplanes.

According to a report by Global Industry Analysts Inc., the current global market for nanotubes is pegged at roughly US$5 billion and its market share is growing sharply, reflecting the rising sentiment worldwide in carbon nanotubes’ potential as a wonder technology.

Masdar Institute’s efforts to capitalize on this emerging technology have resulted in several cutting-edge carbon nanotube research projects, including an attempt to create carbon nanotube-strengthened concrete, super capacitors that can hold 50 times more charge, and a membrane that can bind organic micro-pollutants.

As the UAE moves towards a clean energy future, innovations in renewable energy storage systems and other sustainable technologies are crucial for the country’s successful transition, and researchers at Masdar Institute believe that carbon nanotubes will play a huge role in achieving energy sustainability.

Here’s a link to and a citation for the paper,

Processing and property investigation of high-density carbon nanostructured papers with superior conductive and mechanical properties by Hammad Younesa, Rashid Abu Al-Ruba, Md. Mahfuzur Rahmana, Ahmed Dalaqa, Amal Al Ghaferia, Tushar Shahb. Diamond and Related Materials Volume 68, September 2016, Pages 109–117  DOI: http://dx.doi.org/10.1016/j.diamond.2016.06.016

This paper is behind a paywall.

Buckypaper technology in Florida (US) receives $!.4M grant

Just after suggesting (as per my Nov. 26, 2013 posting) that Florida is quietly becoming a center for nanotechnology efforts in the US, there’s a $1.4M funding announcement for Florida State University’s High-Performance Materials Institute (HPMI. From the Nov. 27, 2013 news item on Nanowerk,

Florida State researchers have been awarded more than $1.4 million from the National Science Foundation to develop a system that will produce large amounts of a state-of-the-art material made from carbon nanotubes that researchers believe could transform everything from the way airplanes are built to how prosthetic limbs fit the human body.

“The goal is clear — to show industry the ability to use this in large-scale quantities,” said Richard Liang, director of FSU’s High-Performance Materials Institute (HPMI) and a professor for the FAMU-FSU College of Engineering. “We’re looking at a more efficient, cost effective way to do this.”

The Nov. 26, 2013 Florida State University (FSU) news release (also on EurekAlert), which originated the news item, provides greater detail about buckypaper, the team’s research work, and the team’s hopes for this grant,

The material, buckypaper, is a feather-light sheet made of carbon nanotubes that is being tested in electronics, energy, medicine, space and transportation.  The aviation industry, for example, is doing tests with buckypaper, and it’s projected that it could replace metal shielding in the Boeing 787, currently made up of 60 miles of cable.

Engineers believe that replacing the cable with buckypaper could reduce the weight of the Boeing 787 by as much as 25 percent.

Florida State researchers have been engaged in other projects with buckypaper as well, including the use of the material in creating more advanced and comfortable prosthetic sockets for amputee patients and multifunctional lightweight composites for aerospace applications.

As revolutionary as buckypaper technology is, a major hurdle for its future use is that it can take two or more hours and can cost as much as $500 to make just a small 7-inch by 7-inch piece.  Companies like Boeing need large amounts of it to use on an aircraft.

However, the current process is neither fast nor cheap.

So, Liang will spend the next four years developing a process to produce large-scale amounts of buckypaper. The process and materials would then be patented and marketed to meet the demands of the industrial partners.

Liang will be joined on the project by Arda Vanli, an HPMI researcher and an assistant professor in the Department of Industrial and Manufacturing Engineering, as well as researchers from Georgia Institute of Technology.

The US National Science Foundation (NSF) webpage listing the award describes the specific research being undertaken and introduces the term ‘Bucky-tapes’,

Award Abstract #1344672
SNM: Roll-to-Roll Manufacturing of High Quality Bucky-tape with Aligned and Crosslinked Carbon Nanotubes Through In-line Sensing and Control

Carbon nanotubes (CNTs) demonstrate amazing properties; however, currently only a fraction of these properties can be transferred into products that can be used by engineers and consumers. To effectively transfer CNTs? properties into useful products requires a method to efficiently align and covalently interconnect the CNTs into tailored architectures at the nanoscale. This project will establish the fundamental understanding and foundation for using CNTs to make thin sheet materials, called Bucky-tapes, which can be rapidly produced in roll form and scaled-up for industrial applications. The proposed method will use a modified die-casting manufacturing process utilizing the self-repelling effects of selected flow media. In-situ ultra-violet (UV) reaction chemistry can covalently interconnect the CNTs rapidly to improve the load transfer and thermal and electronic transport properties of CNT networks. In-line multi-stage stretching of the web could orient the randomly dispersed interconnected CNT networks into specific patterns to provide greater strength and optimized transport properties. In-line Raman spectra monitoring and multistage process models will provide affordable, closed loop quality control and variation reduction methods for a high quality consistent nanomanufacturing process. A prototype will be built to demonstrate the continuous roll-to-roll process for manufacturing strong Bucky-tapes with high electrical and thermal conductivity, and low manufacturing cost.

This project can transform CNT thin films networks from a lab-scale demonstration material into commercially viable products with superior properties potentially surpassing the state-of-the-art carbon fiber material. The continuous Bucky-tapes can lead to new materials applications in aerospace, electronics, energy, medicine, and transportation. For example, continuous Bucky-tape could replace metal shielding of 60 miles of cables in the Boeing 787 and reduce cable weight by 25%. The education and outreach plan will expose especially under-represented students to molecular design, nanomanufacturing process development and quality control, structure-property relationship studies. Application oriented materials-by-design and nanomanufacturing process development will motivate students into nanotechnology, manufacturing and new materials development.

I had mentioned this team’s work on buckypaper (or are they now calling it Bucky-tape?) in an Oct. 4, 2011 posting which features a video about buckypaper and in which I noted the possible applications for buckypaper closely mirror those for CNC (cellulose nanocrystals) or, as it’s also known,  NCC (nanocrystalline cellulose).

You can check out Florida State University’s High Performance Materials Institute here.

Buckypaper and nanocrystalline cellulose; two different paths to the same ends?

Buckypaper interests me largely because of its name (along with Buckyballs and Buckytubes [usually called carbon nanotubes]). I believe the names are derived from Buckminsterfullerenes a form of carbon engineered (it can be found in nature) in the labs at Rice University. From the Wikipedia essay on Buckminsterfullerenes,

Buckminsterfullerene is a spherical fullerene molecule with the formula C60. It was first prepared in 1985 by Harold Kroto, James Heath, Sean O’Brien, Robert Curl and Richard Smalley at Rice University.  Kroto, Curl, and Smalley were awarded the 1996 Nobel Prize in Chemistry for their roles in the discovery of buckminsterfullerene and the related class of molecules, the fullerenes. The name is an homage to Richard Buckminster Fuller, whose geodesic domes it resembles. Buckminsterfullerene was the first fullerene molecule discovered and it is also the most common in terms of natural occurrence, as it can be found in small quantities in soot.

Buckypaper is a main focus at the High Performance Materials Institute at the Florida State University, which has just *released a promotional video (according to the Oct. 3, 2011 news item on Nanowerk). Here’s the video,

It reminds me a little of the video for Nokia’s Morph concept, which was released a few years back. I haven’t heard any substantive news about that project although there are the occasional updates. For example, the Morph was originally described it as a phone and then they changed it to the Morph concept. I’d love to see a prototype one of these days. (There’s more about the Morph and its incarnations in my Sept. 29, 2010 posting.)

The descriptions for applications using Buckypaper reminded me of nanocrystalline cellulose as I’ve seen some of the same claims made for that substance. I’m hoping to hear about the new plant in Windsor, Québec which is supposed to be opening this fall. From the ArboraNano new projects page,

Currently, Canada has an 18- to 24-month global lead in the commercial production of NCC as a 1 ton/day demonstration plant located in Windsor, Quebec enters the final phases of construction. Startup is planned for Fall 2011.

It’s good to see all these different research efforts and to reflect on the innovation being demonstrated.

* Nov. 27, 2013: changed ‘release’ to ‘released’.