Tag Archives: e-paper

Making a graphene micro-supercapacitor with a home DVD burner

Not all science research and breakthroughs require massive investments of money, sometimes all you need is a home DVD burner as this Feb. 19, 2013 news release on EurekAlert notes,

While the demand for ever-smaller electronic devices has spurred the miniaturization of a variety of technologies, one area has lagged behind in this downsizing revolution: energy-storage units, such as batteries and capacitors.

Now, Richard Kaner, a member of the California NanoSystems Institute at UCLA and a professor of chemistry and biochemistry, and Maher El-Kady, a graduate student in Kaner’s laboratory, may have changed the game.

The UCLA researchers have developed a groundbreaking technique that uses a DVD burner to fabricate micro-scale graphene-based supercapacitors — devices that can charge and discharge a hundred to a thousand times faster than standard batteries. These micro-supercapacitors, made from a one-atom–thick layer of graphitic carbon, can be easily manufactured and readily integrated into small devices such as next-generation pacemakers.

The new cost-effective fabrication method, described in a study published this week in the journal Nature Communications, holds promise for the mass production of these supercapacitors, which have the potential to transform electronics and other fields.

“Traditional methods for the fabrication of micro-supercapacitors involve labor-intensive lithographic techniques that have proven difficult for building cost-effective devices, thus limiting their commercial application,” El-Kady said. “Instead, we used a consumer-grade LightScribe DVD burner to produce graphene micro-supercapacitors over large areas at a fraction of the cost of traditional devices. [emphasis mine] Using this technique, we have been able to produce more than 100 micro-supercapacitors on a single disc in less than 30 minutes, using inexpensive materials.”

The University of California at Los Angeles (UCLA) Feb. 19, 2013 news release written by David Malasarn, the origin of the EurekAlert news release, features more information about the process,

The process of miniaturization often relies on flattening technology, making devices thinner and more like a geometric plane that has only two dimensions. In developing their new micro-supercapacitor, Kaner and El-Kady used a two-dimensional sheet of carbon, known as graphene, which only has the thickness of a single atom in the third dimension.
Kaner and El-Kady took advantage of a new structural design during the fabrication. For any supercapacitor to be effective, two separated electrodes have to be positioned so that the available surface area between them is maximized. This allows the supercapacitor to store a greater charge. A previous design stacked the layers of graphene serving as electrodes, like the slices of bread on a sandwich. While this design was functional, however, it was not compatible with integrated circuits.
In their new design, the researchers placed the electrodes side by side using an interdigitated pattern, akin to interwoven fingers. This helped to maximize the accessible surface area available for each of the two electrodes while also reducing the path over which ions in the electrolyte would need to diffuse. As a result, the new supercapacitors have more charge capacity and rate capability than their stacked counterparts.
Interestingly, the researchers found that by placing more electrodes per unit area, they boosted the micro-supercapacitor’s ability to store even more charge.
Kaner and El-Kady were able to fabricate these intricate supercapacitors using an affordable and scalable technique that they had developed earlier. They glued a layer of plastic onto the surface of a DVD and then coated the plastic with a layer of graphite oxide. Then, they simply inserted the coated disc into a commercially available LightScribe optical drive — traditionally used to label DVDs — and took advantage of the drive’s own laser to create the interdigitated pattern. The laser scribing is so precise that none of the “interwoven fingers” touch each other, which would short-circuit the supercapacitor.
“To label discs using LightScribe, the surface of the disc is coated with a reactive dye that changes color on exposure to the laser light. Instead of printing on this specialized coating, our approach is to coat the disc with a film of graphite oxide, which then can be directly printed on,” Kaner said. “We previously found an unusual photo-thermal effect in which graphite oxide absorbs the laser light and is converted into graphene in a similar fashion to the commercial LightScribe process. With the precision of the laser, the drive renders the computer-designed pattern onto the graphite oxide film to produce the desired graphene circuits.”
“The process is straightforward, cost-effective and can be done at home,” El-Kady said. “One only needs a DVD burner and graphite oxide dispersion in water, which is commercially available at a moderate cost.”
The new micro-supercapacitors are also highly bendable and twistable, making them potentially useful as energy-storage devices in flexible electronics like roll-up displays and TVs, e-paper, and even wearable electronics.

The reference to e-paper and roll-up displays calls to mind work being done at Queen’s University (Kingston, Canada) and Roel Vertegaal’s work on bendable, flexible phones and computers (my Jan. 9, 2013 posting). Could this work on micro-supercapacitors have an impact on that work?

Here’s an image (supplied by UCLA) of the micro-supercapacitors ,

Kaner and El-Kady's micro-supercapacitors

Kaner and El-Kady’s micro-supercapacitors

UCLA has  also supplied a video of Kaner and El-Kady discussing their work,

Interestingly this video has been supported by GE (General Electric), a company which seems to be doing a great deal to be seen on the internet these days as per my Feb. 11, 2013 posting titled, Visualizing nanotechnology data with Seed Media Group and GE (General Electric).

Getting back to the researchers, they are looking for industry partners as per Malasarn’s news release.

Pebble’s e-paper watch wins over $3M in funding through crowdfunding

I gather it’s the most successful crowdfunding project Kickstarter has hosted yet. The Pebble team asked for $100,000 to realize their e-paper/ smartwatch project and have raised over $3M while they still have 30 days left in their campaign. In the kind of twist that makes one smirk, they posted the project on Kickstarter as they were unable to raise sufficient funds in Silicon Valley. From the April 16, 2012 Q&A with Alexandra Chung at Wired,

Wired: Are you surprised by the reception to Pebble? What were you hoping for when you launched on Kickstarter?

Migicovsky [Eric Migicovsky, Pebble founder and lead designer]: We were expecting $100,000 over a month, so when it came in two hours, it was a surprise. On Thursday, we were earning $80,000 an hour. By Sunday morning, we passed the Wasteland 2, which was the second most popular Kickstarter after Double Fine Adventures.

Wired: Has the influx of funding affected your production plans? Are you changing your strategy at all?

Migicovsky: We’re basically leveling up. We had a variety of paths we could have followed. We were originally aiming for $100,000, so we had a production path that we could have followed to meet that $100,000. Now we’re following a path that is several levels higher than that.

Right now, we don’t have any specifics for where the product is being made. There are various levels of contract manufacturers, and we’re going to use a contract manufacturer. We’re moving to a one-stop shop, so we come with X amount of orders.

On the one hand, six months is not very long to bring a product to market. But we have this huge backer community that will help us get there. They are providing the funding that’s helping us make quality decisions, like spending money now on making a more aesthetically pleasing product. We’re making those decisions now.

We had a design plan with several different levels. It’s not like we are drastically altering the design. We just had “gotta haves,” like 7-day battery life, and then the “nice to haves” like more water-resistance, which are the features we’re moving into now.

Here’s a description of the pr0ject and the product from the April 17, 2012 news item on the BBC News website,

The Pebble watch reached the $1m mark in 28 hours. The firm behind the device, which has been designing smartwatches for three years, said that it was “blown away” by the support.

The watch has an electronic paper screen and connects via Bluetooth with iPhones or Android powered devices to allow users to customise the watch face and download apps.

The display stays on at all times and is backlit for night viewing. The firm says that the rechargeable battery will last a week.

It can display distance and speed for runners and cyclists, control a smartphone’s music, and show emails, messages and reminders.

The watch will go head to head with an Android-compatible device released in April by electronic giant Sony Corp. The Sony Smartwatch costs $149.99.

This video should answer a few more questions about the watch,

Migicovsky is Canadian. Originally from Vancouver, he graduated from the University of Waterloo and made his way to California. From the April 17, 2012 article by Chuck Howitt for the Record.com,

The Pebble smartwatch is a “natural evolution” of the inPulse smartwatch that Migicovsky started working on while a student at UW [University of Waterloo] in 2008.

Released in 2009, the inPulse connected wirelessly with BlackBerry smartphones to indicate when the user had an email, message or call.

Sold through a company he called Allerta Inc., sales of the inPulse have been rather modest, about 1,500 to date, admits Migicovsky.

So the 26-year-old Vancouver native set his sights on the booming iPhone and Android markets.

To crack the California market and raise funds at the same time, he applied for admission to Y Combinator, a technology incubator based in Silicon Valley, in early 2011.

Successful applicants are guaranteed about $20,000 on admission plus more funding at the end of an intense three-month internship. Migicovsky was able to raise about $375,000 by the time he left Y Combinator, which he used to start working on the Pebble.

When he hit the venture capital market, he got a lukewarm response for the Pebble.

Most venture capitalists “have an aversion to hardware,” he said. “The general feeling is it costs more money. There is a little bit more risk.”

You can find out more about Pebble at the company website and, if you were wondering what SDK (as mentioned in the video) means, it’s Software Development Kit.

I recently wrote about e-paper in my April 3, 2012 posting titled,
Folding screens at University of Toronto and EPD (electronic paper display) with LG.

Electronic paper from Taiwan

I have Taiwan and its Industrial Technology Research Institute (ITRI) on my radar this week. After announcing the results of their Global Nano contest, they announced a breakthrough for electronic paper technology. From the Oct. 10, 2011 news item on Nanowerk,

ITRI (Industrial Technology Research Institute), Taiwan’s largest and one of the world’s leading high-tech research and development institutions, introduces i2R e-Paper™, the first electronic paper technology to provide a re-writable, re-usable and environmentally friendly recyclable print medium — an “electronic paper” — to reduce traditional paper consumption. ITRI will receive a “2011 R&D 100 Award” from R&D Magazine next week for this breakthrough technology.

i2R e-Paper™ can be manufactured in a variety of sizes. It will limit waste on short-lived business initiatives such as advertising banners, corporate visitor ID badges, transit passes, and museum or parking lot tickets. In the future, the technology may be used for producing digital books and pictorials without restriction on length, wall banners, large size electronic bulletin boards and other innovative applications. It is highly flexible and bendable.

Here’s a little more information about the technology,

i2R e-Paper™, whether note card or banner roll size, does not consume electricity to maintain an image. To print and change content, users simply need a thermal printer fitted with a thermal head. Heat generated from the thermal head uses minimal power consumption and interacts with the environmentally friendly composition of the e-Paper to capture an image. Re-using the i2R e-Paper™ is as easy as putting it back into any thermal printer device. The old image is removed and replaced with a new one — no ink, no toner and no paper are consumed.

ITRI’s patented cholesteric liquid crystal technology is not the same cholesterol generally referred to in the biomedical industry, but rather has a structure similar to cholesterol molecules. Cholesteric liquid crystal is a reflective display technology. It utilizes ambient light sources from the external environment to display images, does not require any backlighting and doesn’t consume power in maintaining the display of content or diagrams. The cholesteric liquid crystal can produce red, green and blue colors by adding different pitch spherical composite ion-exchangers to produce different colors. It is also one of the future display materials for color e-books.

It’ll be interesting to see if businesses and consumers accept this new technology. ITRI is licensing i2R e-Paper™ in Taiwan and is in talks with interested US companies, according to the news item.

I first wrote about electronic paper in my May 1, 2009 posting where, inevitably, Neal Stephenson’s book Diamond Age is mentioned along with one of that year’s breakthroughs.

E-paper technology takes another step forward, spooky magnetic attractions, and the business of nano

If you’ve read Neal Stephenson’s ‘Diamond Age’ then you’ll probably remember a passage near the beginning where a main character unrolls his flexible screen before glancing at the daily news. We’re not there yet with e-paper because there’s a problem with brightness (reflectance of ambient light). Most e-paper screens give 40% reflectance and that’s not been enough until this week when Gamma Dyanmics took a step closer to achieving the e-newspaper dream with their electrofluidic display. They are working on a international joint project with the University of Cincinnati, Sun Chemical, and Polymer Visual. They’ve unveiled a prototype and published a paper in the May issue of Nature Photonics (this is behind a paywall). For a consumer-friendly article describing the work, go to Fast Company here. For more technically-minded descriptions go here for a longer version and here for a shorter version.

Thanks to Fast Company, I found this video called, Magnetic Attractions. Artists at NASA created a short video illustrating various magnetic forces. What makes it spooky? They even show the forces extending through walls. You can see it here.

You might want to take a boo at Howard Lovy’s March 2009 posting about nano business and nano possibilities on Small Tech Talk. It was written in response to this (from Lovy’s post),

It has gotten to the point now where Scott E. Rickert, chief executive of Nanofilm Ltd., has gone as far as to declare that “the era of endless exploration is over — at least as long as the economy stumbles.” Writing in IndustryWeek, Rickert expresses his impatience now with nanotech information that is not directly related to business.

“Nanobusiness is business. Period. First, last, always,” Rickert declares.

I like Lovy’s response to this. As for me, some of the business people have extremist positions not that far removed from those of some scientists who think that they should be allowed to research whatever they want and that business is a dirty word.

E-ink and nanotech scholarships in Alberta

I purchased the October 2008 issue of Esquire magazine (as per my last blog posting where you can also find a link to Andrew Maynard’s posting about the issue) available from my local store. Unfortunately, they don’t stock the super duper version which has the first ever e-ink cover since a limited number of those were printed and made  available only in the US. On the upside, the non super duper e-ink version (identical in every other aspect) offers a description of the process (parts of it) on p. 73.

Apparently, the magazine’s project had its genesis seven years ago in a visit to a start up company called E Ink. The company had developed a technology now found in cell-phone screens and electronic readers (e.g. Kindle). It’s a kind of ink-based electronic display. At the time, technology that would allow them to create an “e paper” thin and flexible enough to function as a magazine cover was not in place but that all changed last year.

One of E Ink’s partners, the Nicobar Group (based in Shanghai) had developed circuitry that was promising but there was a problem (along with other problems) with power requirements. The cover had to last at least 90 days. They solved the problem by refrigerating the circuit boards as long as possible throughout the process. (If you have a super duper issue, you should be able to extend its life past 90 days by refrigerating it.)

Each cover had its circuit board set by hand then the company doing the binding (RR Donnelly) had to find a way to protect the circuitry from the impact of its binding machines.

There’s more detail in the magazine (although not as much as I would like) which celebrates Esquire’s 75th anniversary not only with a new type of technology but also with profiles of 75 people the editors think will influence the 21st Century.

I should note that science fiction got there first (as far as I know) with Neal Stephenson’s nanotechnology-influenced novel Diamond Age which describes a world with e-paper newspapers and books.

One bit of news from Alberta, the provincial government announced funding scholarships for graduate students who are studying nanotechnology. Details here.