Tag Archives: electromagnetic radiation

Viscous electronics and graphene

Caption: From cars on a highway to a viscous fluid like oil, our understanding of electron behaviour is being changed by new research. Credit: College of Design and Engineering, National University of Singapore

An October 21, 2024 news item on phys.org announces the new research illustrated in the above, Note: Links have been removed,

In high school science class, we learned that plugging a cable into an electrical circuit sets off a flow of electrons, powering everything from our lights to our phones. Traditionally, we’ve understood how electrons behave in metals and semiconductors through this simple model: electrons are imagined as tiny, independent particles, much like cars on an open highway—each one moving freely, without interacting much with the others.

It’s a straightforward perspective that has been the foundation of electronics for many years, helping us understand and design the electronic devices that underpin much of modern life.

However, this traditional view falls short in the case of some emerging quantum materials such as the ultrathin, and highly conductive material graphene. In these materials, rather than behaving like individual cars on a highway, electrons instead act together in a way that resembles a viscous fluid such as oil. This finding could be transformative for the future development of a broad range of technologies.

Assistant Professor Denis Bandurin and his team, who are from the Department of Materials Science and Engineering at the College of Design and Engineering at the National University of Singapore, are exploring how quantum materials interact with electromagnetic radiation at the nanoscale to uncover new scientific phenomena and their potential use in developing future technologies.

An October 21, 2024 National University of Singapore (NUS) press release (also on EurekAlert but lightly edited) by Asst Prof Denis Bandurin, which originated the news item, delves further into the topic,

In a recent study, published in Nature Nanotechnology, the team reported that when graphene is exposed to electromagnetic radiation of terahertz frequencies, electron fluid heats up and its viscosity is drastically reduced, resulting in lower electrical resistance – much like how oil, honey and other viscous fluids flow more easily as they are heated on a stove.

Advancing the frontiers of THz waves detection

Terahertz (THz) waves are a special and technologically challenging part of the electromagnetic spectrum – situated between microwaves and infrared light – that have a vast range of potential applications. Being able to detect THz waves could unlock major advances in technologies.

In communications for example, current Wi-Fi technology operates at several GHz, limiting how much data can be transmitted. THz radiation, with its much higher frequency, could serve as the “carrier frequency” for ultrafast, beyond 5G networks, enabling faster data transfer for Internet of Things (IoT) connected devices, self-driving cars and countless other applications.

In medical imaging and industrial quality control, THz waves can penetrate many materials, making them useful for non-invasive scans. They are also safer than X-rays, providing a highly selective and precise imaging tool.

Going further afield, THz vision enables observational astronomy, allowing scientists to observe distant galaxies and exoplanets that cannot be seen by visible light.

THz radiation therefore offers huge potential. However, until recently, detecting it has been a significant challenge. THz waves are too fast for traditional semiconductor chips to handle and too slow for conventional optoelectronic devices.

The Viscous Electron Bolometer

The study by the NUS team showed that by harnessing the viscosity reduction effect, scientists can create innovative devices that can detect THz waves by sensing the changes in electrical resistance. Indeed, in the current study, Asst Prof Bandurin and his team has developed a new class of electronic device called a viscous electron bolometer.

Representing the first practical, real-world application of viscous electronics – a concept that was once thought to be purely theoretical – these bolometers are able to sense changes in resistance extremely accurately and quickly, operating, in principle, at the pico-second scale. In other words, trillionths of a second.

Understanding and exploiting the way electrons move together as a collective fluid opens the way for us to completely rethink the design of electronic devices. With this in mind, Asst Prof Bandurin and his team are actively working on optimising these viscous electron bolometers for practical applications.

As scientists uncover more secrets in the emerging world of quantum materials, it’s clear that traditional models of electron behaviour are no longer sufficient. By embracing this new understanding of viscous electronics, we could be on the verge of unlocking a new wave of technological possibilities.

Here’s a link to and a citation for the paper,

Viscous terahertz photoconductivity of hydrodynamic electrons in graphene by M. Kravtsov, A. L. Shilov, Y. Yang, T. Pryadilin, M. A. Kashchenko, O. Popova, M. Titova, D. Voropaev, Y. Wang, K. Shein, I. Gayduchenko, G. N. Goltsman, M. Lukianov, A. Kudriashov, T. Taniguchi, K. Watanabe, D. A. Svintsov, S. Adam, K. S. Novoselov, A. Principi & D. A. Bandurin. Nature Nanotechnology (2024)
DOI: https://doi.org/10.1038/s41565-024-01795-y Published: 07 October 2024

This paper is behind a paywall.

For anyone who noted the name ‘K.S. Novoselov’, it’s Konstantin Novoselov who along with Andre Geim received the 2011 Nobel prize in physics for their work with graphene.

A different type of ‘smart’ window with a new solar cell technology

I always like a ‘smart’ window story. Given my issues with summer (I don’t like the heat), anything which promises to help reduce the heat in my home at that time of year, has my vote. Unfortunately, solutions don’t seem to have made a serious impact on the marketplace. Nonetheless, there’s always hope and perhaps this development at Princeton University will be the one to break through the impasse. From a June 30, 2017 news item on ScienceDaily,

Smart windows equipped with controllable glazing can augment lighting, cooling and heating systems by varying their tint, saving up to 40 percent in an average building’s energy costs.

These smart windows require power for operation, so they are relatively complicated to install in existing buildings. But by applying a new solar cell technology, researchers at Princeton University have developed a different type of smart window: a self-powered version that promises to be inexpensive and easy to apply to existing windows. This system features solar cells that selectively absorb near-ultraviolet (near-UV) light, so the new windows are completely self-powered.

A June 30, 2017 Princeton University news release, which originated the news item, expands on the theme,

“Sunlight is a mixture of electromagnetic radiation made up of near-UV rays, visible light, and infrared energy, or heat,” said Yueh-Lin (Lynn) Loo, director of the Andlinger Center for Energy and the Environment, and the Theodora D. ’78 and William H. Walton III ’74 Professor in Engineering. “We wanted the smart window to dynamically control the amount of natural light and heat that can come inside, saving on energy cost and making the space more comfortable.”

The smart window controls the transmission of visible light and infrared heat into the building, while the new type of solar cell uses near-UV light to power the system.

“This new technology is actually smart management of the entire spectrum of sunlight,” said Loo, who is a professor of chemical and biological engineering. Loo is one of the authors of a paper, published June 30, that describes this technology, which was developed in her lab.

Because near-UV light is invisible to the human eye, the researchers set out to harness it for the electrical energy needed to activate the tinting technology.

“Using near-UV light to power these windows means that the solar cells can be transparent and occupy the same footprint of the window without competing for the same spectral range or imposing aesthetic and design constraints,” Loo added. “Typical solar cells made of silicon are black because they absorb all visible light and some infrared heat – so those would be unsuitable for this application.”

In the paper published in Nature Energy, the researchers described how they used organic semiconductors – contorted hexabenzocoronene (cHBC) derivatives – for constructing the solar cells. The researchers chose the material because its chemical structure could be modified to absorb a narrow range of wavelengths – in this case, near-UV light. To construct the solar cell, the semiconductor molecules are deposited as thin films on glass with the same production methods used by organic light-emitting diode manufacturers. When the solar cell is operational, sunlight excites the cHBC semiconductors to produce electricity.

At the same time, the researchers constructed a smart window consisting of electrochromic polymers, which control the tint, and can be operated solely using power produced by the solar cell. When near-UV light from the sun generates an electrical charge in the solar cell, the charge triggers a reaction in the electrochromic window, causing it to change from clear to dark blue. When darkened, the window can block more than 80 percent of light.

Nicholas Davy, a doctoral student in the chemical and biological engineering department and the paper’s lead author, said other researchers have already developed transparent solar cells, but those target infrared energy. However, infrared energy carries heat, so using it to generate electricity can conflict with a smart window’s function of controlling the flow of heat in or out of a building. Transparent near-UV solar cells, on the other hand, don’t generate as much power as the infrared version, but don’t impede the transmission of infrared radiation, so they complement the smart window’s task.

Davy said that the Princeton team’s aim is to create a flexible version of the solar-powered smart window system that can be applied to existing windows via lamination.

“Someone in their house or apartment could take these wireless smart window laminates – which could have a sticky backing that is peeled off – and install them on the interior of their windows,” said Davy. “Then you could control the sunlight passing into your home using an app on your phone, thereby instantly improving energy efficiency, comfort, and privacy.”

Joseph Berry, senior research scientist at the National Renewable Energy Laboratory, who studies solar cells but was not involved in the research, said the research project is interesting because the device scales well and targets a specific part of the solar spectrum.

“Integrating the solar cells into the smart windows makes them more attractive for retrofits and you don’t have to deal with wiring power,” said Berry. “And the voltage performance is quite good. The voltage they have been able to produce can drive electronic devices directly, which is technologically quite interesting.”

Davy and Loo have started a new company, called Andluca Technologies, based on the technology described in the paper, and are already exploring other applications for the transparent solar cells. They explained that the near-UV solar cell technology can also power internet-of-things sensors and other low-power consumer products.

“It does not generate enough power for a car, but it can provide auxiliary power for smaller devices, for example, a fan to cool the car while it’s parked in the hot sun,” Loo said.

Here’s a link to and a citation for the paper,

Pairing of near-ultraviolet solar cells with electrochromic windows for smart management of the solar spectrum by Nicholas C. Davy, Melda Sezen-Edmonds, Jia Gao, Xin Lin, Amy Liu, Nan Yao, Antoine Kahn, & Yueh-Lin Loo. Nature Energy 2, Article number: 17104 (2017 doi:10.1038/nenergy.2017.104 Published online: 30 June 2017

This paper is behind a paywall.

Here’s what a sample of the special glass looks like,

Graduate student Nicholas Davy holds a sample of the special window glass. (Photos by David Kelly Crow)