I’ve long been interested in electrochromic windows and this is the first I’ve heard of a problem with limited lifespans. Here’s more from an Oct. 1, 2015 news item on Nanowerk (Note: A link has been removed),
Electrochromic windows, so-called ‘smart windows’, share a well-known problem with rechargeable batteries – their limited lifespan. Researchers at Uppsala University [Sweden] have now worked out an entirely new way to rejuvenate smart windows which have started to show signs of age. The study, published in Nature Materials (“Eliminating degradation and uncovering ion-trapping dynamics in electrochromic WO3 thin films”), may open the way to other areas of application.
The electrochromic smart windows are controlled electrically. This kind of window is the result of research carried out at Uppsala University. Commercial production has recently been started by the company ChromoGenics AB.
The electrochromic smart window is made up of a series of thin layers on top of each other. The most important of these are two layers of tungsten oxide and nickel oxide, both about a third of a micrometer thick. They are separated by an electrolyte layer. The window’s opacity to visible light and solar energy varies when an electrical current flows between the oxide layers.
“The principle is the same as for an electric battery. Here the tungsten-oxide is the cathode and the nickel-oxide the anode. Opacity depends on how much the ‘battery’ is charged,” says Rui-Tao Wen, a doctoral student who carried out the study as part of his thesis.
The lifespan of both electric batteries and electrochromic smart windows is a well-known problem. They need to work after being charged and discharged many times if they are to be really profitable.
In the study, the researchers show that an electrochromic tungsten oxide layer which has been charged and discharged many times and has started to lose its capacity can be restored to its former high capacity. This is achieved by running a weak electric current through it while it is in light mode. This takes about an hour. In this way, the electric charge which has ‘fastened’ in the material is removed and the tungsten oxide layer is like new again.
“This is a new way to rejuvenate smart windows so that they last much longer. And the same principle might perhaps be used for electric batteries,” says Claes-Göran Granqvist, senior professor at the Ångström Laboratory, Uppsala University and one of the authors of the study.
Here’s a link to and a citation for the paper,
Eliminating degradation and uncovering ion-trapping dynamics in electrochromic WO3 thin films by Rui-Tao Wen, Claes G. Granqvist, & Gunnar A. Niklasson. Nature Materials 14, 996–1001 (2015) doi:10.1038/nmat4368 Published online 10 August 2015
This paper is behind a paywall.