Tag Archives: fique fiber

Nano-enabled fique fiber filters harmful dyes from water

A Sept. 30, 2013 news item on ScienceDaily highlights a new technique for cleaning water,

A cheap and simple process using natural fibers embedded with nanoparticles can almost completely rid water of harmful textile dyes in minutes, report Cornell University and Colombian researchers who worked with native Colombian plant fibers.

Dyes, such as indigo blue used to color blue jeans, threaten waterways near textile plants in South America, India and China. Such dyes are toxic, and they discolor the water, thereby reducing light to the water plants, which limits photosynthesis and lowers the oxygen in the water.

The study, published in the August issue of the journal Green Chemistry, describes a proof of principle, but the researchers are testing how effectively their method treats such endocrine-disrupting water pollutants as phenols, pesticides, antibiotics, hormones and phthalates.

The Sept. 30, 2013 Cornell University news release on EurekAlert, which originated the news item,, describes the research in more detail,

The research takes advantage of nano-sized cavities found in cellulose that co-author Juan Hinestroza, Cornell associate professor of fiber science, has previously used to produce nanoparticles inside cotton fibers.

The paper describes the method: Colombian fique plant fibers, commonly used to make coffee bags, are immersed in a solution of sodium permanganate and then treated with ultrasound; as a result, manganese oxide molecules grow in the tiny cellulose cavities. Manganese oxides in the fibers react with the dyes and break them down into non-colored forms.

In the study, the treated fibers removed 99 percent of the dye from water within minutes. Furthermore, the same fibers can be used repeatedly — after eight cycles, the fibers still removed between 97 percent and 99 percent of the dye.

“No expensive or particular starting materials are needed to synthesize the biocomposite,” said Combariza [Marianny Combariza, co-author and researcher at Colombia’s Universidad Industrial de Santander]. “The synthesis can be performed in a basic chemistry lab.”

“This is the first evidence of the effectiveness of this simple technique,” said Hinestroza. “It uses water-based chemistry, and it is easily transferable to real-world situations.”

The researchers are testing their process on other types of pollutants, other fibers and composite materials. “We are working now on developing a low-cost filtering unit prototype to treat polluted waters,” said Combariza. “We are not only focused on manganese oxides, we also work on a variety of materials based on transition metal oxides that show exceptional degradation activity.”

Here’s a link to and a citation for the paper,

Biocomposite of nanostructured MnO2 and fique fibers for efficient dye degradation by Martha L. Chacón-Patiño,a   Cristian Blanco-Tirado, Juan P. Hinestroza, and  Marianny Y. Combariza. Green Chem., 2013,15, 2920-2928 DOI: 10.1039/C3GC40911B First published online 19 Aug 2013

This paper is behind a paywall.

For anyone not familiar with the fique plant,

The native Columbian fique plant, Frucraea Andina. (Credit: Vasyl Kacapyr)

The native Columbian fique plant, Frucraea Andina. (Credit: Vasyl Kacapyr)

I have mentioned Juan Hinestroza and the research he and his students perform on nano-enabled textiles a number of times including this May 15, 2012 posting on anti-malaria textiles.