Tag Archives: Haidan Wen

Stress makes quantum dots ‘breathe’

A March 19, 2015 news item on ScienceDaily describes some new research on quantum dots,

Researchers at the Department of Energy’s SLAC National Accelerator Laboratory watched nanoscale semiconductor crystals expand and shrink in response to powerful pulses of laser light. This ultrafast “breathing” provides new insight about how such tiny structures change shape as they start to melt — information that can help guide researchers in tailoring their use for a range of applications.

In the experiment using SLAC’s Linac Coherent Light Source (LCLS) X-ray laser, a DOE Office of Science User Facility, researchers first exposed the nanocrystals to a burst of laser light, followed closely by an ultrabright X-ray pulse that recorded the resulting structural changes in atomic-scale detail at the onset of melting.

“This is the first time we could measure the details of how these ultrasmall materials react when strained to their limits,” said Aaron Lindenberg, an assistant professor at SLAC and Stanford who led the experiment. The results were published March 12 [2015] in Nature Communications.

A March 18, 2015 SLAC news release, which originated the news item, provides a general description of quantum dots,

The crystals studied at SLAC are known as “quantum dots” because they display unique traits at the nanoscale that defy the classical physics governing their properties at larger scales. The crystals can be tuned by changing their size and shape to emit specific colors of light, for example.

So scientists have worked to incorporate them in solar panels to make them more efficient and in computer displays to improve resolution while consuming less battery power. These materials have also been studied for potential use in batteries and fuel cells and for targeted drug delivery.

Scientists have also discovered that these and other nanomaterials, which may contain just tens or hundreds of atoms, can be far more damage-resistant than larger bits of the same materials because they exhibit a more perfect crystal structure at the tiniest scales. This property could prove useful in battery components, for example, as smaller particles may be able to withstand more charging cycles than larger ones before degrading.

The news release then goes on to describe the latest research showing the dots ‘breathe’ (Note: A link has been removed),

In the LCLS experiment, researchers studied spheres and nanowires made of cadmium sulfide and cadmium selenide that were just 3 to 5 nanometers, or billionths of a meter, across. The nanowires were up to 25 nanometers long. By comparison, amino acids – the building blocks of proteins – are about 1 nanometer in length, and individual atoms are measured in tenths of nanometers.

By examining the nanocrystals from many different angles with X-ray pulses, researchers reconstructed how they change shape when hit with an optical laser pulse. They were surprised to see the spheres and nanowires expand in width by about 1 percent and then quickly contract within femtoseconds, or quadrillionths of a second. They also found that the nanowires don’t expand in length, and showed that the way the crystals respond to strain was coupled to how their structure melts.

In an earlier, separate study, another team of researchers had used LCLS to explore the response of larger gold particles on longer timescales.

“In the future, we want to extend these experiments to more complex and technologically relevant nanostructures, and also to enable X-ray exploration of nanoscale devices while they are operating,” Lindenberg said. “Knowing how materials change under strain can be used together with simulations to design new materials with novel properties.”

Participating researchers were from SLAC, Stanford and two of their joint institutes, the Stanford Institute for Materials and Energy Sciences (SIMES) and Stanford PULSE Institute; University of California, Berkeley; University of Duisburg-Essen in Germany; and Argonne National Laboratory. The work was supported by the DOE Office of Science and the German Research Council.

Here’s a link to and a citation for the paper,

Visualization of nanocrystal breathing modes at extreme strains by Erzsi Szilagyi, Joshua S. Wittenberg, Timothy A. Miller, Katie Lutker, Florian Quirin, Henrik Lemke, Diling Zhu, Matthieu Chollet, Joseph Robinson, Haidan Wen, Klaus Sokolowski-Tinten, & Aaron M. Lindenberg. Nature Communications 6, Article number: 6577 doi:10.1038/ncomms7577 Published 12 March 2015

This paper is behind a paywall but there is a free preview available through ReadCube Access.

Heat, evolution, and the shape of gold nanorods

A Feb. 23, 2015 news item on Azonano features gold nanorods and their shapeshifting ways when releasing heat,

Researchers at the U.S. Department of Energy’s Argonne National Laboratory have revealed previously unobserved behaviors that show how details of the transfer of heat at the nanoscale cause nanoparticles to change shape in ensembles.

The new findings depict three distinct stages of evolution in groups of gold nanorods, from the initial rod shape to the intermediate shape to a sphere-shaped nanoparticle. The research suggests new rules for the behavior of nanorod ensembles, providing insights into how to increase heat transfer efficiency in a nanoscale system.

A Feb. 18, 2015 Argonne National Laboratory news release by Justin H. S. Breaux, which originated the news item, provides more details about the work,

At the nanoscale, individual gold nanorods have unique electronic, thermal and optical properties. Understanding these properties and managing how collections of these elongated nanoparticles absorb and release this energy as heat will drive new research towards next-generation technologies such as water purification systems, battery materials and cancer research.

A good deal is known about how single nanorods behave—but little is known about how nanorods behave in ensembles of millions. Understanding how the individual behavior of each nanorod, including how its orientation and rate of transition differ from those around it, impacts the collective kinetics of the ensemble and is critical to using nanorods in future technologies.

“We started with a lot of questions,” said Argonne physicist Yuelin Li, “like ‘How much power can the particles sustain before losing functionality? How do individual changes at the nanoscale affect the overall functionality? How much heat is released to the surrounding area?’ Each nanorod is continuously undergoing a change in shape when heated beyond melting temperature, which means a change in the surface area and thus a change in its thermal and hydrodynamic properties.”

The researchers used a laser to heat the nanoparticles and X-rays to analyze their changing shapes. Generally, nanorods transition into nanospheres more quickly when supplied with a higher intensity of laser power. In this case, completely different ensemble behaviors were observed when this intensity increased incrementally. The intensity of the heat applied changes not only the nanoparticles’ shape at various rates but also affects their ability to efficiently absorb and release heat.

“For us, the key was to understand just how efficient the nanorods were at transferring light into heat in many different scenarios,” said nanoscientist Subramanian Sankaranarayanan of Argonne’s Center for Nanoscale Materials. “Then we had to determine the physics behind how heat was transferred and all the different ways these nanorods could transition into nanospheres.”

To observe how the rod makes this transition, researchers first shine a laser pulse at the nanorod suspended in a water solution at Argonne’s Advanced Photon Source. The laser lasts for less than a hundred femtoseconds, nearly one trillion times faster than a blink of the eye. What follows is a series of focused and rapid X-ray bursts using a technique called small angle X-ray scattering. The resulting data is used to determine the average shape of the particle as it changes over time.

In this way, scientists can reconstruct the minute changes occurring in the shape of the nanorod. However, to understand the physics underlying this phenomenon, the researchers needed to look deeper at how individual atoms vibrate and move during the transition. For this, they turned to the field of molecular dynamics using the supercomputing power of the 10-petaflop Mira supercomputer at the Argonne Leadership Computing Facility.

Mira used mathematical equations to pinpoint the individual movements of nearly two million of the nanorods’ atoms in the water. Using factors such as the shape, temperature and rate of change, the researchers built simulations of the nanorod in many different scenarios to see how the structure changes over time.

“In the end,” said Sankaranarayanan, “we discovered the heat transfer rates for shorter but wider nanospheres are lower than for their rod-shaped predecessors. This decrease in heat transfer efficiency at the nanoscale plays a key role in accelerating the transition from rod to sphere when heated beyond the melting temperature.”

Here’s a link to and a citation for the paper,

Femtosecond Laser Pulse Driven Melting in Gold Nanorod Aqueous Colloidal Suspension: Identification of a Transition from Stretched to Exponential Kinetics by Yuelin Li, Zhang Jiang, Xiao-Min Lin, Haidan Wen, Donald A. Walko, Sanket A. Deshmukh, Ram Subbaraman, Subramanian K. R. S. Sankaranarayanan, Stephen K. Gray, & Phay Ho. Scientific Reports 5, Article number: 8146 doi:10.1038/srep08146 Published 30 January 2015

This article is open access.

Wacky oxide. biological synchronicity, and human brainlike computing

Research out of Pennsylvania State University (Penn State, US) has uncovered another approach  to creating artificial brains (more about the other approaches later in this post), from a May 14, 2014 news item on Science Daily,

Current computing is based on binary logic — zeroes and ones — also called Boolean computing. A new type of computing architecture that stores information in the frequencies and phases of periodic signals could work more like the human brain to do computing using a fraction of the energy of today’s computers.

A May 14, 2014 Pennsylvania State University news release, which originated the news item, describes the research in more detail,

Vanadium dioxide (VO2) is called a “wacky oxide” because it transitions from a conducting metal to an insulating semiconductor and vice versa with the addition of a small amount of heat or electrical current. A device created by electrical engineers at Penn State uses a thin film of VO2 on a titanium dioxide substrate to create an oscillating switch. Using a standard electrical engineering trick, Nikhil Shukla, a Ph.D. student in the group of Professor Suman Datta and co-advised by Professor Roman Engel-Herbert at Penn State, added a series resistor to the oxide device to stabilize their oscillations over billions of cycles. When Shukla added a second similar oscillating system, he discovered that over time the two devices would begin to oscillate in unison. This coupled system could provide the basis for non-Boolean computing. The results are reported in the May 14 [2014] online issue of Nature Publishing Group’s Scientific Reports.

“It’s called a small-world network,” explained Shukla. “You see it in lots of biological systems, such as certain species of fireflies. The males will flash randomly, but then for some unknown reason the flashes synchronize over time.” The brain is also a small-world network of closely clustered nodes that evolved for more efficient information processing.

“Biological synchronization is everywhere,” added Datta, professor of electrical engineering at Penn State and formerly a Principal Engineer in the Advanced Transistor and Nanotechnology Group at Intel Corporation. “We wanted to use it for a different kind of computing called associative processing, which is an analog rather than digital way to compute.” An array of oscillators can store patterns, for instance, the color of someone’s hair, their height and skin texture. If a second area of oscillators has the same pattern, they will begin to synchronize, and the degree of match can be read out. “They are doing this sort of thing already digitally, but it consumes tons of energy and lots of transistors,” Datta said. Datta is collaborating with co-author and Professor of Computer Science and Engineering, Vijay Narayanan, in exploring the use of these coupled oscillations in solving visual recognition problems more efficiently than existing embedded vision processors as part of a National Science Foundation Expedition in Computing program.

Shukla and Datta called on the expertise of Cornell University materials scientist Darrell Schlom to make the VO2 thin film, which has extremely high quality similar to single crystal silicon. Georgia Tech computer engineer Arijit Raychowdhury and graduate student Abhinav Parihar mathematically simulated the nonlinear dynamics of coupled phase transitions in the VO2 devices. Parihar created a short video* simulation of the transitions, which occur at a rate close to a million times per second, to show the way the oscillations synchronize. Penn State professor of materials science and engineering Venkatraman Gopalan used the Advanced Photon Source at Argonne National laboratory to visually characterize the structural changes occurring in the oxide thin film in the midst of the oscillations.

Datta believes it will take seven to ten years to scale up from their current network of two-three coupled oscillators to the 100 million or so closely packed oscillators required to make a neuromorphic computer chip. One of the benefits of the novel device is that it will use only about one percent of the energy of digital computing, allowing for new ways to design computers. Much work remains to determine if VO2 can be integrated into current silicon wafer technology. “It’s a fundamental building block for a different computing paradigm that is analog rather than digital,” Shukla concluded.

There are two papers being published about this work,

Synchronizing a single-electron shuttle to an external drive by Michael J Moeckel, Darren R Southworth, Eva M Weig, and Florian Marquardt. New J. Phys. 16 043009 doi:10.1088/1367-2630/16/4/043009

Synchronized charge oscillations in correlated electron systems by Nikhil Shukla, Abhinav Parihar, Eugene Freeman, Hanjong Paik, Greg Stone, Vijaykrishnan Narayanan, Haidan Wen, Zhonghou Cai, Venkatraman Gopalan, Roman Engel-Herbert, Darrell G. Schlom, Arijit Raychowdhury & Suman Datta. Scientific Reports 4, Article number: 4964 doi:10.1038/srep04964 Published 14 May 2014

Both articles are open access.

Finally, the researchers have provided a video animation illustrating their vanadium dioxide switches in action,

As noted earlier, there are other approaches to creating an artificial brain, i.e., neuromorphic engineering. My April 7, 2014 posting is the most recent synopsis posted here; it includes excerpts from a Nanowerk Spotlight article overview along with a mention of the ‘brain jelly’ approach and a discussion of my somewhat extensive coverage of memristors and a mention of work on nanoionic devices. There is also a published roadmap to neuromorphic engineering featuring both analog and digital devices, mentioned in my April 18, 2014 posting.