Tag Archives: Hewlett Packard Enterprise (HPE)

Device with brainlike plasticity

A September 1, 2021 news item on ScienceDaily announces a new type of memristor from Texas A&M University (Texas A&M or TAMU) and the National University of Singapore (NUS)

In a discovery published in the journal Nature, an international team of researchers has described a novel molecular device with exceptional computing prowess.

Reminiscent of the plasticity of connections in the human brain, the device can be reconfigured on the fly for different computational tasks by simply changing applied voltages. Furthermore, like nerve cells can store memories, the same device can also retain information for future retrieval and processing.

Two of the universities involved in the research have issued news/press releases. I’m going to start with the September 1, 2021 Texas A&M University news release (also on EurekAlert), which originated the news item on ScienceDaily,

“The brain has the remarkable ability to change its wiring around by making and breaking connections between nerve cells. Achieving something comparable in a physical system has been extremely challenging,” said Dr. R. Stanley Williams [emphasis mine], professor in the Department of Electrical and Computer Engineering at Texas A&M University. “We have now created a molecular device with dramatic reconfigurability, which is achieved not by changing physical connections like in the brain, but by reprogramming its logic.”

Dr. T. Venkatesan, director of the Center for Quantum Research and Technology (CQRT) at the University of Oklahoma, Scientific Affiliate at National Institute of Standards and Technology, Gaithersburg, and adjunct professor of electrical and computer engineering at the National University of Singapore, added that their molecular device might in the future help design next-generation processing chips with enhanced computational power and speed, but consuming significantly reduced energy.

Whether it is the familiar laptop or a sophisticated supercomputer, digital technologies face a common nemesis, the von Neumann bottleneck. This delay in computational processing is a consequence of current computer architectures, wherein the memory, containing data and programs, is physically separated from the processor. As a result, computers spend a significant amount of time shuttling information between the two systems, causing the bottleneck. Also, despite extremely fast processor speeds, these units can be idling for extended amounts of time during periods of information exchange.

As an alternative to conventional electronic parts used for designing memory units and processors, devices called memristors offer a way to circumvent the von Neumann bottleneck. Memristors, such as those made of niobium dioxide and vanadium dioxide, transition from being an insulator to a conductor at a set temperature. This property gives these types of memristors the ability to perform computations and store data.

However, despite their many advantages, these metal oxide memristors are made of rare-earth elements and can operate only in restrictive temperature regimes. Hence, there has been an ongoing search for promising organic molecules that can perform a comparable memristive function, said Williams.

Dr. Sreebrata Goswami, a professor at the Indian Association for the Cultivation of Science, designed the material used in this work. The compound has a central metal atom (iron) bound to three phenyl azo pyridine organic molecules called ligands.

“This behaves like an electron sponge that can absorb as many as six electrons reversibly, resulting in seven different redox states,” said Sreebrata. “The interconnectivity between these states is the key behind the reconfigurability shown in this work.”

Dr. Sreetosh Goswami, a researcher at the National University of Singapore, devised this project by creating a tiny electrical circuit consisting of a 40-nanometer layer of molecular film sandwiched between a layer of gold on top and gold-infused nanodisc and indium tin oxide at the bottom.

On applying a negative voltage on the device, Sreetosh witnessed a current-voltage profile that was nothing like anyone had seen before. Unlike metal-oxide memristors that can switch from metal to insulator at only one fixed voltage, the organic molecular devices could switch back and forth from insulator to conductor at several discrete sequential voltages.

“So, if you think of the device as an on-off switch, as we were sweeping the voltage more negative, the device first switched from on to off, then off to on, then on to off and then back to on. I’ll say that we were just blown out of our seat,” said Venkatesan. “We had to convince ourselves that what we were seeing was real.”

Sreetosh and Sreebrata investigated the molecular mechanisms underlying the curious switching behavior using an imaging technique called Raman spectroscopy. In particular, they looked for spectral signatures in the vibrational motion of the organic molecule that could explain the multiple transitions. Their investigation revealed that sweeping the voltage negative triggered the ligands on the molecule to undergo a series of reduction, or electron-gaining, events that caused the molecule to transition between off state and on states.

Next, to describe the extremely complex current-voltage profile of the molecular device mathematically, Williams deviated from the conventional approach of basic physics-based equations. Instead, he described the behavior of the molecules using a decision tree algorithm with “if-then-else” statements, a commonplace line of code in several computer programs, particularly digital games.

“Video games have a structure where you have a character that does something, and then something occurs as a result. And so, if you write that out in a computer algorithm, they are if-then-else statements,” said Williams. “Here, the molecule is switching from on to off as a consequence of applied voltage, and that’s when I had the eureka moment to use decision trees to describe these devices, and it worked very well.” 

But the researchers went a step further to exploit these molecular devices to run programs for different real-world computational tasks. Sreetosh showed experimentally that their devices could perform fairly complex computations in a single time step and then be reprogrammed to perform another task in the next instant.

“It was quite extraordinary; our device was doing something like what the brain does, but in a very different way,” said Sreetosh. “When you’re learning something new or when you’re deciding, the brain can actually reconfigure and change physical wiring around. Similarly, we can logically reprogram or reconfigure our devices by giving them a different voltage pulse then they’ve seen before.” 

Venkatesan noted that it would take thousands of transistors to perform the same computational functions as one of their molecular devices with its different decision trees. Hence, he said their technology might first be used in handheld devices, like cell phones and sensors, and other applications where power is limited.

Other contributors to the research include Dr. Abhijeet Patra and Dr. Ariando from the National University of Singapore; Dr. Rajib Pramanick and Dr. Santi Prasad Rath from the Indian Association for the Cultivation of Science; Dr. Martin Foltin from Hewlett Packard Enterprise, Colorado; and Dr. Damien Thompson from the University of Limerick, Ireland.

Venkatesan said that this research is indicative of the future discoveries from this collaborative team, which will include the center of nanoscience and engineering at the Indian Institute of Science and the Microsystems and Nanotechnology Division at the NIST.

I’ve highlighted R. Stanley Williams because he and his team at HP [Hewlett Packard] Labs helped to kick off current memristor research in 2008 with the publication of two papers as per my April 5, 2010 posting,

In 2008, two memristor papers were published in Nature and Nature Nanotechnology, respectively. In the first (Nature, May 2008 [article still behind a paywall], a team at HP Labs claimed they had proved the existence of memristors (a fourth member of electrical engineering’s ‘Holy Trinity of the capacitor, resistor, and inductor’). In the second paper (Nature Nanotechnology, July 2008 [article still behind a paywall]) the team reported that they had achieved engineering control.

The novel memory device is based on a molecular system that can transition between on and off states at several discrete sequential voltages Courtesy: National University of Singapore

There is more technical detail in the September 2, 2022 NUS press release (also on EurekAlert),

Many electronic devices today are dependent on semiconductor logic circuits based on switches hard-wired to perform predefined logic functions. Physicists from the National University of Singapore (NUS), together with an international team of researchers, have developed a novel molecular memristor, or an electronic memory device, that has exceptional memory reconfigurability. 

Unlike hard-wired standard circuits, the molecular device can be reconfigured using voltage to embed different computational tasks. The energy-efficient new technology, which is capable of enhanced computational power and speed, can potentially be used in edge computing, as well as handheld devices and applications with limited power resource.

“This work is a significant breakthrough in our quest to design low-energy computing. The idea of using multiple switching in a single element draws inspiration from how the brain works and fundamentally reimagines the design strategy of a logic circuit,” said Associate Professor Ariando from the NUS Department of Physics who led the research.

The research was first published in the journal Nature on 1 September 2021, and carried out in collaboration with the Indian Association for the Cultivation of Science, Hewlett Packard Enterprise, the University of Limerick, the University of Oklahoma, and Texas A&M University.

Brain-inspired technology

“This new discovery can contribute to developments in edge computing as a sophisticated in-memory computing approach to overcome the von Neumann bottleneck, a delay in computational processing seen in many digital technologies due to the physical separation of memory storage from a device’s processor,” said Assoc Prof Ariando. The new molecular device also has the potential to contribute to designing next generation processing chips with enhanced computational power and speed.

“Similar to the flexibility and adaptability of connections in the human brain, our memory device can be reconfigured on the fly for different computational tasks by simply changing applied voltages. Furthermore, like how nerve cells can store memories, the same device can also retain information for future retrieval and processing,” said first author Dr Sreetosh Goswami, Research Fellow from the Department of Physics at NUS.

Research team member Dr Sreebrata Goswami, who was a Senior Research Scientist at NUS and previously Professor at the Indian Association for the Cultivation of Science, conceptualised and designed a molecular system belonging to the chemical family of phenyl azo pyridines that have a central metal atom bound to organic molecules called ligands. “These molecules are like electron sponges that can offer as many as six electron transfers resulting in five different molecular states. The interconnectivity between these states is the key behind the device’s reconfigurability,” explained Dr Sreebrata Goswami.

Dr Sreetosh Goswami created a tiny electrical circuit consisting a 40-nanometer layer of molecular film sandwiched between a top layer of gold, and a bottom layer of gold-infused nanodisc and indium tin oxide. He observed an unprecedented current-voltage profile upon applying a negative voltage to the device. Unlike conventional metal-oxide memristors that are switched on and off at only one fixed voltage, these organic molecular devices could switch between on-off states at several discrete sequential voltages.

Using an imaging technique called Raman spectroscopy, spectral signatures in the vibrational motion of the organic molecule were observed to explain the multiple transitions. Dr Sreebrata Goswami explained, “Sweeping the negative voltage triggered the ligands on the molecule to undergo a series of reduction, or electron-gaining which caused the molecule to transition between off and on states.”

The researchers described the behavior of the molecules using a decision tree algorithm with “if-then-else” statements, which is used in the coding of several computer programs, particularly digital games, as compared to the conventional approach of using basic physics-based equations.

New possibilities for energy-efficient devices

Building on their research, the team used the molecular memory devices to run programs for different real-world computational tasks. As a proof of concept, the team demonstrated that their technology could perform complex computations in a single step, and could be reprogrammed to perform another task in the next instant. An individual molecular memory device could perform the same computational functions as thousands of transistors, making the technology a more powerful and energy-efficient memory option.

“The technology might first be used in handheld devices, like cell phones and sensors, and other applications where power is limited,” added Assoc Prof Ariando.

The team in the midst of building new electronic devices incorporating their innovation, and working with collaborators to conduct simulation and benchmarking relating to existing technologies.

Other contributors to the research paper include Abhijeet Patra and Santi Prasad Rath from NUS, Rajib Pramanick from the Indian Association for the Cultivation of Science, Martin Foltin from Hewlett Packard Enterprise, Damien Thompson from the University of Limerick, T. Venkatesan from the University of Oklahoma, and R. Stanley Williams from Texas A&M University.

Here’s a link to and a citation for the paper,

Decision trees within a molecular memristor by Sreetosh Goswami, Rajib Pramanick, Abhijeet Patra, Santi Prasad Rath, Martin Foltin, A. Ariando, Damien Thompson, T. Venkatesan, Sreebrata Goswami & R. Stanley Williams. Nature volume 597, pages 51–56 (2021) DOI: https://doi.org/10.1038/s41586-021-03748-0 Published 01 September 2021 Issue Date 02 September 2021

This paper is behind a paywall.

X-rays reveal memristor workings

A June 14, 2016 news item on ScienceDaily focuses on memristors. (It’s been about two months since my last memristor posting on April 22, 2016 regarding electronic synapses and neural networks). This piece announces new insight into how memristors function at the atomic scale,

In experiments at two Department of Energy national labs — SLAC National Accelerator Laboratory and Lawrence Berkeley National Laboratory — scientists at Hewlett Packard Enterprise (HPE) [also referred to as HP Labs or Hewlett Packard Laboratories] have experimentally confirmed critical aspects of how a new type of microelectronic device, the memristor, works at an atomic scale.

This result is an important step in designing these solid-state devices for use in future computer memories that operate much faster, last longer and use less energy than today’s flash memory. …

“We need information like this to be able to design memristors that will succeed commercially,” said Suhas Kumar, an HPE scientist and first author on the group’s technical paper.

A June 13, 2016 SLAC news release, which originated the news item, offers a brief history according to HPE and provides details about the latest work,

The memristor was proposed theoretically [by Dr. Leon Chua] in 1971 as the fourth basic electrical device element alongside the resistor, capacitor and inductor. At its heart is a tiny piece of a transition metal oxide sandwiched between two electrodes. Applying a positive or negative voltage pulse dramatically increases or decreases the memristor’s electrical resistance. This behavior makes it suitable for use as a “non-volatile” computer memory that, like flash memory, can retain its state without being refreshed with additional power.

Over the past decade, an HPE group led by senior fellow R. Stanley Williams has explored memristor designs, materials and behavior in detail. Since 2009 they have used intense synchrotron X-rays to reveal the movements of atoms in memristors during switching. Despite advances in understanding the nature of this switching, critical details that would be important in designing commercially successful circuits  remained controversial. For example, the forces that move the atoms, resulting in dramatic resistance changes during switching, remain under debate.

In recent years, the group examined memristors made with oxides of titanium, tantalum and vanadium. Initial experiments revealed that switching in the tantalum oxide devices could be controlled most easily, so it was chosen for further exploration at two DOE Office of Science User Facilities – SLAC’s Stanford Synchrotron Radiation Lightsource (SSRL) and Berkeley Lab’s Advanced Light Source (ALS).

At ALS, the HPE researchers mapped the positions of oxygen atoms before and after switching. For this, they used a scanning transmission X-ray microscope and an apparatus they built to precisely control the position of their sample and the timing and intensity of the 500-electronvolt ALS X-rays, which were tuned to see oxygen.

The experiments revealed that even weak voltage pulses create a thin conductive path through the memristor. During the pulse the path heats up, which creates a force that pushes oxygen atoms away from the path, making it even more conductive. Reversing the voltage pulse resets the memristor by sucking some of oxygen atoms back into the conducting path, thereby increasing the device’s resistance. The memristor’s resistance changes between 10-fold and 1 million-fold, depending on operating parameters like the voltage-pulse amplitude. This resistance change is dramatic enough to exploit commercially.

To be sure of their conclusion, the researchers also needed to understand if the tantalum atoms were moving along with the oxygen during switching. Imaging tantalum required higher-energy, 10,000-electronvolt X-rays, which they obtained at SSRL’s Beam Line 6-2. In a single session there, they determined that the tantalum remained stationary.

“That sealed the deal, convincing us that our hypothesis was correct,” said HPE scientist Catherine Graves, who had worked at SSRL as a Stanford graduate student. She added that discussions with SLAC experts were critical in guiding the HPE team toward the X-ray techniques that would allow them to see the tantalum accurately.

Kumar said the most promising aspect of the tantalum oxide results was that the scientists saw no degradation in switching over more than a billion voltage pulses of a magnitude suitable for commercial use. He added that this knowledge helped his group build memristors that lasted nearly a billion switching cycles, about a thousand-fold improvement.

“This is much longer endurance than is possible with today’s flash memory devices,” Kumar said. “In addition, we also used much higher voltage pulses to accelerate and observe memristor failures, which is also important in understanding how these devices work. Failures occurred when oxygen atoms were forced so far away that they did not return to their initial positions.”

Beyond memory chips, Kumar says memristors’ rapid switching speed and small size could make them suitable for use in logic circuits. Additional memristor characteristics may also be beneficial in the emerging class of brain-inspired neuromorphic computing circuits.

“Transistors are big and bulky compared to memristors,” he said. “Memristors are also much better suited for creating the neuron-like voltage spikes that characterize neuromorphic circuits.”

The researchers have provided an animation illustrating how memristors can fail,

This animation shows how millions of high-voltage switching cycles can cause memristors to fail. The high-voltage switching eventually creates regions that are permanently rich (blue pits) or deficient (red peaks) in oxygen and cannot be switched back. Switching at lower voltages that would be suitable for commercial devices did not show this performance degradation. These observations allowed the researchers to develop materials processing and operating conditions that improved the memristors’ endurance by nearly a thousand times. (Suhas Kumar) Courtesy: SLAC

This animation shows how millions of high-voltage switching cycles can cause memristors to fail. The high-voltage switching eventually creates regions that are permanently rich (blue pits) or deficient (red peaks) in oxygen and cannot be switched back. Switching at lower voltages that would be suitable for commercial devices did not show this performance degradation. These observations allowed the researchers to develop materials processing and operating conditions that improved the memristors’ endurance by nearly a thousand times. (Suhas Kumar) Courtesy: SLAC

Here’s a link to and a citation for the paper,

Direct Observation of Localized Radial Oxygen Migration in Functioning Tantalum Oxide Memristors by Suhas Kumar, Catherine E. Graves, John Paul Strachan, Emmanuelle Merced Grafals, Arthur L. David Kilcoyne3, Tolek Tyliszczak, Johanna Nelson Weker, Yoshio Nishi, and R. Stanley Williams. Advanced Materials, First published: 2 February 2016; Print: Volume 28, Issue 14 April 13, 2016 Pages 2772–2776 DOI: 10.1002/adma.201505435

This paper is behind a paywall.

Some of the ‘memristor story’ is contested and you can find a brief overview of the discussion in this Wikipedia memristor entry in the section on ‘definition and criticism’. There is also a history of the memristor which dates back to the 19th century featured in my May 22, 2012 posting.