Tag Archives: Kevin Golovin

Nanoscale fletching for a safer alternative non-stick coating

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Before the ‘fletching’ explanation (in the news release), there’s the announcement in a July 27, 2025 news item on ScienceDaily,

A new material developed by researchers from University of Toronto Engineering could offer a safer alternative to the non-stick chemicals commonly used in cookware and other applications.

The new substance repels both water and grease about as well as standard non-stick coatings — but it contains much lower amounts of per- and polyfluoroalkyl substances (PFAS), a family of chemicals that have raised environmental and health concerns.

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A July 23, 2025 University of Toronto (U of T) news release (also on EurekAlert but published July 25, 2025) by Tyler Irving, which originated the news item goes on to describe nanoscale fletching, Note: Links have been removed,

“The research community has been trying to develop safer alternatives to PFAS for a long time,” says Professor Kevin Golovin, who heads the Durable Repellent Engineered Advanced Materials (DREAM) Laboratory at U of T Engineering. 

“The challenge is that while it’s easy to create a substance that will repel water, it’s hard to make one that will also repel oil and grease to the same degree. Scientists had hit an upper limit to the performance of these alternative materials.” 

Since its invention in the late 1930s, Teflon — also known as polytetrafluoroethylene or PTFE — has become famous for its ability to repel water, oil and grease alike. Teflon is part of a larger family of substances known as per- and polyfluoroalkyl substances (PFAS). 

PFAS molecules are made of chains of carbon atoms, each of which is bonded to several fluorine atoms. The inertness of carbon-fluorine bonds is responsible for the non-stick properties of PFAS. 

However, this chemical inertness also causes PFAS to resist the normal processes that would break down other organic molecules over time. For this reason, they are sometimes called ‘forever chemicals.’ 

In addition to their persistence, PFAS are known to accumulate in biological tissues, and their concentrations can become amplified as they travel up the food chain. 

Various studies have linked exposure to high levels of PFAS to certain types of cancer, birth defects and other health problems, with the longer chain PFAS generally considered more harmful than the shorter ones. 

Despite the risks, the lack of alternatives means that PFAS remain ubiquitous in consumer products: they are widely used not only in cookware, but also in rain-resistant fabrics, food packaging and even in makeup. 

“The material we’ve been working with as an alternative to PFAS is called polydimethylsiloxane or PDMS,” says Golovin. 

“PDMS is often sold under the name silicone, and depending on how it’s formulated, it can be very biocompatible — in fact it’s often used in devices that are meant to be implanted into the body. But until now, we couldn’t get PDMS to perform quite as well as PFAS.” 

To overcome this problem, PhD student Samuel Au developed a new chemistry technique that the team is calling nanoscale fletching [emphasis mine]. The technique is described in a paper published in Nature Communications. 

“Unlike typical silicone, we bond short chains of PDMS to a base material — you can think of them like bristles on a brush,” says Au. 

“To improve their ability to repel oil, we have now added in the shortest possible PFAS molecule, consisting of a single carbon with three fluorines on it. We were able to bond about seven of those to the end of each PDMS bristle. 

“If you were able to shrink down to the nanometre scale, it would look a bit like the feathers that you see around the back end of an arrow, where it notches to the bow. That’s called fletching, so this is nanoscale fletching.” 

Au and the team coated their new material on a piece of fabric, then placed drops of various oils on it to see how well it could repel them. On a scale developed by the American Association of Textile Chemists and Colorists, the new coating achieved a grade of 6, placing it on par with many standard PFAS-based coatings. 

“While we did use a PFAS molecule in this process, it is the shortest possible one and therefore does not bioaccumulate,” says Golovin. 

“What we’ve seen in the literature, and even in the regulations, is that it’s the longest-chain PFAS that are getting banned first, with the shorter ones considered much less harmful. Our hybrid material provides the same performance as what had been achieved with long-chain PFAS, but with greatly reduced risk.” 

Golovin says that the team is open to collaborating with manufacturers of non-stick coatings who might wish to scale up and commercialize the process. In the meantime, they will continue working on even more alternatives. 

“The holy grail of this field would be a substance that outperforms Teflon, but with no PFAS at all,” says Golovin. 

“We’re not quite there yet, but this is an important step in the right direction.”

Here’s a link to and a citation for the paper,

Nanoscale fletching of liquid-like polydimethylsiloxane with single perfluorocarbons enables sustainable oil-repellency by Samuel Au, Jeremy R. Gauthier, Boran Kumral, Tobin Filleter, Scott Mabury & Kevin Golovin. Nature Communications volume 16, Article number: 6789 (2025) DOI: https://doi.org/10.1038/s41467-025-62119-9 Published: 23 July 2025

This paper is open access.

Reducing microplastic pollution from when you wash your clothes with a new coating

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A January 26, 2023 University of Toronto news release (also found on EurekAlert and here but published on January 30, 2023) by Safa Jinje announced a coating the minimizes the amount of microplastic entering the water when your clothes are washed, Note: Links have been removed,

A team of University of Toronto Engineering researchers, led by Professor Kevin Golovin, have designed a solution to reduce the amount of microplastic fibres that are shed when clothes made of synthetic fabrics are washed.   

In a world swamped by fast fashion — an industry that produces a high-volume of cheaply made clothing at an immense cost to the environment — more than two-thirds of clothes are now made of synthetic fabrics. 

When clothes made from synthetic fabrics, such as nylon, polyester, acrylic and rayon, are washed in washing machines, the friction caused by cleaning cycles produces tiny tears in the fabric. These tears in turn cause microplastic fibres measuring less than 500 micrometres in length to break off and make their way down laundry drains to enter waterways.   

Once microplastics end up in oceans and freshwater lakes and rivers, the particles are difficult to remove and will take decades or more to fully break down. The accumulation of this debris in bodies of water can threaten marine life. It can also become part of the human food chain through its presence in food and tap water, with effects on human health that are not yet clear.  

Governments around the world have been looking for ways to minimize the pollution that comes from washing synthetic fabrics. One example is washing machine filters, which have emerged as a leading fix to stop microplastic fibres from entering waterways. In Ontario, legislative members have introduced a bill that would require filters in new washing machines in the province.  

“And yet, when we look at what governments around the world are doing, there is no trend towards preventing the creation of microplastic fibres in the first place,” says Golovin.  

“Our research is pushing in a different direction, where we actually solve the problem rather than putting a Band-Aid on the issue.”   

Golovin and his team have created a two-layer coating made of polydimethylsiloxane (PDMS) brushes, which are linear, single polymer chains grown from a substrate to form a nanoscale surface layer.  

Experiments conducted by the team showed that this coating can significantly reduce microfibre shedding of nylon clothing after repeated laundering. The researchers share their findings in a new paper published in Nature Sustainability. 

“My lab has been working with this coating on other surfaces, including glass and metals, for a few years now,” says Golovin. “One of the properties we have observed is that it is quite slippery, meaning it has very low friction.” 

PDMS is a silicon-based organic polymer that is found in many household products. Its presence in shampoos makes hair shiny and slippery. It is also used as a food additive in oils to prevent liquids from foaming when bottled. 

Dr. Sudip Kumar Lahiri, a postdoctoral researcher in Golovin’s lab and lead author of the study, had the idea that if they could reduce the friction that occurs during wash cycles with a PDMS-based fabric finish, then that could stop fibres from rubbing together and breaking off during laundering.  

One of the biggest challenges the researchers faced during their study was ensuring the PDMS brushes stayed on the fabric. Lahiri, who is a textile engineer by trade, developed a molecular primer based on his understanding of fabric dyes.  

Lahiri reasoned that the type of bonding responsible for keeping dyed apparel colourful after repeated washes could work for the PDMS coating as well.  

Neither the primer nor the PDMS brushes work separately to decrease the microplastic-fibre shedding. But together, they created a strong finish that reduced the release of microfibres by more than 90% after nine washes.  

“PDMS brushes are environmentally friendly because they are not derived from petroleum like many polymers used today,” says Golovin, who was awarded a Connaught New Researcher award for this work.  

“With the addition of Sudip’s primer, our coating is robust enough to remain on the garment and continue to reduce micro-fibre shedding over time.”  

Since PDMS is naturally a hydrophobic (water-repellent) material, the researchers are currently working on making the coating hydrophilic, so that coated fabrics will be better able to wick away sweat. The team has also expanded the research to look beyond nylon fabrics, including polyester and synthetic-fabric blends.  

“Many textiles are made of multiple types of fibres,” says Golovin. “We are working to formulate the correct polymer architecture so that our coating can durably adhere to all of those fibres simultaneously.” 

Here’s a link to and a citation for the paper,

Polydimethylsiloxane-coated textiles with minimized microplastic pollution by Sudip Kumar Lahiri, Zahra Azimi Dijvejin & Kevin Golovin. Nature Sustainability (2023) DOI: https://doi.org/10.1038/s41893-022-01059-4 Published: 26 January 2023

This paper is behind a paywall.

Arc’teryx performance apparel and University of British Columbia (Canada) scientists stay green and dry

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As rainy season approaches in the Pacific Northwest of Canada and the US, there’s some good news about a sustainable water- and oil-repellent fabric. Sadly, it won’t be available this year but it’s something to look forward to.

An August 10, 2020 news item on phys.org announces the news from the University of British Columbia (UBC) about a greener, water-repellent fabric,

A sustainable, non-toxic and high-performance water-repellent fabric has long been the holy grail of outdoor enthusiasts and clothing companies alike. New research from UBC Okanagan and outdoor apparel giant Arc’teryx is making that goal one step closer to reality with one of the world’s first non-toxic oil and water-repellent performance textile finishes.

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An August 10, 2020 UBC Okanagan news release (also on EurekAlert), which originated the news item, provides more detail,

Outdoor fabrics are typically treated with perfluorinated compounds (PFCs) to repel oil and water. But according to Sadaf Shabanian, doctoral student at UBC Okanagan’s School of Engineering and study lead author, PFCs come with a number of problems.

“PFCs have long been the standard for stain repellents, from clothing to non-stick frying pans, but we know these chemicals have a detrimental impact on human health and the environment,” explains Shabanian. “They pose a persistent, long-term risk to health and the environment because they take hundreds of years to breakdown and linger both in the environment and our bodies.”

According to Mary Glasper, materials developer at Arc’teryx and collaborator on the project, these lasting impacts are one of the major motivations for clothing companies to seek out new methods to achieve the same or better repellent properties in their products.

To solve the problem, Shabanian and the research team added a nanoscopic layer of silicone to each fibre in a woven fabric, creating an oil-repellent jacket fabric that repels water, sweat and oils.

By understanding how the textile weave and fibre roughness affect the liquid interactions, Shabanian says she was able to design a fabric finish that did not use any PFCs.

“The best part of the new design is that the fabric finish can be made from biodegradable materials and can be recyclable,” she says. “It addresses many of the issues related to PFC-based repellent products and remains highly suitable for the kind of technical apparel consumers and manufacturers are looking for.”

Arc’teryx is excited about the potential of this solution.

“An oil- and water-repellent finish that doesn’t rely on PFCs is enormously important in the world of textiles and is something the whole outdoor apparel industry has been working on for years,” says Glasper. “Now that we have a proof-of-concept, we’ll look to expand its application to other DWR-treated textiles used in our products and to improve the durability of the treatment.”

“Working to lessen material impacts on the environment is crucial for Arc’teryx to meet our goal of reducing our greenhouse gas emissions by 65 per cent in intensity by 2030,” she adds.

Kevin Golovin, principal investigator of the Okanagan Polymer Engineering Research & Applications Lab where the research was done, says the new research is important because it opens up a new area of green textile manufacturing.

He explains that while the new technology has immense potential, there are still several more years of development and testing needed before people will see fabrics with this treatment in stores.

“Demonstrating oil repellency without the use of PFCs is a critical first step towards a truly sustainable fabric finish,” says Golovin. “And it’s something previously thought impossible.”

The research is funded through a grant from the Natural Sciences and Engineering Research Council of Canada (NSERC), with support from Arc’teryx Equipment Inc.

Arc’teryx is based in North Vancouver (Canada).

Here’s a link to and a citation for the paper,

Rational design of perfluorocarbon-free oleophobic textiles by Sadaf Shabanian, Behrooz Khatir, Ambreen Nisar & Kevin Golovin. Nature Sustainability (2020) DOI: https://doi.org/10.1038/s41893-020-0591-9 Published: 10 August 2020

This paper is behind a paywall.

Comfortable, bulletproof clothing for Canada’s Department of National Defence

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h/t to Miriam Halpenny’s October 14, 2019 Castanet article as seen on the Vancouverisawesome website for this news about bulletproof clothing being developed for Canada’s National Department of Defence. I found a September 4, 2019 University of British Columbia Okanagan news release describing the research and the funds awarded to it,

The age-old technique of dressing in layers is a tried and tested way to protect from the elements. Now thanks to $1.5 million in new funding for UBC’s Okanagan campus, researchers are pushing the practice to new limits by creating a high-tech body armour solution with multiple layers of protection against diverse threats.

“Layers are great for regulating body heat, protecting us from inclement weather and helping us to survive in extreme conditions,” says Keith Culver, director of UBC’s Survive and Thrive Applied Research (STAR) initiative, which is supporting the network of researchers who will be working together over the next three years. “The idea is to design and integrate some of the most advanced fabrics and materials into garments that are comfortable, practical and can even stop a bullet.”

The research network working to develop these new Comfort-Optimized Materials For Operational Resilience, Thermal-transport and Survivability (COMFORTS) aims to create a futuristic new body armour solution by combining an intelligent, moisture-wicking base layer that has insulating properties with a layer of lightweight, ballistic-resistant material using cross-linker technology. It will also integrate a water, dust and gas repellent outer layer and will be equipped with comfort sensors to monitor the wearer’s response to extreme conditions.

“Although the basic idea seems simple, binding all these different materials and technologies together into a smart armour solution that is durable, reliable and comfortable is incredibly complex,” says Kevin Golovin, assistant professor of mechanical engineering at UBCO and principal investigator of the COMFORTS research network. “We’re putting into practice years of research and expertise in materials science to turn the concept into reality.”

The COMFORTS network is a collaboration between the University of British Columbia, the University of Alberta and the University of Victoria and is supported by a number of industrial partners. The network has received a $1.5M contribution agreement from the Department of National Defence through its Innovation for Defence Excellence and Security (IDEaS) program, designed to support innovation in defence and security.

“The safety and security threats faced by our military are ever-changing,” says Culver. “Hazards extend beyond security threats from foreign forces to natural disasters now occurring more frequently than ever before. Almost every year we’re seeing natural disasters, forest fires and floods that put not just ordinary Canadians at risk but also the personnel that respond directly to those threats. Our goal is to better protect those who put their lives on the line to protect the rest of us.”

While the initial COMFORTS technologies developed will be for defence and security applications, Culver says the potential extends well beyond the military.

“Imagine a garment that could keep its users comfortable and safe as they explore the tundra of the Canadian arctic, fight a raging forest fire or respond to a corrosive chemical spill,” says Culver. “I imagine everyone from first responders to soldiers to extreme athletes being impacted by this kind of innovation in protective clothing.”

The research will be ongoing with eight projects planned over the next three years. Some of the protective materials testing will take place at UBC’s STAR Impact Research Facility (SIRF), located just north of UBC’s Okanagan campus. The ballistic and blast simulation facility is the only one of its kind in Canada—it supports research and testing of ballistic and blast-resistant armour, ceramic and other composite materials, as well as helmets and other protective gear.

“I anticipate we will see some exciting new, field-tested technologies developed within the next few years,” says Culver. “I look forward to seeing where this collaboration will lead us.”

To learn more about the COMFORTS project, visit: ok.ubc.ca/okanagan-stories/textile-tech

UBC Expert Q&A

Western Canada primed to be defense and security research hotspot

World-class vineyards and sunny lakeside resorts have long been the reputation for BC’s Okanagan Valley. That reputation has expanded with Kelowna’s growth as a tech hub, according to Professor Keith Culver, director of UBC’s Survive and Thrive Research (STAR) initiative, but core expertise in defense and security research has also been rapidly expanding since UBC launched the STAR initiative five years ago.

Culver is a professor, legal theorist, self-described convener and coach with proven expertise assembling multi-disciplinary research teams working at the vanguard of innovation. One of these teams, led by Assistant Professor of Mechanical Engineering Kevin Golovin, was recently awarded a $1.5 million contract by the Department of National Defense to develop next-generation, high-performance body armour that increases the safety and comfort of Canadian soldiers.

What is UBC’s STAR initiative?

UBC STAR is a group of researchers and partners working together to solve human performance challenges. We know that solving complex problems requires a multi-disciplinary approach, so we build teams with specialized expertise from across both our campuses and other Western Canadian universities. Then we blend that expertise with the know-how and production capabilities of private and public sector partners to put solutions into practice. Above all, STAR helps university researchers and partners to work together in new, more productive ways.

You recently received considerable new funding from the Department of National Defence. Can you tell us about that research

A team of researchers from UBC, the University of Alberta and the University of Victoria have established a research network to invent and test new materials for the protection of humans operating in extreme environments – in this case, soldiers doing their jobs on foot. Assistant Professor Kevin Golovin of UBC Okanagan’s School of Engineering is leading the network with support from UBC STAR. The network brings together three leading Western Canadian universities to work together with industry to develop new technologies for the defence and security sector.

The network is developing several kinds of protective materials and hazard sensors for use in protective armour for soldiers and first responders. The name of the network captures its focus nicely: Comfort-Optimized Materials For Operational Resilience, Thermal-transport and Survivabilty (COMFORTS). Researchers in engineering, chemistry and other disciplines are developing new textile technologies and smart armour solutions that will be rigorously tested for thermal resistance to increase soldier comfort. We’re fortunate to be working with a great group of companies ready to turn our research into solutions ready for use. We’ll help to solve the challenges facing Canadian first responders and soldiers while enabling Canadian companies to sell those solutions to international markets.

What does the safety and security landscape look like in Western Canada?

I think there’s a perception out there that this kind of research is only happening in places like Halifax, Toronto or Waterloo. Western Canadian expertise is sometimes overlooked by Ottawa and Toronto, but there’s incredible expertise and cutting-edge research happening here in the west, and we are fortunate to have a strong private sector partner community that understands safety and security problems in military contexts, and in forestry, mining and wildfire and flood response. Our understanding of hazardous environments gives us a head start in putting technologies and strategies to work safely in extreme conditions, and we’re coming to realize that our creative solutions can both help Canadians and others around the world.

Why do companies want to work with UBC STAR and its Western Canadian partners?

We have great researchers and great facilities – our blast simulator and ballistics range are second to none – but we offer much more than expertise and equipment. UBC STAR is fundamentally about making the most of collaboration. We work together with our partners to understand the nature of problems and what could contribute to a solution. We readily draw on expertise from multiple universities and firms to assemble the right team. And we know that we are in the middle of a great living lab for testing solutions –with rural and urban areas of varying sizes, climates and terrains. We’re situated in an ideal place to work through technology development, while identifying the strategies and standards needed to put innovative technology to good use.

How do you expect this sector to develop over the next decade?

I see a boom coming in this sector. In Canada, and around the world, we are witnessing a rise in natural disasters that put first responders and others at risk, and our research can help improve their safety. At the same time, we are seeing a rise in global political tensions calling for Canadian military deployment in peacekeeping and other support roles. Our military needs help protecting its members so they can do their jobs in dangerous places. And, of course, when we develop protective materials for first responders and soldiers, the same solutions can be easily adapted for use in sport and health – such as protecting children playing contact sports or our aging population from slip and fall injuries. I think I speak for everyone involved in this research when I say that it’s incredibly rewarding to see how solutions found addressing one question often have far broader benefits for Canadians in every walk of life.

To learn more about STAR, visit: star.ubc.ca

About UBC’s Okanagan campus

UBC’s Okanagan campus is an innovative hub for research and learning in the heart of British Columbia’s stunning Okanagan Valley. Ranked among the top 20 public universities in the world, UBC is home to bold thinking and discoveries that make a difference. Established in 2005, the Okanagan campus combines a globally recognized UBC education with a tight-knit and entrepreneurial community that welcomes students and faculty from around the world.

To find out more, visit: ok.ubc.ca

Courtesy: UBC Okanagan

I have mentioned* bulletproof clothing here in a November 4, 2013 posting featuring a business suit that included carbon nanotubes providing protection from bullets. Here’s where you can order one.

*’mentioned’ was substituted for ‘featured’ as a grammar correction on July 6, 2020.