Tag Archives: lignocellulose

Fortify wood with eco-friendly nano-iron

An April 28, 2025 news item on ScienceDaily announced an investigation into making wood stronger,

Scientists and engineers are developing high-performance materials from eco-friendly sources like plant waste. A key component, lignocellulose — found in wood and many plants — can be easily collected and chemically modified to improve its properties.

By using these kinds of chemical changes, researchers are creating advanced materials and new ways to design and build sustainably. With about 181.5 billion tons of wood produced globally each year, it’s one of the largest renewable material sources.

Researchers from the College of Engineering and Computer Science at Florida Atlantic University, and collaborators from the University of Miami and Oak Ridge National Laboratory, wanted to find out if adding extremely hard minerals at the nanoscale could make the walls of wood cells stronger — without making the wood heavy, expensive or bad for the environment. Few studies have investigated how treated wood performs at different scales, and none have successfully strengthened entire pieces of wood by incorporating inorganic minerals directly into the cell walls.

Caption: A microCT image that shows the distribution of the iron mineral in the wood cell wall (in turquoise). Credit: Florida Atlantic University

An April 28, 2025 Florida Atlantic University (FAU) news release (also on EurekAlert) by Gisele Galoustian, which originated the news item, provides more technical details about the work,Note: Links have been removed,

The research team focused on a special type of hardwood known as ring-porous wood, which comes from broad-leaf trees like oak, maple, cherry and walnut. These trees feature large, ring-shaped vessels in the wood that transport water from the roots to the leaves. For the study, researchers used red oak, a common hardwood in North America, and introduced an iron compound into the wood through a simple chemical reaction. By mixing ferric nitrate with potassium hydroxide, they created ferrihydrite, an iron oxide mineral commonly found in soil and water.

Results of the study, published in the journal ACS Applied Materials and Interfaces, revealed that a simple, cost-effective chemical method using a safe mineral called nanocrystalline iron oxyhydroxide can strengthen the tiny cell walls within wood while adding only a small amount of extra weight. Although the internal structure became more durable, the wood’s overall behavior – such as how it bends or breaks – remained largely unchanged. This is likely because the treatment weakened the connections between individual wood cells, affecting how the material holds together on a larger scale.

The findings suggest that, with the right chemical treatment, it’s possible to enhance the strength of wood and other plant-based materials without increasing their weight or harming the environment. These bio-based materials could one day replace traditional construction materials like steel and concrete in applications such as tall buildings, bridges, furniture and flooring.

“Wood, like many natural materials, has a complex structure with different layers and features at varying scales. To truly understand how wood bears loads and eventually fails, it’s essential to examine it across these different levels,” said Vivian Merk, Ph.D., senior author and an assistant professor in the FAU Department of Ocean and Mechanical Engineering, the FAU Department of Biomedical Engineering, and the FAU Department of Chemistry and Biochemistry within the Charles E. Schmidt College of Science. “To test our hypothesis – that adding tiny mineral crystals to the cell walls would strengthen them – we employed several types of mechanical testing at both the nanoscale and the macroscopic scale.”

For the study, researchers used advanced tools like atomic force microscopy (AFM) to examine the wood at a very small scale, allowing them to measure properties such as stiffness and elasticity. Specifically, they employed a technique called AM-FM (Amplitude Modulation – Frequency Modulation), which vibrates the AFM tip at two different frequencies. One frequency generates detailed surface images, while the other measures the material’s elasticity and stickiness. This method gave them a precise view of how the wood’s cell walls were altered after being treated with minerals.

Additionally, the team conducted nanoindentation tests within a scanning electron microscope (SEM), where tiny probes were pressed into the wood to measure its response to force in different areas. To round out their analysis, they performed standard mechanical tests – such as bending both untreated and treated wood samples – to evaluate their overall strength and how they broke under stress.

“By looking at wood at different levels – from the microscopic structures inside the cell walls all the way up to the full piece of wood – we were able to learn more about how to chemically improve natural materials for real-world use,” said Merk.

This combination of small- and large-scale testing helped the researchers understand how the treatment affected both the fine details inside the cell walls and the overall strength of the wood.

“This research marks a significant advancement in sustainable materials science and a meaningful stride toward eco-friendly construction and design,” said Stella Batalama, Ph.D., the dean of the College of Engineering and Computer Science. “By reinforcing natural wood through environmentally conscious and cost-effective methods, our researchers are laying the groundwork for a new generation of bio-based materials that have the potential to replace traditional materials like steel and concrete in structural applications. The impact of this work reaches far beyond the field of engineering – it contributes to global efforts to reduce carbon emissions, cut down on waste, and embrace sustainable, nature-inspired solutions for everything from buildings to large-scale infrastructure.”

Study co-authors are Steven A. Soini, a Ph.D. graduate from the FAU College of Engineering and Computer Science and FAU Charles E. Schmidt College of Science; Inam Lalani, a Ph.D. student at the University of Miami; Matthew L. Maron, Ph.D., a doctoral researcher at the University of Miami; David Gonzalez, a graduate student in the FAU College of Engineering and Computer Science; Hassan Mahfuz, Ph.D., a professor in the FAU Department of Ocean and Mechanical Engineering; and Neus Domingo-Marimon, Ph.D., senior R&D staff scientist, group leader for the Functional Atomic Force Microscopy Group, Oak Ridge National Laboratory.

Here’s a link to and a citation for the paper,

Multiscale Mechanical Characterization of Mineral-Reinforced Wood Cell Walls by Steven A. Soini, Inam Lalani, Matthew L.Maron, David Gonzalez, Hassan Mahfuz, Neus Domingo-Marimon, Vivian Merk. ACS Applied Materials & Interfaces (ACS Appl. Mater. Interfaces) 2025, 17, 12, 18887–18896 DOI: https://doi.org/10.1021/acsami.4c22384 Published: March 12, 2025 Copyright © 2025 American Chemical Society

This paper is behind a paywall.

One last comment, I love wordplay, so I offer my thanks to Gisele Galoustian for the news release’s original title “‘Wood you believe it?’ FAU engineers fortify wood with eco-friendly nano-iron.”

Europe’s search for raw materials and hopes for nanotechnology-enabled solutions

A Feb. 27, 2015 news item on Nanowerk highlights the concerns over the availability of raw materials and European efforts to address those concerns,

Critical raw materials’ are crucial to many European industries but they are vulnerable to scarcity and supply disruption. As such, it is vital that Europe develops strategies for meeting the demand for raw materials. One such strategy is finding methods or substances that can replace the raw materials that we currently use. With this in mind, four EU projects working on substitution in catalysis, electronics and photonics presented their work at the Third Innovation Network Workshop on substitution of Critical Raw Materials hosted by the CRM_INNONET project in Brussels earlier this month [February 2015].

A Feb. 26, 2015 CORDIS press release, which originated the news item, goes on to describe four European Union projects working on nanotechnology-enabled solutions,

NOVACAM

NOVACAM, a coordinated Japan-EU project, aims to develop catalysts using non-critical elements designed to unlock the potential of biomass into a viable energy and chemical feedstock source.

The project is using a ‘catalyst by design’ approach for the development of next generation catalysts (nanoscale inorganic catalysts), as NOVACAM project coordinator Prof. Emiel Hensen from Eindhoven University of Technology in the Netherlands explained. Launched in September 2013, the project is developing catalysts which incorporate non-critical metals to catalyse the conversion of lignocellulose into industrial chemical feedstocks and bio-fuels. The first part of the project has been to develop the principle chemistry while the second part is to demonstrate proof of process. Prof. Hensen predicts that perhaps only two of three concepts will survive to this phase.

The project has already made significant progress in glucose and ethanol conversion, according to Prof. Hensen, and has produced some important scientific publications. The consortium is working with and industrial advisory board comprising Shell in the EU and Nippon Shokubai in Japan.

FREECATS

The FREECATS project, presented by project coordinator Prof. Magnus Rønning from the Norwegian University of Science and Technology, has been working over the past three years to develop new metal-free catalysts. These would be either in the form of bulk nanomaterials or in hierarchically organised structures – both of which would be capable of replacing traditional noble metal-based catalysts in catalytic transformations of strategic importance.

Prof. Magnus Rønning explained that the application of the new materials could eliminate the need for the use for platinum group metals (PGM) and rare earth metals – in both cases Europe is very reliant on other countries for these materials. Over the course of its research, FREECATS targeted three areas in particular – fuel cells, the production of light olefins and water and wastewater purification.

By working to replace the platinum in fuel cells, the project is supporting the EU’s aim of replacing the internal combustion engine by 2050. However, as Prof. Rønning noted, while platinum has been optimized for use over several decades, the materials FREECATS are using are new and thus come with their new challenges which the project is addressing.

HARFIR

Prof. Atsufumi Hirohata of the University of York in the United Kingdom, project coordinator of HARFIR, described how the project aims to discover an antiferromagnetic alloy that does not contain the rare metal Iridium. Iridium is becoming more and more widely used in numerous spin electronic storage devices, including read heads in hard disk drives. The world supply depends on Platinum ore that comes mainly from South Africa. The situation is much worse than for other rare earth elements as the price has been shooting up over recent years, according to Prof. Hirohata.

The HARFIR team, divided between Europe and Japan, aims to replace Iridium alloys with Heusler alloys. The EU team, led by Prof. Hirohata, has been working on the preparation of polycrystalline and epitaxial thin films of Heusler Alloys, with the material design led by theoretical calculations. The Japanese team, led by Prof. Koki Takanashi at Tohoku University, is meanwhile working on the preparation of epitaxial thin films, measurements of fundamental properties and structural/magnetic characterisation by neutron and synchrotron x-ray beams.

One of the biggest challenges has been that Heusler alloys have a relatively complicated atomic structure. In terms of HARFIR’s work, if any atomic disordering at the edge of nanopillar devices, the magnetic properties that are needed are lost. The team is exploring solutions to this challenge.

IRENA

Prof. of Esko Kauppinen Aalto University in Finland closed off the first session of the morning with his presentation of the IRENA project. Launched in September 2013, the project will run until mid 2017 working towards the aim of developing high performance materials, specifically metallic and semiconducting single-walled carbon nanotube (SWCNT) thin films to completely eliminate the use of the critical metals in electron devices. The ultimate aim is to replace Indium in transparent conducting films, and Indium and Gallium as a semiconductor in thin film field effect transistors (TFTs).

The IRENA team is developing an alternative that is flexible, transparent and stretchable so that it can meet the demands of the electronics of the future – including the possibility to print electronics.

IRENA involves three partners from Europe and three from Japan. The team has expertise in nanotube synthesis, thin film manufacturing and flexible device manufacturing, modelling of nanotube growth and thin film charge transport processes, and the project has benefitted from exchanges of team members between institutions. One of the key achievements so far is that the project has succeeded in using a nanotube thin film for the first time as the both the electrode and hole blocking layer in an organic solar cell.

You’ll note that Japan is a partner in all of these projects. In all probability, these initiatives have something to do with rare earths which are used in much of today’s electronics technology and Japan is sorely lacking in those materials. China, by comparison, has dominated the rare earths export industry and here’s an excerpt from my Nov. 1, 2013 posting where I outline the situation (which I suspect hasn’t changed much since),

As for the short supply mentioned in the first line of the news item, the world’s largest exporter of rare earth elements at 90% of the market, China, recently announced a cap according to a Sept. 6, 2013 article by David Stanway for Reuters. The Chinese government appears to be curtailing exports as part of an ongoing, multi-year strategy. Here’s how Cientifica‘s (an emerging technologies consultancy, etc.) white paper (Simply No Substitute?) about critical materials published in 2012 (?), described the situation,

Despite their name, REE are not that rare in the Earth’s crust. What has happened in the past decade is that REE exports from China undercut prices elsewhere, leading to the closure of mines such as the Mountain Pass REE mine in California. Once China had acquired a dominant market position, prices began to rise. But this situation will likely ease. The US will probably begin REE production from the Mountain Pass mine later in 2012, and mines in other countries are expected to start operation soon as well.

Nevertheless, owing to their broad range of uses REE will continue to exert pressures on their supply – especially for countries without notable REE deposits. This highlights two aspects of importance for strategic materials: actual rarity and strategic supply issues such as these seen for REE. Although strategic and diplomatic supply issues may have easier solutions, their consideration for manufacturing industries will almost be the same – a shortage of crucial supply lines.

Furthermore, as the example of REE shows, the identification of long-term supply problems can often be difficult, and not every government has the same strategic foresight that the Chinese demonstrated. And as new technologies emerge, new elements may see an unexpected, sudden demand in supply. (pp. 16-17)

Meanwhile, in response to China’s decision to cap its 2013 REE exports, the Russian government announced a $1B investment to 2018 in rare earth production,, according to a Sept. 10, 2013 article by Polina Devitt for Reuters.

I’m not sure you’ll be able to access Tim Harper’s white paper as he is now an independent, serial entrepreneur. I most recently mentioned him in relation to his articles (on Azonano) about the nanotechnology scene in a Feb. 12, 2015 posting where you’ll also find contact details for him.