Tag Archives: Project Jacquard

MXene-coated yarn for wearable electronics

There’s been a lot of talk about wearable electronics, specifically e-textiles, but nothing seems to have entered the marketplace. Scaling up your lab discoveries for industrial production can be quite problematic. From an October 10, 2019 news item on ScienceDaily,

Producing functional fabrics that perform all the functions we want, while retaining the characteristics of fabric we’re accustomed to is no easy task.

Two groups of researchers at Drexel University — one, who is leading the development of industrial functional fabric production techniques, and the other, a pioneer in the study and application of one of the strongest, most electrically conductive super materials in use today — believe they have a solution.

They’ve improved a basic element of textiles: yarn. By adding technical capabilities to the fibers that give textiles their character, fit and feel, the team has shown that it can knit new functionality into fabrics without limiting their wearability.

An October 10, 2019 Drexel University news release (also on EurekAlert), which originated the news item, details the proposed solution (pun! as you’ll see in the video following this excerpt),

In a paper recently published in the journal Advanced Functional Materials, the researchers, led by Yury Gogotsi, PhD, Distinguished University and Bach professor in Drexel’s College of Engineering, and Genevieve Dion, an associate professor in Westphal College of Media Arts & Design and director of Drexel’s Center for Functional Fabrics, showed that they can create a highly conductive, durable yarn by coating standard cellulose-based yarns with a type of conductive two-dimensional material called MXene.

Hitting snags

“Current wearables utilize conventional batteries, which are bulky and uncomfortable, and can impose design limitations to the final product,” they write. “Therefore, the development of flexible, electrochemically and electromechanically active yarns, which can be engineered and knitted into full fabrics provide new and practical insights for the scalable production of textile-based devices.”

The team reported that its conductive yarn packs more conductive material into the fibers and can be knitted by a standard industrial knitting machine to produce a textile with top-notch electrical performance capabilities. This combination of ability and durability stands apart from the rest of the functional fabric field today.

Most attempts to turn textiles into wearable technology use stiff metallic fibers that alter the texture and physical behavior of the fabric. Other attempts to make conductive textiles using silver nanoparticles and graphene and other carbon materials raise environmental concerns and come up short on performance requirements. And the coating methods that are successfully able to apply enough material to a textile substrate to make it highly conductive also tend to make the yarns and fabrics too brittle to withstand normal wear and tear.

“Some of the biggest challenges in our field are developing innovative functional yarns at scale that are robust enough to be integrated into the textile manufacturing process and withstand washing,” Dion said. “We believe that demonstrating the manufacturability of any new conductive yarn during experimental stages is crucial. High electrical conductivity and electrochemical performance are important, but so are conductive yarns that can be produced by a simple and scalable process with suitable mechanical properties for textile integration. All must be taken into consideration for the successful development of the next-generation devices that can be worn like everyday garments.”

The winning combination

Dion has been a pioneer in the field of wearable technology, by drawing on her background on fashion and industrial design to produce new processes for creating fabrics with new technological capabilities. Her work has been recognized by the Department of Defense, which included Drexel, and Dion, in its Advanced Functional Fabrics of America effort to make the country a leader in the field.

She teamed with Gogotsi, who is a leading researcher in the area of two-dimensional conductive materials, to approach the challenge of making a conductive yarn that would hold up to knitting, wearing and washing.

Gogotsi’s group was part of the Drexel team that discovered highly conductive two-dimensional materials, called MXenes, in 2011 and have been exploring their exceptional properties and applications for them ever since. His group has shown that it can synthesize MXenes that mix with water to create inks and spray coatings without any additives or surfactants – a revelation that made them a natural candidate for making conductive yarn that could be used in functional fabrics. [Gogotsi’s work was featured here in a May 6, 2019 posting]

“Researchers have explored adding graphene and carbon nanotube coatings to yarn, our group has also looked at a number of carbon coatings in the past,” Gogotsi said. “But achieving the level of conductivity that we demonstrate with MXenes has not been possible until now. It is approaching the conductivity of silver nanowire-coated yarns, but the use of silver in the textile industry is severely limited due to its dissolution and harmful effect on the environment. Moreover, MXenes could be used to add electrical energy storage capability, sensing, electromagnetic interference shielding and many other useful properties to textiles.”

In its basic form, titanium carbide MXene looks like a black powder. But it is actually composed of flakes that are just a few atoms thick, which can be produced at various sizes. Larger flakes mean more surface area and greater conductivity, so the team found that it was possible to boost the performance of the yarn by infiltrating the individual fibers with smaller flakes and then coating the yarn itself with a layer of larger-flake MXene.

Putting it to the test

The team created the conductive yarns from three common, cellulose-based yarns: cotton, bamboo and linen. They applied the MXene material via dip-coating, which is a standard dyeing method, before testing them by knitting full fabrics on an industrial knitting machine – the kind used to make most of the sweaters and scarves you’ll see this fall.

Each type of yarn was knit into three different fabric swatches using three different stitch patterns – single jersey, half gauge and interlock – to ensure that they are durable enough to hold up in any textile from a tightly knit sweater to a loose-knit scarf.

“The ability to knit MXene-coated cellulose-based yarns with different stitch patterns allowed us to control the fabric properties, such as porosity and thickness for various applications,” the researchers write.

To put the new threads to the test in a technological application, the team knitted some touch-sensitive textiles – the sort that are being explored by Levi’s and Yves Saint Laurent as part of Google’s Project Jacquard.

Not only did the MXene-based conductive yarns hold up against the wear and tear of the industrial knitting machines, but the fabrics produced survived a battery of tests to prove its durability. Tugging, twisting, bending and – most importantly – washing, did not diminish the touch-sensing abilities of the yarn, the team reported – even after dozens of trips through the spin cycle.

Pushing forward

But the researchers suggest that the ultimate advantage of using MXene-coated conductive yarns to produce these special textiles is that all of the functionality can be seamlessly integrated into the textiles. So instead of having to add an external battery to power the wearable device, or wirelessly connect it to your smartphone, these energy storage devices and antennas would be made of fabric as well – an integration that, though literally seamed, is a much smoother way to incorporate the technology.

“Electrically conducting yarns are quintessential for wearable applications because they can be engineered to perform specific functions in a wide array of technologies,” they write.

Using conductive yarns also means that a wider variety of technological customization and innovations are possible via the knitting process. For example, “the performance of the knitted pressure sensor can be further improved in the future by changing the yarn type, stitch pattern, active material loading and the dielectric layer to result in higher capacitance changes,” according to the authors.

Dion’s team at the Center for Functional Fabrics is already putting this development to the test in a number of projects, including a collaboration with textile manufacturer Apex Mills – one of the leading producers of material for car seats and interiors. And Gogotsi suggests the next step for this work will be tuning the coating process to add just the right amount of conductive MXene material to the yarn for specific uses.

“With this MXene yarn, so many applications are possible,” Gogotsi said. “You can think about making car seats with it so the car knows the size and weight of the passenger to optimize safety settings; textile pressure sensors could be in sports apparel to monitor performance, or woven into carpets to help connected houses discern how many people are home – your imagination is the limit.”

Researchers have produced a video about their work,

Here’s a link to and a citation for the paper,

Knittable and Washable Multifunctional MXene‐Coated Cellulose Yarns by Simge Uzun, Shayan Seyedin, Amy L. Stoltzfus, Ariana S. Levitt, Mohamed Alhabeb, Mark Anayee, Christina J. Strobel, Joselito M. Razal, Genevieve Dion, Yury Gogotsi. Advanced Functional Materials DOI: https://doi.org/10.1002/adfm.201905015 First published: 05 September 2019

This paper is behind a paywall.

Cientifica’s latest smart textiles and wearable electronics report

After publishing a report on wearable technology in May 2016 (see my June 2, 2016 posting), Cientifica has published another wearable technology report, this one is titled, Smart Textiles and Wearables: Markets, Applications and Technologies. Here’s more about the latest report from the report order page,

“Smart Textiles and Wearables: Markets, Applications and Technologies” examines the markets for textile based wearable technologies, the companies producing them and the enabling technologies. This is creating a 4th industrial revolution for the textiles and fashion industry worth over $130 billion by 2025.

Advances in fields such as nanotechnology, organic electronics (also known as plastic electronics) and conducting polymers are creating a range of textile–based technologies with the ability to sense and react to the world around them.  This includes monitoring biometric data such as heart rate, the environmental factors such as temperature and The presence of toxic gases producing real time feedback in the form of electrical stimuli, haptic feedback or changes in color.

The report identifies three distinct generations of textile wearable technologies.

First generation is where a sensor is attached to apparel and is the approach currently taken by major sportswear brands such as Adidas, Nike and Under Armour
Second generation products embed the sensor in the garment as demonstrated by products from Samsung, Alphabet, Ralph Lauren and Flex.
In third generation wearables the garment is the sensor and a growing number of companies including AdvanPro, Tamicare and BeBop sensors are making rapid progress in creating pressure, strain and temperature sensors.

Third generation wearables represent a significant opportunity for new and established textile companies to add significant value without having to directly compete with Apple, Samsung and Intel.

The report predicts that the key growth areas will be initially sports and wellbeing

followed by medical applications for patient monitoring. Technical textiles, fashion and entertainment will also be significant applications with the total market expected to rise to over $130 billion by 2025 with triple digit compound annual growth rates across many applications.

The rise of textile wearables also represents a significant opportunity for manufacturers of the advanced materials used in their manufacture. Toray, Panasonic, Covestro, DuPont and Toyobo are already suppling the necessary materials, while researchers are creating sensing and energy storage technologies, from flexible batteries to graphene supercapacitors which will power tomorrows wearables. The report details the latest advances and their applications.

This report is based on an extensive research study of the wearables and smart textile markets backed with over a decade of experience in identifying, predicting and sizing markets for nanotechnologies and smart textiles. Detailed market figures are given from 2016-2025, along with an analysis of the key opportunities, and illustrated with 139 figures and 6 tables.

The September 2016 report is organized differently and has a somewhat different focus from the report published in May 2016. Not having read either report, I’m guessing that while there might be a little repetition, you might better consider them to be companion volumes.

Here’s more from the September 2016 report’s table of contents which you can download from the order page (Note: The formatting has been changed),

SMART TEXTILES AND WEARABLES:
MARKETS, APPLICATIONS AND
TECHNOLOGIES

Contents  1
List of Tables  4
List of Figures  4
Introduction  8
How to Use This Report  8
Wearable Technologies and the 4Th Industrial Revolution  9
The Evolution of Wearable Technologies  10
Defining Smart Textiles  15
Factors Affecting The Adoption of Smart Textiles for Wearables  18
Cost  18
Accuracy  18
On Shoring  19
Power management  19
Security and Privacy  20
Markets  21
Total Market Growth and CAGR  21
Market Growth By Application  21
Adding Value To Textiles Through Technology  27
How Nanomaterials Add Functionality and Value  31
Business Models  33
Applications  35
Sports and Wellbeing  35
1st Generation Technologies  35
Under Armour Healthbox Wearables  35
Adidas MiCoach  36
Sensoria  36
EMPA’s Long Term Research  39
2nd Generation Technologies  39
Google’s Project Jacquard  39
Samsung Creative Lab  43
Microsoft Collaborations  44
Intel Systems on a Chip  44
Flex (Formerly Flextronics) and MAS Holdings  45
Jiobit  46
Asensei Personal Trainer  47
OmSignal Smart Clothing  48
Ralph Lauren PoloTech  49
Hexoskin Performance Management  50
Jabil Circuit Textile Heart Monitoring  51
Stretch Sense Sensors  52
NTT Data and Toray  54
Goldwin Inc. and DoCoMo  55
SupaSpot Inc Smart Sensors  55
Wearable Experiments and Brand Marketing  56
Wearable Life Sciences Antelope  57
Textronics NuMetrex  59
3rd Generation Technologies  60
AdvanPro Pressure Sensing Shoes  60
Tamicare 3D printed Wearables with Integrated Sensors  62
AiQ Smart Clothing Stainless Steel Yarns  64
Flex Printed Inks And Conductive Yarns  66
Sensing Tech Conductive Inks  67
EHO Textiles Body Motion Monitoring  68
Bebop Sensors Washable E-Ink Sensors  70
Fraunhofer Institute for Silicate Research Piezolectric Polymer
Sensors  71
CLIM8 GEAR Heated Textiles  74
VTT Smart Clothing Human Thermal Model  74
ATTACH (Adaptive Textiles Technology with Active Cooling and Heating) 76
Energy Storage and Generation  78
Intelligent Textiles Military Uniforms  78
BAE Systems Broadsword Spine  79
Stretchable Batteries  80
LG Chem Cable Batteries  81
Supercapacitors  83
Swinburne Graphene Supercapacitors  83
MIT Niobium Nanowire Supercapacitors  83
Energy Harvesting  86
Kinetic  86
StretchSense Energy Harvesting Kit  86
NASA Environmental Sensing Fibers  86
Solar  87
Powertextiles  88
Sphelar Power Corp Solar Textiles  88
Ohmatex and Powerweave  89
Fashion  89
1st Generation Technologies  92
Cute Circuit LED Couture  92
MAKEFASHION LED Couture  94
2nd Generation Technologies  94
Covestro Luminous Clothing  94
3rd Generation Technologies  96
The Unseen Temperature Sensitive Dyes  96
Entertainment  98
Wearable Experiments Marketing  98
Key Technologies 100
Circuitry  100
Conductive Inks for Fabrics  100
Conductive Ink For Printing On Stretchable Fabrics  100
Creative Materials Conductive Inks And Adhesives  100
Dupont Stretchable Electronic Inks  101
Aluminium Inks From Alink Co  101
Conductive Fibres  102
Circuitex Silver Coated Nylon  102
Textronics Yarns and Fibres  102
Novonic Elastic Conductive Yarn  103
Copper Coated Polyacrylonitrile (PAN) Fibres  103
Printed electronics  105
Covestro TPU Films for Flexible Circuits  105
Sensors  107
Electrical  107
Hitoe  107
Cocomi  108
Panasonic Polymer Resin  109
Cardiac Monitoring  110
Mechanical  113
Strain  113
Textile-Based Weft Knitted Strain Sensors  113
Chain Mail Fabric for Smart Textiles  113
Nano-Treatment for Conductive Fiber/Sensors 115
Piezoceramic materials  116
Graphene-Based Woven Fabric  117
Pressure Sensing  117
LG Innotek Flexible Textile Pressure Sensors  117
Hong Kong Polytechnic University Pressure Sensing Fibers  119
Conductive Polymer Composite Coatings  122
Printed Textile Sensors To Track Movement  125
Environment  127
Photochromic Textiles  127
Temperature  127
Sefar PowerSens  127
Gasses & Chemicals  127
Textile Gas Sensors  127
Energy  130
Storage  130
Graphene Supercapacitors  130
Niobium Nanowire Supercapacitors  130
Stretchy supercapacitors  132
Energy Generation  133
StretchSense Energy Harvesting Kit  133
Piezoelectric Or Thermoelectric Coated Fibres  134
Optical  137
Light Emitting  137
University of Manchester Electroluminescent Inks and Yarns 137
Polyera Wove  138
Companies Mentioned  141
List of Tables
Table 1 CAGR by application  22
Table 2 Value of market by application 2016-25 (millions USD)  24
Table 3 % market share by application  26
Table 4 CAGR 2016-25 by application  26
Table 5 Technology-Enabled Market Growth in Textile by Sector (2016-22) 28
Table 6 Value of nanomaterials by sector 2016-22 ($ Millions)  33
List of Figures
Figure 1 The 4th Industrial Revolution (World Economic Forum)  9
Figure 2 Block Diagram of typical MEMS digital output motion sensor: ultra
low-power high performance 3-axis “femto” accelerometer used in
fitness tracking devices.  11
Figure 3 Interior of Fitbit Flex device (from iFixit)  11
Figure 4 Internal layout of Fitbit Flex. Red is the main CPU, orange is the
BTLE chip, blue is a charger, yellow is the accelerometer (from iFixit)  11
Figure 5 Intel’s Curie processor stretches the definition of ‘wearable’  12
Figure 6 Typical Textile Based Wearable System Components  13
Figure 7 The Chromat Aeros Sports Bra “powered by Intel, inspired by wind, air and flight.”  14
Figure 8 The Evolution of Smart textiles  15
Figure 9 Goldwin’s C2fit IN-pulse sportswear using Toray’s Hitoe  16
Figure 10 Sensoglove reads grip pressure for golfers  16
Figure 11 Textile Based Wearables Growth 2016-25(USD Millions)  21
Figure 12 Total market for textile based wearables 2016-25 (USD Millions)  22
Figure 13 Health and Sports Market Size 2016-20 (USD Millions)  23
Figure 14 Health and Sports Market Size 2016-25 (USD Millions)  23
Figure 15 Critical steps for obtaining FDA medical device approval  25
Figure 16 Market split between wellbeing and medical 2016-25  26
Figure 17 Current World Textile Market by Sector (2016)  27
Figure 18 The Global Textile Market By Sector ($ Millions)  27
Figure 19 Compound Annual Growth Rates (CAGR) by Sector (2016-25)  28
Figure 20 The Global Textile Market in 2022  29
Figure 21 The Global Textile Market in 2025  30
Figure 22 Textile Market Evolution (2012-2025)  30
Figure 23 Total Value of Nanomaterials in Textiles 2012-2022 ($ Millions)  31
Figure 24 Value of Nanomaterials in Textiles by Sector 2016-2025 ($ Millions) 32
Figure 25 Adidas miCoach Connect Heart Rate Monitor  36
Figure 26 Sensoria’s Hear[t] Rate Monitoring Garments . 37
Figure 27 Flexible components used in Google’s Project Jacquard  40
Figure 28 Google and Levi’s Smart Jacket  41
Figure 29 Embedded electronics Google’s Project Jacquard  42
Figure 30 Samsung’s WELT ‘smart’ belt  43
Figure 31 Samsung Body Compass at CES16  44
Figure 32 Lumo Run washable motion sensor  45
Figure 33 OMSignal’s Smart Bra  49
Figure 34 PoloTech Shirt from Ralph Lauren  50
Figure 35 Hexoskin Data Acquisition and Processing  51
Figure 36 Peak+™ Hear[t] Rate Monitoring Garment  52
Figure 37 StretchSense CEO Ben O’Brien, with a fabric stretch sensor  53
Figure 38 C3fit Pulse from Goldwin Inc  55
Figure 39 The Antelope Tank-Top  58
Figure 40 Sportswear with integrated sensors from Textronix  60
Figure 41 AdvanPro’s pressure sensing insoles  61
Figure 42 AdvanPro’s pressure sensing textile  62
Figure 43 Tamicare 3D Printing Sensors and Apparel  63
Figure 44 Smart clothing using stainless steel yarns and textile sensors from AiQ  65
Figure 45 EHO Smart Sock  69
Figure 46 BeBop Smart Car Seat Sensor  71
Figure 47 Non-transparent printed sensors from Fraunhofer ISC  73
Figure 48 Clim8 Intelligent Heat Regulating Shirt  74
Figure 49 Temperature regulating smart fabric printed at UC San Diego  76
Figure 50 Intelligent Textiles Ltd smart uniform  79
Figure 51 BAE Systems Broadsword Spine  80
Figure 52 LG Chem cable-shaped lithium-ion battery powers an LED display even when twisted and strained  81
Figure 53 Supercapacitor yarn made of niobium nanowires  84
Figure 54 Sphelar Textile  89
Figure 55 Sphelar Textile Solar Cells  89
Figure 56 Katy Perry wears Cute Circuit in 2010  91
Figure 57 Cute Circuit K Dress  93
Figure 58 MAKEFASHION runway at the Brother’s “Back to Business” conference, Nashville 2016  94
Figure 59 Covestro material with LEDs are positioned on formable films made from thermoplastic polyurethane (TPU).  95
Figure 60 Unseen headpiece, made of 4000 conductive Swarovski stones, changes color to correspond with localized brain activity  96
Figure 61 Eighthsense a coded couture piece.  97
Figure 62 Durex Fundawear  98
Figure 63 Printed fabric sensors from the University of Tokyo  100
Figure 64 Tony Kanaan’s shirt with electrically conductive nano-fibers  107
Figure 65 Panasonic stretchable resin technology  109
Figure 66 Nanoflex moniroring system  111
Figure 67 Knitted strain sensors  113
Figure 68 Chain Mail Fabric for Smart Textiles  114
Figure 69 Electroplated Fabric  115
Figure 70 LG Innotek flexible textile pressure sensors  118
Figure 71 Smart Footwear installed with fabric sensors. (Credit: Image courtesy of The Hong Kong Polytechnic University)  120
Figure 72 SOFTCEPTOR™ textile strain sensors  122
Figure 73 conductive polymer composite coating for pressure sensing  123
Figure 74 Fraunhofer ISC_ printed sensor  125
Figure 75 The graphene-coated yarn sensor. (Image: ETRI)  128
Figure 76 Supercapacitor yarn made of niobium nanowires  131
Figure 77 StretchSense Energy Harvesting Kit  134
Figure 78 Energy harvesting textiles at the University of Southampton  135
Figure 79 Polyera Wove Flexible Screen  139

If you compare that with the table of contents for the May 2016 report in my June 2, 2016 posting, you can see the difference.

Here’s one last tidbit, a Sept. 15, 2016 news item on phys.org highlights another wearable technology report,

Wearable tech, which was seeing sizzling sales growth a year ago [2015], is cooling this year amid consumer hesitation over new devices, a survey showed Thursday [Sept. 15, 2016].

The research firm IDC said it expects global sales of wearables to grow some 29.4 percent to some 103 million units in 2016.

That follows 171 percent growth in 2015, fueled by the launch of the Apple Watch and a variety of fitness bands.

“It is increasingly becoming more obvious that consumers are not willing to deal with technical pain points that have to date been associated with many wearable devices,” said IDC analyst Ryan Reith.

So-called basic wearables—including fitness bands and other devices that do not run third party applications—will make up the lion’s share of the market with some 80.7 million units shipped this year, according to IDC.

According to IDC, it seems that the short term does not promise the explosive growth of the previous year but that new generations of wearable technology, according to both IDC and Cientifica, offer considerable promise for the market.