Tag Archives: Seth Darling

Technology for mopping up oil spills

It’s a little disheartening to write about technology for mopping up oils spills as there doesn’t to be much improvement in the situation as Adele Peters notes in her June 4, 2021 article (A decade after Deepwater Horizon, we’re still cleaning up oil spills the same way) for Fast Company (Note: Links have been removed),

Off the coastline of Sri Lanka, where a burning cargo ship has been spilling toxic chemicals and plastic pellets over the past two weeks, the government is preparing for the next possible stage of the disaster: As the ship sinks, it may also spill some of the hundreds of tons of oil in its fuel tanks.

The government is readying oil dispersants, booms, and oil skimmers, all tools that were used in the massive Deepwater Horizon oil spill in the Gulf of Mexico in 2010. They didn’t work perfectly then—more than 1,000 miles of shoreline were polluted—and more than a decade later, they’re still commonly used. But solutions that might work better are under development, including reusable sponges that can suck up oil both on the surface and underwater.

Dispersants, one common tool now, are chemicals designed to break up the oil into tiny droplets so that, in theory, microorganisms in the water can break down the oil more easily. But at least one study found that dispersant could harm those organisms. Deep-sea coral also appears to suffer more from the mix of dispersant and oil than oil alone. Booms are designed to contain oil on the surface so it can be scraped off with a skimmer, but that only works if the water’s relatively calm, and it doesn’t deal with oil below the surface. The oil on the surface can also be burned, but it creates a plume of thick black smoke. “That does get rid of the oil from the water, but then it turns a water pollution problem into an air pollution problem,” says Seth Darling, a senior scientist at Argonne National Laboratory who developed an alternative called the Oleo Sponge [emphasis mine].

… a team from two German universities that developed a system of wood chips that can be dropped in the water to collect oil even in rough weather, when current tools don’t work well. The system is ready for deployment if a spill happens in the Baltic Sea. Another earlier-stage solution proposes using a robot to detect and capture oil.

I’m glad to see at least one new oil spill cleanup technology being readied for deployment in Peters’ June 4, 2021 article, we should be preparing for more spills as the Arctic melts and plans are made to develop new shipping routes.

Amongst other oil spill cleanup technologies, Peters mentions the ‘Oleo Sponge’, which was featured here in a March 30, 2017 posting when researchers were looking for investors to commercialize the product. According to Peters the oleo sponge hasn’t yet made it to market; it’s a fate many of these technologies are destined to meet. Meanwhile, scientists continue to develop new methods and techniques for mopping up oil spills as safely as possible. For example, there’s an oil spill sucking robot mentioned in my October 30, 2020 posting, which features yet another article by Peters.

In the summer of 2020 there were two major oil spills, one in the Russian Arctic and one in an ecologically sensitive area near Mauritius. For more about those events, there’s an August 14, 2020 posting, which starts with news of an oil spill technology featuring dog fur and then focuses primarily on the oil spill in the Russian Arctic with a brief mention of the spill near Mauritius in June 2020 (scroll down to the ‘Exceptionally warm weather’ subhead and see the paragraph above it for the mention and a link to a story).

Would you like to invest in the Argonne National Laboratory’s reusable oil spill sponge?

A March 7, 2017 news item on phys.org describes some of the US Argonne National Laboratory’s research into oil spill cleanup technology,

When the Deepwater Horizon drilling pipe blew out seven years ago, beginning the worst oil spill [BP oil spill in the Gulf of Mexico] in U.S. history, those in charge of the recovery discovered a new wrinkle: the millions of gallons of oil bubbling from the sea floor weren’t all collecting on the surface where it could be skimmed or burned. Some of it was forming a plume and drifting through the ocean under the surface.

Now, scientists at the U.S. Department of Energy’s (DOE) Argonne National Laboratory have invented a new foam, called Oleo Sponge, that addresses this problem. The material not only easily adsorbs oil from water, but is also reusable and can pull dispersed oil from the entire water column—not just the surface.

A March 6, 2017 Argonne National Laboratory news release (also on EurekAlert) by Louise Lerner, which originated the news item, provides more information about the work,

“The Oleo Sponge offers a set of possibilities that, as far as we know, are unprecedented,” said co-inventor Seth Darling, a scientist with Argonne’s Center for Nanoscale Materials and a fellow of the University of Chicago’s Institute for Molecular Engineering.

We already have a library of molecules that can grab oil, but the problem is how to get them into a useful structure and bind them there permanently.

The scientists started out with common polyurethane foam, used in everything from furniture cushions to home insulation. This foam has lots of nooks and crannies, like an English muffin, which could provide ample surface area to grab oil; but they needed to give the foam a new surface chemistry in order to firmly attach the oil-loving molecules.

Previously, Darling and fellow Argonne chemist Jeff Elam had developed a technique called sequential infiltration synthesis, or SIS, which can be used to infuse hard metal oxide atoms within complicated nanostructures.

After some trial and error, they found a way to adapt the technique to grow an extremely thin layer of metal oxide “primer” near the foam’s interior surfaces. This serves as the perfect glue for attaching the oil-loving molecules, which are deposited in a second step; they hold onto the metal oxide layer with one end and reach out to grab oil molecules with the other.

The result is Oleo Sponge, a block of foam that easily adsorbs oil from the water. The material, which looks a bit like an outdoor seat cushion, can be wrung out to be reused—and the oil itself recovered.

Oleo Sponge

At tests at a giant seawater tank in New Jersey called Ohmsett, the National Oil Spill Response Research & Renewable Energy Test Facility, the Oleo Sponge successfully collected diesel and crude oil from both below and on the water surface.

“The material is extremely sturdy. We’ve run dozens to hundreds of tests, wringing it out each time, and we have yet to see it break down at all,” Darling said.

Oleo Sponge could potentially also be used routinely to clean harbors and ports, where diesel and oil tend to accumulate from ship traffic, said John Harvey, a business development executive with Argonne’s Technology Development and Commercialization division.

Elam, Darling and the rest of the team are continuing to develop the technology.

“The technique offers enormous flexibility, and can be adapted to other types of cleanup besides oil in seawater. You could attach a different molecule to grab any specific substance you need,” Elam said.

The team is actively looking to commercialize [emphasis mine] the material, Harvey said; those interested in licensing the technology or collaborating with the laboratory on further development may contact partners@anl.gov.

Here’s a link to and a citation for the paper,

Advanced oil sorbents using sequential infiltration synthesis by Edward Barry, Anil U. Mane, Joseph A. Libera, Jeffrey W. Elam, and Seth B. Darling. J. Mater. Chem. A, 2017,5, 2929-2935 DOI: 10.1039/C6TA09014A First published online 11 Jan 2017

This paper is behind a paywall.

The two most recent posts here featuring oil spill technology are my Nov. 3, 2016 piece titled: Oil spill cleanup nanotechnology-enabled solution from A*STAR and my Sept. 15, 2016 piece titled: Canada’s Ingenuity Lab receives a $1.7M grant to develop oil recovery system for oil spills. I hope that one of these days someone manages to commercialize at least one of the new oil spill technologies. It seems that there hasn’t been much progress since the BP (Deepwater Horizon) oil spill. If someone has better information than I do about the current state of oil spill cleanup technologies, please do leave a comment.