Tag Archives: Stockholm University

Microsoft, D-Wave Systems, quantum computing, and quantum supremacy?

Before diving into some of the latest quantum computing doings, here’s why quantum computing is so highly prized and chased after, from the Quantum supremacy Wikipedia entry, Note: Links have been removed,

In quantum computing, quantum supremacy or quantum advantage is the goal of demonstrating that a programmable quantum computer can solve a problem that no classical computer can solve in any feasible amount of time, irrespective of the usefulness of the problem.[1][2][3] The term was coined by John Preskill in 2011,[1][4] but the concept dates to Yuri Manin’s 1980[5] and Richard Feynman’s 1981[6] proposals of quantum computing.

Quantum supremacy and quantum advantage have been mentioned a few times here over the years. You can check my March 6, 2020 posting for when researchers from the University of California at Santa Barbara claimed quantum supremacy and my July 31, 2023 posting for when D-Wave Systems claimed a quantum advantage on optimization problems. I’d understood quantum supremacy and quantum advantage to be synonymous but according the article in Betakit (keep scrolling down to the D-Wave subhead and then, to ‘A controversy of sorts’ subhead in this posting), that’s not so.

The latest news on the quantum front comes from Microsoft (February 2025) and D-Wave systems (March 2025).

Microsoft claims a new state of matter for breakthroughs in quantum computing

Here’s the February 19, 2025 news announcement from Microsoft’s Chetan Nayak, Technical Fellow and Corporate Vice President of Quantum Hardware, Note: Links have been removed,

Quantum computers promise to transform science and society—but only after they achieve the scale that once seemed distant and elusive, and their reliability is ensured by quantum error correction. Today, we’re announcing rapid advancements on the path to useful quantum computing:

  • Majorana 1: the world’s first Quantum Processing Unit (QPU) powered by a Topological Core, designed to scale to a million qubits on a single chip.
  • A hardware-protected topological qubit: research published today in Nature, along with data shared at the Station Q meeting, demonstrate our ability to harness a new type of material and engineer a radically different type of qubit that is small, fast, and digitally controlled.
  • A device roadmap to reliable quantum computation: our path from single-qubit devices to arrays that enable quantum error correction.
  • Building the world’s first fault-tolerant prototype (FTP) based on topological qubits: Microsoft is on track to build an FTP of a scalable quantum computer—in years, not decades—as part of the final phase of the Defense Advanced Research Projects Agency (DARPA) Underexplored Systems for Utility-Scale Quantum Computing (US2QC) program.

Together, these milestones mark a pivotal moment in quantum computing as we advance from scientific exploration to technological innovation.

Harnessing a new type of material

All of today’s announcements build on our team’s recent breakthrough: the world’s first topoconductor. This revolutionary class of materials enables us to create topological superconductivity, a new state of matter that previously existed only in theory. The advance stems from Microsoft’s innovations in the design and fabrication of gate-defined devices that combine indium arsenide (a semiconductor) and aluminum (a superconductor). When cooled to near absolute zero and tuned with magnetic fields, these devices form topological superconducting nanowires with Majorana Zero Modes (MZMs) at the wires’ ends.

Chris Vallance’s February 19, 2025 article for the British Broadcasting Corporation (BBC) news online website provides a description of Microsoft’s claims and makes note of the competitive quantum research environment,

Microsoft has unveiled a new chip called Majorana 1 that it says will enable the creation of quantum computers able to solve “meaningful, industrial-scale problems in years, not decades”.

It is the latest development in quantum computing – tech which uses principles of particle physics to create a new type of computer able to solve problems ordinary computers cannot.

Creating quantum computers powerful enough to solve important real-world problems is very challenging – and some experts believe them to be decades away.

Microsoft says this timetable can now be sped up because of the “transformative” progress it has made in developing the new chip involving a “topological conductor”, based on a new material it has produced.

The firm believes its topoconductor has the potential to be as revolutionary as the semiconductor was in the history of computing.

But experts have told the BBC more data is needed before the significance of the new research – and its effect on quantum computing – can be fully assessed.

Jensen Huang – boss of the leading chip firm, Nvidia – said in January he believed “very useful” quantum computing would come in 20 years.

Chetan Nayak, a technical fellow of quantum hardware at Microsoft, said he believed the developments would shake up conventional thinking about the future of quantum computers.

“Many people have said that quantum computing, that is to say useful quantum computers, are decades away,” he said. “I think that this brings us into years rather than decades.”

Travis Humble, director of the Quantum Science Center of Oak Ridge National Laboratory in the US, said he agreed Microsoft would now be able to deliver prototypes faster – but warned there remained work to do.

“The long term goals for solving industrial applications on quantum computers will require scaling up these prototypes even further,” he said.

While rivals produced a steady stream of announcements – notably Google’s “Willow” at the end of 2024 – Microsoft seemed to be taking longer.

Pursuing this approach was, in the company’s own words, a “high-risk, high-rewards” strategy, but one it now believes is going to pay off.

If you have the time, do read Vallance’s February 19, 2025 article.

The research paper

Purdue University’s (Indiana, US) February 25, 2025 news release on EurekAlert announces publication of the research, Note: Links have been removed,

Microsoft Quantum published an article in Nature on Feb. 19 [2025] detailing recent advances in the measurement of quantum devices that will be needed to realize a topological quantum computer. Among the authors are Microsoft scientists and engineers who conduct research at Microsoft Quantum Lab West Lafayette, located at Purdue University. In an announcement by Microsoft Quantum, the team describes the operation of a device that is a necessary building block for a topological quantum computer. The published results are an important milestone along the path to construction of quantum computers that are potentially more robust and powerful than existing technologies.

“Our hope for quantum computation is that it will aid chemists, materials scientists and engineers working on the design and manufacturing of new materials that are so important to our daily lives,” said Michael Manfra, scientific director of Microsoft Quantum Lab West Lafayette and the Bill and Dee O’Brien Distinguished Professor of Physics and Astronomy, professor of materials engineering, and professor of electrical and computer engineering at Purdue. “The promise of quantum computation is in accelerating scientific discovery and its translation into useful technology. For example, if quantum computers reduce the time and cost to produce new lifesaving therapeutic drugs, that is real societal impact.” 

The Microsoft Quantum Lab West Lafayette team advanced the complex layered materials that make up the quantum plane of the full device architecture used in the tests. Microsoft scientists working with Manfra are experts in advanced semiconductor growth techniques, including molecular beam epitaxy, that are used to build low-dimensional electron systems that form the basis for quantum bits, or qubits. They built the semiconductor and superconductor layers with atomic layer precision, tailoring the material’s properties to those needed for the device architecture.

Manfra, a member of the Purdue Quantum Science and Engineering Institute, credited the strong relationship between Purdue and Microsoft, built over the course of a decade, with the advances conducted at Microsoft Quantum Lab West Lafayette. In 2017 Purdue deepened its relationship with Microsoft with a multiyear agreement that includes embedding Microsoft employees with Manfra’s research team at Purdue.

“This was a collaborative effort by a very sophisticated team, with a vital contribution from the Microsoft scientists at Purdue,” Manfra said. “It’s a Microsoft team achievement, but it’s also the culmination of a long-standing partnership between Purdue and Microsoft. It wouldn’t have been possible without an environment at Purdue that was conducive to this mode of work — I attempted to blend industrial with academic research to the betterment of both communities. I think that’s a success story.”

Quantum science and engineering at Purdue is a pillar of the Purdue Computes initiative, which is focused on advancing research in computing, physical AI, semiconductors and quantum technologies.

“This research breakthrough in the measurement of the state of quasi particles is a milestone in the development of topological quantum computing, and creates a watershed moment in the semiconductor-superconductor hybrid structure,” Purdue President Mung Chiang said. “Marking also the latest success in the strategic initiative of Purdue Computes, the deep collaboration that Professor Manfra and his team have created with the Microsoft Quantum Lab West Lafayette on the Purdue campus exemplifies the most impactful industry research partnership at any American university today.”

Most approaches to quantum computers rely on local degrees of freedom to encode information. The spin of an electron is a classic example of a qubit. But an individual spin is prone to disturbance — by relatively common things like heat, vibrations or interactions with other quantum particles — which can corrupt quantum information stored in the qubit, necessitating a great deal of effort in detecting and correcting errors. Instead of spin, topological quantum computers store information in a more distributed manner; the qubit state is encoded in the state of many particles acting in concert. Consequently, it is harder to scramble the information as the state of all the particles must be changed to alter the qubit state.

In the Nature paper, the Microsoft team was able to accurately and quickly measure the state of quasi particles that form the basis of the qubit.

“The device is used to measure a basic property of a topological qubit quickly,” Manfra said. “The team is excited to build on these positive results.”

“The team in West Lafayette pushed existing epitaxial technology to a new state-of-the-art for semiconductor-superconductor hybrid structures to ensure a perfect interface between each of the building blocks of the Microsoft hybrid system,” said Sergei Gronin, a Microsoft Quantum Lab scientist.

“The materials quality that is required for quantum computing chips necessitates constant improvements, so that’s one of the biggest challenges,” Gronin said. “First, we had to adjust and improve semiconductor technology to meet a new level that nobody was able to achieve before. But equally important was how to create this hybrid system. To do that, we had to merge a semiconducting part and a superconducting part. And that means you need to perfect the semiconductor and the superconductor and perfect the interface between them.”

While work discussed in the Nature article was performed by Microsoft employees, the exposure to industrial-scale research and development is an outstanding opportunity for Purdue students in Manfra’s academic group as well. John Watson, Geoffrey Gardner and Saeed Fallahi, who are among the coauthors of the paper, earned their doctoral degrees under Manfra and now work for Microsoft Quantum at locations in Redmond, Washington, and Copenhagen, Denmark. Most of Manfra’s former students now work for quantum computing companies, including Microsoft. Tyler Lindemann, who works in the West Lafayette lab and helped to build the hybrid semiconductor-superconductor structures required for the device, is earning a doctoral degree from Purdue under Manfra’s supervision.

“Working in Professor Manfra’s lab in conjunction with my work for Microsoft Quantum has given me a head start in my professional development, and been fruitful for my academic work,” Lindemann said. “At the same time, many of the world-class scientists and engineers at Microsoft Quantum have some background in academia, and being able to draw from their knowledge and experience is an indispensable resource in my graduate studies. From both perspectives, it’s a great opportunity.”

Here’s a link to and a citation for the paper,

Interferometric single-shot parity measurement in InAs–Al hybrid devices by Microsoft Azure Quantum, Morteza Aghaee, Alejandro Alcaraz Ramirez, Zulfi Alam, Rizwan Ali, Mariusz Andrzejczuk, Andrey Antipov, Mikhail Astafev, Amin Barzegar, Bela Bauer, Jonathan Becker, Umesh Kumar Bhaskar, Alex Bocharov, Srini Boddapati, David Bohn, Jouri Bommer, Leo Bourdet, Arnaud Bousquet, Samuel Boutin, Lucas Casparis, Benjamin J. Chapman, Sohail Chatoor, Anna Wulff Christensen, Cassandra Chua, Patrick Codd, William Cole, Paul Cooper, Fabiano Corsetti, Ajuan Cui, Paolo Dalpasso, Juan Pablo Dehollain, Gijs de Lange, Michiel de Moor, Andreas Ekefjärd, Tareq El Dandachi, Juan Carlos Estrada Saldaña, Saeed Fallahi, Luca Galletti, Geoff Gardner, Deshan Govender, Flavio Griggio, Ruben Grigoryan, Sebastian Grijalva, Sergei Gronin, Jan Gukelberger, Marzie Hamdast, Firas Hamze, Esben Bork Hansen, Sebastian Heedt, Zahra Heidarnia, Jesús Herranz Zamorano, Samantha Ho, Laurens Holgaard, John Hornibrook, Jinnapat Indrapiromkul, Henrik Ingerslev, Lovro Ivancevic, Thomas Jensen, Jaspreet Jhoja, Jeffrey Jones, Konstantin V. Kalashnikov, Ray Kallaher, Rachpon Kalra, Farhad Karimi, Torsten Karzig, Evelyn King, Maren Elisabeth Kloster, Christina Knapp, Dariusz Kocon, Jonne V. Koski, Pasi Kostamo, Mahesh Kumar, Tom Laeven, Thorvald Larsen, Jason Lee, Kyunghoon Lee, Grant Leum, Kongyi Li, Tyler Lindemann, Matthew Looij, Julie Love, Marijn Lucas, Roman Lutchyn, Morten Hannibal Madsen, Nash Madulid, Albert Malmros, Michael Manfra, Devashish Mantri, Signe Brynold Markussen, Esteban Martinez, Marco Mattila, Robert McNeil, Antonio B. Mei, Ryan V. Mishmash, Gopakumar Mohandas, Christian Mollgaard, Trevor Morgan, George Moussa, Chetan Nayak, Jens Hedegaard Nielsen, Jens Munk Nielsen, William Hvidtfelt Padkar Nielsen, Bas Nijholt, Mike Nystrom, Eoin O’Farrell, Thomas Ohki, Keita Otani, Brian Paquelet Wütz, Sebastian Pauka, Karl Petersson, Luca Petit, Dima Pikulin, Guen Prawiroatmodjo, Frank Preiss, Eduardo Puchol Morejon, Mohana Rajpalke, Craig Ranta, Katrine Rasmussen, David Razmadze, Outi Reentila, David J. Reilly, Yuan Ren, Ken Reneris, Richard Rouse, Ivan Sadovskyy, Lauri Sainiemi, Irene Sanlorenzo, Emma Schmidgall, Cristina Sfiligoj, Mustafeez Bashir Shah, Kevin Simoes, Shilpi Singh, Sarat Sinha, Thomas Soerensen, Patrick Sohr, Tomas Stankevic, Lieuwe Stek, Eric Stuppard, Henri Suominen, Judith Suter, Sam Teicher, Nivetha Thiyagarajah, Raj Tholapi, Mason Thomas, Emily Toomey, Josh Tracy, Michelle Turley, Shivendra Upadhyay, Ivan Urban, Kevin Van Hoogdalem, David J. Van Woerkom, Dmitrii V. Viazmitinov, Dominik Vogel, John Watson, Alex Webster, Joseph Weston, Georg W. Winkler, Di Xu, Chung Kai Yang, Emrah Yucelen, Roland Zeisel, Guoji Zheng & Justin Zilke. Nature 638, 651–655 (2025). DOI: https://doi.org/10.1038/s41586-024-08445-2 Published online: 19 February 2025 Issue Date: 20 February 2025

This paper is open access. Note: I usually tag all of the authors but not this time.

Controversy over this and previous Microsoft quantum computing claims

Elizabeth Hlavinka’s March 17, 2025 article for Salon.com provides an overview, Note: Links have been removed,

The matter making up the world around us has long-since been organized into three neat categories: solids, liquids and gases. But last month [February 2025], Microsoft announced that it had allegedly discovered another state of matter originally theorized to exist in 1937. 

This new state of matter called the Majorana zero mode is made up of quasiparticles, which act as their own particle and antiparticle. The idea is that the Majorana zero mode could be used to build a quantum computer, which could help scientists answer complex questions that standard computers are not capable of solving, with implications for medicine, cybersecurity and artificial intelligence.

In late February [2025], Sen. Ted Cruz presented Microsoft’s new computer chip at a congressional hearing, saying, “Technologies like this new chip I hold in the palm of my hand, the Majorana 1 quantum chip, are unlocking a new era of computing that will transform industries from health care to energy, solving problems that today’s computers simply cannot.”

However, Microsoft’s announcement, claiming a “breakthrough in quantum computing,” was met with skepticism from some physicists in the field. Proving that this form of quantum computing can work requires first demonstrating the existence of Majorana quasiparticles, measuring what the Majorana particles are doing, and creating something called a topological qubit used to store quantum information.

But some say that not all of the data necessary to prove this has been included in the research paper published in Nature, on which this announcement is based. And due to a fraught history of similar claims from the company being disputed and ultimately rescinded, some are extra wary of the results. [emphasis mine]

It’s not the first time Microsoft has faced backlash from presenting findings in the field. In 2018, the company reported that they had detected the presence of Majorana zero-modes in a research paper, but it was retracted by Nature, the journal that published it after a report from independent experts put their findings under more intense scrutiny.

In the [2018] report, four physicists not involved in the research concluded that it did not appear that Microsoft had intentionally misrepresented the data, but instead seemed to be “caught up in the excitement of the moment [emphasis mine].”

Establishing the existence of these particles is extremely complex in part because disorder in the device can create signals that mimic these quasiparticles when they are not actually there. 

Modern computers in use today are encoded in bits, which can either be in a zero state (no current flowing through them), or a one state (current flowing.) These bits work together to send information and signals that communicate with the computer, powering everything from cell phones to video games.

Companies like Google, IBM and Amazon have invested in designing another form of quantum computer that uses chips built with “qubits,” or quantum bits. Qubits can exist in both zero and one states at the same time due to a phenomenon called superposition. 

However, qubits are subject to external noise from the environment that can affect their performance, said Dr. Paolo Molignini, a researcher in theoretical quantum physics at Stockholm University.

“Because qubits are in a superposition of zero and one, they are very prone to errors and they are very prone to what is called decoherence, which means there could be noise, thermal fluctuations or many things that can collapse the state of the qubits,” Molignini told Salon in a video call. “Then you basically lose all of the information that you were encoding.”

In December [2024], Google said its quantum computer could perform a calculation that a standard computer could complete in 10 septillion years — a period far longer than the age of the universe — in just under five minutes.

However, a general-purpose computer would require billions of qubits, so these approaches are still a far cry from having practical applications, said Dr. Patrick Lee, a physicist at the Massachusetts Institute of Technology [MIT], who co-authored the report leading to the 2018 Nature paper’s retraction.

Microsoft is taking a different approach to quantum computing by trying to develop  a topological qubit, which has the ability to store information in multiple places at once. Topological qubits exist within the Majorana zero states and are appealing because they can theoretically offer greater protection against environmental noise that destroys information within a quantum system.

Think of it like an arrow, where the arrowhead holds a portion of the information and the arrow tail holds the rest, Lee said. Distributing information across space like this is called topological protection.

“If you are able to put them far apart from each other, then you have a chance of maintaining the identity of the arrow even if it is subject to noise,” Lee told Salon in a phone interview. “The idea is that if the noise affects the head, it doesn’t kill the arrow and if it affects only the tail it doesn’t kill your arrow. It has to affect both sides simultaneously to kill your arrow, and that is very unlikely if you are able to put them apart.”

… Lee believes that even if the data doesn’t entirely prove that topological qubits exist in the Majorana zero-state, it still represents a scientific advancement. But he noted that several important issues need to be solved before it has practical implications. For one, the coherence time of these particles — or how long they can exist without being affected by environmental noise — is still very short, he explained.

“They make a measurement, come back, and the qubit has changed, so you have lost your coherence,” Lee said. “With this very short time, you cannot do anything with it.”

“I just wish they [Microsoft] were a bit more careful with their claims because I fear that if they don’t measure up to what they are saying, there might be a backlash at some point where people say, ‘You promised us all these fancy things and where are they now?’” Molignini said. “That might damage the entire quantum community, not just themselves.”

Iif you have the time, please read Hlavinka’s March 17, 2025 article in its entirety .

D-Wave Quantum Systems claims quantum supremacy over real world problem solution

A March 15, 2025 article by Bob Yirka for phys.org announces the news from D-Wave Quantum Systems. Note: The company, which had its headquarters in Canada (Burnaby, BC) now seems to be a largely US company with its main headquarters in Palo Alto, California and an ancillary or junior (?) headquarters in Canada, Note: A link has been removed,

A team of quantum computer researchers at quantum computer maker D-Wave, working with an international team of physicists and engineers, is claiming that its latest quantum processor has been used to run a quantum simulation faster than could be done with a classical computer.

In their paper published in the journal Science, the group describes how they ran a quantum version of a mathematical approximation regarding how matter behaves when it changes states, such as from a gas to a liquid—in a way that they claim would be nearly impossible to conduct on a traditional computer.

Here’s a March 12, 2025 D-Wave Systems (now D-Wave Quantum Systems) news release touting its real world problem solving quantum supremacy,

New landmark peer-reviewed paper published in Science, “Beyond-Classical Computation in Quantum Simulation,” unequivocally validates D-Wave’s achievement of the world’s first and only demonstration of quantum computational supremacy on a useful, real-world problem

Research shows D-Wave annealing quantum computer performs magnetic materials simulation in minutes that would take nearly one million years and more than the world’s annual electricity consumption to solve using a classical supercomputer built with GPU clusters

D-Wave Advantage2 annealing quantum computer prototype used in supremacy achievement, a testament to the system’s remarkable performance capabilities

PALO ALTO, Calif. – March 12, 2025 – D-Wave Quantum Inc. (NYSE: QBTS) (“D-Wave” or the “Company”), a leader in quantum computing systems, software, and services and the world’s first commercial supplier of quantum computers, today announced a scientific breakthrough published in the esteemed journal Science, confirming that its annealing quantum computer outperformed one of the world’s most powerful classical supercomputers in solving complex magnetic materials simulation problems with relevance to materials discovery. The new landmark peer-reviewed paper, Beyond-Classical Computation in Quantum Simulation,” validates this achievement as the world’s first and only demonstration of quantum computational supremacy on a useful problem.

An international collaboration of scientists led by D-Wave performed simulations of quantum dynamics in programmable spin glasses—computationally hard magnetic materials simulation problems with known applications to business and science—on both D-Wave’s Advantage2TM prototype annealing quantum computer and the Frontier supercomputer at the Department of Energy’s Oak Ridge National Laboratory. The work simulated the behavior of a suite of lattice structures and sizes across a variety of evolution times and delivered a multiplicity of important material properties. D-Wave’s quantum computer performed the most complex simulation in minutes and with a level of accuracy that would take nearly one million years using the supercomputer. In addition, it would require more than the world’s annual electricity consumption to solve this problem using the supercomputer, which is built with graphics processing unit (GPU) clusters.

“This is a remarkable day for quantum computing. Our demonstration of quantum computational supremacy on a useful problem is an industry first. All other claims of quantum systems outperforming classical computers have been disputed or involved random number generation of no practical value,” said Dr. Alan Baratz, CEO of D-Wave. “Our achievement shows, without question, that D-Wave’s annealing quantum computers are now capable of solving useful problems beyond the reach of the world’s most powerful supercomputers. We are thrilled that D-Wave customers can use this technology today to realize tangible value from annealing quantum computers.”

Realizing an Industry-First Quantum Computing Milestone
The behavior of materials is governed by the laws of quantum physics. Understanding the quantum nature of magnetic materials is crucial to finding new ways to use them for technological advancement, making materials simulation and discovery a vital area of research for D-Wave and the broader scientific community. Magnetic materials simulations, like those conducted in this work, use computer models to study how tiny particles not visible to the human eye react to external factors. Magnetic materials are widely used in medical imaging, electronics, superconductors, electrical networks, sensors, and motors.

“This research proves that D-Wave’s quantum computers can reliably solve quantum dynamics problems that could lead to discovery of new materials,” said Dr. Andrew King, senior distinguished scientist at D-Wave. “Through D-Wave’s technology, we can create and manipulate programmable quantum matter in ways that were impossible even a few years ago.”

Materials discovery is a computationally complex, energy-intensive and expensive task. Today’s supercomputers and high-performance computing (HPC) centers, which are built with tens of thousands of GPUs, do not always have the computational processing power to conduct complex materials simulations in a timely or energy-efficient manner. For decades, scientists have aspired to build a quantum computer capable of solving complex materials simulation problems beyond the reach of classical computers. D-Wave’s advancements in quantum hardware have made it possible for its annealing quantum computers to process these types of problems for the first time.

“This is a significant milestone made possible through over 25 years of research and hardware development at D-Wave, two years of collaboration across 11 institutions worldwide, and more than 100,000 GPU and CPU hours of simulation on one of the world’s fastest supercomputers as well as computing clusters in collaborating institutions,” said Dr. Mohammad Amin, chief scientist at D-Wave. “Besides realizing Richard Feynman’s vision of simulating nature on a quantum computer, this research could open new frontiers for scientific discovery and quantum application development.” 

Advantage2 System Demonstrates Powerful Performance Gains
The results shown in “Beyond-Classical Computation in Quantum Simulation” were enabled by D-Wave’s previous scientific milestones published in Nature Physics (2022) and Nature (2023), which theoretically and experimentally showed that quantum annealing provides a quantum speedup in complex optimization problems. These scientific advancements led to the development of the Advantage2 prototype’s fast anneal feature, which played an essential role in performing the precise quantum calculations needed to demonstrate quantum computational supremacy.

“The broader quantum computing research and development community is collectively building an understanding of the types of computations for which quantum computing can overtake classical computing. This effort requires ongoing and rigorous experimentation,” said Dr. Trevor Lanting, chief development officer at D-Wave. “This work is an important step toward sharpening that understanding, with clear evidence of where our quantum computer was able to outperform classical methods. We believe that the ability to recreate the entire suite of results we produced is not possible classically. We encourage our peers in academia to continue efforts to further define the line between quantum and classical capabilities, and we believe these efforts will help drive the development of ever more powerful quantum computing technology.”

The Advantage2 prototype used to achieve quantum computational supremacy is available for customers to use today via D-Wave’s Leap™ real-time quantum cloud service. The prototype provides substantial performance improvements from previous-generation Advantage systems, including increased qubit coherence, connectivity, and energy scale, which enables higher-quality solutions to larger, more complex problems. Moreover, D-Wave now has an Advantage2 processor that is four times larger than the prototype used in this work and has extended the simulations of this paper from hundreds of qubits to thousands of qubits, which are significantly larger than those described in this paper.

Leading Industry Voices Echo Support
Dr. Hidetoshi Nishimori, Professor, Department of Physics, Tokyo Institute of Technology:
“This paper marks a significant milestone in demonstrating the real-world applicability of large-scale quantum computing. Through rigorous benchmarking of quantum annealers against state-of-the-art classical methods, it convincingly establishes a quantum advantage in tackling practical problems, revealing the transformative potential of quantum computing at an unprecedented scale.”

Dr. Seth Lloyd, Professor of Quantum Mechanical Engineering, MIT:
Although large-scale, fully error-corrected quantum computers are years in the future, quantum annealers can probe the features of quantum systems today. In an elegant paper, the D-Wave group has used a large-scale quantum annealer to uncover patterns of entanglement in a complex quantum system that lie far beyond the reach of the most powerful classical computer. The D-Wave result shows the promise of quantum annealers for exploring exotic quantum effects in a wide variety of systems.”

Dr. Travis Humble, Director of Quantum Science Center, Distinguished Scientist at Oak Ridge National Laboratory:
“ORNL seeks to expand the frontiers of computation through many different avenues, and benchmarking quantum computing for materials science applications provides critical input to our understanding of new computational capabilities.”

Dr. Juan Carrasquilla, Associate Professor at the Department of Physics, ETH Zürich:
“I believe these results mark a critical scientific milestone for D-Wave. They also serve as an invitation to the scientific community, as these results offer a strong benchmark and motivation for developing novel simulation techniques for out-of-equilibrium dynamics in quantum many-body physics. Furthermore, I hope these findings encourage theoretical exploration of the computational challenges involved in performing such simulations, both classically and quantum-mechanically.”

Dr. Victor Martin-Mayor, Professor of Theoretical Physics, Universidad Complutense de Madrid:
“This paper is not only a tour-de-force for experimental physics, it is also remarkable for the clarity of the results. The authors have addressed a problem that is regarded both as important and as very challenging to a classical computer. The team has shown that their quantum annealer performs better at this task than the state-of-the-art methods for classical simulation.”

Dr. Alberto Nocera, Senior Staff Scientist, The University of British Columbia:
“Our work shows the impracticability of state-of-the-art classical simulations to simulate the dynamics of quantum magnets, opening the door for quantum technologies based on analog simulators to solve scientific questions that may otherwise remain unanswered using conventional computers.”

About D-Wave Quantum Inc.
D-Wave is a leader in the development and delivery of quantum computing systems, software, and services. We are the world’s first commercial supplier of quantum computers, and the only company building both annealing and gate-model quantum computers. Our mission is to help customers realize the value of quantum, today. Our 5,000+ qubit Advantage™ quantum computers, the world’s largest, are available on-premises or via the cloud, supported by 99.9% availability and uptime. More than 100 organizations trust D-Wave with their toughest computational challenges. With over 200 million problems submitted to our Advantage systems and Advantage2™ prototypes to date, our customers apply our technology to address use cases spanning optimization, artificial intelligence, research and more. Learn more about realizing the value of quantum computing today and how we’re shaping the quantum-driven industrial and societal advancements of tomorrow: www.dwavequantum.com.

Forward-Looking Statements
Certain statements in this press release are forward-looking, as defined in the Private Securities Litigation Reform Act of 1995. These statements involve risks, uncertainties, and other factors that may cause actual results to differ materially from the information expressed or implied by these forward-looking statements and may not be indicative of future results. These forward-looking statements are subject to a number of risks and uncertainties, including, among others, various factors beyond management’s control, including the risks set forth under the heading “Risk Factors” discussed under the caption “Item 1A. Risk Factors” in Part I of our most recent Annual Report on Form 10-K or any updates discussed under the caption “Item 1A. Risk Factors” in Part II of our Quarterly Reports on Form 10-Q and in our other filings with the SEC. Undue reliance should not be placed on the forward-looking statements in this press release in making an investment decision, which are based on information available to us on the date hereof. We undertake no duty to update this information unless required by law.

Here’s a link to and a citation for the most recent paper,

Beyond-classical computation in quantum simulation by Andrew D. King , Alberto Nocera, Marek M. Rams, Jacek Dziarmaga, Roeland Wiersema, William Bernoudy, Jack Raymond, Nitin Kaushal, Niclas Heinsdorf, Richard Harris, Kelly Boothby, Fabio Altomare, Mohsen Asad, Andrew J. Berkley, Martin Boschnak, Kevin Chern, Holly Christiani, Samantha Cibere, Jake Connor, Martin H. Dehn, Rahul Deshpande, Sara Ejtemaee, Pau Farre, Kelsey Hamer, Emile Hoskinson, Shuiyuan Huang, Mark W. Johnson, Samuel Kortas, Eric Ladizinsky, Trevor Lanting, Tony Lai, Ryan Li, Allison J. R. MacDonald, Gaelen Marsden, Catherine C. McGeoch, Reza Molavi, Travis Oh, Richard Neufeld, Mana Norouzpour, Joel Pasvolsky, Patrick Poitras, Gabriel Poulin-Lamarre, Thomas Prescott, Mauricio Reis, Chris Rich, Mohammad Samani, Benjamin Sheldan, Anatoly Smirnov, Edward Sterpka, Berta Trullas Clavera, Nicholas Tsai, Mark Volkmann, Alexander M. Whiticar, Jed D. Whittaker, Warren Wilkinson, Jason Yao, T.J. Yi, Anders W. Sandvik, Gonzalo Alvarez, Roger G. Melko, Juan Carrasquilla, Marcel Franz, and Mohammad H. Amin. Science 12 Mar 2025 First Release DOI: 10.1126/science.ado6285

This paper appears to be open access.Note: I usually tag all of the authors but not this time either.

A controversy of sorts

Madison McLauchlan’s March 19, 2025 article for Betakit (website for Canadian Startup News & Tech Innovation), Note: Links have been removed,

Canadian-born company D-Wave Quantum Systems said it achieved “quantum supremacy” last week after publishing what it calls a groundbreaking paper in the prestigious journal Science. Despite the lofty term, Canadian experts say supremacy is not the be-all, end-all of quantum innovation. 

D-Wave, which has labs in Palo Alto, Calif., and Burnaby, BC, claimed in a statement that it has shown “the world’s first and only demonstration of quantum computational supremacy on a useful, real-world problem.”

Coined in the early 2010s by physicist John Preskill, quantum supremacy is the ability of a quantum computing system to solve a problem no classical computer can in a feasible amount of time. The metric makes no mention of whether the problem needs to be useful or relevant to real life. Google researchers published a paper in Nature in 2019 claiming they cleared that bar with the Sycamore quantum processor. Researchers at the University of Science and Technology in China claimed they demonstrated quantum supremacy several times. 

D-Wave’s attempt differs in that its researchers aimed to solve a real-world materials-simulation problem with quantum computing—one the company claims would be nearly impossible for a traditional computer to solve in a reasonable amount of time. D-Wave used an annealing designed to solve optimization problems. The problem is represented like an energy space, where the “lowest energy state” corresponds to the solution. 

While exciting, quantum supremacy is just one metric among several that mark the progress toward widely useful quantum computers, industry experts told BetaKit. 

“It is a very important and mostly academic metric, but certainly not the most important in the grand scheme of things, as it doesn’t take into account the usefulness of the algorithm,” said Martin Laforest, managing partner at Quantacet, a specialized venture capital fund for quantum startups. 

He added that Google and Xanadu’s [Xanadu Quantum Technologies based in Toronto, Canada] past claims to quantum supremacy were “extraordinary pieces of work, but didn’t unlock practicality.” 

Laforest, along with executives at Canadian quantum startups Nord Quantique and Photonic, say that the milestones of ‘quantum utility’ or ‘quantum advantage’ may be more important than supremacy. 

According to Quantum computing company Quera [QuEra?], quantum advantage is the demonstration of a quantum algorithm solving a real-world problem on a quantum computer faster than any classical algorithm running on any classical computer. On the other hand, quantum utility, according to IBM, refers to when a quantum computer is able to perform reliable computations at a scale beyond brute-force classical computing methods that provide exact solutions to computational problems. 

Error correction hasn’t traditionally been considered a requirement for quantum supremacy, but Laforest told BetaKit the term is “an ever-moving target, constantly challenged by advances in classical algorithms.” He added: “In my opinion, some level of supremacy or utility may be possible in niche areas without error correction, but true disruption requires it.”

Paul Terry, CEO of Vancouver-based Photonic, thinks that though D-Wave’s claim to quantum supremacy shows “continued progress to real value,” scalability is the industry’s biggest hurdle to overcome.

But as with many milestone claims in the quantum space, D-Wave’s latest innovation has been met with scrutiny from industry competitors and researchers on the breakthrough’s significance, claiming that classical computers have achieved similar results. Laforest echoed this sentiment.

“Personally, I wouldn’t say it’s an unequivocal demonstration of supremacy, but it is a damn nice experiment that once again shows the murky zone between traditional computing and early quantum advantage,” Laforest said.

Originally founded out of the University of British Columbia, D-Wave went public on the New York Stock Exchange just over two years ago through a merger with a special-purpose acquisition company in 2022. D-Wave became a Delaware-domiciled corporation as part of the deal.

Earlier this year, D-Wave’s stock price dropped after Nvidia CEO Jensen Huang publicly stated that he estimated that useful quantum computers were more than 15 years away. D-Wave’s stock price, which had been struggling, has seen a considerable bump in recent months alongside a broader boost in the quantum market. The price popped after its most recent earnings, shared right after its quantum supremacy announcement. 

The beat goes on

Some of this is standard in science. There’s always a debate over big claims and it’s not unusual for people to get over excited and have to make a retraction. Scientists are people too. That said, there’s a lot of money on the line and that appears to be making situation even more volatile than usual.

That last paragraph was completed on the morning of March 21, 2025 and later that afternoon I came across this March 21, 2025 article by Michael Grothaus for Fast Company, Note: Links have been removed,

Quantum computing stocks got pummeled yesterday, with the four most prominent public quantum computing companies—IonQ, Rigetti Computing, Quantum Computing Inc., and D-Wave Quantum Inc.—falling anywhere from over 9% to over 18%. The reason? A lot of it may have to do with AI chip giant Nvidia. Again.

Stocks crash yesterday on Nvidia quantum news

Yesterday was a bit of a bloodbath on the stock market for the four most prominent publicly traded quantum computing companies. …

All four of these quantum computing stocks [IonQ, Inc.; Rigetti Computing, Inc.; Quantum Computing Inc.; D-Wave Quantum Inc.] tumbled on the day that AI chip giant Nvidia kicked off its two-day Quantum Day event. In a blog post from January 14 announcing Quantum Day, Nvidia said the event “brings together leading experts for a comprehensive and balanced perspective on what businesses should expect from quantum computing in the coming decades — mapping the path toward useful quantum applications.”

Besides bringing quantum experts together, the AI behemoth also announced that it will be launching a new quantum computing research center in Boston.

Called the NVIDIA Accelerated Quantum Research Center (NVAQC), the new research lab “will help solve quantum computing’s most challenging problems, ranging from qubit noise to transforming experimental quantum processors into practical devices,” the company said in a press release.

The NVAQC’s location in Boston means it will be near both Harvard University and the Massachusetts Institute of Technology (MIT). 

Before Nvidia’s announcement yesterday, IonQ, Rigetti, D-Wave, and Quantum Computing Inc. were the leaders in the nascent field of quantum computing. And while they still are right now (Nvidia’s quantum research lab hasn’t been built yet), the fear is that Nvidia could use its deep pockets to quickly buy its way into a leadership spot in the field. With its $2.9 trillion market cap, the company can easily afford to throw billions of research dollars into quantum computing.

As noted by the Motley Fool, the location of the NVIDIA Accelerated Quantum Research Center in Boston will also allow Nvidia to more easily tap into top quantum talent from Harvard and MIT—talent that may have otherwise gone to IonQ, Rigetti, D-Wave, and Quantum Computing Inc.

Nvidia’s announcement is a massive about-face from the company in regard to how it views quantum computing. It’s also the second time that Nvidia has caused quantum stocks to crash this year. Back in January, shares in prominent quantum computing companies fell after Huang said that practical use of quantum computing was decades away.

Those comments were something quantum computing company CEOs like D-Wave’s Alan Baratz took issue with. “It’s an egregious error on Mr. Huang’s part,” Bartaz told Fast Company at the time. “We’re not decades away from commercial quantum computers. They exist. There are companies that are using our quantum computer today.”

According to Investor’s Business Daily, Huang reportedly got the idea for Nvidia’s Quantum Day event after the blowback to his comments, inviting quantum computing executives to the event to explain why he was incorrect about quantum computing.

The word is volatile.

Audio map of 24 emotions

Caption: Audio map of vocal bursts across 24 emotions. To visit the online map and hear the sounds, go to https://s3-us-west-1.amazonaws.com/vocs/map.html# and move the cursor across the map. Credit: Courtesy of Alan Cowen

The real map, not the the image of the map you see above, offers a disconcerting (for me, anyway) experience. Especially since I’ve just finished reading Lisa Feldman Barrett’s 2017 book, How Emotions are Made, where she presents her theory of ‘constructed emotion. (There’s more about ‘constructed emotion’ later in this post.)

Moving on to the story about the ‘auditory emotion map’ in the headline, a February 4, 2019 University of California at Berkeley news release by Yasmin Anwar (also on EurekAlert but published on Feb. 5, 2019) describes the work,

Ooh, surprise! Those spontaneous sounds we make to express everything from elation (woohoo) to embarrassment (oops) say a lot more about what we’re feeling than previously understood, according to new research from the University of California, Berkeley.

Proving that a sigh is not just a sigh [a reference to the song, As Time Goes By? The lyric is “a kiss is still a kiss, a sigh is just a sigh …”], UC Berkeley scientists conducted a statistical analysis of listener responses to more than 2,000 nonverbal exclamations known as “vocal bursts” and found they convey at least 24 kinds of emotion. Previous studies of vocal bursts set the number of recognizable emotions closer to 13.

The results, recently published online in the American Psychologist journal, are demonstrated in vivid sound and color on the first-ever interactive audio map of nonverbal vocal communication.

“This study is the most extensive demonstration of our rich emotional vocal repertoire, involving brief signals of upwards of two dozen emotions as intriguing as awe, adoration, interest, sympathy and embarrassment,” said study senior author Dacher Keltner, a psychology professor at UC Berkeley and faculty director of the Greater Good Science Center, which helped support the research.

For millions of years, humans have used wordless vocalizations to communicate feelings that can be decoded in a matter of seconds, as this latest study demonstrates.

“Our findings show that the voice is a much more powerful tool for expressing emotion than previously assumed,” said study lead author Alan Cowen, a Ph.D. student in psychology at UC Berkeley.

On Cowen’s audio map, one can slide one’s cursor across the emotional topography and hover over fear (scream), then surprise (gasp), then awe (woah), realization (ohhh), interest (ah?) and finally confusion (huh?).

Among other applications, the map can be used to help teach voice-controlled digital assistants and other robotic devices to better recognize human emotions based on the sounds we make, he said.

As for clinical uses, the map could theoretically guide medical professionals and researchers working with people with dementia, autism and other emotional processing disorders to zero in on specific emotion-related deficits.

“It lays out the different vocal emotions that someone with a disorder might have difficulty understanding,” Cowen said. “For example, you might want to sample the sounds to see if the patient is recognizing nuanced differences between, say, awe and confusion.”

Though limited to U.S. responses, the study suggests humans are so keenly attuned to nonverbal signals – such as the bonding “coos” between parents and infants – that we can pick up on the subtle differences between surprise and alarm, or an amused laugh versus an embarrassed laugh.

For example, by placing the cursor in the embarrassment region of the map, you might find a vocalization that is recognized as a mix of amusement, embarrassment and positive surprise.

A tour through amusement reveals the rich vocabulary of laughter and a spin through the sounds of adoration, sympathy, ecstasy and desire may tell you more about romantic life than you might expect,” said Keltner.

Researchers recorded more than 2,000 vocal bursts from 56 male and female professional actors and non-actors from the United States, India, Kenya and Singapore by asking them to respond to emotionally evocative scenarios.

Next, more than 1,000 adults recruited via Amazon’s Mechanical Turk online marketplace listened to the vocal bursts and evaluated them based on the emotions and meaning they conveyed and whether the tone was positive or negative, among several other characteristics.

A statistical analysis of their responses found that the vocal bursts fit into at least two dozen distinct categories including amusement, anger, awe, confusion, contempt, contentment, desire, disappointment, disgust, distress, ecstasy, elation, embarrassment, fear, interest, pain, realization, relief, sadness, surprise (positive) surprise (negative), sympathy and triumph.

For the second part of the study, researchers sought to present real-world contexts for the vocal bursts. They did this by sampling YouTube video clips that would evoke the 24 emotions established in the first part of the study, such as babies falling, puppies being hugged and spellbinding magic tricks.

This time, 88 adults of all ages judged the vocal bursts extracted from YouTube videos. Again, the researchers were able to categorize their responses into 24 shades of emotion. The full set of data were then organized into a semantic space onto an interactive map.

“These results show that emotional expressions color our social interactions with spirited declarations of our inner feelings that are difficult to fake, and that our friends, co-workers, and loved ones rely on to decipher our true commitments,” Cowen said.

The writer assumes that emotions are pre-existing. Somewhere, there’s happiness, sadness, anger, etc. It’s the pre-existence that Lisa Feldman Barret challenges with her theory that we construct our emotions (from her Wikipedia entry),

She highlights differences in emotions between different cultures, and says that emotions “are not triggered; you create them. They emerge as a combination of the physical properties of your body, a flexible brain that wires itself to whatever environment it develops in, and your culture and upbringing, which provide that environment.”

You can find Barrett’s December 6, 2017 TED talk here wheres she explains her theory in greater detail. One final note about Barrett, she was born and educated in Canada and now works as a Professor of Psychology at Northeastern University, with appointments at Harvard Medical School and Massachusetts General Hospital at Northeastern University in Boston, Massachusetts; US.

A February 7, 2019 by Mark Wilson for Fast Company delves further into the 24 emotion audio map mentioned at the outset of this posting (Note: Links have been removed),

Fear, surprise, awe. Desire, ecstasy, relief.

These emotions are not distinct, but interconnected, across the gradient of human experience. At least that’s what a new paper from researchers at the University of California, Berkeley, Washington University, and Stockholm University proposes. The accompanying interactive map, which charts the sounds we make and how we feel about them, will likely persuade you to agree.

At the end of his article, Wilson also mentions the Dalai Lama and his Atlas of Emotions, a data visualization project, (featured in Mark Wilson’s May 13, 2016 article for Fast Company). It seems humans of all stripes are interested in emotions.

Here’s a link to and a citation for the paper about the audio map,

Mapping 24 emotions conveyed by brief human vocalization by Cowen, Alan S;, Elfenbein, Hillary Ange;, Laukka, Petri; Keltner, Dacher. American Psychologist, Dec 20, 2018, No Pagination Specified DOI: 10.1037/amp0000399


This paper is behind a paywall.

Weaving at the nanoscale

A Jan. 21, 2016 news item on ScienceDaily announces a brand new technique,

For the first time, scientists have been able to weave a material at molecular level. The research is led by University of California Berkeley, in cooperation with Stockholm University. …

A Jan. 21, 2016 Stockholm University press release, which originated the news item, provides more information,

Weaving is a well-known way of making fabric, but has until now never been used at the molecular level. Scientists have now been able to weave organic threads into a three-dimensional material, using copper as a template. The new material is a COF, covalent organic framework, and is named COF-505. The copper ions can be removed and added without changing the underlying structure, and at the same time the elasticity can be reversibly changed.

– It almost looks like a molecular version of the Vikings chain-armour. The material is very flexible, says Peter Oleynikov, researcher at the Department of Materials and Environmental Chemistry at Stockholm University.

COF’s are like MOF’s porous three-dimensional crystals with a very large internal surface that can adsorb and store enormous quantities of molecules. A potential application is capture and storage of carbon dioxide, or using COF’s as a catalyst to make useful molecules from carbon dioxide.

Complex structure determined in Stockholm

The research is led by Professor Omar Yaghi at University of California Berkeley. At Stockholm University Professor Osamu Terasaki, PhD Student Yanhang Ma and Researcher Peter Oleynikov have contributed to determine the structure of COF-505 at atomic level from a nano-crystal, using electron crystallography methods.

– It is a difficult, complicated structure and it was very demanding to resolve. We’ve spent lot of time and efforts on the structure solution. Now we know exactly where the copper is and we can also replace the metal. This opens up many possibilities to make other materials, says Yanhang Ma, PhD Student at the Department of Materials and Environmental Chemistry at Stockholm University.

Another of the collaborating institutions, US Department of Energy Lawrence Berkeley National Laboratory issued a Jan. 21, 2016 news release on EurekAlert, providing a different perspective and some additional details,

There are many different ways to make nanomaterials but weaving, the oldest and most enduring method of making fabrics, has not been one of them – until now. An international collaboration led by scientists at the U.S. Department of Energy (DOE)’s Lawrence Berkeley National Laboratory (Berkeley Lab) and the University of California (UC) Berkeley, has woven the first three-dimensional covalent organic frameworks (COFs) from helical organic threads. The woven COFs display significant advantages in structural flexibility, resiliency and reversibility over previous COFs – materials that are highly prized for their potential to capture and store carbon dioxide then convert it into valuable chemical products.

“Weaving in chemistry has been long sought after and is unknown in biology,” Yaghi says [Omar Yaghi, chemist who holds joint appointments with Berkeley Lab’s Materials Sciences Division and UC Berkeley’s Chemistry Department and is the co-director of the Kavli Energy NanoScience Institute {Kavli-ENSI}]. “However, we have found a way of weaving organic threads that enables us to design and make complex two- and three-dimensional organic extended structures.”

COFs and their cousin materials, metal organic frameworks (MOFs), are porous three-dimensional crystals with extraordinarily large internal surface areas that can absorb and store enormous quantities of targeted molecules. Invented by Yaghi, COFs and MOFs consist of molecules (organics for COFs and metal-organics for MOFs) that are stitched into large and extended netlike frameworks whose structures are held together by strong chemical bonds. Such frameworks show great promise for, among other applications, carbon sequestration.

Through another technique developed by Yaghi, called “reticular chemistry,” these frameworks can also be embedded with catalysts to carry out desired functions: for example, reducing carbon dioxide into carbon monoxide, which serves as a primary building block for a wide range of chemical products including fuels, pharmaceuticals and plastics.

In this latest study, Yaghi and his collaborators used a copper(I) complex as a template for bringing threads of the organic compound “phenanthroline” into a woven pattern to produce an immine-based framework they dubbed COF-505. Through X-ray and electron diffraction characterizations, the researchers discovered that the copper(I) ions can be reversibly removed or restored to COF-505 without changing its woven structure. Demetalation of the COF resulted in a tenfold increase in its elasticity and remetalation restored the COF to its original stiffness.

“That our system can switch between two states of elasticity reversibly by a simple operation, the first such demonstration in an extended chemical structure, means that cycling between these states can be done repeatedly without degrading or altering the structure,” Yaghi says. “Based on these results, it is easy to imagine the creation of molecular cloths that combine unusual resiliency, strength, flexibility and chemical variability in one material.”

Yaghi says that MOFs can also be woven as can all structures based on netlike frameworks. In addition, these woven structures can also be made as nanoparticles or polymers, which means they can be fabricated into thin films and electronic devices.

“Our weaving technique allows long threads of covalently linked molecules to cross at regular intervals,” Yaghi says. “These crossings serve as points of registry, so that the threads have many degrees of freedom to move away from and back to such points without collapsing the overall structure, a boon to making materials with exceptional mechanical properties and dynamics.”

###

This research was primarily supported by BASF (Germany) and King Abdulaziz City for Science and Technology (KACST).

It’s unusual that neither Stockholm University not the Lawrence Berkeley National Laboratory list all of the institutions involved. To get a sense of this international collaboration’s size, I’m going to list them,

  • 1Department of Chemistry, University of California, Berkeley, Materials Sciences Division, Lawrence Berkeley National Laboratory, and Kavli Energy NanoSciences Institute, Berkeley, CA 94720, USA.
  • 2Department of Materials and Environmental Chemistry, Stockholm University, SE-10691 Stockholm, Sweden.
  • 3Department of New Architectures in Materials Chemistry, Materials Science Institute of Madrid, Consejo Superior de Investigaciones Científicas, Madrid 28049, Spain.
  • 4Nanomaterials Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba 305-8565, Japan.
  • 5NSF Nanoscale Science and Engineering Center (NSEC), University of California at Berkeley, 3112 Etcheverry Hall, Berkeley, CA 94720, USA.
  • 6Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA.
  • 7King Abdulaziz City of Science and Technology, Post Office Box 6086, Riyadh 11442, Saudi Arabia.
  • 8Material Sciences Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720, USA.
  • 9School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, China.

Given that some of the money came from a German company, I’m surprised not one German institution was involved.

Here’s a link to and citation for the paper,

Weaving of organic threads into a crystalline covalent organic framework by Yuzhong Liu, Yanhang Ma, Yingbo Zhao, Xixi Sun, Felipe Gándara, Hiroyasu Furukawa, Zheng Liu, Hanyu Zhu, Chenhui Zhu, Kazutomo Suenaga, Peter Oleynikov, Ahmad S. Alshammari, Xiang Zhang, Osamu Terasaki, Omar M. Yaghi. Science  22 Jan 2016: Vol. 351, Issue 6271, pp. 365-369 DOI: 10.1126/science.aad4011

This paper is behind a paywall.

Archimedes as in nano-archimedes and graphene nanoscrolls

Over the last 10 days or so, I’ve stumbled across two references to Archimedes in my constant search for information on nanotechnology. Not remembering my ancient Greeks very well, I found this about him on Wikipedia (Note: Links and footnotes have been removed),

Archimedes of Syracuse (Greek: Ἀρχιμήδης; c. 287 BC – c. 212 BC) was a Greek mathematician, physicist, engineer, inventor, and astronomer. Although few details of his life are known, he is regarded as one of the leading scientists in classical antiquity. Among his advances in physics are the foundations of hydrostatics, statics and an explanation of the principle of the lever. He is credited with designing innovative machines, including siege engines and the screw pump that bears his name. Modern experiments have tested claims that Archimedes designed machines capable of lifting attacking ships out of the water and setting ships on fire using an array of mirrors.

Archimedes is generally considered to be the greatest mathematician of antiquity and one of the greatest of all time.

His influence lives on as he’s referenced in an Aug. 15, 2013 news item on Nanowerk concerning graphene nanoscrolls,

Researchers at Umeå University, together with researchers at Uppsala University and Stockholm University, show in a new study how nitrogen doped graphene can be rolled into perfect Archimedean nano scrolls by adhering magnetic iron oxide nanoparticles on the surface of the graphene sheets. The new material may have very good properties for application as electrodes in for example Li-ion batteries.

The Aug. 15, 2013 Umeå University press release,which originated the news item, provides technical details,

In the study the researchers have modified the graphene by replacing some of the carbon atoms by nitrogen atoms. By this method they obtain anchoring sites for the iron oxide nanoparticles that are decorated onto the graphene sheets in a solution process. In the decoration process one can control the type of iron oxide nanoparticles that are formed on the graphene surface, so that they either form so called hematite (the reddish form of iron oxide that often is found in nature) or maghemite, a less stable and more magnetic form of iron oxide.

“Interestingly we observed that when the graphene is decorated by maghemite, the graphene sheets spontaneously start to roll into perfect Archimedean nano scrolls, while when decorated by the less magnetic hematite nanoparticles the graphene remain as open sheets, says Thomas Wågberg, Senior lecturer at the Department of Physics at Umeå University.

The nanoscrolls can be visualized as traditional “Swiss rolls” where the sponge-cake represents the graphene, and the creamy filling is the iron oxide nanoparticles. The graphene nanoscrolls are however around one million times thinner.

The results that now have been published in Nature Communications are conceptually interesting for several reasons. It shows that the magnetic interaction between the iron oxide nanoparticles is one of the main effects behind the scroll formation. It also shows that the nitrogen defects in the graphene lattice are necessary for both stabilizing a sufficiently high number of maghemite nanoparticles, and also responsible for “buckling” the graphene sheets and thereby lowering the formation energy of the nanoscrolls.

The process is extraordinary efficient. Almost 100 percent of the graphene sheets are scrolled. After the decoration with maghemite particles the research team could not find any open graphene sheets.

Moreover, they showed that by removing the iron oxide nanoparticles by acid treatment the nanoscrolls again open up and go back to single graphene sheets

The researchers have an image showing a partially reopened scroll (despite references to Archimedes and swiss rolls, I see a plant leaf or flower unfurling),

Caption: Snapshot of a partially re-opened nanoscroll. The atomic layer thick graphene resembles a thin foil with some few wrinkles. [Courtesy of  Umeå University]

Caption: Snapshot of a partially re-opened nanoscroll. The atomic layer thick graphene resembles a thin foil with some few wrinkles. [Courtesy of Umeå University]

Here’s a link to and a citation for the published paper,

Tiva Sharifi, Eduardo Gracia-Espino, Hamid Reza Barzegar, Xueen Jia, Florian Nitze, Guangzhi Hu, Per Nordblad, Cheuk-Wai Tai, and Thomas Wågberg: Formation of nitrogen-doped graphene nanoscrolls by adsorption of magnetic γ-Fe2O3 nanoparticles, Nature Communications (2013), DOI:10.1038/ncomms3319.

The article is behind a paywall.

The other Archimedes reference is regarding a new website, nano-archimedes, mentioned in an Aug. 10, 2013 news item on Nanowerk,

Nano-archimedes is a Technology Computer Aided Design tool (TCAD) for the simulation of electron transport in nanometer scale semiconductor devices (nanodevices). It is based on the Wigner equation, a convenient reformulation of the Schrödinger equation in terms of a phase-space, which allows the application of stochastic particles methods and the extension towards mixed state kinetic descriptions such as the Wigner-Boltzmann equation.

There’s more on the nano-archimedes homepage,

It is an experimental code for validation and analysis of the compatibility of existing quantum particle concepts in algorithmic schemes. Our preliminary results have clearly shown that time-dependent, full quantum and multi-dimensional simulations of electron transport can be achieved with no special computational requirements. The code is already able to simulate time dependent phenomena such as two-dimensional wave phase breaking and single electron ballistic transport with open boundary conditions aiming to have, very soon, full quantum self-consistent calculations for nanodevices.

nano-archimedes runs both on serial and parallel machines and the parallelization scheme is based on OpenMP – a standard library for parallel calculations. The code is entirely written in C and can compile on a huge variety of machines without any particular effort. The only external dependence is OpenMP, everything else is embedded in the code to make it truly cross-platform.

I found the background of the team members behind this effort rather interesting, from the Team page,

Main developer and principal maintainer of the code:
Jean Michel Sellier, IICT, Bulgarian Academy of Sciences, Bulgaria, supported by the AComIn project.

Main developer, theory and physical analysis:
Mihail Nedjalkov, Institute for Microelectronics, TU Wien, Austria.

Advisory board:
Ivan Dimov, Bulgarian Academy of Sciences, Bulgaria.
Siegfried Selberherr, Institute for Microelectronics, TU Wien, Austria.

Website Master:
Marc Sellier, working at Selliweb, Italy.

I don’t often have a chance to mention Bulgaria and I expect that’s due to the fact that my linguistic skills are largely English with a little French flavour thrown into the mix. The consequence is that I’m confined and while  I realize English is the dominant language in science there’s still a lot of scientific materials that never finds its way into English and I don’t trust machine translations.