Tag Archives: University of Surrey

Early morning run could power your electrical wearables

I don’t think this is going to be happening tomorrow but here’s a relatively recent news item on ScienceDaily from August 22, 2024 about bioenergy harvesting and wearable technology,

Your early morning run could soon help harvest enough electricity to power your wearable devices, thanks to new nanotechnology developed at the University of Surrey [UK].

Surrey’s Advanced Technology Institute (ATI) has developed highly energy-efficient, flexible nanogenerators, which demonstrate a 140-fold increase in power density when compared to conventional nanogenerators. ATI researchers believe that this development could pave the way for nano-devices that are as efficient as today’s solar cells.

An August 21, 2024 University of Surrey press release (also on EurekAlert but published August 22, 2024), which originated the news item, provides more information about the research,

Surrey’s devices can convert small amounts of everyday mechanical energy, like motion, into a significantly higher amount of electrical power, similar to how an amplifier boosts sound in an electronic system. For instance, if a traditional nanogenerator produces 10 milliwatts of power, this new technology could increase that output to over 1,000 milliwatts, making it suitable for energy harvesting in various everyday applications. 

ATI’s nanogenerator works like a relay team – instead of one electrode (the runner) passing energy (charge) by itself. Each runner collects a baton (charge), adds more and then passes all batons to the next runner, boosting the overall energy that is collected in a process called the charge regeneration effect. 

Lead author of the study from the University of Surrey, Md Delowar Hussain, said: 

“The dream of nanogenerators is to capture and use energy from everyday movements, like your morning run, mechanical vibrations, ocean waves or opening a door. The key innovation with our nanogenerator is that we’ve fine-tuned the technology with 34 tiny energy collectors using a laser technique that can be scaled up for manufacture to increase energy efficiency further. 

“What’s really exciting is that our little device with high energy harvesting density could one day rival the power of solar panels and could be used to run anything from self-powered sensors to smart home systems that run without ever needing a battery change.” 

The device is a triboelectric nanogenerator (TENG) – a device that can capture and turn the energy from simple, everyday movements into electricity. They work by using materials that become electrically charged when they come into contact and then separate – similar to when you rub a balloon on your hair, and it sticks due to static electricity.  

Dr Bhaskar Dudem, co-author of the study from the University of Surrey, said:  

“We are soon going to launch a company focused on self-powered, non-invasive healthcare sensors using triboelectric technology. Innovations like these will enable us to drive new spin-out activities in sustainable health tech, improve sensitivity, and emphasize industrial scalability.” 

Professor Ravi Silva, co-author of the study and Director of the Advanced Technology Institute at the University of Surrey, said: 

“With the ever-increasing technology around us, it is predicted that we will have over 50 billion Internet of Things (IoT) devices in the next few years that will need energy to be powered. Local green energy solutions are needed, and this could be a convenient wireless technology that harnesses energy from any mechanical movements to power small devices. It offers an opportunity for the scientific and engineering community to find innovative and sustainable solutions to global challenges.” 

“We are incredibly excited about the potential of these nanogenerators to transform how we think about energy. You could also imagine these devices being used in IoT-based self-powered smart systems like autonomous wireless operations, security monitoring, and smart home systems, or even for supporting dementia patients, an area in which the University of Surrey has great expertise.” 

Here’s a link to and a citation for the paper,

Exploring charge regeneration effect in interdigitated array electrodes-based TENGs for a more than 100-fold enhanced power density by Md Delowar Hussain, Bhaskar Dudem, Dimitar I. Kutsarov, S. Ravi P. Silva. Nano Energy Volume 130, November 2024, 110112 DOI: https://doi.org/10.1016/j.nanoen.2024.110112 Available online 13 August 2024, Version of Record 21 August 2024

This paper is open access under a Creative Commons license.

Augmented reality and the future of paper books

I’ve started to think that paper books will be on an ‘endangered species’ list in the not too distant future. Now, it seems researchers at the University of Surrey (UK) may have staved off that scenario according to an August 3, 2022 news item on ScienceDaily,

Augmented reality might allow printed books to make a comeback against the e-book trend, according to researchers from the University of Surrey.

An August 3, 2022 University of Surrey press release (also on EurekAlert), which originated the news item, describes the idea and the research in more detail,

Surrey has introduced the third generation (3G) version of its Next Generation Paper (NGP) project, allowing the reader to consume information on the printed paper and screen side by side.  

Dr Radu Sporea, Senior lecturer at the Advanced Technology Institute (ATI), comments: 

“The way we consume literature has changed over time with so many more options than just paper books. Multiple electronic solutions currently exist, including e-readers and smart devices, but no hybrid solution which is sustainable on a commercial scale.  

“Augmented books, or a-books, can be the future of many book genres, from travel and tourism to education. This technology exists to assist the reader in a deeper understanding of the written topic and get more through digital means without ruining the experience of reading a paper book.” 

Power efficiency and pre-printed conductive paper are some of the new features which allow Surrey’s augmented books to now be manufactured on a semi-industrial scale. With no wiring visible to the reader, Surrey’s augmented reality books allow users to trigger digital content with a simple gesture (such as a swipe of a finger or turn of a page), which will then be displayed on a nearby device.  

George Bairaktaris, Postgraduate researcher at the University of Surrey and part of the Next Generation Paper project team, said: 

“The original research was carried out to enrich travel experiences by creating augmented travel guides. This upgraded 3G model allows for the possibility of using augmented books for different areas such as education. In addition, the new model disturbs the reader less by automatically recognising the open page and triggering the multimedia content.” 

“What started as an augmented book project, evolved further into scalable user interfaces. The techniques and knowledge from the project led us into exploring organic materials and printing techniques to fabricate scalable sensors for interfaces beyond the a-book”.

…  

Caption: Next Generation Paper book example Credit: Courtesy of Advanced Technology Institute at the University of Surrey

Here’s a link to and a citation for the paper,

Augmented Books: Hybrid Electronics Bring Paper to Life by Georgios Bairaktaris, Brice Le Borgne, Vikram Turkani, Emily Corrigan-Kavanagh, David M. Frohlich, Radu A. Sporea. IEEE Pervasive Computing (early access) PrePrints pp. 1-8, DOI: 10.1109/MPRV.2022.3181440 Published: July 12, 2022

This paper is behind a paywall.

Should AI algorithms get patents for their inventions and is anyone talking about copyright for texts written by AI algorithms?

A couple of Australian academics have written a comment for the journal Nature, which bears the intriguing subtitle: “The patent system assumes that inventors are human. Inventions devised by machines require their own intellectual property law and an international treaty.” (For the curious, I’ve linked to a few of my previous posts touching on intellectual property [IP], specifically the patent’s fraternal twin, copyright at the end of this piece.)

Before linking to the comment, here’s the May 27, 2022 University of New South Wales (UNCSW) press release (also on EurekAlert but published May 30, 2022) which provides an overview of their thinking on the subject, Note: Links have been removed,

It’s not surprising these days to see new inventions that either incorporate or have benefitted from artificial intelligence (AI) in some way, but what about inventions dreamt up by AI – do we award a patent to a machine?

This is the quandary facing lawmakers around the world with a live test case in the works that its supporters say is the first true example of an AI system named as the sole inventor.

In commentary published in the journal Nature, two leading academics from UNSW Sydney examine the implications of patents being awarded to an AI entity.

Intellectual Property (IP) law specialist Associate Professor Alexandra George and AI expert, Laureate Fellow and Scientia Professor Toby Walsh argue that patent law as it stands is inadequate to deal with such cases and requires legislators to amend laws around IP and patents – laws that have been operating under the same assumptions for hundreds of years.

The case in question revolves around a machine called DABUS (Device for the Autonomous Bootstrapping of Unified Sentience) created by Dr Stephen Thaler, who is president and chief executive of US-based AI firm Imagination Engines. Dr Thaler has named DABUS as the inventor of two products – a food container with a fractal surface that helps with insulation and stacking, and a flashing light for attracting attention in emergencies.

For a short time in Australia, DABUS looked like it might be recognised as the inventor because, in late July 2021, a trial judge accepted Dr Thaler’s appeal against IP Australia’s rejection of the patent application five months earlier. But after the Commissioner of Patents appealed the decision to the Full Court of the Federal Court of Australia, the five-judge panel upheld the appeal, agreeing with the Commissioner that an AI system couldn’t be named the inventor.

A/Prof. George says the attempt to have DABUS awarded a patent for the two inventions instantly creates challenges for existing laws which has only ever considered humans or entities comprised of humans as inventors and patent-holders.

“Even if we do accept that an AI system is the true inventor, the first big problem is ownership. How do you work out who the owner is? An owner needs to be a legal person, and an AI is not recognised as a legal person,” she says.

Ownership is crucial to IP law. Without it there would be little incentive for others to invest in the new inventions to make them a reality.

“Another problem with ownership when it comes to AI-conceived inventions, is even if you could transfer ownership from the AI inventor to a person: is it the original software writer of the AI? Is it a person who has bought the AI and trained it for their own purposes? Or is it the people whose copyrighted material has been fed into the AI to give it all that information?” asks A/Prof. George.

For obvious reasons

Prof. Walsh says what makes AI systems so different to humans is their capacity to learn and store so much more information than an expert ever could. One of the requirements of inventions and patents is that the product or idea is novel, not obvious and is useful.

“There are certain assumptions built into the law that an invention should not be obvious to a knowledgeable person in the field,” Prof. Walsh says.

“Well, what might be obvious to an AI won’t be obvious to a human because AI might have ingested all the human knowledge on this topic, way more than a human could, so the nature of what is obvious changes.”

Prof. Walsh says this isn’t the first time that AI has been instrumental in coming up with new inventions. In the area of drug development, a new antibiotic was created in 2019 – Halicin – that used deep learning to find a chemical compound that was effective against drug-resistant strains of bacteria.

“Halicin was originally meant to treat diabetes, but its effectiveness as an antibiotic was only discovered by AI that was directed to examine a vast catalogue of drugs that could be repurposed as antibiotics. So there’s a mixture of human and machine coming into this discovery.”

Prof. Walsh says in the case of DABUS, it’s not entirely clear whether the system is truly responsible for the inventions.

“There’s lots of involvement of Dr Thaler in these inventions, first in setting up the problem, then guiding the search for the solution to the problem, and then interpreting the result,” Prof. Walsh says.

“But it’s certainly the case that without the system, you wouldn’t have come up with the inventions.”

Change the laws

Either way, both authors argue that governing bodies around the world will need to modernise the legal structures that determine whether or not AI systems can be awarded IP protection. They recommend the introduction of a new ‘sui generis’ form of IP law – which they’ve dubbed ‘AI-IP’ – that would be specifically tailored to the circumstances of AI-generated inventiveness. This, they argue, would be more effective than trying to retrofit and shoehorn AI-inventiveness into existing patent laws.

Looking forward, after examining the legal questions around AI and patent law, the authors are currently working on answering the technical question of how AI is going to be inventing in the future.

Dr Thaler has sought ‘special leave to appeal’ the case concerning DABUS to the High Court of Australia. It remains to be seen whether the High Court will agree to hear it. Meanwhile, the case continues to be fought in multiple other jurisdictions around the world.

Here’s a link to and a citation for the paper,

Artificial intelligence is breaking patent law by Alexandra George & Toby Walsh. Nature (Nature) COMMENT ISSN 1476-4687 (online) 24 May 2022 ISSN 0028-0836 (print) Vol 605 26 May 2022 pp. 616-18 DOI: 10.1038/d41586-022-01391-x

This paper appears to be open access.

The Journey

DABIUS has gotten a patent in one jurisdiction, from an August 8, 2021 article on brandedequity.com,

The patent application listing DABUS as the inventor was filed in patent offices around the world, including the US, Europe, Australia, and South Afica. But only South Africa granted the patent (Australia followed suit a few days later after a court judgment gave the go-ahard [and rejected it several months later]).

Natural person?

This September 27, 2021 article by Miguel Bibe for Inventa covers some of the same ground adding some some discussion of the ‘natural person’ problem,

The patent is for “a food container based on fractal geometry”, and was accepted by the CIPC [Companies and Intellectual Property Commission] on June 24, 2021. The notice of issuance was published in the July 2021 “Patent Journal”.  

South Africa does not have a substantive patent examination system and, instead, requires applicants to merely complete a filing for their inventions. This means that South Africa patent laws do not provide a definition for “inventor” and the office only proceeds with a formal examination in order to confirm if the paperwork was filled correctly.

… according to a press release issued by the University of Surrey: “While patent law in many jurisdictions is very specific in how it defines an inventor, the DABUS team is arguing that the status quo is not fit for purpose in the Fourth Industrial Revolution.”

On the other hand, this may not be considered as a victory for the DABUS team since several doubts and questions remain as to who should be considered the inventor of the patent. Current IP laws in many jurisdictions follow the traditional term of “inventor” as being a “natural person”, and there is no legal precedent in the world for inventions created by a machine.

August 2022 update

Mike Masnick in an August 15, 2022 posting on Techdirt provides the latest information on Stephen Thaler’s efforts to have patents and copyrights awarded to his AI entity, DABUS,

Stephen Thaler is a man on a mission. It’s not a very good mission, but it’s a mission. He created something called DABUS (Device for the Autonomous Bootstrapping of Unified Sentience) and claims that it’s creating things, for which he has tried to file for patents and copyrights around the globe, with his mission being to have DABUS named as the inventor or author. This is dumb for many reasons. The purpose of copyright and patents are to incentivize the creation of these things, by providing to the inventor or author a limited time monopoly, allowing them to, in theory, use that monopoly to make some money, thereby making the entire inventing/authoring process worthwhile. An AI doesn’t need such an incentive. And this is why patents and copyright only are given to persons and not animals or AI.

… Thaler’s somewhat quixotic quest continues to fail. The EU Patent Office rejected his application. The Australian patent office similarly rejected his request. In that case, a court sided with Thaler after he sued the Australian patent office, and said that his AI could be named as an inventor, but thankfully an appeals court set aside that ruling a few months ago. In the US, Thaler/DABUS keeps on losing as well. Last fall, he lost in court as he tried to overturn the USPTO ruling, and then earlier this year, the US Copyright Office also rejected his copyright attempt (something it has done a few times before). In June, he sued the Copyright Office over this, which seems like a long shot.

And now, he’s also lost his appeal of the ruling in the patent case. CAFC, the Court of Appeals for the Federal Circuit — the appeals court that handles all patent appeals — has rejected Thaler’s request just like basically every other patent and copyright office, and nearly all courts.

If you have the time, the August 15, 2022 posting is an interesting read.

Consciousness and ethical AI

Just to make things more fraught, an engineer at Google has claimed that one of their AI chatbots has consciousness. From a June 16, 2022 article (in Canada’s National Post [previewed on epaper]) by Patrick McGee,

Google has ignited a social media firestorm on the the nature of consciousness after placing an engineer on paid leave with his belief that the tech group’s chatbot has become “sentient.”

Blake Lemoine, a senior software engineer in Google’s Responsible AI unit, did not receive much attention when he wrote a Medium post saying he “may be fired soon for doing AI ethics work.”

But a Saturday [June 11, 2022] profile in the Washington Post characterized Lemoine as “the Google engineer who thinks “the company’s AI has come to life.”

This is not the first time that Google has run into a problem with ethics and AI. Famously, Timnit Gebru who co-led (with Margaret Mitchell) Google’s ethics and AI unit departed in 2020. Gebru said (and maintains to this day) she was fired. They said she was ?, they never did make a final statement although after an investigation Gebru did receive an apology. You *can* read more about Gebru and the issues she brought to light in her Wikipedia entry. Coincidentally (or not), Margaret Mitchell was terminated/fired in February 2021 from Google after criticizing the company for Gebru’s ‘firing’. See a February 19, 2021 article by Megan Rose Dickey for TechCrunch for details about what the company has admitted is a firing or Margaret Mitchell’s termination from the company.

Getting back intellectual property and AI.

What about copyright?

There are no mentions of copyright in the earliest material I have here about the ‘creative’ arts and artificial intelligence is this, “Writing and AI or is a robot writing this blog?” posted July 16, 2014. More recently, there’s “Beer and wine reviews, the American Chemical Society’s (ACS) AI editors, and the Turing Test” posted May 20, 2022. The type of writing featured is not literary or typically considered creative writing.

On the more creative front, there’s “True love with AI (artificial intelligence): The Nature of Things explores emotional and creative AI (long read)” posted on December 3, 2021. The literary/creative portion of the post can be found under the ‘AI and creativity’ subhead approximately 30% of the way down and where I mention Douglas Coupland. Again, there’s no mention of copyright.

It’s with the visual arts that copyright gets mentioned. The first one I can find here is “Robot artists—should they get copyright protection” posted on July 10, 2017.

Fun fact: Andres Guadamuz who was mentioned in my posting took to his own blog where he gave my blog a shout out while implying that I wasn’t thoughtful. The gist of his August 8, 2017 posting was that he was misunderstood by many people, which led to the title for his post, “Should academics try to engage the public?” Thankfully, he soldiers on trying to educate us with his TechnoLama blog.

Lastly, there’s this August 16, 2019 posting “AI (artificial intelligence) artist got a show at a New York City art gallery” where you can scroll down to the ‘What about intellectual property?’ subhead about 80% of the way.

You look like a thing …

i am recommending a book for anyone who’d like to learn a little more about how artificial intelligence (AI) works, “You look like a thing and I love you; How Artificial Intelligence Works and Why It’s Making the World a Weirder Place” by Janelle Shane (2019).

It does not require an understanding of programming/coding/algorithms/etc.; Shane makes the subject as accessible as possible and gives you insight into why the term ‘artificial stupidity’ is more applicable than you might think. You can find Shane’s website here and you can find her 10 minute TED talk here.

*’can’ added to sentence on May 12, 2023.

Implanted biosensors could help sports professionals spy on themselves

A May 21, 2020 news item on Nanowerk describes the latest in sports self-monitoring research (or as I like to think of it, spying on yourself),

Researchers from the University of Surrey have revealed their new biodegradable motion sensor – paving the way for implanted nanotechnology that could help future sports professionals better monitor their movements to aid rapid improvements, or help caregivers remotely monitor people living with dementia.

A May 21, 12020 University of Surrey press release (also on EurekAlert), which originated the news item, mentioned the collaboration with a South Korean University and provides a few details about this work,

In a paper published by Nano Energy, a team from Surrey’s Advanced Technology Institute (ATI), in partnership with Kyung Hee University in South Korea, detail how they developed a nano-biomedical motion sensor which can be paired with AI systems to recognise movements of distinct body parts.

The ATI’s technology builds on its previous work around triboelectric nanogenerators (TENG), where researchers used the technology to harness human movements and generate small amounts of electrical energy. Combining the two means self-powered sensors are possible without the need for chemical or wired power sources.

In their new research, the team from the ATI developed a flexible, biodegradable and long-lasting TENG from silk cocoon waste. They used a new alcohol treatment technique, which leads to greater durability for the device, even under harsh or humid environments.

Dr. Bhaskar Dudem, project lead and Research Fellow at the ATI, said: “We are excited to show the world the immense potential of our durable, silk film based nanogenerator. It’s ability to work in severe environments while being able to generate electricity and monitor human movements positions our TENG in a class of its own when it comes to the technology.”

Professor Ravi Silva, Director of the ATI, said: “We are proud of Dr Dudem’s work which is helping the ATI lead the way in developing wearable, flexible, and biocompatible TENGs that efficiently harvest environmental energies. If we are to live in a future where autonomous sensing and detecting of pathogens is important, the ability to create both self-powered and wireless biosensors linked to AI is a significant boost.”

Here’s a link to and a citation for the paper,

Exploring theoretical and experimental optimization towards high-performance triboelectric nanogenerators using microarchitecture silk cocoon films by Bhaskar Dudem, R.D. Ishara G. Dharmasena, Sontyana Adonijah Graham, Jung Woo Leem, Harishkumarreddy Patnam, Anki Reddy Mule, S. Ravi P. Silva, Jae Su Yu. Nano Energy DOI: https://doi.org/10.1016/j.nanoen.2020.104882 Available online 11 May 2020, 104882

This paper is behind a paywall.

Human-machine interfaces and ultra-small nanoprobes

We’re back on the cyborg trail or what I sometimes refer to as machine/flesh. A July 3, 2019 news item on ScienceDaily describes the latest attempts to join machine with flesh,

Machine enhanced humans — or cyborgs as they are known in science fiction — could be one step closer to becoming a reality, thanks to new research Lieber Group at Harvard University, as well as scientists from University of Surrey and Yonsei University.

Researchers have conquered the monumental task of manufacturing scalable nanoprobe arrays small enough to record the inner workings of human cardiac cells and primary neurons.

The ability to read electrical activities from cells is the foundation of many biomedical procedures, such as brain activity mapping and neural prosthetics. Developing new tools for intracellular electrophysiology (the electric current running within cells) that push the limits of what is physically possible (spatiotemporal resolution) while reducing invasiveness could provide a deeper understanding of electrogenic cells and their networks in tissues, as well as new directions for human-machine interfaces.

The Lieber Group at Harvard University provided this image illustrating the work,

U-shaped nanowires can record electrical chatter inside a brain or heart cell without causing any damage. The devices are 100 times smaller than their biggest competitors, which kill a cell after recording. Courtesy: University of Surrey

A July 3, 2019 University of Surrey press release (also on EurekAlert), which originated the news item, provides more details about this UK/US/China collaboration,

In a paper published by Nature Nanotechnology, scientists from Surrey’s Advanced Technology Institute (ATI) and Harvard University detail how they produced an array of the ultra-small U-shaped nanowire field-effect transistor probes for intracellular recording. This incredibly small structure was used to record, with great clarity, the inner activity of primary neurons and other electrogenic cells, and the device has the capacity for multi-channel recordings.

Dr Yunlong Zhao from the ATI at the University of Surrey said: “If our medical professionals are to continue to understand our physical condition better and help us live longer, it is important that we continue to push the boundaries of modern science in order to give them the best possible tools to do their jobs. For this to be possible, an intersection between humans and machines is inevitable.

“Our ultra-small, flexible, nanowire probes could be a very powerful tool as they can measure intracellular signals with amplitudes comparable with those measured with patch clamp techniques; with the advantage of the device being scalable, it causes less discomfort and no fatal damage to the cell (cytosol dilation). Through this work, we found clear evidence for how both size and curvature affect device internalisation and intracellular recording signal.”

Professor Charles Lieber from the Department of Chemistry and Chemical Biology at Harvard University said: “This work represents a major step towards tackling the general problem of integrating ‘synthesised’ nanoscale building blocks into chip and wafer scale arrays, and thereby allowing us to address the long-standing challenge of scalable intracellular recording.

“The beauty of science to many, ourselves included, is having such challenges to drive hypotheses and future work. In the longer term, we see these probe developments adding to our capabilities that ultimately drive advanced high-resolution brain-machine interfaces and perhaps eventually bringing cyborgs to reality.”

Professor Ravi Silva, Director of the ATI at the University of Surrey, said: “This incredibly exciting and ambitious piece of work illustrates the value of academic collaboration. Along with the possibility of upgrading the tools we use to monitor cells, this work has laid the foundations for machine and human interfaces that could improve lives across the world.”

Dr Yunlong Zhao and his team are currently working on novel energy storage devices, electrochemical probing, bioelectronic devices, sensors and 3D soft electronic systems. Undergraduate, graduate and postdoc students with backgrounds in energy storage, electrochemistry, nanofabrication, bioelectronics, tissue engineering are very welcome to contact Dr Zhao to explore the opportunities further.

Here’s a link to and a citation for the paper,

Scalable ultrasmall three-dimensional nanowire transistor probes for intracellular recording by Yunlong Zhao, Siheng Sean You, Anqi Zhang, Jae-Hyun Lee, Jinlin Huang & Charles M. Lieber. Nature Nanotechnology (2019) DOI: https://doi.org/10.1038/s41565-019-0478-y Published 01 July 2019

The link I’ve provided leads to a paywall. However, I found a freely accessible version of the paper (this may not be the final published version) here.

‘Hunting’ pharmaceuticals and removing them from water

Pharmaceuticals are not the first pollutants people think of when discussing water pollution but, for those who don’t know, it’s a big issue and scientists at the University of Surrey (UK) have developed a technology they believe will help to relieve the contamination. From an April 10, 2017 University of Surrey press release (also on EurekAlert),

The research involves the detection and removal of pharmaceuticals in or from water, as contamination from pharmaceuticals can enter the aquatic environment as a result of their use for the treatment of humans and animals. This contamination can be excreted unchanged, as metabolites, as unused discharge or by drug manufacturers.

The research has found that a new type of ‘supermolecule’, calix[4], actively seeks certain pharmaceuticals and removes them from water.

Contamination of water is a serious concern for environmental scientists around the world, as substances include hormones from the contraceptive pill, and pesticides and herbicides from allotments. Contamination can also include toxic metals such as mercury, arsenic, or cadmium, which was previously used in paint, or substances that endanger vital species such as bees.

Professor Danil de Namor, University of Surrey Emeritus Professor and leader of the research, said: “Preliminary extraction data are encouraging as far as the use of this receptor for the selective removal of these drugs from water and the possibility of constructing a calix[4]-based sensing devices.

“From here, we can design receptors so that they can bind selectively with pollutants in the water so the pollutants can be effectively removed. This research will allow us to know exactly what is in the water, and from here it will be tested in industrial water supplies, so there will be cleaner water for everyone.

“The research also creates the possibility of using these materials for on-site monitoring of water, without having to transport samples to the laboratory.”

Dr Brendan Howlin, University of Surrey co-investigator, said: “This study allows us to visualise the specific receptor-drug interactions leading to the selective behaviour of the receptor. As well as the health benefits of this research, molecular simulation is a powerful technique that is applicable to a wide range of materials.

“We were very proud that the work was carried out with PhD students and a final year project student, and research activities are already taking place with the Department of Chemical and Processing Engineering (CPI) and the Advanced Technology Institute (ATI).

“We are also very pleased to see that as soon as the paper was published online by the European Journal of Pharmaceutical Sciences, we received invitations to give keynote lectures at two international conferences on pharmaceuticals in Europe later this year.”

That last paragraph is intriguing and it marks the first time I’ve seen that claim in a press release announcing the publication of a piece of research.

Here’s a link to and a citation for the paper,

A calix[4]arene derivative and its selective interaction with drugs (clofibric acid, diclofenac and aspirin) by Angela F Danil de Namor, Maan Al Nuaim, Jose A Villanueva Salas, Sophie Bryant, Brendan Howlin. European Journal of Pharmaceutical Sciences Volume 100, 30 March 2017, Pages 1–8 https://doi.org/10.1016/j.ejps.2016.12.027

This paper is behind a paywall.

Nanotechnology cracks Wall Street (Daily)

David Dittman’s Jan. 11, 2017 article for wallstreetdaily.com portrays a great deal of excitement about nanotechnology and the possibilities (I’m highlighting the article because it showcases Dexter Johnson’s Nanoclast blog),

When we talk about next-generation aircraft, next-generation wearable biomedical devices, and next-generation fiber-optic communication, the consistent theme is nano: nanotechnology, nanomaterials, nanophotonics.

For decades, manufacturers have used carbon fiber to make lighter sports equipment, stronger aircraft, and better textiles.

Now, as Dexter Johnson of IEEE [Institute of Electrical and Electronics Engineers] Spectrum reports [on his Nanoclast blog], carbon nanotubes will help make aerospace composites more efficient:

Now researchers at the University of Surrey’s Advanced Technology Institute (ATI), the University of Bristol’s Advanced Composite Centre for Innovation and Science (ACCIS), and aerospace company Bombardier [headquartered in Montréal, Canada] have collaborated on the development of a carbon nanotube-enabled material set to replace the polymer sizing. The reinforced polymers produced with this new material have enhanced electrical and thermal conductivity, opening up new functional possibilities. It will be possible, say the British researchers, to embed gadgets such as sensors and energy harvesters directly into the material.

When it comes to flight, lighter is better, so building sensors and energy harvesters into the body of aircraft marks a significant leap forward.

Johnson also reports for IEEE Spectrum on a “novel hybrid nanomaterial” based on oscillations of electrons — a major advance in nanophotonics:

Researchers at the University of Texas at Austin have developed a hybrid nanomaterial that enables the writing, erasing and rewriting of optical components. The researchers believe that this nanomaterial and the techniques used in exploiting it could create a new generation of optical chips and circuits.

Of course, the concept of rewritable optics is not altogether new; it forms the basis of optical storage mediums like CDs and DVDs. However, CDs and DVDs require bulky light sources, optical media and light detectors. The advantage of the rewritable integrated photonic circuits developed here is that it all happens on a 2-D material.

“To develop rewritable integrated nanophotonic circuits, one has to be able to confine light within a 2-D plane, where the light can travel in the plane over a long distance and be arbitrarily controlled in terms of its propagation direction, amplitude, frequency and phase,” explained Yuebing Zheng, a professor at the University of Texas who led the research… “Our material, which is a hybrid, makes it possible to develop rewritable integrated nanophotonic circuits.”

Who knew that mixing graphene with homemade Silly Putty would create a potentially groundbreaking new material that could make “wearables” actually useful?

Next-generation biomedical devices will undoubtedly include some of this stuff:

A dash of graphene can transform the stretchy goo known as Silly Putty into a pressure sensor able to monitor a human pulse or even track the dainty steps of a small spider.

The material, dubbed G-putty, could be developed into a device that continuously monitors blood pressure, its inventors hope.

The guys who made G-putty often rely on “household stuff” in their research.

It’s nice to see a blogger’s work be highlighted. Congratulations Dexter.

G-putty was mentioned here in a Dec. 30, 2016 posting which also includes a link to Dexter’s piece on the topic.

Soft contact lenses key to supercapacitor breaththrough

It seems like pretty exciting news for anyone following the supercapacitor story but they are being awfully cagey about it all in a Dec. 6, 2016 news item on Nanowerk,

Ground-breaking research from the University of Surrey and Augmented Optics Ltd., in collaboration with the University of Bristol, has developed potentially transformational technology which could revolutionise the capabilities of appliances that have previously relied on battery power to work.

This development by Augmented Optics Ltd., could translate into very high energy density super-capacitors making it possible to recharge your mobile phone, laptop or other mobile devices in just a few seconds.

The technology could have a seismic impact across a number of industries, including transport, aerospace, energy generation, and household applications such as mobile phones, flat screen electronic devices, and biosensors. It could also revolutionise electric cars, allowing the possibility for them to recharge as quickly as it takes for a regular non-electric car to refuel with petrol – a process that currently takes approximately 6-8 hours to recharge. Imagine, instead of an electric car being limited to a drive from London to Brighton, the new technology could allow the electric car to travel from London to Edinburgh without the need to recharge, but when it did recharge for this operation to take just a few minutes to perform.

I imagine the reason for the caginess has to do with the efforts to commercialize the technology. In any event, here’s a little more from a Dec. 5, 2016 University of Surrey press release by Ashley Lovell,

Supercapacitor buses are already being used in China, but they have a very limited range whereas this technology could allow them to travel a lot further between recharges. Instead of recharging every 2-3 stops this technology could mean they only need to recharge every 20-30 stops and that will only take a few seconds.

Elon Musk, of Tesla and SpaceX, has previously stated his belief that supercapacitors are likely to be the technology for future electric air transportation. We believe that the present scientific advance could make that vision a reality.

The technology was adapted from the principles used to make soft contact lenses, which Dr Donald Highgate (of Augmented Optics, and an alumnus of the University of Surrey) developed following his postgraduate studies at Surrey 40 years ago. Supercapacitors, an alternative power source to batteries, store energy using electrodes and electrolytes and both charge and deliver energy quickly, unlike conventional batteries which do so in a much slower, more sustained way. Supercapacitors have the ability to charge and discharge rapidly over very large numbers of cycles. However, because of their poor energy density per kilogramme (approximately just one twentieth of existing battery technology), they have, until now, been unable to compete with conventional battery energy storage in many applications.

Dr Brendan Howlin of the University of Surrey, explained: “There is a global search for new energy storage technology and this new ultra capacity supercapacitor has the potential to open the door to unimaginably exciting developments.”

The ground-breaking research programme was conducted by researchers at the University of Surrey’s Department of Chemistry where the project was initiated by Dr Donald Highgate of Augmented Optics Ltd. The research team was co-led by the Principal Investigators Dr Ian Hamerton and Dr Brendan Howlin. Dr Hamerton continues to collaborate on the project in his new post at the University of Bristol, where the electrochemical testing to trial the research findings was carried out by fellow University of Bristol academic – David Fermin, Professor of Electrochemistry in the School of Chemistry.

Dr Ian Hamerton, Reader in Polymers and Composite Materials from the Department of Aerospace Engineering, University of Bristol said: “While this research has potentially opened the route to very high density supercapacitors, these *polymers have many other possible uses in which tough, flexible conducting materials are desirable, including bioelectronics, sensors, wearable electronics, and advanced optics. We believe that this is an extremely exciting and potentially game changing development.”

*the materials are based on large organic molecules composed of many repeated sub-units and bonded together to form a 3-dimensional network.

Jim Heathcote, Chief Executive of both Augmented Optics Ltd and Supercapacitor Materials Ltd, said: “It is a privilege to work with the teams from the University of Surrey and the University of Bristol. The test results from the new polymers suggest that extremely high energy density supercapacitors could be constructed in the very new future. We are now actively seeking commercial partners [emphasis mine] in order to supply our polymers and offer assistance to build these ultra high energy density storage devices.”

I was not able to find a website for Augmented Optics but there is one for SuperCapacitor Materials here.

Bacteria and an anti-superbug coating from Ireland’s Sligo Institute of Technology

Unlike today’s (April 28, 2016) earlier piece about dealing with bacteria, the focus for this research is on superbugs and not the bacteria which form biofilm on medical implants and such. An April 21, 2016 news item on RTE News makes the announcement about a new means of dealing with superbugs,

A discovery by a team of scientists in Ireland could stem the spread of deadly superbugs predicted to kill millions of people worldwide over the coming decades.

The research has found an agent that can be baked into everyday items like smart-phones and door handles to combat the likes of MRSA and E. coli.

The nanotechnology has a 99.9 % kill rate of potentially lethal and drug-resistant bacteria, they say.

Lead scientist Professor Suresh C. Pillai, of Sligo Institute of Technology’s Nanotechnology Research Group, says the discovery is the culmination of 12 years work.

“This is a game changer,” he said.

“This breakthrough will change the whole fight against superbugs. It can effectively control the spread of bacteria.”

An April 21, 2016 Sligo Institute of Technology press release provides some context for the work and a few details about the coating,

News of the discovery comes just days after UK Chancellor of the Exchequer George Osborne warned that superbugs could become deadlier than cancer and are on course to kill 10 million people globally by 2050.

Speaking at the International Monetary Fund (IMF) in Washington, Mr Osborne warned that the problem would slash global GDP by around €100 trillion if it was not tackled.

Using nanotechnology, the discovery is an effective and practical antimicrobial solution — an agent that kills microorganisms or inhibits their growth — that can be used to protect a range of everyday items.

Items include anything made from glass, metallics and ceramics including computer or tablet screens, smartphones, ATMs, door handles, TVs, handrails, lifts, urinals, toilet seats, fridges, microwaves and ceramic floor or wall tiles.

It will be of particular use in hospitals and medical facilities which are losing the battle against the spread of killer superbugs.

Other common uses would include in swimming pools and public buildings, on glass in public buses and trains, sneeze guards protecting food in delis and restaurants as well as in clean rooms in the medical sector.

“It’s absolutely wonderful to finally be at this stage. This breakthrough will change the whole fight against superbugs. It can effectvely control the spread of bacteria,” said Prof. Pillai.

He continued: “Every single person has a sea of bacteria on their hands. The mobile phone is the most contaminated personal item that we can have. Bacteria grows on the phone and can live there for up to five months. As it is contaminated with proteins from saliva and from the hand, It’s fertile land for bacteria and has been shown to carry 30 times more bacteria than a toilet seat.”

The research started at Dublin Institute of Technology (DIT)’s CREST and involves scientists now based at IT Sligo, Dublin City University (DCU) and the University of Surrey. Major researchers included Dr Joanna Carroll and Dr Nigel S. Leyland.

It has been funded for the past eight years by John Browne, founder and CEO of Kastus Technologies Ltd, who is bringing the product to a global market. He was also supported by significant investment from Enterprise Ireland.

As there is nothing that will effectively kill antibiotic-resistant superbugs completely from the surface of items, scientists have been searching for a way to prevent the spread.

This has been in the form of building or ‘baking’ antimicrobial surfaces into products during the manufacturing process.

However, until now, all these materials were toxic or needed UV light in order to make them work. This meant they were not practical for indoor use and had limited commercial application.

“The challenge was the preparation of a solution that was activated by indoor light rather than UV light and we have now done that,” said Prof Pillai.

The new water-based solution can be sprayed onto any glass, ceramic or metallic surface during the production process, rendering the surface 99.9 per cent resistant to superbugs like MRSA, E. coli and other fungi. [emphasis mine]

The solution is sprayed on the product — such as a smartphone glass surface — and then ‘baked’ into it, forming a super-hard surface. The coating is transparent, permanent and scratch resistant and actually forms a harder surface than the original glass or ceramic material.

The team first developed the revolutionary material to work on ceramics and has spent the last five years adapting the formula – which is non-toxic and has no harmful bi-products ‑- to make it work on glass and metallic surfaces.

Research is now underway by the group on how to adapt the solution for use in plastics and paint, allowing even wider use of the protective material.

Prof Pillai, Kastus and the team have obtained a US and a UK patent on the unique process with a number of global patent applications pending. It is rare for such an academic scientific discovery to have such commercial viability.

“I was sold on this from the first moment I heard about it. It’s been a long road to here but it was such a compelling story that it was hard to walk away from so I had to see it through to the end,” said John Browne, Kastus CEO.

He continued: “This is a game changer. The uniqueness of antimicrobia surface treatment means that the applications for it in the real world are endless. The multinational glass manufacturers we are in negotiations with to sell the product to have been searching for years to come up with such a solution but have failed.”

If the coating kills 99.9%, doesn’t that mean 0.1% are immune? If that’s the case, won’t they reproduce and eventually establish themselves as a new kind of superbug?

Here’s a link to and a citation for the paper,

Highly Efficient F, Cu doped TiO2 anti-bacterial visible light active photocatalytic coatings to combat hospital-acquired infections by Nigel S. Leyland, Joanna Podporska-Carroll, John Browne, Steven J. Hinder, Brid Quilty, & Suresh C. Pillai. Scientific Reports 6, Article number: 24770 (2016) doi:10.1038/srep24770 Published online: 21 April 2016

This paper is open access.

Watching paint dry at the nanoscale

When paint dries it separates itself into two layers and according to scientists this may have implications for improving performance in products ranging from paints to beauty and cosmetics. From a March 18, 2016 news item on ScienceDaily,

New research published today in the journal Physical Review Letters has described a new physical mechanism that separates particles according to their size during the drying of wet coatings. The discovery could help improve the performance of a wide variety of everyday goods, from paint to sunscreen.

A March 18, 2016 University of Surrey (England) press release (also on EurekAlert), which originated the news item, provides more details,

Researchers from the University of Surrey [England, UK] in collaboration with the Université Claude Bernard, Lyon [France] used computer simulation and materials experiments to show how when coatings with different sized particles, such as paints dry, the coating spontaneously forms two layers.

This mechanism can be used to control the properties at the top and bottom of coatings independently, which could help increase performance of coatings across industries as diverse as beauty and pharmaceuticals.

Dr Andrea Fortini, of the University of Surrey and lead author explained:

“When coatings such as paint, ink or even outer layers on tablets are made, they work by spreading a liquid containing solid particles onto a surface, and allowing the liquid to evaporate. This is nothing new, but what is exciting is that we’ve shown that during evaporation, the small particles push away the larger ones, remaining at the top surface whilst the larger are pushed to bottom. This happens naturally.”

Dr Fortini continued, “This type of ‘self-layering’ in a coating could be very useful. For example, in a sun screen, most of the sunlight-blocking particles could be designed to push their way to the top, leaving particles that can adhere to the skin near the bottom of the coating. Typically the particles used in coatings have sizes that are 1000 times smaller than the width of a human hair so engineering these coatings takes place at a microscopic level. ”

The team is continuing to work on such research to understand how to control the width of the layer by changing the type and amount of small particles in the coating and explore their use in industrial products such as paints, inks, and adhesives

Here’s a link to and a citation for the paper,

Dynamic Stratification in Drying Films of Colloidal Mixtures by Andrea Fortini, Ignacio Martín-Fabiani, Jennifer Lesage De La Haye, Pierre-Yves Dugas, Muriel Lansalot, Franck D’Agosto, Elodie Bourgeat-Lami, Joseph L. Keddie, and Richard P. Sear. Phys. Rev. Lett. 116, 118301 – Published 18 March 2016 DOI:http://dx.doi.org/10.1103/PhysRevLett.116.118301

© 2016 American Physical Society

This article is behind a paywall.