Tag Archives: Xiaoshuang Chen

A nonvolatile photo-memristor

Credit: by Xiao Fu, Tangxin Li, Bin Caid, Jinshui Miao, Gennady N. Panin, Xinyu Ma, Jinjin Wang, Xiaoyong Jiang, Qing Lia, Yi Dong, Chunhui Hao, Juyi Sun, Hangyu Xu, Qixiao Zhao, Mengjia Xia, Bo Song, Fansheng Chen, Xiaoshuang Chen, Wei Lu, Weida Hu

it took a while to get there but the February 13, 2023 news item on phys.org announced research into extending memristors from tunable conductance to reconfigurable photo-response,

In traditional vision systems, the optical information is captured by a frame-based digital camera, and then the digital signal is processed afterwards using machine-learning algorithms. In this scenario, a large amount of data (mostly redundant) has to be transferred from a standalone sensing elements to the processing units, which leads to high latency and power consumption.

To address this problem, much effort has been devoted to developing an efficient approach, where some of the memory and computational tasks are offloaded to sensor elements that can perceive and process the optical signal simultaneously.

In a new paper published in Light: Science & Applications, a team of scientists, led by Professor Weida Hu from School of Physics and Optoelectronic Engineering, Hangzhou Institute for Advanced Study, University of Chinese Academy of Sciences, Hangzhou, China, State Key Laboratory of Infrared Physics, Shanghai Institute of Technical Physics, Chinese Academy of Sciences, Shanghai, China, and co-workers have developed a non-volatile photo-memristor, in which the reconfigurable responsivity can be modulated by the charge and/or photon flux through it and further stored in the device.

A February 13, 2023 Chinese Academy of Sciences press release, which originated the news item, provided more technical detail about the work,

The non-volatile photo-memristor has a simple two-terminal architecture, in which photoexcited carriers and oxygen-related ions are coupled, leading to a displaced and pinched hysteresis in the current-voltage characteristics. For the first time, non-volatile photo-memristors implement computationally complete logic with photoresponse-stateful operations, for which the same photo-memristor serves as both a logic gate and memory, using photoresponse as a physical state variable instead of light, voltage and memresistance. Polarity reversal of photo-memristors shows great potential for in-memory sensing and computing with feature extraction and image recognition for neuromorphic vision.

The photo-memristor demonstrates tunable short-circuit current in a non-volatile mode under illumination. By mimicking the biological functionalities of the human retina and designing specific device structures, the devices can act as neural network for neuromorphic visual processing and implementation of completely photoresponse-stateful logic operations triggered by electrical and light stimuli together. It can support various kinds of sensing tasks with all-in-one sensing-memory-computing approaches. These scientists summarize the operational principle and feature of their device:

“We design[ed] a two-terminal device with MoS2-xOx and specific graphene for three purposes in one: (1) to provide low barrier energy for the migration of oxygen ions; (2) to perform as geometry-asymmetric metal–semiconductor–metal van der Waals heterostructures with multi-photoresponse states; and (3) as an extension of a memristor, this device not only provides tunable conductance, but also demonstrates reconfigurable photoresponse for reading at zero bias voltage.”

“Moreover, the tunable short-circuit photocurrent and photoresponse can be increased to 889.8 nA and 98.8 mA/W, respectively, which are much higher than that of other reconfigurable phototransistors based on 2D materials. To reverse the channel polarity and obtain a gate-tunable short-circuit photocurrent, the channel semiconductor must be thin enough. Thus, it is difficult to use the thick film needed to absorb enough light to get a large signal. In our case, the mechanism of the two-terminal device rearrangement is based on ion migration, which is not limited by the thickness. We can increase the thickness of the film to absorb more photons and get a large short-circuit photocurrent.” they added.

“This new concept of a two-terminal photo-memristor not only enables all-in-one sensing-memory-computing approaches for neuromorphic vision hardware, but also brings great convenience for high-density integration.” the scientists forecast.

Here’s a link to and a citation for the paper,

Graphene/MoS2−xOx/graphene photomemristor with tunable non-volatile responsivities for neuromorphic vision processing by Xiao Fu, Tangxin Li, Bin Caid, Jinshui Miao, Gennady N. Panin, Xinyu Ma, Jinjin Wang, Xiaoyong Jiang, Qing Lia, Yi Dong, Chunhui Hao, Juyi Sun, Hangyu Xu, Qixiao Zhao, Mengjia Xia, Bo Song, Fansheng Chen, Xiaoshuang Chen, Wei Lu, Weida Hu. Light: Science & Applications volume 12, Article number: 39 (2023) DOI: https://doi.org/10.1038/s41377-023-01079-5 Published: 07 February 2023

This paper is open access.

Graphene with a pentagonal pattern

Graphene has been viewed, until now, as having an hexgonal (six-sided) pattern. However, researchers have discovered a new graphene pattern according to a Feb. 3, 2015 news item on Nanowerk,

Researchers at Virginia Commonwealth University and universities in China and Japan have discovered a new structural variant of carbon called “penta-graphene” – a very thin sheet of pure carbon that has a unique structure inspired by a pentagonal pattern of tiles found paving the streets of Cairo.

The newly discovered material, called penta-graphene, is a single layer of carbon pentagons that resembles the Cairo tiling, and that appears to be dynamically, thermally and mechanically stable.

A Feb. 3, 2015 Virginia Commonwealth University (VCU) news release by Brian McNeill (also on EurekAlert), which originated the news item, provides more information about the research,

“The three last important forms of carbon that have been discovered were fullerene, the nanotube and graphene. Each one of them has unique structure. Penta-graphene will belong in that category,” said the paper’s senior author, Puru Jena, Ph.D., distinguished professor in the Department of Physics in VCU’s College of Humanities and Sciences.

Qian Wang, Ph.D., a professor at Peking University and an adjunct professor at VCU, was dining in a restaurant in Beijing with her husband when she noticed artwork on the wall depicting pentagon tiles from the streets of Cairo.

“I told my husband, “Come, see! This is a pattern composed only of pentagons,'” she said. “I took a picture and sent it to one of my students, and said, ‘I think we can make this. It might be stable. But you must check it carefully.’ He did, and it turned out that this structure is so beautiful yet also very simple.”

Most forms of carbon are made of hexagonal building blocks, sometimes interspersed with pentagons. Penta-graphene would be a unique two-dimensional carbon allotrope composed exclusively of pentagons.

Along with Jena and Wang, the paper’s authors include Shunhong Zhang, Ph.D candidate, from Peking University; Jian Zhou, Ph.D., a postdoctoral researcher at VCU; Xiaoshuang Chen, Ph.D., from the Chinese Academy of Science in Shanghai; and Yoshiyuki Kawazoe, Ph.D., from Tohoku University in Sendai, Japan.

The researchers simulated the synthesis of penta-graphene using computer modelling. The results suggest that the material might outperform graphene in certain applications, as it would be mechanically stable, possess very high strength, and be capable of withstanding temperatures of up to 1,000 degrees Kelvin.

“You know the saying, diamonds are forever? That’s because it takes a lot of energy to convert diamond back into graphite,” Jena said. “This will be similar.”

Penta-graphene has several interesting and unusual properties, Jena said. For example, penta-graphene is a semiconductor, whereas graphene is a conductor of electricity.

“When you take graphene and roll it up, you make what is called a carbon nanotube which can be metallic or semiconducting,” Jena said. “Penta-graphene, when you roll it up, will also make a nanotube, but it is always semiconducting.”

The way the material stretches is also highly unusual, the researchers said.

“If you stretch graphene, it will expand along the direction it is stretched, but contract along the perpendicular direction.” Wang said. “However, if you stretch penta-graphene, it will expand in both directions.”

The material’s mechanical strength, derived from a rare property known as Negative Poisson’s Ratio, may hold especially interesting applications for technology, the researchers said.

Penta-graphene’s properties suggest that it may have applications in electronics, biomedicine, nanotechnology and more.

The next step, Jena said, is for scientists to synthesize penta-graphene.

“Once you make it, it [will be] very stable. So the question becomes, how do you make it? In this paper, we have some ideas. Right now, the project is theoretical. It’s based on computer modelling, but we believe in this prediction quite strongly. And once you make it, it will open up an entirely new branch of carbon science. Two-dimensional carbon made completely of pentagons has never been known.”

Here’s a graphic representation of the new graphene material,

Caption: The newly discovered material, called penta-graphene, is a single layer of carbon pentagons that resembles the Cairo tiling, and that appears to be dynamically, thermally and mechanically stable. Credit: Virginia Commonwealth University

Caption: The newly discovered material, called penta-graphene, is a single layer of carbon pentagons that resembles the Cairo tiling, and that appears to be dynamically, thermally and mechanically stable.
Credit: Virginia Commonwealth University

Here’s a link to and a citation for the paper,

Penta-graphene: A new carbon allotrope by Shunhong Zhanga, Jian Zhou, Qian Wanga, Xiaoshuang Chen, Yoshiyuki Kawazoe, and Puru Jena. PNAS February 2, 2015 doi: 10.1073/pnas.1416591112 Published online before print February 2, 2015

This paper is behind a paywall.