This December 9, 2020 news item on Nanowerk announces research into a nanodiamond filter which can clean hot wastewater,
Although most of the planet is covered by water, only a fraction of it is clean enough for humans to use. Therefore, it is important to recycle this resource whenever possible. Current purification techniques cannot adequately handle the very hot wastewater generated by some industries.
A December 9, 2020 American Chemical Society (ACS) news release, which originated the news item, provides more detail,
Some oil recovery methods and other industrial processes result in hot wastewater, which requires energy-intensive cooling before it can be purified through traditional reverse osmosis membranes. After purification, the water then needs to be heated before it can be re-used. At such high temperatures, traditional reverse osmosis membranes filter slowly, allowing more salts, solids and other contaminants to get through. Researchers have embedded extremely tiny nanodiamonds — carbon spheres produced by explosions in small, closed containers without oxygen present — onto these membranes in previous studies. Although the membranes effectively and quickly filtered large volumes of water and can protect against fouling, they were not tested with very hot samples. To optimize the membranes for use with hot wastewater, Khorshidi, Sadrzadeh and colleagues wanted to modify the nanodiamond spheres and embed them in a new way.
The team attached amines to nanodiamonds and bathed them in an ethyl acetate solution to prevent the spheres from clumping. Then, a monomer was added that reacted with the amines to create chemical links to the traditional membrane base. Synergistic effects of the amine links and the ethyl acetate treatment resulted in thicker, more temperature-stable membranes, contributing to improvements in their performance. By increasing the amount of amine-enhanced nanodiamonds in the membrane, the researchers obtained higher filtration rates with a greater proportion of impurities being removed, even after 9 hours at 167 F, when compared to membranes without nanodiamonds. The new method produced membranes that could more effectively treat wastewater at high temperatures, the researchers say.
The authors acknowledge funding from Canada’s Oil Sands Innovation Alliance and The Natural Sciences and Engineering Research Council of Canada (NSERC).
Here’s a link to and a citation for the paper,
Nanodiamond-Enabled Thin-Film Nanocomposite Polyamide Membranes for High-Temperature Water Treatment by Pooria Karami, Behnam Khorshidi, Laleh Shamaei, Eric Beaulieu, João B. P. Soares, and Mohtada Sadrzadeh. ACS Appl. Mater. Interfaces 2020, 12, 47, 53274–53285 DOI: https://doi.org/10.1021/acsami.0c15194 Publication Date: November 10, 2020 Copyright © 2020 American Chemical Society
This paper is behind a paywall.