Tag Archives: superconducting materials

Superconductivity with spin

Vivid lines of light tracing a pattern reminiscent of a spinning top toy Courtesy: Harvard University

Vivid lines of light tracing a pattern reminiscent of a spinning top toy Courtesy: Harvard University

An Oct. 14, 2016 Harvard University John A. Paulson School of Engineering and Applied Sciences (SEAS) press release (also on EurekAlert) by Leah Burrows describes how scientists have discovered a way to transmit spin information through supercapacitors,

Researchers from the Harvard John A. Paulson School of Engineering and Applied Sciences (SEAS) have made a discovery that could lay the foundation for quantum superconducting devices. Their breakthrough solves one the main challenges to quantum computing: how to transmit spin information through superconducting materials.

Every electronic device — from a supercomputer to a dishwasher — works by controlling the flow of charged electrons. But electrons can carry so much more information than just charge; electrons also spin, like a gyroscope on axis.

Harnessing electron spin is really exciting for quantum information processing because not only can an electron spin up or down — one or zero — but it can also spin any direction between the two poles. Because it follows the rules of quantum mechanics, an electron can occupy all of those positions at once. Imagine the power of a computer that could calculate all of those positions simultaneously.

A whole field of applied physics, called spintronics, focuses on how to harness and measure electron spin and build spin equivalents of electronic gates and circuits.

By using superconducting materials through which electrons can move without any loss of energy, physicists hope to build quantum devices that would require significantly less power.

But there’s a problem.

According to a fundamental property of superconductivity, superconductors can’t transmit spin. Any electron pairs that pass through a superconductor will have the combined spin of zero.

In work published recently in Nature Physics, the Harvard researchers found a way to transmit spin information through superconducting materials.

“We now have a way to control the spin of the transmitted electrons in simple superconducting devices,” said Amir Yacoby, Professor of Physics and of Applied Physics at SEAS and senior author of the paper.

It’s easy to think of superconductors as particle super highways but a better analogy would be a super carpool lane as only paired electrons can move through a superconductor without resistance.

These pairs are called Cooper Pairs and they interact in a very particular way. If the way they move in relation to each other (physicists call this momentum) is symmetric, then the pair’s spin has to be asymmetric — for example, one negative and one positive for a combined spin of zero. When they travel through a conventional superconductor, Cooper Pairs’ momentum has to be zero and their orbit perfectly symmetrical.

But if you can change the momentum to asymmetric — leaning toward one direction — then the spin can be symmetric. To do that, you need the help of some exotic (aka weird) physics.

Superconducting materials can imbue non-superconducting materials with their conductive powers simply by being in close proximity. Using this principle, the researchers built a superconducting sandwich, with superconductors on the outside and mercury telluride in the middle. The atoms in mercury telluride are so heavy and the electrons move so quickly, that the rules of relativity start to apply.

“Because the atoms are so heavy, you have electrons that occupy high-speed orbits,” said Hechen Ren, coauthor of the study and graduate student at SEAS. “When an electron is moving this fast, its electric field turns into a magnetic field which then couples with the spin of the electron. This magnetic field acts on the spin and gives one spin a higher energy than another.”

So, when the Cooper Pairs hit this material, their spin begins to rotate.

“The Cooper Pairs jump into the mercury telluride and they see this strong spin orbit effect and start to couple differently,” said Ren. “The homogenous breed of zero momentum and zero combined spin is still there but now there is also a breed of pairs that gains momentum, breaking the symmetry of the orbit. The most important part of that is that the spin is now free to be something other than zero.”

The team could measure the spin at various points as the electron waves moved through the material. By using an external magnet, the researchers could tune the total spin of the pairs.

“This discovery opens up new possibilities for storing quantum information. Using the underlying physics behind this discovery provides also new possibilities for exploring the underlying nature of superconductivity in novel quantum materials,” said Yacoby.

Here’s a link to and a citation for the paper,

Controlled finite momentum pairing and spatially varying order parameter in proximitized HgTe quantum wells by Sean Hart, Hechen Ren, Michael Kosowsky, Gilad Ben-Shach, Philipp Leubner, Christoph Brüne, Hartmut Buhmann, Laurens W. Molenkamp, Bertrand I. Halperin, & Amir Yacoby. Nature Physics (2016) doi:10.1038/nphys3877 Published online 19 September 2016

This paper is behind a paywall.

A new, stable open-shell carbon molecule from Oregon

This discovery could one day make organic solar cells more efficient than silicon ones. Researchers at the University of Oregon announced their discovery in a June 9, 2016 news item on ScienceDaily,

University of Oregon chemists have synthesized a stable and long-lasting carbon-based molecule that, they say, potentially could be applicable in solar cells and electronic devices.

The molecule changes its bonding patterns to a magnetic biradical state when heated; it then returns to a fully bonded non-magnetic closed state at room temperature. That transition, they report, can be done repeatedly without decomposition. It remains stable in the presence of both heat and oxygen.

A June 9, 2016 University of Oregon news release on EurekAlert, which originated the news item, provides more detail,

 

Biradical refers to organic compounds, known as open-shell molecules, that have two free-flowing, non-bonding electrons. Producing them using techniques to control their electron spin, and thus provide semiconducting properties, in a heated state has been hampered by instability since the first synthetic biradical hydrocarbon was made in 1907.

“Potentially our approach could help to make organic solar cells more efficient than silicon solar cells, but that’s probably far in the future,” said UO doctoral student Gabriel E. Rudebusch, the paper’s lead author. “Our synthesis is rapid and efficient. We easily can make a gram of this compound, which is very stable when exposed to oxygen and heat. This stability has been almost unheard of in the literature about biradical compounds.”

The four-step synthesis of the compound — diindenoanthracene, or DIAn — and how it held up when tested in superconducting materials were detailed in a proof-of-principle paper published online May 23 by the journal Nature Chemistry. The UO team collaborated with experts in Japan, Spain and Sweden.

The molecular framework for the new molecule involves the hydrocarbon anthracene, which has three linearly fused hexagonal benzene rings, in combination with two five-membered pentagonal rings.

“The big difference between our new molecule and a lot of other biradical molecules that have been produced is those five-membered rings,” said co-author Michael M. Haley, who holds the UO’s Richard M. and Patricia H. Noyes Professorship in Chemistry. “They have the inherent ability to accept electrons or give up electrons. This means DIAn can move both negative and positive charges, which is an essential property for useful devices such as transistors and solar cells. Also, we can heat up our molecule to 150 degrees Celsius, bring it back to room temperature and heat it up again, repeatedly, and we see no decomposition in its reaction to oxygen. The unique features of DIAn are essential if these molecules are to have a use in the real world.”

Haley’s lab is now seeking to develop derivatives of the new molecule to help move the technology forward into potential applications.

Here’s a link to and a citation for the paper,

Diindeno-fusion of an anthracene as a design strategy for stable organic biradicals by Gabriel E. Rudebusch, José L. Zafra, Kjell Jorner, Kotaro Fukuda, Jonathan L. Marshall, Iratxe Arrechea-Marcos, Guzmán L. Espejo, Rocío Ponce Ortiz, Carlos J. Gómez-García, Lev N. Zakharov, Masayoshi Nakano, Henrik Ottosson, Juan Casado & Michael M. Haley. Nature Chemistry (2016)  doi:10.1038/nchem.2518 Published online 23 May 2016

This paper is behind a paywall.

There is another June 9, 2016 University of Oregon news release by Jim Barlow about this discovery. It covers much of the same material but focuses more closely on Rudebusch’s perspective.