Tag Archives: nanoscience

Mixing the unmixable for all new nanoparticles

This news comes out of the University of Maryland and the discovery could led to nanoparticles that have never before been imagined. From a March 29, 2018 news item on ScienceDaily,

Making a giant leap in the ‘tiny’ field of nanoscience, a multi-institutional team of researchers is the first to create nanoscale particles composed of up to eight distinct elements generally known to be immiscible, or incapable of being mixed or blended together. The blending of multiple, unmixable elements into a unified, homogenous nanostructure, called a high entropy alloy nanoparticle, greatly expands the landscape of nanomaterials — and what we can do with them.

This research makes a significant advance on previous efforts that have typically produced nanoparticles limited to only three different elements and to structures that do not mix evenly. Essentially, it is extremely difficult to squeeze and blend different elements into individual particles at the nanoscale. The team, which includes lead researchers at University of Maryland, College Park (UMD)’s A. James Clark School of Engineering, published a peer-reviewed paper based on the research featured on the March 30 [2018] cover of Science.

A March 29, 2018 University of Maryland press release (also on EurekAlert), which originated the news item, delves further (Note: Links have been removed),

“Imagine the elements that combine to make nanoparticles as Lego building blocks. If you have only one to three colors and sizes, then you are limited by what combinations you can use and what structures you can assemble,” explains Liangbing Hu, associate professor of materials science and engineering at UMD and one of the corresponding authors of the paper. “What our team has done is essentially enlarged the toy chest in nanoparticle synthesis; now, we are able to build nanomaterials with nearly all metallic and semiconductor elements.”

The researchers say this advance in nanoscience opens vast opportunities for a wide range of applications that includes catalysis (the acceleration of a chemical reaction by a catalyst), energy storage (batteries or supercapacitors), and bio/plasmonic imaging, among others.

To create the high entropy alloy nanoparticles, the researchers employed a two-step method of flash heating followed by flash cooling. Metallic elements such as platinum, nickel, iron, cobalt, gold, copper, and others were exposed to a rapid thermal shock of approximately 3,000 degrees Fahrenheit, or about half the temperature of the sun, for 0.055 seconds. The extremely high temperature resulted in uniform mixtures of the multiple elements. The subsequent rapid cooling (more than 100,000 degrees Fahrenheit per second) stabilized the newly mixed elements into the uniform nanomaterial.

“Our method is simple, but one that nobody else has applied to the creation of nanoparticles. By using a physical science approach, rather than a traditional chemistry approach, we have achieved something unprecedented,” says Yonggang Yao, a Ph.D. student at UMD and one of the lead authors of the paper.

To demonstrate one potential use of the nanoparticles, the research team used them as advanced catalysts for ammonia oxidation, which is a key step in the production of nitric acid (a liquid acid that is used in the production of ammonium nitrate for fertilizers, making plastics, and in the manufacturing of dyes). They were able to achieve 100 percent oxidation of ammonia and 99 percent selectivity toward desired products with the high entropy alloy nanoparticles, proving their ability as highly efficient catalysts.

Yao says another potential use of the nanoparticles as catalysts could be the generation of chemicals or fuels from carbon dioxide.

“The potential applications for high entropy alloy nanoparticles are not limited to the field of catalysis. With cross-discipline curiosity, the demonstrated applications of these particles will become even more widespread,” says Steven D. Lacey, a Ph.D. student at UMD and also one of the lead authors of the paper.

This research was performed through a multi-institutional collaboration of Prof. Liangbing Hu’s group at the University of Maryland, College Park; Prof. Reza Shahbazian-Yassar’s group at University of Illinois at Chicago; Prof. Ju Li’s group at the Massachusetts Institute of Technology; Prof. Chao Wang’s group at Johns Hopkins University; and Prof. Michael Zachariah’s group at the University of Maryland, College Park.

What outside experts are saying about this research:

“This is quite amazing; Dr. Hu creatively came up with this powerful technique, carbo-thermal shock synthesis, to produce high entropy alloys of up to eight different elements in a single nanoparticle. This is indeed unthinkable for bulk materials synthesis. This is yet another beautiful example of nanoscience!,” says Peidong Yang, the S.K. and Angela Chan Distinguished Professor of Energy and professor of chemistry at the University of California, Berkeley and member of the American Academy of Arts and Sciences.

“This discovery opens many new directions. There are simulation opportunities to understand the electronic structure of the various compositions and phases that are important for the next generation of catalyst design. Also, finding correlations among synthesis routes, composition, and phase structure and performance enables a paradigm shift toward guided synthesis,” says George Crabtree, Argonne Distinguished Fellow and director of the Joint Center for Energy Storage Research at Argonne National Laboratory.

More from the research coauthors:

“Understanding the atomic order and crystalline structure in these multi-element nanoparticles reveals how the synthesis can be tuned to optimize their performance. It would be quite interesting to further explore the underlying atomistic mechanisms of the nucleation and growth of high entropy alloy nanoparticle,” says Reza Shahbazian-Yassar, associate professor at the University of Illinois at Chicago and a corresponding author of the paper.

“Carbon metabolism drives ‘living’ metal catalysts that frequently move around, split, or merge, resulting in a nanoparticle size distribution that’s far from the ordinary, and highly tunable,” says Ju Li, professor at the Massachusetts Institute of Technology and a corresponding author of the paper.

“This method enables new combinations of metals that do not exist in nature and do not otherwise go together. It enables robust tuning of the composition of catalytic materials to optimize the activity, selectivity, and stability, and the application will be very broad in energy conversions and chemical transformations,” says Chao Wang, assistant professor of chemical and biomolecular engineering at Johns Hopkins University and one of the study’s authors.

Here’s a link to and a citation for the paper,

Carbothermal shock synthesis of high-entropy-alloy nanoparticles by Yonggang Yao, Zhennan Huang, Pengfei Xie, Steven D. Lacey, Rohit Jiji Jacob, Hua Xie, Fengjuan Chen, Anmin Nie, Tiancheng Pu, Miles Rehwoldt, Daiwei Yu, Michael R. Zachariah, Chao Wang, Reza Shahbazian-Yassar, Ju Li, Liangbing Hu. Science 30 Mar 2018: Vol. 359, Issue 6383, pp. 1489-1494 DOI: 10.1126/science.aan5412

This paper is behind a paywall.

Book announcement: Nanotechnology: The Future is Tiny

The book has a pretty cover (carbon nanotubes in the left corner, nanoparticles? next, and a circuit board to complete the image),

NanowerkBook_NanoFutureIsTiny

The book, written by Michael Berger, publisher of the Nanowerk website, was announced in an Aug. 31, 2016 Nanowerk Spotlight article (Note: Links have been removed),

“Nanotechnology: The Future is Tiny” puts a spotlight on some of the scientists who are pushing the boundaries of technology and it gives examples of their work and how they are advancing knowledge one little step at a time.

Written by Nanowerk’s Michael Berger, this book is a collection of essays about researchers involved in all facets of nanotechnologies. Nanoscience and nanotechnology research are truly multidisciplinary and international efforts, covering a wide range of scientific disciplines such as medicine, materials sciences, chemistry, biology and biotechnology, physics and electronics.

Here’s more about the book before I comment on the marketing (from the Nanotechnology: The Future is Tiny webpage on the Royal Society of Chemistry’s website),

Nanotechnology: The Future is Tiny introduces 176 different research projects from around the world that are exploring the different areas of nanotechnologies. Using interviews and descriptions of the projects, the collection of essays provides a unique commentary on the current status of the field. From flexible electronics that you can wear to nanomaterials used for cancer diagnostics and therapeutics, the book gives a new perspective on the current work into developing new nanotechnologies. Each chapter delves into a specific area of nanotechnology research including graphene, energy storage, electronics, 3D printing, nanomedicine, nanorobotics as well as environmental implications.

Through the scientists’ own words, the book gives a personal perspective on how nanotechnologies are created and developed, and an exclusive look at how today’s research will create tomorrow’s products and applications. This book will appeal to anyone who has an interest in the research and future of nanotechnology.

Publication Details
Print publication date: 30 Aug 2016
Copyright: 2016
Print ISBN: 978-1-78262-526-1
PDF eISBN: 978-1-78262-887-3
EPUB eISBN: 978-1-78262-888-0
DOI:10.1039/9781782628873

According to Berger’s description of his book (from the Aug. 31, 2016 Nanowerk Spotlight article),

Some stories are more like an introduction to nanotechnology, some are about understanding current developments, and some are advanced technical discussions of leading edge research. Reading this book will shatter the monolithic term “nanotechnology” into the myriad of facets that it really is.

Berger has taken on a very challenging task for a writer. It’s very difficult to produce a book that will satisfy the range of audiences described. Appealing to a different audience in each chapter is probably the only way to approach the task.  I think the book may prove especially useful for someone who’s more of a beginner or intermediate because it lets you find your level and as you grow in confidence you can approach more challenging chapters. The mystery is which chapters are for beginner/intermediates?

A rather interesting marketing strategy has been adopted, which has direct bearing on this mystery. The publisher, the Royal Society of Chemistry (RSC), has made some material available for free (sort of). There is no direct charge for the Front Matter, the Preface, the Table of Contents, or Chapter 1: Generating Energy Becomes Personal but you do need registration to access the materials. Plus, I believe they’re having a problem of some kind as the same information was accessed each time I clicked whether it was on the Front Matter, the Preface, or the Table of Contents. As for Chapter 1, you will get an abstract only.

You can purchase chapters individually or buy the hardback version of the book for £66.99 or the full ebook (EPUB) version for £200.97. Chapter 2: No More Rigid Boxes—Fully Flexible and Transparent Electronics (PDF) is available for £28.00. The pricing seems designed to encourage hardback purchases. It seems anyone who only wants one chapter is going to have guess as to whether it was written for an expert, a beginner, or someone in between.

Depending on your circumstances, taking a chance may be worth it. Based on the Nanowerk Spotlight articles, Berger writes with clarity and understanding of his subject matter. I’ve found value even in some of his more challenging pieces.

Nanotechnology and the European Economy; Nokia and IBM’s augmented reality meetings; Don Eigler hypes nanotechnology; physical/virtual/augmented reality meetings with IBM and Nokia

In keeping with my belief that the developments I’m observing are threads in a complex conversation (as per yesterday’s [Oct.20.09] posting), I’m back to highlighting various news items that hint at possible trends.

The European Commission’s Directorate-General for Research has published a call for proposals to study the economic impact of nanotechnology and nanosciences. You can get more details here on Azonano or view the call here.

There’s an interview with Don Eigler, the IBM scientist who’s known for moving Xenon atoms individually so they spell out IBM, in New Scientist here. Interestingly, Mr. Eigler does not have any concerns with regard to health fears related to nanotechnology. He’s aware of toxicology issues but he thinks that if we get it right, there’ll be very few problems, if any.

Following on my ‘nature of reality’ kick, this item about IBM and Nokia developing software that allows virtual reality/augmented reality meetings in physical space caught my attention.From the news item on Physorg.com

With support from IBM Research and Nokia Research Center, the VTT Technical Research Centre of Finland created an experimental system that enables people in multiple locations to interact and collaborate with avatars and objects in a single, virtual meeting . Objects and avatars are located in a “virtual” space that mirrors the corresponding physical room.

There is a video included with the story and it looked like the meeting was taking place in three spaces, two of them were physical and one was virtual. One office (physical) had two people who were interacting with virtual objects while simultaneously meeting in a virtual meeting room with their avatars and the same virtual objects they’d been interacting with in the physical space. A third person (in a geographically removed physical office) joined them in the virtual meeting. Do take a look.

The questions that spring to my mind are these: are all the spaces real? Is one space more real than the others and why? Some might argue that the virtual space is less real because it isn’t physical but then neither are your emotions. Also in the postings here about perception and quantum realities (Oct. 16, 19, and 20, 2009), I noted that our perceptions of reality at the macro level do not coincide with the realities of the quantum world which occasions this questions, What is the nature of reality?