Tag Archives: Ireland

‘What becomes of the broken-hearted?’ Trinity College Dublin scientists may have an answer

Leave a reply

While Valentine’s Day as celebrated here in Canada and elsewhere (but not everywhere) on February 14 of each year is usually marked in a purely joyous fashion,I’m going to focus on heartbreak. Here is one of the greatest versions of ‘What becomes of the broken-hearted?’ Then, repair follows in the context of some cardiac research coming out of Ireland,

Thank you Joan Osborne and the Funk Brothers. If you haven’t seen ‘Standing in the shadows of Motown’, you may want to make a point of it.

As for the musical question in the headline, researchers at Trinity College Dublin may have an answer of sorts. A February 13, 2020 Trinity College Dublin press release (also on EurekAlert) describes how broken hearts can be mended,

Bioengineers from Trinity College Dublin, Ireland, have developed a prototype patch that does the same job as crucial aspects of heart tissue.

Their patch withstands the mechanical demands and mimics the electrical signalling properties that allow our hearts to pump blood rhythmically round our bodies.

Their work essentially takes us one step closer to a functional design that could mend a broken heart.

One in six men and one in seven women in the EU will suffer a heart attack at some point in their lives. Worldwide, heart disease kills more women and men – regardless of race, than any other disease.

Cardiac patches lined with heart cells can be applied surgically to restore heart tissue in patients who have had damaged tissue removed after a heart attack and to repair congenital heart defects in infants and children. Ultimately, though, the goal is to create cell-free patches that can restore the synchronous beating of the heart cells, without impairing the heart muscle movement.

The bioengineers report their work, which takes us one step closer to such a reality, in the journal Advanced Functional Materials.

Michael Monaghan, ussher assistant professor in biomedical engineering at Trinity, and senior author on the paper, said:

“Despite some advances in the field, heart disease still places a huge burden on our healthcare systems and the life quality of patients worldwide. It affects all of us either directly or indirectly through family and friends. As a result, researchers are continuously looking to develop new treatments which can include stem cell treatments, biomaterial gel injections and assistive devices.”

“Ours is one of few studies that looks at a traditional material, and through effective design allows us to mimic the direction-dependent mechanical movement of the heart, which can be sustained repeatably. This was achieved through a novel method called ‘melt electrowriting’ and through close collaboration with the suppliers located nationally we were able to customise the process to fit our design needs.”

This work was performed in the Trinity Centre for Biomedical Engineering, based in the Trinity Biomedical Sciences Institute in collaboration with Spraybase®, a subsidiary of Avectas Ltd. It was funded by Enterprise Ireland through the Innovation Partnership Program (IPP).

Dr Gillian Hendy, director of Spraybase® is a co-author on the paper. Dr Hendy commended the team at Trinity on the work completed and advancements made on the Spraybase® Melt Electrowriting (MEW) System. The success achieved by the team highlights the potential applications of this novel technology in the cardiac field and succinctly captures the benefits of industry and academic collaboration, through platforms such as the IPP.

Engineering replacement materials for heart tissue is challenging since it is an organ that is constantly moving and contracting. The mechanical demands of heart muscle (myocardium) cannot be met using polyester-based thermoplastic polymers, which are predominantly the approved options for biomedical applications.

However, the functionality of thermoplastic polymers could be leveraged by its structural geometry. The bioengineers then set about making a patch that could control the expansion of a material in multiple directions and tune this using an engineering design approach.

The patches were manufactured via melt electrowriting – a core technology of Spraybase® – which is reproducible, accurate, and scalable. The patches were also coated with the electroconductive polymer polypyrrole to provide electrical conductivity while maintaining cell compatibility.

The patch withstood repeated stretching, which is a dominant concern for cardiac biomaterials, and showed good elasticity, to accurately mimic that key property of heart muscle.

Professor Monaghan added:

“Essentially, our material addresses a lot of requirements. The bulk material is currently approved for medical device use, the design accommodates the movement of the pumping heart, and has been functionalised to accommodate signaling between isolated contractile tissues.”

“This study currently reports the development of our method and design, but we are now looking forward to furthering the next generation of designs and materials with the eventual aim of applying this patch as a therapy for a heart attack.”

Dr Dinorath Olvera, Trinity, first author on the paper, added:

“Our electroconductive patches support electrical conduction between biological tissue in an ex vivo model. These results therefore represent a significant step towards generating a bioengineered patch capable of recapitulating aspects of heart tissue – namely its mechanical movement and electrical signalling.”

Here’s a link to and a citation for the paper,

Electroconductive Melt Electrowritten Patches Matching the Mechanical Anisotropy of Human Myocardium by Dinorath Olvera, Mina Sohrabi Molina, Gillian Hendy, Michael G. Monaghan. Advanced Functional Materials DOI: https://doi.org/10.1002/adfm.201909880 First published: 12 February 2020

This paper is behind a paywall.

Here are links, should you be interested in the company partnering with the researchers, Spraybase®, or its parent company, Avectas Ltd.

Finally, the singer who made ‘What becomes of the broken-hearted?’ a hit in 1965 was Jimmy Ruffin,

Enjoy.

Science inspired by superheroes, Ant-Man and the Wasp

Leave a reply

It’s interesting to see scientists take science fiction and use it as inspiration; something which I think happens more often than we know. After all, when someone asks where you got an idea, it can be difficult to track down the thought process that started it all.

Scientists at Virginia Tech (Virginia Polytechnic Institute and State University) are looking for a new source of inspiration after offering a close examination of how insect-size superheroes, Ant-Man and the Wasp might breathe. From a December 11, 2018 news item on phys.org (Note: A link has been removed),

Max Mikel-Stites and Anne Staples were searching for a sequel.

This summer, Staples, an associate professor in the Department of Biomedical Engineering and Mechanics in the College of Engineering, and graduate student Mikel-Stites published a paper in the inaugural issue of the Journal of Superhero Science titled, “Ant-Man and the Wasp: Microscale Respiration and Microfluidic Technology.”

Now, they needed a new hero.

The two were working with a team of graduate students, brainstorming who could be the superhero subject for their next scientific inquiry. Superman? Batgirl? Aquaman?

Mikel-Stites lobbied for an investigation of Dazzler’s sonoluminescent powers. Staples was curious how Mera, The Princes sof Atlantis, used her hydrokinetic powers.

It turns out, comic books are a great inspiration for scientific discovery.

This month, Mikel-Stites is presenting the findings of their paper at the American Physical Society’s Division of Fluid Dynamics meeting.

The wonder team’s paper looked at how Ant-Man and the Wasp breathe when they shrink down to insect-size and Staples’ lab studied how fluids flow in nature. Insects naturally move fluids and gases efficiently at tiny scales. If engineers can learn how insects breathe, they can use the knowledge to invent new microfluidic technologies.

A November 2018 Virginia Tech news release (also on EurekAlert but published on December 11, 2018) by Nancy Dudek describes the ‘Ant-Man and Wasp respiratory project’ before revealing the inspiration for the team’s new project,

“Before the 2018 ‘Ant-Man and the Wasp’ movie, my lab was already wondering about insect-scale respiration,” said Staples. “I wanted to get people to appreciate different breathing mechanisms.”

For most of Mikel-Stites’ life, he had been nit-picking at the “science” in science-fiction movies.

“I couldn’t watch ‘Armageddon’ once they got up to space station Mir and there was artificial gravity. Things like that have always bothered me. But for ‘Ant-Man and the Wasp’ it was worse,” he said.

Staples and Mikel-Stites decided to join forces to research Ant-Man’s microscale respiration.

Mikel-Stites was stung by what he dubbed “the altitude problem or death-zone dilemma.” For Ant-Man and the Wasp to shrink down to insect size and still breathe, they would have to overcome an atmospheric density similar to the top of Mt. Everest. Their tiny bodies would also require higher metabolisms. For their survival, the Marvel comic universe had to give Ant-Man and the Wasp superhero technologies.

“I thought it would be fun to find a solution for how this small-scale respiration would work,”said Mikel-Stites.”I started digging through Ant-Man’s history. I looped through scenes in the 2015 movie where we could address the physics. Then I did the same thing with trailers from the 2018 movie. I used that to make a list of problems and a list of solutions.”

Ant-Man and the Wasp solve the altitude problem with their superhero suits. In their publication, Mikel-Stites and Staples write that the masks in Ant-Man and the Wasp’s suits contain “a combination of an air pump, a compressor, and a molecular filter including Pym particle technology,” that allows them to breathe while they are insect-sized.

“This publication showed how different physics phenomena can dominate at different size scales, how well-suited organisms are for their particular size, and what happens when you start altering that,” said Mikel-Stites. “It also shows that Hollywood doesn’t always get it right when it comes to science!”

Their manuscript was accepted by the Journal of Superhero Science before the release of the sequel, “Ant-Man and the Wasp.” Mikel-Stites was concerned the blockbuster might include new technologies or change Ant-Man’s canon. If the Marvel comic universe changed between the 2015 ‘Ant-Man’ movie and the sequel, their hypotheses would be debunked and they would be forced to retract their paper.

“I went to the 2018 movie before the manuscript came out in preprint so that if the movie contradicted us we could catch it. But the 2018 movie actually supported everything we had said, which was really nice,” said Mikel-Stites. Most moviegoers simply watched the special effects and left the theater entertained. But Mikel-Stitesleft the movie with confirmation of the paper’s hypotheses.

The Staples lab members are not the only ones interested in tiny technologies. From lab-on-a-chip microfluidic devices to nanoparticles that deliver drugs directly to cells, consumers will ultimately benefit from this small scientific field that delivers big results.

“In both the movies and science, shrinking is a common theme and has been for the last 50-60 years. This idea is something that we all like to think about. Given enough time, we can reach the point where science can take it from the realms of magic into something that we actually have an explanation for,” Mikel-Stites said.

In fact, the Staples lab group has already done just that.

While Mikel-Stites is presenting his superhero science at the APS meeting, his colleague Krishnashis Chatterjee, who recently completed his Ph.D. in engineering mechanics will be presenting his research on fabricating and testing four different insect-inspired micro-fluidic devices.

From fiction to function, the Staples lab likes to have fun along the way.

“I think that it is really important to connect with people and be engaged in science with topics they already know about. With this superhero science paper I wanted to support this mission,” Staples said.

And who did the lab mates choose for their next superhero science subject? The Princess of Atlantis, Mera. They hope they can publish another superhero science paper that really makes waves.

Here’s a link to and a citation for the paper,

Ant-Man and The Wasp: Microscale Respiration and Microfluidic Technology by Anne Staples and Maxwell Mikel-Stites. Superhero Science and Technology (SST) Vol 1 No 1 (2018): https://doi.org/10.24413/sst.2018.1.2474 July 2018 ISSN 2588-7637

This paper is open access.

And, just because the idea of a superhero science journal tickles my fancy, here’s a little more from the journal’s About webpage,

Serial title
Superhero Science and Technolog

Focus and Scope
Superhero Science and Technology (SST) is multi-disciplinary journal that considers new research in the fields of science, technology, engineering and ethics motivated and presented using the superhero genre.

The superhero genre has become one of the most popular in modern cinema. Since the 2000 film X-Men, numerous superhero-themed films based on characters from Marvel Comics and DC Comics have been released. Films such as The Avengers, Iron Man 3, Avengers: Age of Ultron and Captain America: Civil War have all earned in excess of $1 billion dollars at the box office, thus demonstrating their relevance in modern society and popular culture.

Of particular interest for Superhero Science and Technology are articles that motivate new research by using the platform of superheroes, supervillains, their superpowers, superhero/supervillain exploits in Hollywood blockbuster films or superhero/supervillain adventures from comic books. Articles should be written in a manner so that they are accessible to both the academic community and the interested non-scientist i.e. general public, given the popularity of the superhero genre.

Dissemination of content using this approach provides a potential for the researcher to communicate their work to a larger audience, thus increasing their visibility and outreach within and outside of the academic domain.

The scope of the journal includes but is not limited to:
Genetic editing approaches;
Innovations in the field of robotics;
New and advanced materials;
Additive Manufacturing i.e. 3D printing, for both bio and non-bio applications;
Advancements in bio-chemical processing;
Biomimicry technologies;
Space physics, astrophysical and cosmological research;
Developments in propulsion systems;
Responsible innovation;
Ethical issues pertaining to technologies and their use for human enhancement or augmentation.

Open Access Policy
SST is licensed under a Creative Commons Attribution 4.0 International (CC BY 4.0) licence. You are free to use the work, but you have to attribute (refer to) the work in the manner specified by the author or licensor (but not in any way that suggests that they endorse you or your use of the work). The easiest way to refer to an article is to use the HOWTO CITE tool that you’ll find alongside each article in the right sidebar.

…

I also looked up the editorial team, from the journal’s Editorial Team webpage,

Editor-in-Chief
Dr. Barry W. Fitzgerald, TU Delft, the Netherlands
Editorial Board
Prof. Wim Briels, University of Twente, the Netherlands
Dr. Ian Clancy, University of Limerick, Ireland
Dr. Neil Clancy, University College London, UK
Dr. Tom Hunt, University of Kent, UK
Ass. Prof. Johan Padding, TU Delft, the Netherlands
Ass. Prof. Aimee van Wynsberghe, TU Delft, the Netherlands
Prof. Ilja Voets, TU Eindhoven, the Netherlands


For anyone unfamiliar with the abbreviation, TU stands for University of Technology or Technische Universiteit in Dutch.

Cellulose biosensor heralds new bioimaging approach to tissue engineering

Leave a reply

I keep an eye on how nanocellulose is being used in various applications and I’m not sure that this cellulose biosensor quite fits the bill as nanocellulose, nonetheless, it’s interesting and that’s enough for me. From a December 12, 2018 Sechenov University (Russia) press release on EurekAlert,

I.M. Sechenov First Moscow State Medical University teamed up together with Irish colleagues to develop a new imaging approach for tissue engineering. The team produced so-called ‘hybrid biosensor’ scaffold materials, which are based on cellulose matrices labeled with pH- and calcium-sensitive fluorescent proteins. These materials enable visualization of the metabolism and other important biomarkers in the engineered artificial tissues by microscopy. The results of the work were published in the Acta Biomaterialia journal.
The success of tissue engineering is based on the use of scaffold matrices – materials that support the viability and direct the growth of cells, tissues, and organoids. Scaffolds are important for basic and applied biomedical research, tissue engineering and regenerative medicine, and are promising for development of new therapeutics. However, the ability ‘to see’ what happens within the scaffolds during the tissue growth poses a significant research challenge

“We developed a new approach allowing visualization of scaffold-grown tissue and cells by using labeling with biosensor fluorescent proteins. Due to the high specificity of labeling and the use of fluorescence microscopy FLIM, we can quantify changes in pH and calcium in the vicinity of cells,” says Dr. Ruslan Dmitriev, Group Leader at the University College Cork and the Institute for Regenerative Medicine (I.M. Sechenov First Moscow State Medical University).
To achieve the specific labeling of cellulose matrices, researchers used well-known cellulose-binding proteins. The use of extracellular pH- and calcium-sensitive biosensors allow for analysis of cell metabolism: indeed, the extracellular acidification is directly associated with the balance of cell energy production pathways and the glycolytic flux (release of lactate). It is also a frequent hallmark of cancer and transformed cell types. On the other hand, calcium plays a key role in the extra- and intracellular signaling affecting cell growth and differentiation.

The approach was tested on different types of cellulose matrices (bacterial and produced from decellularised plant tissues) using 3D culture of human colon cancer cells and stem-cell derived mouse small intestinal organoids. The scaffolds informed on changes in the extracellular acidification and were used together with the analysis of real-time oxygenation of intestinal organoids. The resulting data can be presented in the form of colour maps, corresponding to the areas of cell growth within different microenvironments.

“Our results open new prospects in the imaging of tissue-engineered constructs for regenerative medicine. They enable deeper understanding of tissue metabolism in 3D and are also highly promising for commercialisation,” concludes Dr. Dmitriev.

The researchers have provided an image to illustrate their work,

Caption: A 3D reconstruction of a cellulose matrix stained with a pH-sensitive biosensor. Credit: Dr. R. Dmitriev

Here’s a link to and a citation for the paper,

Cellulose-based scaffolds for fluorescence lifetime imaging-assisted tissue engineering by Neil O’Donnell, Irina A. Okkelman, Peter Timashev, Tatyana I.Gromovykh, Dmitri B. Papkovsky, Ruslan I.Dmitriev. Acta Biomaterialia Volume 80, 15 October 2018, Pages 85-96 DOI: https://doi.org/10.1016/j.actbio.2018.09.034


This paper is behind a paywall.

Tracks of my tears could power smartphone?

Leave a reply

So far the researchers aren’t trying to power anything with tears but they have discovered that tears could be used to generate electricity (from an Oct. 2, 2017 news item on phys.org),

A team of Irish scientists has discovered that applying pressure to a protein found in egg whites and tears can generate electricity. The researchers from the Bernal Institute, University of Limerick (UL), Ireland, observed that crystals of lysozyme, a model protein that is abundant in egg whites of birds as well as in the tears, saliva and milk of mammals can generate electricity when pressed. Their report is published today (October 2) in the journal, Applied Physics Letters.

An Oct. 2, 2017 University of Limerick press release (also on EurekAlert), which originated the news item, offers additional detail,

The ability to generate electricity by applying pressure, known as direct piezoelectricity, is a property of materials such as quartz that can convert mechanical energy into electrical energy and vice versa. Such materials are used in a variety of applications ranging from resonators and vibrators in mobile phones to deep ocean sonars and ultrasound imaging. Bone, tendon and wood are long known to possess piezoelectricity.

“While piezoelectricity is used all around us, the capacity to generate electricity from this particular protein had not been explored. The extent of the piezoelectricity in lysozyme crystals is significant. It is of the same order of magnitude found in quartz. However, because it is a biological material, it is non toxic so it could have many innovative applications such as electroactive anti-microbial coatings for medical implants,” explained Aimee Stapleton, the lead author and an Irish Research Council EMBARK Postgraduate Fellow in the Department of Physics and Bernal Institute of UL.

Crystals of lysozyme are easy to make from natural sources. “The high precision structure of lysozyme crystals has been known since 1965,” said structural biologist at UL and co-author Professor Tewfik Soulimane.
“In fact, it is the second protein structure and the first enzyme structure that was ever solved,” he added, “but we are the first to use these crystals to show the evidence of piezoelectricity”.

According to team leader Professor Tofail Syed of UL’s Department of Physics, “Crystals are the gold-standard for measuring piezoelectricity in non-biological materials. Our team has shown that the same approach can be taken in understanding this effect in biology. This is a new approach as scientists so far have tried to understand piezoelectricity in biology using complex hierarchical structures such as tissues, cells or polypeptides rather than investigating simpler fundamental building blocks”.

The discovery may have wide reaching applications and could lead to further research in the area of energy harvesting and flexible electronics for biomedical devices. Future applications of the discovery may include controlling the release of drugs in the body by using lysozyme as a physiologically mediated pump that scavenges energy from its surroundings. Being naturally biocompatible and piezoelectric, lysozyme may present an alternative to conventional piezoelectric energy harvesters, many of which contain toxic elements such as lead.

Professor Luuk van der Wielen, Director of Bernal Institute and Bernal Professor of Biosystems Engineering and Design expressed his delight at this breakthrough by UL scientists.

“The €109-million Bernal Institute has the ambition to impact the world on the basis of top science in an increasingly international context. The impact of this discovery in the field of biological piezoelectricity will be huge and Bernal scientists are leading from the front the progress in this field,” he said.

Here’s a link to and a citation for the paper,

The direct piezoelectric effect in the globular protein lysozyme featured by A. Stapleton, M. R. Noor, J. Sweeney, V. Casey, A. L. Kholkin, C. Silien, A. A. Gandhi, T. Soulimane, and S. A. M. Tofail. Appl. Phys. Lett. 111, 142902 (2017); doi: http://dx.doi.org/10.1063/1.4997446

This paper is open access.

As for Tracks of My Tears,

Nanowire fingerprint technology

Leave a reply

Apparently this technology from France’s Laboratoire d’électronique des technologies de l’information (CEA-Leti) will make fingerprinting more reliable. From a Sept. 5, 2017 news item on Nanowerk,

Leti today announced that the European R&D project known as PiezoMAT has developed a pressure-based fingerprint sensor that enables resolution more than twice as high as currently required by the U.S. Federal Bureau of Investigation (FBI).

The project’s proof of concept demonstrates that a matrix of interconnected piezoelectric zinc-oxide (ZnO) nanowires grown on silicon can reconstruct the smallest features of human fingerprints at 1,000 dots per inch (DPI).

“The pressure-based fingerprint sensor derived from the integration of piezo-electric ZnO nanowires grown on silicon opens the path to ultra-high resolution fingerprint sensors, which will be able to reach resolution much higher than 1,000 DPI,” said Antoine Viana, Leti’s project manager. “This technology holds promise for significant improvement in both security and identification applications.”

A Sept. 5, 2017 Leti press release, which originated the news item, delves further,

The eight-member project team of European companies, universities and research institutes fabricated a demonstrator embedding a silicon chip with 250 pixels, and its associated electronics for signal collection and post-processing. The chip was designed to demonstrate the concept and the major technological achievements, not the maximum potential nanowire integration density. Long-term development will pursue full electronics integration for optimal sensor resolution.

The project also provided valuable experience and know-how in several key areas, such as optimization of seed-layer processing, localized growth of well-oriented ZnO nanowires on silicon substrates, mathematical modeling of complex charge generation, and synthesis of new polymers for encapsulation. The research and deliverables of the project have been presented in scientific journals and at conferences, including Eurosensors 2016 in Budapest.

The 44-month, €2.9 million PiezoMAT (PIEZOelectric nanowire MATrices) research project was funded by the European Commission in the Seventh Framework Program. Its partners include:

  • Leti (Grenoble, France): A leading European center in the field of microelectronics, microtechnology and nanotechnology R&D, Leti is one of the three institutes of the Technological Research Division at CEA, the French Alternative Energies and Atomic Energy Commission. Leti’s activities span basic and applied research up to pilot industrial lines. www.leti-cea.com/cea-tech/leti/english
  • Fraunhofer IAF (Freiburg, Germany): Fraunhofer IAF, one of the leading research facilities worldwide in the field of III-V semiconductors, develops electronic and optical devices based on modern micro- and nanostructures. Fraunhofer IAF’s technologies find applications in areas such as security, energy, communication, health, and mobility. www.iaf.fraunhofer.de/en
  • Centre for Energy Research, Hungarian Academy of Sciences (Budapest, Hungary):  The Institute for Technical Physics and Materials Science, one of the institutes of the Research Centre, conducts interdisciplinary research on complex functional materials and nanometer-scale structures, exploration of physical, chemical, and biological principles, and their exploitation in integrated micro- and nanosystems www.mems.hu, www.energia.mta.hu/en
  • Universität Leipzig (Leipzig, Germany): Germany’s second-oldest university with continuous teaching, established in 1409, hosts about 30,000 students in liberal arts, medicine and natural sciences. One of its scientific profiles is “Complex Matter”, and contributions to PIEZOMAT are in the field of nanostructures and wide gap materials. www.zv.uni-leipzig.de/en/
  • Kaunas University of Technology (Kaunas, Lithuania): One of the largest technical universities in the Baltic States, focusing its R&D activities on novel materials, smart devices, advanced measurement techniques and micro/nano-technologies. The Institute of Mechatronics specializes on multi-physics simulation and dynamic characterization of macro/micro-scale transducers with well-established expertise in the field of piezoelectric devices. http://en.ktu.lt/
  • SPECIFIC POLYMERS (Castries, France): SME with twelve employees and an annual turnover of about 1M€, SPECIFIC POLYMERS acts as an R&D service provider and scale-up producer in the field of functional polymers with high specificity (>1000 polymers in catalogue; >500 customers; >50 countries). www.specificpolymers.fr/
  • Tyndall National Institute (Cork, Ireland): Tyndall National Institute is one of Europe’s leading research centres in Information and Communications Technology (ICT) research and development and the largest facility of its type in Ireland. The Institute employs over 460 researchers, engineers and support staff, with a full-time graduate cohort of 135 students. With a network of 200 industry partners and customers worldwide, Tyndall generates around €30M income each year, 85% from competitively won contracts nationally and internationally. Tyndall is a globally leading Institute in its four core research areas of Photonics, Microsystems, Micro/Nanoelectronics and Theory, Modeling and Design. www.tyndall.ie/
  • OT-Morpho (Paris, France): OT-Morpho is a world leader in digital security & identification technologies with the ambition to empower citizens and consumers alike to interact, pay, connect, commute, travel and even vote in ways that are now possible in a connected world. As our physical and digital, civil and commercial lifestyles converge, OT-Morpho stands precisely at that crossroads to leverage the best in security and identity technologies and offer customized solutions to a wide range of international clients from key industries, including Financial services, Telecom, Identity, Security and IoT. With close to €3bn in revenues and more than 14,000 employees, OT-Morpho is the result of the merger between OT (Oberthur Technologies) and Safran Identity & Security (Morpho) completed in 31 May 2017. Temporarily designated by the name “OT-Morpho”, the new company will unveil its new name in September 2017. For more information, visit www.morpho.com and www.oberthur.com

I have tended to take fingerprint technology for granted but last fall (2016) I stumbled on a report suggesting that forensic sciences, including fingerprinting, was perhaps not as conclusive as one might expect after watching fictional police procedural television programmes. My Sept. 23, 2016 posting features the US President’s Council of Advisors on Science and Technology (PCAST) released a report (‘Forensic Science in Criminal Courts: Ensuring Scientific Validity of Feature-Comparison Methods‘ 174 pp PDF).

Graphene and silly putty combined to create ultra sensitive sensors

Leave a reply

One of my favourite kinds of science story is the one where scientists turn to a children’s toy for their research. In this case, it’s silly putty. Before launching into the science part of this story, here’s more about silly putty from its Wikipedia entry (Note: A ll links have been removed),

During World War II, Japan invaded rubber-producing countries as they expanded their sphere of influence in the Pacific Rim. Rubber was vital for the production of rafts, tires, vehicle and aircraft parts, gas masks, and boots. In the U.S., all rubber products were rationed; citizens were encouraged to make their rubber products last until the end of the war and to donate spare tires, boots, and coats. Meanwhile, the government funded research into synthetic rubber compounds to attempt to solve this shortage.[10]

Credit for the invention of Silly Putty is disputed[11] and has been attributed variously to Earl Warrick,[12] of the then newly formed Dow Corning; Harvey Chin; and James Wright, a Scottish-born inventor working for General Electric in New Haven, Connecticut.[13] Throughout his life, Warrick insisted that he and his colleague, Rob Roy McGregor, received the patent for Silly Putty before Wright did; but Crayola’s history of Silly Putty states that Wright first invented it in 1943.[10][14][15] Both researchers independently discovered that reacting boric acid with silicone oil would produce a gooey, bouncy material with several unique properties. The non-toxic putty would bounce when dropped, could stretch farther than regular rubber, would not go moldy, and had a very high melting temperature. However, the substance did not have all the properties needed to replace rubber.[1]

In 1949 toy store owner Ruth Fallgatter came across the putty. She contacted marketing consultant Peter C.L. Hodgson (1912-1976).[16] The two decided to market the bouncing putty by selling it in a clear case. Although it sold well, Fallgatter did not pursue it further. However, Hodgson saw its potential.[1][3]

Already US$12,000 in debt, Hodgson borrowed US$147 to buy a batch of the putty to pack 1 oz (28 g) portions into plastic eggs for US$1, calling it Silly Putty. Initially, sales were poor, but after a New Yorker article mentioned it, Hodgson sold over 250,000 eggs of silly putty in three days.[3] However, Hodgson was almost put out of business in 1951 by the Korean War. Silicone, the main ingredient in silly putty, was put on ration, harming his business. A year later the restriction on silicone was lifted and the production of Silly Putty resumed.[17][9] Initially, it was primarily targeted towards adults. However, by 1955 the majority of its customers were aged 6 to 12. In 1957, Hodgson produced the first televised commercial for Silly Putty, which aired during the Howdy Doody Show.[18]

In 1961 Silly Putty went worldwide, becoming a hit in the Soviet Union and Europe. In 1968 it was taken into lunar orbit by the Apollo 8 astronauts.[17]

Peter Hodgson died in 1976. A year later, Binney & Smith, the makers of Crayola products, acquired the rights to Silly Putty. As of 2005, annual Silly Putty sales exceeded six million eggs.[19]

Silly Putty was inducted into the National Toy Hall of Fame on May 28, 2001. [20]

I had no idea silly putty had its origins in World War II era research. At any rate, it’s made its way back to the research lab to be united with graphene according to a Dec. 8, 2016 news item  on Nanowerk,

Researchers in AMBER, the Science Foundation Ireland-funded materials science research centre, hosted in Trinity College Dublin, have used graphene to make the novelty children’s material silly putty® (polysilicone) conduct electricity, creating extremely sensitive sensors. This world first research, led by Professor Jonathan Coleman from TCD and in collaboration with Prof Robert Young of the University of Manchester, potentially offers exciting possibilities for applications in new, inexpensive devices and diagnostics in medicine and other sectors.

A Dec. 9, 2016 Trinity College Dublin press release (also on EurekAlert), which originated the news item, describes their ‘G-putty’ in more detail,

Prof Coleman, Investigator in AMBER and Trinity’s School of Physics along with postdoctoral researcher Conor Boland, discovered that the electrical resistance of putty infused with graphene (“G-putty”) was extremely sensitive to the slightest deformation or impact. They mounted the G-putty onto the chest and neck of human subjects and used it to measure breathing, pulse and even blood pressure. It showed unprecedented sensitivity as a sensor for strain and pressure, hundreds of times more sensitive than normal sensors. The G-putty also works as a very sensitive impact sensor, able to detect the footsteps of small spiders. It is believed that this material will find applications in a range of medical devices.

Prof Coleman said, “What we are excited about is the unexpected behaviour we found when we added graphene to the polymer, a cross-linked polysilicone. This material as well known as the children’s toy silly putty. It is different from familiar materials in that it flows like a viscous liquid when deformed slowly but bounces like an elastic solid when thrown against a surface. When we added the graphene to the silly putty, it caused it to conduct electricity, but in a very unusual way. The electrical resistance of the G-putty was very sensitive to deformation with the resistance increasing sharply on even the slightest strain or impact. Unusually, the resistance slowly returned close to its original value as the putty self-healed over time.”

He continued, “While a common application has been to add graphene to plastics in order to improve the electrical, mechanical, thermal or barrier properties, the resultant composites have generally performed as expected without any great surprises. The behaviour we found with G-putty has not been found in any other composite material. This unique discovery will open up major possibilities in sensor manufacturing worldwide.”

Dexter Johnson in a Dec. 14, 2016 posting on his Nanoclast blog (on the IEEE [Institute of Electrical and Electronics Engineers]) puts this research into context,

For all the talk and research that has gone into exploiting graphene’s pliant properties for use in wearable and flexible electronics, most of the polymer composites it has been mixed with to date have been on the hard and inflexible side.

It took a team of researchers in Ireland to combine graphene with the children’s toy Silly Putty to set the nanomaterial community ablaze with excitement. The combination makes a new composite that promises to make a super-sensitive strain sensor with potential medical diagnostic applications.

…

“Ablaze with excitement,” eh? As Dexter rarely slips into hyperbole, this must be a big deal.

The researchers have made this video available,

For the very interested, here’s a link to and a citation for the paper,

Sensitive electromechanical sensors using viscoelastic graphene-polymer nanocomposites by Conor S. Boland, Umar Khan, Gavin Ryan, Sebastian Barwich, Romina Charifou, Andrew Harvey, Claudia Backes, Zheling Li, Mauro S. Ferreira, Matthias E. Möbius, Robert J. Young, Jonathan N. Coleman. Science  09 Dec 2016: Vol. 354, Issue 6317, pp. 1257-1260 DOI: 10.1126/science.aag2879

This paper is behind a paywall.

Epic Scottish poetry and social network science

Leave a reply

It’s been a while since I’ve run a social network story here and this research into a 250-year controversy piqued my interest anew. From an Oct. 20, 2016 Coventry University (UK) press release (also on EurekAlert) Note: A link has been removed,

The social networks behind one of the most famous literary controversies of all time have been uncovered using modern networks science.

Since James Macpherson published what he claimed were translations of ancient Scottish Gaelic poetry by a third-century bard named Ossian, scholars have questioned the authenticity of the works and whether they were misappropriated from Irish mythology or, as heralded at the time, authored by a Scottish equivalent to Homer.

Now, in a joint study by Coventry University, the National University of Ireland, Galway and the University of Oxford, published today in the journal Advances in Complex Systems, researchers have revealed the structures of the social networks underlying the Ossian’s works and their similarities to Irish mythology.

The researchers mapped the characters at the heart of the works and the relationships between them to compare the social networks found in the Scottish epics with classical Greek literature and Irish mythology.

The study revealed that the networks in the Scottish poems bore no resemblance to epics by Homer, but strongly resembled those in mythological stories from Ireland.

The Ossianic poems are considered to be some of the most important literary works ever to have emerged from Britain or Ireland, given their influence over the Romantic period in literature and the arts. Figures from Brahms to Wordsworth reacted enthusiastically; Napoleon took a copy on his military campaigns and US President Thomas Jefferson believed that Ossian was the greatest poet to have ever existed.

The poems launched the romantic portrayal of the Scottish Highlands which persists, in many forms, to the present day and inspired Romantic nationalism all across Europe.

Professor Ralph Kenna, a statistical physicist based at Coventry University, said:

By working together, it shows how science can open up new avenues of research in the humanities. The opposite also applies, as social structures discovered in Ossian inspire new questions in mathematics.”

Dr Justin Tonra, a digital humanities expert from the National University of Ireland, Galway said:

From a humanities point of view, while it cannot fully resolve the debate about Ossian, this scientific analysis does reveal an insightful statistical picture: close similarity to the Irish texts which Macpherson explicitly rejected, and distance from the Greek sources which he sought to emulate.”

A statistical physicist, eh? I find that specialty quite an unexpected addition to the team stretching my ideas about social networks in new directions.

Getting back to the research, the scientists have supplied this image to illustrate their work,

Caption: In the social network underlying the Ossianic epic, the 325 nodes represent characters appearing in the narratives and the 748 links represent interactions between them. Credit: Coventry University

Caption: In the social network underlying the Ossianic epic, the 325 nodes represent characters appearing in the narratives and the 748 links represent interactions between them. Credit: Coventry University

Here’s a link to and a citation for the paper,

A networks-science investigation into the epic poems of Ossian by Joseph Yose, Ralph Kenna, Pádraig MacCarron, Thierry Platini, Justin Tonra.  Complex Syst. DOI: http://dx.doi.org/10.1142/S0219525916500089 Published: 21 October 2016

This paper is behind a paywall.

Bacteria and an anti-superbug coating from Ireland’s Sligo Institute of Technology

Leave a reply

Unlike today’s (April 28, 2016) earlier piece about dealing with bacteria, the focus for this research is on superbugs and not the bacteria which form biofilm on medical implants and such. An April 21, 2016 news item on RTE News makes the announcement about a new means of dealing with superbugs,

A discovery by a team of scientists in Ireland could stem the spread of deadly superbugs predicted to kill millions of people worldwide over the coming decades.

The research has found an agent that can be baked into everyday items like smart-phones and door handles to combat the likes of MRSA and E. coli.

The nanotechnology has a 99.9 % kill rate of potentially lethal and drug-resistant bacteria, they say.

Lead scientist Professor Suresh C. Pillai, of Sligo Institute of Technology’s Nanotechnology Research Group, says the discovery is the culmination of 12 years work.

“This is a game changer,” he said.

“This breakthrough will change the whole fight against superbugs. It can effectively control the spread of bacteria.”

An April 21, 2016 Sligo Institute of Technology press release provides some context for the work and a few details about the coating,

News of the discovery comes just days after UK Chancellor of the Exchequer George Osborne warned that superbugs could become deadlier than cancer and are on course to kill 10 million people globally by 2050.

Speaking at the International Monetary Fund (IMF) in Washington, Mr Osborne warned that the problem would slash global GDP by around €100 trillion if it was not tackled.

Using nanotechnology, the discovery is an effective and practical antimicrobial solution — an agent that kills microorganisms or inhibits their growth — that can be used to protect a range of everyday items.

Items include anything made from glass, metallics and ceramics including computer or tablet screens, smartphones, ATMs, door handles, TVs, handrails, lifts, urinals, toilet seats, fridges, microwaves and ceramic floor or wall tiles.

It will be of particular use in hospitals and medical facilities which are losing the battle against the spread of killer superbugs.

Other common uses would include in swimming pools and public buildings, on glass in public buses and trains, sneeze guards protecting food in delis and restaurants as well as in clean rooms in the medical sector.

…

“It’s absolutely wonderful to finally be at this stage. This breakthrough will change the whole fight against superbugs. It can effectvely control the spread of bacteria,” said Prof. Pillai.

He continued: “Every single person has a sea of bacteria on their hands. The mobile phone is the most contaminated personal item that we can have. Bacteria grows on the phone and can live there for up to five months. As it is contaminated with proteins from saliva and from the hand, It’s fertile land for bacteria and has been shown to carry 30 times more bacteria than a toilet seat.”

The research started at Dublin Institute of Technology (DIT)’s CREST and involves scientists now based at IT Sligo, Dublin City University (DCU) and the University of Surrey. Major researchers included Dr Joanna Carroll and Dr Nigel S. Leyland.

It has been funded for the past eight years by John Browne, founder and CEO of Kastus Technologies Ltd, who is bringing the product to a global market. He was also supported by significant investment from Enterprise Ireland.

As there is nothing that will effectively kill antibiotic-resistant superbugs completely from the surface of items, scientists have been searching for a way to prevent the spread.

This has been in the form of building or ‘baking’ antimicrobial surfaces into products during the manufacturing process.

However, until now, all these materials were toxic or needed UV light in order to make them work. This meant they were not practical for indoor use and had limited commercial application.

“The challenge was the preparation of a solution that was activated by indoor light rather than UV light and we have now done that,” said Prof Pillai.

The new water-based solution can be sprayed onto any glass, ceramic or metallic surface during the production process, rendering the surface 99.9 per cent resistant to superbugs like MRSA, E. coli and other fungi. [emphasis mine]

The solution is sprayed on the product — such as a smartphone glass surface — and then ‘baked’ into it, forming a super-hard surface. The coating is transparent, permanent and scratch resistant and actually forms a harder surface than the original glass or ceramic material.

The team first developed the revolutionary material to work on ceramics and has spent the last five years adapting the formula – which is non-toxic and has no harmful bi-products ‑- to make it work on glass and metallic surfaces.

Research is now underway by the group on how to adapt the solution for use in plastics and paint, allowing even wider use of the protective material.

Prof Pillai, Kastus and the team have obtained a US and a UK patent on the unique process with a number of global patent applications pending. It is rare for such an academic scientific discovery to have such commercial viability.

“I was sold on this from the first moment I heard about it. It’s been a long road to here but it was such a compelling story that it was hard to walk away from so I had to see it through to the end,” said John Browne, Kastus CEO.

He continued: “This is a game changer. The uniqueness of antimicrobia surface treatment means that the applications for it in the real world are endless. The multinational glass manufacturers we are in negotiations with to sell the product to have been searching for years to come up with such a solution but have failed.”

If the coating kills 99.9%, doesn’t that mean 0.1% are immune? If that’s the case, won’t they reproduce and eventually establish themselves as a new kind of superbug?

Here’s a link to and a citation for the paper,

Highly Efficient F, Cu doped TiO2 anti-bacterial visible light active photocatalytic coatings to combat hospital-acquired infections by Nigel S. Leyland, Joanna Podporska-Carroll, John Browne, Steven J. Hinder, Brid Quilty, & Suresh C. Pillai. Scientific Reports 6, Article number: 24770 (2016) doi:10.1038/srep24770 Published online: 21 April 2016

This paper is open access.

Graphene Flagship high points

Leave a reply

The European Union’s Graphene Flagship project has provided a series of highlights in place of an overview for the project’s ramp-up phase (in 2013 the Graphene Flagship was announced as one of two winners of a science competition, the other winner was the Human Brain Project, with two prizes of 1B Euros for each project). Here are the highlights from the April 19, 2016 Graphene Flagship press release,

Graphene and Neurons – the Best of Friends

Flagship researchers have shown that it is possible to interface untreated graphene with neuron cells whilst maintaining the integrity of these vital cells [1]. This result is a significant first step towards using graphene to produce better deep brain implants which can both harness and control the brain.

Graphene and Neurons
 

This paper emerged from the Graphene Flagship Work Package Health and Environment. Prof. Prato, the WP leader from the University of Trieste in Italy, commented that “We are currently involved in frontline research in graphene technology towards biomedical applications, exploring the interactions between graphene nano- and micro-sheets with the sophisticated signalling machinery of nerve cells. Our work is a first step in that direction.”

[1] Fabbro A., et al., Graphene-Based Interfaces do not Alter Target Nerve Cells. ACS Nano, 10 (1), 615 (2016).

Pressure Sensing with Graphene: Quite a Squeeze

The Graphene Flagship developed a small, robust, highly efficient squeeze film pressure sensor [2]. Pressure sensors are present in most mobile handsets and by replacing current sensor membranes with a graphene membrane they allow the sensor to decrease in size and significantly increase its responsiveness and lifetime.

Discussing this work which emerged from the Graphene Flagship Work Package Sensors is the paper’s lead author, Robin Dolleman from the Technical University of Delft in The Netherlands “After spending a year modelling various systems the idea of the squeeze-film pressure sensor was formed. Funding from the Graphene Flagship provided the opportunity to perform the experiments and we obtained very good results. We built a squeeze-film pressure sensor from 31 layers of graphene, which showed a 45 times higher response than silicon based devices, while reducing the area of the device by a factor of 25. Currently, our work is focused on obtaining similar results on monolayer graphene.”

 

[2] Dolleman R. J. et al., Graphene Squeeze-Film Pressure Sensors. Nano Lett., 16, 568 (2016)

Frictionless Graphene


Image caption: A graphene nanoribbon was anchored at the tip of a atomic force microscope and dragged over a gold surface. The observed friction force was extremely low.

Image caption: A graphene nanoribbon was anchored at the tip of a atomic force microscope and dragged over a gold surface. The observed friction force was extremely low.

Research done within the Graphene Flagship, has observed the onset of superlubricity in graphene nanoribbons sliding on a surface, unravelling the role played by ribbon size and elasticity [3]. This important finding opens up the development potential of nanographene frictionless coatings. This research lead by the Graphene Flagship Work Package Nanocomposites also involved researchers from Work Package Materials and Work Package Health and the Environment, a shining example of the inter-disciplinary, cross-collaborative approach to research undertaken within the Graphene Flagship. Discussing this further is the Work Package Nanocomposites Leader, Dr Vincenzo Palermo from CNR National Research Council, Italy “Strengthening the collaboration and interactions with other Flagship Work Packages created added value through a strong exchange of materials, samples and information”.

[3] Kawai S., et al., Superlubricity of graphene nanoribbons on gold surfaces. Science. 351, 6276, 957 (2016) 

​Graphene Paddles Forward

Work undertaken within the Graphene Flagship saw Spanish automotive interiors specialist, and Flagship partner, Grupo Antolin SA work in collaboration with Roman Kayaks to develop an innovative kayak that incorporates graphene into its thermoset polymeric matrices. The use of graphene and related materials results in a significant increase in both impact strength and stiffness, improving the resistance to breakage in critical areas of the boat. Pushing the graphene canoe well beyond the prototype demonstration bubble, Roman Kayaks chose to use the K-1 kayak in the Canoe Marathon World Championships held in September in Gyor, Hungary where the Graphene Canoe was really put through its paces.

Talking further about this collaboration from the Graphene Flagship Work Package Production is the WP leader, Dr Ken Teo from Aixtron Ltd., UK “In the Graphene Flagship project, Work Package Production works as a technology enabler for real-world applications. Here we show the worlds first K-1 kayak (5.2 meters long), using graphene related materials developed by Grupo Antolin. We are very happy to see that graphene is creating value beyond traditional industries.” 

​Graphene Production – a Kitchen Sink Approach

Researchers from the Graphene Flagship have devised a way of producing large quantities of graphene by separating graphite flakes in liquids with a rotating tool that works in much the same way as a kitchen blender [4]. This paves the way to mass production of high quality graphene at a low cost.

The method was produced within the Graphene Flagship Work Package Production and is talked about further here by the WP deputy leader, Prof. Jonathan Coleman from Trinity College Dublin, Ireland “This technique produced graphene at higher rates than most other methods, and produced sheets of 2D materials that will be useful in a range of applications, from printed electronics to energy generation.” 

[4] Paton K.R., et al., Scalable production of large quantities of defect-free few-layer graphene by shear exfoliation in liquids. Nat. Mater. 13, 624 (2014).

Flexible Displays – Rolled Up in your Pocket

Working with researchers from the Graphene Flagship the Flagship partner, FlexEnable, demonstrated the world’s first flexible display with graphene incorporated into its pixel backplane. Combined with an electrophoretic imaging film, the result is a low-power, durable display suitable for use in many and varied environments.

Emerging from the Graphene Flagship Work Package Flexible Electronics this illustrates the power of collaboration.  Talking about this is the WP leader Dr Henrik Sandberg from the VTT Technical Research Centre of Finland Ltd., Finland “Here we show the power of collaboration. To deliver these flexible demonstrators and prototypes we have seen materials experts working together with components manufacturers and system integrators. These devices will have a potential impact in several emerging fields such as wearables and the Internet of Things.”

​Fibre-Optics Data Boost from Graphene

A team of researches from the Graphene Flagship have demonstrated high-performance photo detectors for infrared fibre-optic communication systems based on wafer-scale graphene [5]. This can increase the amount of information transferred whilst at the same time make the devises smaller and more cost effective.

Discussing this work which emerged from the Graphene Flagship Work Package Optoelectronics is the paper’s lead author, Daniel Schall from AMO, Germany “Graphene has outstanding properties when it comes to the mobility of its electric charge carriers, and this can increase the speed at which electronic devices operate.”

[5] Schall D., et al., 50 GBit/s Photodetectors Based on Wafer-Scale Graphene for Integrated Silicon Photonic Communication Systems. ACS Photonics. 1 (9), 781 (2014)

​Rechargeable Batteries with Graphene

A number of different research groups within the Graphene Flagship are working on rechargeable batteries. One group has developed a graphene-based rechargeable battery of the lithium-ion type used in portable electronic devices [6]. Graphene is incorporated into the battery anode in the form of a spreadable ink containing a suspension of graphene nanoflakes giving an increased energy efficiency of 20%. A second group of researchers have demonstrated a lithium-oxygen battery with high energy density, efficiency and stability [7]. They produced a device with over 90% efficiency that may be recharged more than 2,000 times. Their lithium-oxygen cell features a porous, ‘fluffy’ electrode made from graphene together with additives that alter the chemical reactions at work in the battery.

Graphene Flagship researchers show how the 2D material graphene can improve the energy capacity, efficiency and stability of lithium-oxygen batteries.

Both devices were developed in different groups within the Graphene Flagship Work Package Energy and speaking of the technology further is Prof. Clare Grey from Cambridge University, UK “What we’ve achieved is a significant advance for this technology, and suggests whole new areas for research – we haven’t solved all the problems inherent to this chemistry, but our results do show routes forward towards a practical device”.

[6] Liu T., et al. Cycling Li-O2 batteries via LiOH formation and decomposition. Science. 350, 6260, 530 (2015)

[7] Hassoun J., et al., An Advanced Lithium-Ion Battery Based on a Graphene Anode and a Lithium Iron Phosphate Cathode. Nano Lett., 14 (8), 4901 (2014)

​Graphene – What and Why?

Graphene is a two-dimensional material formed by a single atom-thick layer of carbon, with the carbon atoms arranged in a honeycomb-like lattice. This transparent, flexible material has a number of unique properties. For example, it is 100 times stronger than steel, and conducts electricity and heat with great efficiency.

A number of practical applications for graphene are currently being developed. These include flexible and wearable electronics and antennas, sensors, optoelectronics and data communication systems, medical and bioengineering technologies, filtration, super-strong composites, photovoltaics and energy storage.

Graphene and Beyond

The Graphene Flagship also covers other layered materials, as well as hybrids formed by combining graphene with these complementary materials, or with other materials and structures, ranging from polymers, to metals, cement, and traditional semiconductors such as silicon. Graphene is just the first of thousands of possible single layer materials. The Flagship plans to accelerate their journey from laboratory to factory floor.

Especially exciting is the possibility of stacking monolayers of different elements to create materials not found in nature, with properties tailored for specific applications. Such composite layered materials could be combined with other nanomaterials, such as metal nanoparticles, in order to further enhance their properties and uses.​

Graphene – the Fruit of European Scientific Excellence

Europe, North America and Asia are all active centres of graphene R&D, but Europe has special claim to be at the centre of this activity. The ground-breaking experiments on graphene recognised in the award of the 2010 Nobel Prize in Physics were conducted by European physicists, Andre Geim and Konstantin Novoselov, both at Manchester University. Since then, graphene research in Europe has continued apace, with major public funding for specialist centres, and the stimulation of academic-industrial partnerships devoted to graphene and related materials. It is European scientists and engineers who as part of the Graphene Flagship are closely coordinating research efforts, and accelerating the transfer of layered materials from the laboratory to factory floor.

For anyone who would like links to the published papers, you can check out an April 20, 2016 news item featuring the Graphene Flagship highlights on Nanowerk.

When based on plastic materials, contemporary art can degrade quickly

Leave a reply

There’s an intriguing April 1, 2016 article by Josh Fischman for Scientific American about a problem with artworks from the 20th century and later—plastic-based materials (Note: A link has been removed),

Conservators at museums and art galleries have a big worry. They believe there is a good chance the art they showcase now will not be fit to be seen in one hundred years, according to researchers in a project  called Nanorestart. Why? After 1940, artists began using plastic-based material that was a far cry from the oil-based paints used by classical painters. Plastic is also far more fragile, it turns out. Its chemical bonds readily break. And they cannot be restored using techniques historically relied upon by conservators.

So art conservation scientists have turned to nanotechnology for help.

Sadly, there isn’t any detail in Fischman’s article (*ETA June 17, 2016 article [for Fast Company] by Charlie Sorrel, which features some good pictures, a succinct summary of Fischman’s article and a literary reference [Kurt Vonnegut’s Bluebeard]I*) about how nanotechnology is playing or might play a role in this conservation effort. Further investigation into the two projects (NanoRestART and POPART) mentioned by Fischman didn’t provide much more detail about NanoRestART’s science aspect but POPART does provide some details.

NanoRestART

It’s probably too soon (this project isn’t even a year-old) to be getting much in the way of the nanoscience details but NanoRestART has big plans according to its website homepage,

…

The conservation of this diverse cultural heritage requires advanced solutions at the cutting edge of modern chemistry and material science in an entirely new scientific framework that will be developed within NANORESTART project.

The NANORESTART project will focus on the synthesis of novel poly-functional nanomaterials and on the development of highly innovative restoration techniques to address the conservation of a wide variety of materials mainly used by modern and contemporary artists.

In NANORESTART, enterprises and academic centers of excellence in the field of synthesis and characterization of nano- and advanced materials have joined forces with complementary conservation institutions and freelance restorers. This multidisciplinary approach will cover the development of different materials in response to real conservation needs, the testing of such materials, the assessment of their environmental impact, and their industrial scalability.

NanoRestART’s (NANOmaterials for the REStoration of works of ART) project page spells out their goals in the order in which they are being approached,

…

The ground-breaking nature of our research can be more easily outlined by focussing on specific issues. The main conservation challenges that will be addressed in the project are:

 

Conservation challenge 1 – Cleaning of contemporary painted and plastic surfaces (CC1)

Conservation challenge 2 – Stabilization of canvases and painted layers in contemporary art (CC2)

Conservation challenge 3 – Removal of unwanted modern materials (CC3)

Conservation challenge 4 – Enhanced protection of artworks in museums and outdoors (CC4)

The European Commission provides more information about the project on its CORDIS website’s NanoRestART webpage including the start and end dates for the project and the consortium members,

From 2015-06-01 to 2018-12-01, ongoing project

CHALMERS TEKNISKA HOEGSKOLA AB
Sweden
MIRABILE ANTONIO
France
NATIONALMUSEET
Denmark
CONSIGLIO NAZIONALE DELLE RICERCHE
Italy
UNIVERSITY COLLEGE CORK, NATIONAL UNIVERSITY OF IRELAND, CORK
Ireland
MBN NANOMATERIALIA SPA
Italy
KEMIJSKI INSTITUT
Slovenia
CHEVALIER AURELIA
France
UNIVERSIDADE FEDERAL DO RIO GRANDE DO SUL
Brazil
UNIVERSITA CA’ FOSCARI VENEZIA
Italy
AKZO NOBEL PULP AND PERFORMANCE CHEMICALS AB
Sweden
COMMISSARIAT A L ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
France
ARKEMA FRANCE SA
France
UNIVERSIDAD DE SANTIAGO DE COMPOSTELA
Spain
UNIVERSITY COLLEGE LONDON
United Kingdom
ZFB ZENTRUM FUR BUCHERHALTUNG GMBH
Germany
UNIVERSITAT DE BARCELONA
Spain
THE BOARD OF TRUSTEES OF THE TATE GALLERY
United Kingdom
ASSOCIAZIONE ITALIANA PER LA RICERCA INDUSTRIALE – AIRI
Italy
THE ART INSTITUTE OF CHICAGO
United States
MINISTERIO DE EDUCACION, CULTURA Y DEPORTE
Spain
STICHTING HET RIJKSMUSEUM
Netherlands
UNIVERSITEIT VAN AMSTERDAM
Netherlands
UNIVERSIDADE FEDERAL DO RIO DE JANEIRO
Brazil
ACCADEMIA DI BELLE ARTI DI BRERA
Italy

It was a bit surprising to see Brazil and the US as participants but The Art Institute of Chicago has done nanotechnology-enabled conservation in the past as per my March 24, 2014 posting about a Renoir painting. I’m not familiar with the Brazilian organization.

POPART

POPART (Preservation of Plastic Artefacts in museum collections) mentioned by Fischman was a European Commission project which ran from 2008 – 2012. Reports can be found on the CORDIS Popart webpage. The final report has some interesting bits (Note: I have added subheads in the [] square brackets),

To achieve a valid comparison of the various invasive and non-invasive techniques proposed for the identification and characterisation of plastics, a sample collection (SamCo) of plastics artefacts of about 100 standard and reference plastic objects was gathered. SamCo was made up of two kinds of reference materials: standards and objects. Each standard represents the reference material of a ‘pure’ plastic; while each object represents the reference of the same plastic as in the standards, but compounded with pigments, dyestuffs, fillers, anti oxidants, plasticizers etc.  Three partners ICN [Instituut Collectie Nederland], V&A [Victoria and Albert Museum] and Natmus [National Museet] collected different natural and synthetic plastics from the ICN reference collections of plastic objects, from flea markets, antique shops and from private collections and from their own collection to contribute to SamCo, the sample collection for identification by POPART partners. …

…

As a successive step, the collections of the following museums were surveyed:

-Victoria & Albert Museum (V&A), London, U.K.
-Stedelijk Museum, Amsterdam, The Netherlands
-Musée d’Art Moderne et d’Art Contemporaine (MAMAC) Nice, France
-Musée d’Art moderne, St. Etienne, France
-Musée Galliera, Paris, France

At the V&A approximately 200 objects were surveyed. Good or fair conservation conditions were found for about 85% of the objects, whereas the remaining 15% was in poor or even in unacceptable (3%) conditions. In particular, crazing and delamination of polyurethane faux leather and surface stickiness and darkening of plasticized PVC were observed. The situation at the Stedelijk Museum in Amsterdam was particularly favourable because a previous survey had been done in 1995 so that it was possible to make a comparison with the Popart survey in 2010. A total number of 40 objects, which comprised plastics early dating from the 1930’s until the newer plastics from the 1980’s, were considered and their actual conservation state compared with the 1995 records. Of the objects surveyed in 2010, it can be concluded that 21 remained in the same condition. 13 objects containing PA, PUR, PVC, PP or natural rubber changed due to chemical and physical degradation while works of art containing either PMMA or PS changed due to mechanical damages and incorrect artist’s technique (inappropriate adhesive) into a lesser condition. 6 works of art (containing either PA or PMMA or both) changed into a better condition due to restoration or replacements.  More than 230 objects have been examined in the 3 museums in France. A particular effort was devoted to the identification of the constituting plastics materials. Surveys have been undertaken without any sophisticated equipment, in order to work in museums everyday conditions. Plastics hidden by other materials or by paint layers were not or hardly accessible, it is why the final count of some plastics may be under estimated in the final results. Another outcome is that plastic identification has been made at a general level only, by trying to identify the polymer family each plastic belongs to. Lastly, evidence of chemical degradation processes that do not cause visible or perceptible damage have not been detected and could not be taken in account in the final results.

… The most damaged artefacts resulted constituted by cellulose acetate, cellulose nitrate and PVC.

[Polly (the doll)]

One of the main issues that is of interest for conservators and curators is to assess which kinds of plastics are most vulnerable to deterioration and to what extent they can deteriorate under the environmental conditions normally encountered in museums. Although one might expect that real time deterioration could be ascertained by a careful investigation of museum objects on display or in storage, real objects or artworks may not sampled due to ethical considerations. Therefore, reference objects were prepared by Natmus in the form of a doll (Polly) for simultaneous exposures in different environmental conditions. The doll comprised of 11 different plastics representative of types typically found in modern museum collections. The 16 identical dolls realized were exposed in different places, not only in normal exhibit conditions, but also in some selected extreme conditions to ascertain possible acceleration of the deterioration process. In most cases the environmental parameters were also measured. The dolls were periodically evaluated by visual inspection and in selected cases by instrumental analyses. 

…

In conclusion the experimental campaign carried out with Polly dolls can be viewed as a pilot study aimed at tackling the practical issues related to the monitoring of real three dimensional plastic artworks and the surrounding environment.

The overall exposure period (one year and half) was sufficient to observe initial changes in the more susceptible polymers, such as polyurethane ethers and esters, and polyamide, with detectable chromatic changes and surface effects. Conversely the other polymers were shown to be stable in the same conditions over this time period.

…

[Polly as an awareness raising tool]

Last but not least, the educational and communication benefits of an object like Polly facilitated the dissemination of the Popart Project to the public, and increased the awareness of issues associated with plastics in museum collections.

…

[Cleaning issues]

Mechanical cleaning has long been perceived as the least damaging technique to remove soiling from plastics. The results obtained from POPART suggest that the risks of introducing scratches or residues by mechanical cleaning are measurable. Some plastics were clearly more sensitive to mechanical damage than others. From the model plastics evaluated, HIPS was the most sensitive followed by HDPE, PVC, PMMA and CA. Scratches could not be measured on XPS due to its inhomogeneous surfaces. Plasticised PVC scratched easily, but appeared to repair itself because plasticiser migrated to surfaces and filled scratches.

Photo micrographs revealed that although all 22 cleaning materials evaluated in POPART scratched test plastics, some scratches were sufficiently shallow to be invisible to the naked eye. Duzzit and Scotch Brite sponges as well as all paper based products caused more scratching of surfaces than brushes and cloths. Some cleaning materials, notably Akapad yellow and white sponges, compressed air, latex and synthetic rubber sponges and goat hair brushes left residues on surfaces. These residues were only visible on glass-clear, transparent test plastics such as PMMA. HDPE and HIPS surfaces both had matte and roughened appearances after cleaning with dry-ice. XPS was completely destroyed by the treatment. No visible changes were present on PMMA and PVC.

Of the cleaning methods evaluated, only canned air, natural and synthetic feather duster left surfaces unchanged. Natural and synthetic feather duster, microfiber-, spectacle – and cotton cloths, cotton bud, sable hair brush and leather chamois showed good results when applied to clean model plastics.

Most mechanical cleaning materials induced static electricity after cleaning, causing immediate attraction of dust. It was also noticed that generally when adding an aqueous cleaning agent to a cleaning material, the area scratched was reduced. This implied that cleaning agents also functioned as lubricants. A similar effect was exhibited by white spirit and isopropanol.
Based on cleaning vectors, Judith Hofenk de Graaff detergent, distilled water and Dehypon LS45 were the least damaging cleaning agents for all model plastics evaluated. None of the aqueous cleaning agents caused visible changes when used in combination with the least damaging cleaning materials. Sable hair brush, synthetic feather duster and yellow Akapad sponge were unsuitable for applying aqueous cleaning agents. Polyvinyl acetate sponge swelled in contact with solvents and was only suitable for aqueous cleaning processes.

Based on cleaning vectors, white spirit was the least damaging solvent. Acetone and Surfynol 61 were the most damaging for all model plastics and cannot be recommended for cleaning plastics. Surfynol 61 dissolved polyvinyl acetate sponge and left a milky residue on surfaces, which was particularly apparent on clear PMMA surfaces. Surfynol 61 left residues on surfaces on evaporating and acetone evaporated too rapidly to lubricate cleaning materials thereby increasing scratching of surfaces.

Supercritical carbon dioxide induced discolouration and mechanical damage to the model plastics, particularly to XPS, CA and PMMA and should not be used for conservation cleaning of plastics.

…

Potential Impact:
Cultural heritage is recognised as an economical factor, the cost of decay of cultural heritage and the risk associated to some material in collection may be high. It is generally estimated that plastics, developed at great numbers since the 20th century’s interbellum, will not survive that long. This means that fewer generations will have access to lasting plastic art for study, contemplation and enjoyment. On the other hand will it normally be easier to reveal a contemporary object’s technological secrets because of better documentation and easier access to artists’ working methods, ideas and intentions. A first more or less world encompassing recognition of the problems involved with museum objects made wholly or in part of plastics was through the conference ‘Saving the twentieth century” held in Ottawa, Canada in 1991. This was followed later by ‘Modern Art, who cares’ in Amsterdam, The Netherlands in 1997, ‘Mortality Immortality? The Legacy of Modern Art’ in Los Angeles, USA in 1998 and, for example much more recent, ‘Plastics –Looking at the future and learning from the Past’ in London, UK in 2007. A growing professional interest in the care of plastics was clearly reflected in the creation of an ICOM-CC working group dedicated to modern materials in 1996, its name change to Modern Materials and Contemporary Art in 2002, and its growing membership from 60 at inception to over 200 at the 16th triennial conference in Lisbon, Portugal in 2011 and tentatively to over 300 as one of the aims put forward in the 2011-2014 programme of that ICOM-CC working group. …

[Intellectual property]

Another element pertaining to conservation of modern art is the copyright of artists that extends at least 50 years beyond their death. Both, damage, value and copyright may influence the way by which damage is measured through scientific analysis, more specifically through the application of invasive or non invasive techniques. Any selection of those will not only have an influence on the extent of observable damage, but also on the detail of information gathered and necessary to explain damage and to suggest conservation measures.

[How much is deteriorating?]

… it is obvious from surveys carried out in several museums in France, the UK and The Netherlands that from 15 to 35 % of what I would then call an average plastic material based collection is in a poor to unacceptable condition. However, some 75 % would require cleaning,

I hope to find out more about how nanotechnology is expected to be implemented in the conservation and preservation of plastic-based art. The NanoRestART project started in June 2015 and hopefully more information will be disseminated in the next year or so.

While it’s not directly related, there was some work with conservation of daguerreotypes (19th century photographic technique) and nanotechnology mentioned in my Nov. 17, 2015 posting which was a followup to my Jan. 10, 2015 posting about the project and the crisis precipitating it.

*ETA June 30, 2016: Here’s clip from a BBC programme, Science in Action broadcast on June 30, 2016 featuring a chat with some of the scientists involved in the NanoRestArt project (Note: This excerpt is from a longer programme and seemingly starts in the middle of a conversation,)